Разработана методика расчета тепловлагопереноса в специальной защитной обуви пожарного-спасателя, которая позволяет учесть терморегуляционные механизмы в стопе для оценки комфортности обуви, изготовленной из определенных пакетов материалов и эксплуатируемой в широком диапазоне внешних воздействий, как по тепловым и влажностным факторам, так и в зависимости от уровня активности (тяжести выполняемой работы) пожарного-спасателя. Для определения безопасной работы в специальной защитной обуви необходима оценка степени деструкции кожи (степень ожога). The article describes the solution of the problem of non-stationary heat transfer in the «foot – footwear – environment» system for multilayer flat, cylindrical or spherical materials and non-stationary heat transfer from the outer surface of the special protective footwear to firefighter's foot. The well-known biothermal equation and the generalized heat transfer equation are used as the basis for the model of heat and moisture transfer in boot materials, taking into account sweating on the human skin surface. It is possible to get data on the thermal state of the foot under various conditions by solving these equations with appropriate coefficients and boundary conditions: zero heat flow in the center of the foot and convective environmental conditions on the surface of the last layer of porous shoe material. Modeling for three cases of human activity: resting state, walking with a speed of 4.8 km/h, light work (in the office room) under the same environmental conditions was carried out. The obtained results showed that the model of heat and moisture transfer in protective boots, taking into account thermoregulatory processes in the foot, can be used to predict the functionality of the materials for the bottom and top of the boots in terms of the skin burns likelihood. The method for calculating heat and moisture transfer in special protective boots for a firefighter-rescuer has been developed, based on the simulation, which includes: - construction of a geometric image of a model of protective boots; - determination of the firefighter-rescuer operating mode; - selection of material packages for the details of the boot top and bottom. An indication of the thermophysical, structural, geometric characteristics of the materials allows, using the selected climatic conditions and the firefighter-rescuer operating mode, to establish the initial and boundary conditions for solving the basic system of heat and moisture transfer equations. The solution of the system of equations with the boundary and initial conditions makes it possible to assess the comfort of boots, as well as the rate of destruction of the skin under intense thermal effects (the probability of burns of varying degrees). Based on this analysis, further optimization of the boots design can be carried out by choosing different material packages or evaluating the thermal effect under various external influences.