Gaseous Salts Of Oxygen-containing Acids Research Articles

Thermochemical study of gaseous salts of oxygen-containing acids: XXII.1 Lead salts

Reactions of gas-phase synthesis of lead phosphates and tellurates have been studied. Standard enthalpies of formation and atomization of gaseous PbPO2, PbPO3, PbP2O6, PbTeO3, and Pb2TeO4 salts have been determined.

Thermochemical study of gaseous salts of oxygen-containing acids: XXI. Zinc phosphate

A gas–phase reaction involving zinc phosphate was studied by the high-temperature massspectrometry method. Standard enthalpies of formation and atomization of the molecules ZnPO3(gas) were determined.

Thermochemical study of gaseous salts of oxygen-containing acids: XX. Germanium salts

Reactions of the gas-phase synthesis of germanium vanadate, borate, and molybdate have been studied. Standard enthalpies of formation and atomization of gaseous salts GeV2O6, GeB2O4, and SnMo2O7 have been determined.

Thermochemical study of gaseous salts of oxygen-containing acids: XIX. Tin salts

Reactions of the gas-phase synthesis of tin vanadates, borates, and molybdates were studied. Standard enthalpies of formation and atomization of gaseous salts SnV2O6, SnB2O4, Sn2B2O5, SnMoO4, Sn2MoO5, and SnMo2O7 were determined.

Thermochemical study of gaseous salts of oxygen-containing acids: XXVIII. Gallium borates

Reactions of the gas-phase synthesis of gallium borate from oxides and its dimerization were studied. It was found that the molecules Ga2O, B2O3, GaBO2, and (GaBO2)2 are present in the vapor above the Ga2O3-B2O3 system. Enthalpies of formation and atomization of gaseous gallium borates were determined.

Thermochemical study of gaseous salts of oxygen-containing acids: XXVII. Antimonites of alkali metals

Vaporization of sodium, potassium, rubidium, and cesium antimonates was studied. Vapors above the studied antimonates contain dimeric (MSbO2)2 molecules in addition to monomeric antimonites MSbO2. Standard enthalpies of formation of these gaseous molecules were determined.

Thermochemical study of gaseous salts of oxygen-containing acids: XXVI. Iodates of alkali metals

Vaporization of iodates of alkali metals was studied. Vapor above the iodates contains dimeric molecules alongside monomers. Standard enthalpies of formation of the gaseous molecules MIO3 and M(IO3)2 were determined.

Thermochemical study of gaseous salts of oxygen-containing acids: XXV. Magnesium borates

Standard enthalpies of formation and atomization of gaseous magnesium borates MgBO2 and MgB2O4 were determined.

Thermochemical study of gaseous salts of oxygen-containing acids: XXIV. Polymers of alkali metals perrenates

The vaporization of alkali metals perrhenates was studied. Standard enthalpies of formation of the gaseous molecules (MReO4)2 were determined.

Thermochemical study of gaseous salts of oxygen-containing acids: XXIII. Molecules MnB2O4, MnNbO2, MnNbO3 and MnTiO3

Gas-phase equilibria involving manganese borate, niobates, and titanate were studied. Standard enthalpies of formation and atomization of the gaseous molecules MnB2O4, MnNbO2, MnNbO3, and MnTiO3 were determined.

Thermochemical study of gaseous salts of oxygen-containing acids: XXII. Tin molybdates

Gas-phase reactions involving tin molybdates were studied. Standard enthalpies of formation and atomization of gaseous salts SnMoO4 and Sn2MoO5 were determined.

Gaseous salts of oxygen-containing acids: Thermal stability, structure, and thermodynamic properties

Experimental data and results of quantum-chemical calculations on the structure and thermodynamic properties of gaseous salts of oxygen-containing acids were systematized. A criterion of thermal stability of these compounds was offered and regularities in the atomization enthalpies were established.

Thermochemical study of gaseous salts of oxygen-containing acids: XXI. Polymers of lithium, potassium, and cesium phosphates

Gas-phase reactions involving monomers and polymers of lithium, potassium, and cesium phosphates were studied. Standard enthalpies of formation and atomization of (MPO3)2, (MPO3)3, KCs(PO3)2, LiK(PO3)2, and (LiPO3)4 were determined.

Thermochemical study of gaseous salts of oxygen-containing acids: XX. Phosphates of beryllium and beryllates of alkaline-earth metals

Gas-phase reactions involving beryllium phosphates and calcium, strontium, and barium beryllates were studied. The standard enthalpies of gaseous formation and atomization of BePO3, BePO2, CaBeO2, SrBeO2, and BaBeO2 salts were determined.

Thermochemical study of gaseous salts of oxygen-containing acids: XIX. Nickel(II) salts

Thermochemical study of gaseous salts of oxygen-containing acids: XIX. Nickel(II) salts

Thermochemical Study of Gaseous Salts of Oxygen-containing Acids: XVIII. Cobalt(II) Salts

Existence of gaseous salts formed by cobalt(II) oxide was established. The standard enthalpies of formation and atomization of the salts were determined.

Thermochemical Study of Gaseous Salts of Oxygen-Containing Acids: XVI. Iron(II) Salts

Existence of gaseous salts formed by iron oxide FeO was established, and their standard enthalpies of formation and atomization were determined.

Thermochemical Study of Gaseous Salts of Oxygen-Containing Acids: XV. Manganese Molybdates and Tungstates

The existence of gaseous manganese molybdates and tungstates MnXO4 and MnXO3 (X = Mo, W) was confirmed, and their standard enthalpies of formation and atomization were determined.

Thermochemical Study of Gaseous Salts of Oxygen-containing Acids: XIV. Barium and Chromium Phosphates

Gas-phase equilibria involving barium and chromium(II) phosphates were studied by high-temperature mass spectrometry. Standard enthalpies of formation and atomization of gaseous BaPO2, BaPO3, CrPO2, and CrPO3 were determined.

Thermochemical study of gaseous salts of oxygen-containing acids: XIII. Molybdates and tungstates of alkaline-earth metals

Gas-phase reactions involving molybdates and tungstates of alkaline-earth metals were studied by high-temperature mass spectrometry. The standard enthalpies of formation and atomization of these salts were determined.