Gas Tracer Tests Research Articles

New Experimental Tools to Use Noble Gases as Artificial Tracers for Groundwater Flow

Labeling groundwater by injecting an artificial tracer is a standard and widely used method to study groundwater flow systems. Noble gases dissolved in groundwater are potentially ideal artificial tracers, as they are not subject to biogeochemical transformations, do not adsorb onto the aquifer matrix, are colorless, and have no negative impact on the quality of groundwater resources. In addition, combining different noble-gas species in multi-tracer tests would allow direct analysis of the spatio-temporal heterogeneity of groundwater flow systems. However, while the handling of noble gases is safe and straightforward for injection into groundwater, conventional methods to analyse dissolved noble gases tend to be impractical for groundwater tracer tests. The sampling and subsequent lab-based analysis of dissolved noble gases are laborious, expensive and time intensive. Therefore, only researchers with access to specialized noble-gas labs have attempted such tracer tests. The recently developed gas-equilibrium membrane-inlet mass spectrometers (GE-MIMS) allow efficient on-site analysis of dissolved gases at high temporal resolution. The GE-MIMS instruments thereby eliminate most of the analytical and logistical constraints of conventional lab-based techniques and therefore provide new opportunities for groundwater tests using artificially injected gases. We used a GE-MIMS to systematically test the applicability of He, Kr, and Xe as artificial groundwater tracers. These gas species were injected into groundwater as Dirac-like pulses at three piezometers located at various locations upstream of a pumping well, where dissolved gas concentrations were continuously monitored with the GE-MIMS instrument. The groundwater travel times observed in these tracer tests ranged from a few hours to several weeks, and were consistent with the groundwater flow field at the experimental test site. Travel times determined from the noble gas tracer tests were also consistent with those obtained traditional dye tracers.

A novel method to measure air-immobile regions of the composting pile by inverse calculation combined with gas tracer test

Air-immobile regions in composting piles obstruct O2 mass transport and exacerbate the formation and emission of harmful off-gases. However, effective methods for measuring the parameters of these air-immobile regions are lacking. With quartz sand piles, this study first adjusted the circumstances of a gas tracer test (gas tracer, its injection volume, and chamber type) using the two-region model (TRM). The effects of β (proportional coefficient of gas in the air-mobile region) and ω (mass exchange coefficient) on the breakthrough curves (BTCs) of the gases were then explored. Finally, an inverse calculation method was used to measure the feature parameters of air-immobile regions in two composting piles (temperature-increasing and thermophilic phases) and estimate the O2 concentrations in different composting piles (50, 100, 200 cm whole height; layers of 50, 100, 200 cm height in a 200-cm high pile). The results showed that the optimal conditions were achieved when 100 mL helium (He) as the gas tracer and a cylinder with a height/diameter ratio of 3 as the chamber were used. With the simulating composting piles, increasing β or ω slowed breakthrough and decreased peak concentration in BTCs of a gas tracer. Tracer-inverse calculation protocol can be used to efficiently estimate the volume ratios of air-immobile regions (φ) and first-order mass transfer coefficient (α), with the values of 39%/46% and 0.001/0.006 min−1 in the composting piles during temperature-increasing /thermophilic phase. The TRM also predicted the O2 concentration in the off-gas or air-mobile/immobile regions of the temperature-increasing-phase composting piles.

A comprehensive performance evaluation methodology for miscible gas flooding: A case study in a giant carbonate reservoir in Middle East

This work focuses on a typical low-permeability carbonate reservoir in Middle East that has been developed by miscible hydrocarbon (HC) gas flooding for more than 10 years. The oilfield is now suffering from gas channeling, high gas/oil ratio (GOR), and invalid gas circulation. To figure out the reasons and propose an optimized development plan, it is necessary to accurately determine the characteristics and behavior of miscible gas flooding. To achieve this, a comprehensive performance evaluation method for miscible gas flooding is established in this work by integrating production data, inter-well gas tracer test, saturation surveillance, pressure surveillance, minimum miscibility pressure (MMP) variation, and streamline simulation. The following miscible HC gas flooding characteristics are interpreted, including typical gas flow path, miscibility behavior, major controlling factors impacting performance, and the main challenges of the current development scheme, which provides a fundament for proposing mitigation plan. By using this evaluation method, the behavior of gas flow in the ongoing miscible flooding process is precisely characterized, which is a “gravity override-gas coning” mode in which gas override is formed by an upward injected gas flow and then gas flows through gas cap to producers that leads to gas coning, resulting in high GOR and invalid gas circulation. This flow mode mainly resulted from the unsatisfied miscibility that led to gas escaping from miscible phase and gas channeling. Furthermore, it was found out that pressure difference is the dominating factor for gas channeling. In addition, we also found that MMP varies during HC gas injection process due to the change in the oil composition, which emphasizes the importance of recovering and maintaining pressure. Based on these findings obtained from extensive dynamic performance analysis and numerical simulations, an optimization strategy is finally proposed for improving the performance of miscible HC gas flooding.

Subsurface monitoring and surveillance using inter-well gas tracers

Abstract Tracer technology has gained considerable attention recently as an effective tool in the reservoir monitoring and surveillance toolkit, particularly in improved oil recovery (IOR) operations. Gas flow paths within the reservoir can be quite different from liquid (oil and water) flow paths. This is primarily due to gravity override, and differences in density and relative permeability between the gas and liquid phases. An Inter Well Gas Tracer Test (IWGTT) is a key monitoring and surveillance tool for any IOR projects. IWGTT should be designed and implemented to track the flow behavior of gas phase. The test generally entails injecting a small amount of unique perflouro-hydrocarbon tracers into the gas phase injectant stream. IWGTT have been conducted on a limited number of fields across the globe, and sample results of some will be presented. The sampling frequency of the tracers from the producers should be designed carefully to collect the necessary data that will provide insights about the connectivity between the injectors and producers well pairs, gas breakthrough times (“time of flight”), and possible interwell fluid saturations. Different fit-for-purpose unique tracers can be deployed in the subject injector(s) stream and their elution can be monitored in the corresponding up-dip producer(s). In addition to reservoir connectivity and breakthrough times between injector and producer pairs, an IWGTT helps in optimizing water altering gas (WAG) operations and production strategies for gas injection projects, improve sweep efficiency and ultimately enhance oil recovery. It can also be used to identify source of inadvertent gas leakage into shallow aquifers or soil gas, and help in the planning and placement of future wells. This paper reviews the workflow and necessary logistics for the successful deployment of an interwell gas tracer test. It will provide the best practices for designing, sampling, analyzing and interpreting a gas tracer deployment. The paper also highlights the benefits of gas tracer data and their usefulness in understanding well interconnectivity and dynamic fluid flow in the reservoir. The results can be used to refine the reservoir simulation model and fine-tune its parameters. This effort should lead to better reservoir description and an improved dynamic simulation model. The challenges associated with IWGTT will also be shared.

In-situ mass spectrometry improves the estimation of stream reaeration from gas-tracer tests

The estimation of gas-exchange rates between streams and the atmosphere is of great importance for the fate of volatile compounds in rivers. For dissolved oxygen, this exchange process is called reaeration, and its accurate and precise estimation is essential for the quantification of metabolic rates. A common method for the determination of gas-exchange rates is through artificial gas-tracer tests with a proxy gas. We present the implementation of a portable gas-equilibrium membrane inlet mass spectrometer (GE-MIMS) to record concentrations of krypton and propane injected as tracer compound in the context of a gas-tracer test. The field-compatible GE-MIMS uses signals of atmospheric measurements for concentration standardization, and allows recording the dissolved-gas concentrations at a high temporal resolution, leading to overall low measurement uncertainty. Furthermore, the in-situ approach avoids loss of gas during the steps of sampling, transport, storage, and analysis required for ex-situ gas measurements. We compare obtained gas-exchange rate coefficients, reaeration and derived metabolic rates from the in-situ measurements to results obtained from head-space sampling of propane followed by laboratory analysis, and find much lower uncertainties with the in-situ method.

Technology Focus: EOR Operations (June 2018)

Technology Focus Carbon-dioxide (CO2) injection is a successful enhanced-oil-recovery (EOR) technology that has been deployed extensively in the Permian Basin of West Texas, enabled by CO2 mostly produced and transported from naturally occurring CO2 reservoirs in Colorado and New Mexico. Further expansion of CO2 EOR has been limited by the availability of affordable CO2 rather than the existence of suitable target reservoirs for redevelopment with CO2 EOR. The US Department of Energy estimates that 67 billion STB of economically recoverable next-generation CO2-EOR oil exist in US conventional reservoirs, with significant potential identified in other oil provinces around the world. This situation may be about to change. On 9 February, Congress passed and the president signed into law a budget agreement that included language to expand a 2009 tax credit for CO2 capture and storage known as 45Q. The key provisions are that, for stored CO2, the tax credit rises to $50 per tonne in 2027, while, for EOR, the equivalent value is $35. The amounts will be adjusted for inflation after 2026. The tax credit is per tonne of CO2 captured as long as it can be established that the CO2 was stored. The tax credit is transferable, hence nontax-paying entities or entities that have no tax liability can benefit from the program. The credit goes to the facility that captures the CO2 and is available for the first 12 years of operation. There is no cap on the arrangement for the tax-credit projects coming online after 2018 or for which construction has started before 2024. As a result, the US now has a carbon-pricing mechanism that could well be enough to unlock a wave of innovative CO2-capture projects and lead to a significant expansion in CO2 EOR, ultimately leading to new infrastructure, storage sites, and technology improvements that give birth to a CO2-capture industry. Recommended additional reading at OnePetro: www.onepetro.org. SPE 185526 Surveillance and Initial Results of an Existing Polymer Flood: A Case History From the Rayoso Formation by L.A. Martino, YPF, et al. SPE 188363 A Field Case Study of an Interwell Gas Tracer Test for Gas-EOR Monitoring by Modiu Sanni, Saudi Aramco, et al. SPE 185734 Case Histories of Solvent Use in Thermal Recovery by Bita Bayestehparvin, University of Calgary, et al.

Evaluation of nitrous oxide as a substitute for sulfur hexafluoride to reduce global warming impacts of ANSI/HPS N13.1 gaseous uniformity testing

The ANSI/HPS N13.1–2011 standard requires gaseous tracer uniformity testing for sampling associated with stacks used in radioactive air emissions. Sulfur hexafluoride (SF6), a greenhouse gas with a high global warming potential, has long been the gas tracer used in such testing. To reduce the impact of gas tracer tests on the environment, nitrous oxide (N2O) was evaluated as a potential replacement to SF6. The physical evaluation included the development of a test plan to record percent coefficient of variance and the percent maximum deviation between the two gases while considering variables such as fan configuration, injection position, and flow rate. Statistical power was calculated to determine how many sample sets were needed, and computational fluid dynamic modeling was utilized to estimate overall mixing in stacks. Results show there are no significant differences between the behaviors of the two gases, and SF6 modeling corroborated N2O test results. Although, in principle, all tracer gases should behave in an identical manner for measuring mixing within a stack, the series of physical tests guided by statistics was performed to demonstrate the equivalence of N2O testing to SF6 testing in the context of stack qualification tests. The results demonstrate that N2O is a viable choice leading to a four times reduction in global warming impacts for future similar compliance driven testing.

Simulation-assisted gas tracer test study of Tarim Yaha gas-condensate reservoir in China

To enhance oil recovery and optimize a production plan, injected water or gas fluid should be monitored and tracked, which can be realized by gas tracer technology. Tracer test technology has become an effective method for evaluating the flow condition of reservoirs and estimate reservoir properties. Gas tracers, such as chemical and radioactive materials, have been used to identify well-to-well connectivity, reservoir heterogeneity, high-permeability pay zones, sweep efficiency, and residual oil saturation. Moreover, tracer tests have been used to evaluate well interference among multiple hydraulically fractured wells and qualitatively predict possible fracture geometries. Therefore, the accurate quantification of tracer transport is of great importance. However, theoretical study of gas tracers in a condensate gas reservoir has not been thoroughly conducted to date. Current tracer transport models mostly focus on the gas tracer flow in oil reservoirs and cannot be directly applied to condensate gas reservoirs. To the best of our knowledge, the application of a gas tracer to recycle gas injection in gas condensate reservoirs has not been thoroughly studied. In this paper, we propose a mathematical model to quantitatively describe the gas tracer transport mechanism in condensate gas reservoirs. Our mathematical model is based on the mass conservation law and is numerically solved via the Integral Finite Difference method. The results predicted by our model have been compared to and verified by real data collected from the field. The model has been used to optimize the recovery of the Yaha Condensate Gas Field in the Tarim Basin, China. With the assistance of our tracer transport model, the pressure drawdown speed of the Yaha field has been successfully slowed from 0.8 MPa/year to 0.5 MPa/year. Generally, this study not only provides key insights into the transport mechanism of gas tracers but also presents the application of numerical tools to guide the production of gas condensate reservoirs. The technique introduced in this study could be potentially extended to condensate oil production in other fields.

Quantifying capture efficiency of gas collection wells with gas tracers

A new in situ method for directly measuring the gas collection efficiency in the region around a gas extraction well was developed. Thirteen tests were conducted by injecting a small volume of gas tracer sequentially at different locations in the landfill cell, and the gas tracer mass collected from each test was used to assess the collection efficiency at each injection point. For 11 tests the gas collection was excellent, always exceeding 70% with seven tests showing a collection efficiency exceeding 90%. For one test the gas collection efficiency was 8±6%. Here, the poor efficiency was associated with a water-laden refuse or remnant daily cover soil located between the point of tracer injection and the extraction well. The utility of in situ gas tracer tests for quantifying landfill gas capture at particular locations within a landfill cell was demonstrated. While there are certainly limitations to this technology, this method may be a valuable tool to help answer questions related to landfill gas collection efficiency and gas flow within landfills. Quantitative data from tracer tests may help assess the utility and cost-effectiveness of alternative cover systems, well designs and landfill gas collection management practices.

Impact of non-idealities in gas-tracer tests on the estimation of reaeration, respiration, and photosynthesis rates in streams

Estimating respiration and photosynthesis rates in streams usually requires good knowledge of reaeration at the given locations. For this purpose, gas-tracer tests can be conducted, and reaeration rate coefficients are determined from the decrease in gas concentration along the river stretch. The typical procedure for analysis of such tests is based on simplifying assumptions, as it neglects dispersion altogether and does not consider possible fluctuations and trends in the input signal. We mathematically derive the influence of these non-idealities on estimated reaeration rates and how they are propagated onto the evaluation of aerobic respiration and photosynthesis rates from oxygen monitoring. We apply the approach to field data obtained from a gas-tracer test using propane in a second-order stream in Southwest Germany. We calculate the reaeration rate coefficients accounting for dispersion as well as trends and uncertainty in the input signals and compare them to the standard approach. We show that neglecting dispersion significantly underestimates reaeration, and results between sections cannot be compared if trends in the input signal of the gas tracer are disregarded. Using time series of dissolved oxygen and the various estimates of reaeration, we infer respiration and photosynthesis rates for the same stream section, demonstrating that the bias and uncertainty of reaeration using the different approaches significantly affects the calculation of metabolic rates.

Field‐Scale Sulfur Hexafluoride Tracer Experiment to Understand Long Distance Gas Transport in the Deep Unsaturated Zone

A natural gradient SF6 tracer experiment provided an unprecedented evaluation of long distance gas transport in the deep unsaturated zone (UZ) under controlled (known) conditions. The field‐scale gas tracer test in the 110‐m‐thick UZ was conducted at the U.S. Geological Survey's Amargosa Desert Research Site (ADRS) in southwestern Nevada. A history of anomalous (theoretically unexpected) contaminant gas transport observed at the ADRS, next to the first commercial low‐level radioactive waste disposal facility in the United States, provided motivation for the SF6 tracer study. Tracer was injected into a deep UZ borehole at depths of 15 and 48 m, and plume migration was observed in a monitoring borehole 9 m away at various depths (0.5–109 m) over the course of 1 yr. Tracer results yielded useful information about gas transport as applicable to the spatial scales of interest for off‐site contaminant transport in arid unsaturated zones. Modeling gas diffusion with standard empirical expressions reasonably explained SF6 plume migration, but tended to underpredict peak concentrations for the field‐scale experiment given previously determined porosity information. Despite some discrepancies between observations and model results, rapid SF6 gas transport commensurate with previous contaminant migration was not observed. The results provide ancillary support for the concept that apparent anomalies in historic transport behavior at the ADRS are the result of factors other than nonreactive gas transport properties or processes currently in effect in the undisturbed UZ.

Residual CO2 saturation estimate using noble gas tracers in a single-well field test: The CO2CRC Otway project

This paper presents the results of a partitioning tracer test using noble gases to measure residual CO2 saturation in the field as one part of the CO2CRC residual saturation and dissolution test sequence. Noble gas tracers were used in a sequential partitioning tracer test. The first tracer test was performed prior to CO2 injection to characterise the aquifer under single-phase conditions. The second tracer test was performed after CO2 had been driven to residual saturation. The noble gas tracers can be regarded as non-partitioning aqueous-phase tracers in the undisturbed aquifer and subsequently as water/CO2 partitioning tracers in the presence of the residual CO2 saturation.One-dimensional radial simulations are used to estimate residual saturation from the tracer tests by fitting only two independent parameters: the apparent dispersivity of each tracer in the aqueous phase and the residual CO2 saturation. This analysis method is validated by successful application to krypton (Kr) and xenon (Xe) production curves from the field data.Both tracers give the same estimate of residual saturation to within the accuracy of the method. Furthermore the estimated residual saturation from the noble gas tracer tests is consistent with independent measurements. However the analysis of the two tracer production curves indicates that Xe has higher dispersivity than Kr, despite having been injected and produced simultaneously and measured from the same samples. Finally the application of this sequential tracer test method to other field settings is discussed.

Poly-Use Multi-Level Sampling System for Soil-Gas Transport Analysis in the Vadose Zone

Soil-gas turnover is important in the global cycling of greenhouse gases. The analysis of soil-gas profiles provides quantitative information on below-ground turnover and fluxes. We developed a poly-use multi-level sampling system (PMLS) for soil-gas sampling, water-content and temperature measurement with high depth resolution and minimal soil disturbance. It is based on perforated access tubes (ATs) permanently installed in the soil. A multi-level sampler allows extraction of soil-gas samples from 20 locations within 1 m depth, while a capacitance probe is used to measure volumetric water contents. During idle times, the ATs are sealed and can be equipped with temperature sensors. Proof-of-concept experiments in a field lysimeter showed good agreement of soil-gas samples and water-content measurements compared with conventional techniques, while a successfully performed gas-tracer test demonstrated the feasibility of the PMLS to determine soil-gas diffusion coefficients in situ. A field application of the PMLS to quantify oxidation of atmospheric CH4 in a field lysimeter and in the forefield of a receding glacier yielded activity coefficients and soil-atmosphere fluxes well in agreement with previous studies. With numerous options for customization, the presented tool extends the methodological choices to investigate soil-gas transport in the vadose zone.

Numerical modeling analysis of VOC removal processes in different aerobic vertical flow systems for groundwater remediation

Vertical flow systems filled with porous medium have been shown to efficiently remove volatile organic contaminants (VOCs) from contaminated groundwater. To apply this semi-natural remediation strategy it is however necessary to distinguish between removal due to biodegradation and due to volatile losses to the atmosphere. Especially for (potentially) toxic VOCs, the latter needs to be minimized to limit atmospheric emissions. In this study, numerical simulation was used to investigate quantitatively the removal of volatile organic compounds in two pilot-scale water treatment systems: an unplanted vertical flow filter and a planted one, which could also be called a vertical flow constructed wetland, both used for the treatment of contaminated groundwater. These systems were intermittently loaded with contaminated water containing benzene and MTBE as main VOCs. The highly dynamic but permanently unsaturated conditions in the porous medium facilitated aerobic biodegradation but could lead to volatile emissions of the contaminants. Experimental data from porous material analyses, flow rate measurements, solute tracer and gas tracer test, as well as contaminant concentration measurements at the boundaries of the systems were used to constrain a numerical reactive transport modeling approach. Numerical simulations considered unsaturated water flow, transport of species in the aqueous and the gas phase as well as aerobic degradation processes, which made it possible to quantify the rates of biodegradation and volatile emissions and calculating their contribution to total contaminant removal. A range of degradation rates was determined using experimental results of both systems under two operation modes and validated by field data obtained at different operation modes applied to the filters. For both filters, simulations and experimental data point to high biodegradation rates, if the flow filters have had time to build up their removal capacity. For this case volatile emissions are negligible and total removal can be attributed to biodegradation, only. The simulation study thus supports the use of both of these vertical flow systems for the treatment of groundwater contaminated with VOCs and the use of reactive transport modeling for the assessment of VOCs removal and operation modes in these high performance treatment systems.

Photoacoustic infrared spectroscopy for conducting gas tracer tests and measuring water saturations in landfills

Gas tracer tests can be used to determine gas flow patterns within landfills, quantify volatile contaminant residence time, and measure water within refuse. While gas chromatography (GC) has been traditionally used to analyze gas tracers in refuse, photoacoustic spectroscopy (PAS) might allow real-time measurements with reduced personnel costs and greater mobility and ease of use. Laboratory and field experiments were conducted to evaluate the efficacy of PAS for conducting gas tracer tests in landfills. Two tracer gases, difluoromethane (DFM) and sulfur hexafluoride (SF 6), were measured with a commercial PAS instrument. Relative measurement errors were invariant with tracer concentration but influenced by background gas: errors were 1–3% in landfill gas but 4–5% in air. Two partitioning gas tracer tests were conducted in an aerobic landfill, and limits of detection (LODs) were 3–4 times larger for DFM with PAS versus GC due to temporal changes in background signals. While higher LODs can be compensated by injecting larger tracer mass, changes in background signals increased the uncertainty in measured water saturations by up to 25% over comparable GC methods. PAS has distinct advantages over GC with respect to personnel costs and ease of use, although for field applications GC analyses of select samples are recommended to quantify instrument interferences.

Gas tracer transport in a heterogeneous fracture in two-phase flow conditions. Experimental and modeling results

Large amounts of gas can result from anaerobic corrosion of metals and from chemical and biological degradation of organic substances in underground repositories for radioactive waste. Gas generation may lead to the formation of a buoyant gas phase bubble (i.e. zone with increased gas saturation surrounded by water) and to the migration of radioactive gaseous species. In this situation, gaseous species migration is controlled by (1) advection, dispersion and diffusion within the gas bubble, and (2) dissolution in the water surrounding the gas bubble and diffusion of the dissolved species away from the interface. A number of gas tracer tests were performed in the framework of the GAs Migration (GAM) project to study the role played by dissolution/diffusion phenomena in gas transport. Tracers were selected to display a large range of solubility and diffusion coefficients, which should have led to significant chromatographic separation in the breakthrough curves (BTCs) of the tracers. However, measured BTCs displayed much smaller chromatographic separation than expected. These curves were interpreted using (1) a numerical model of multiphase flow and tracer transport in the fracture plane and diffusion into the immobile water, and (2) a simple two box model. Results showed that dissolution/diffusion into immobile water regions played a small role, and tailing appears to have been largely controlled by diffusion into dead gas volumes, such as boreholes.

A rapid method for the measurement of sulfur hexafluoride (SF6), trifluoromethyl sulfur pentafluoride (SF5CF3), and Halon 1211 (CF2ClBr) in hydrologic tracer studies

A rapid headspace method for the simultaneous laboratory determination of intentionally introduced hydrologic tracers, sulfur hexafluoride (SF6), trifluoromethyl sulfur pentafluoride (SF5CF3), Halon 1211 (CF2ClBr), and other halocarbons in water and gases is described. The high sensitivity of the procedure allows for introduction of minimal tracer mass (a few grams) into hydrologic systems with a large dynamic range of analytical detection (dilutions to 1:108). Analysis times by gas chromatography with electron capture detector are less than 1 min for SF6; about 2 min for SF6 and SF5CF3; and 4 min for SF6, SF5CF3, and Halon 1211. Many samples can be rapidly collected, preserved in stoppered septum bottles, and analyzed at a later time in the laboratory. Examples are provided showing the effectiveness of the gas tracer test studies in varied hydrogeological settings.

Quantifying Factors Limiting Aerobic Degradation During Aerobic Bioreactor Landfilling

A bioreactor landfill cell at Yolo County, California was operated aerobically for six months to quantify the extent of aerobic degradation and mechanisms limiting aerobic activity during air injection and liquid addition. The portion of the solid waste degraded anaerobically was estimated and tracked through time. From an analysis of in situ aerobic respiration and gas tracer data, it was found that a large fraction of the gas-filled pore space was in immobile zones where it was difficult to maintain aerobic conditions, even at relatively moderate landfill cell-average moisture contents of 33-36%. Even with the intentional injection of air, anaerobic activity was never less than 13%, and sometimes exceeded 65%. Analyses of gas tracer and respiration data were used to quantify rates of respiration and rates of mass transfer to immobile gas zones. The similarity of these rates indicated that waste degradation was influenced significantly by rates of oxygen transfer to immobile gas zones, which comprised 32-92% of the gas-filled pore space. Gas tracer tests might be useful for estimating the size of the mobile/immobile gas zones, rates of mass transfer between these regions, and the difficulty of degrading waste aerobically in particular waste bodies.

Age dating base flow at springs and gaining streams using helium‐3 and tritium: Fischa‐Dagnitz system, southern Vienna Basin, Austria

Springs and gaining streams are locations where groundwater flow paths naturally converge and discharge as a flow‐weighted mixture of water from the contributing aquifer. The age of that water is therefore a good measure of the mean transit time (MTT) of the contributing aquifer. The question examined in this paper is whether tritiogenic helium‐3 and tritium (3Hetrit–3H) can be used to estimate MTT in these settings. To answer that question two factors must be considered: (1) the loss of 3He from discharging groundwater as it becomes exposed to the atmosphere, and (2) the accuracy with which MTT can be determined from flow‐weighted 3Hetrit–3H concentrations. These concepts were tested at the Fischa‐Dagnitz system (springs and emerging stream), which is part of the southern Vienna Basin aquifer. Conducting a gas tracer test, gas exchange coefficients (λ) were established for helium‐4 (4He) and krypton‐84 (84Kr), and derived for helium‐3 (3He) and neon‐20 (20Ne). By simulating measured groundwater inflow and gas transport in the stream, groundwater inflow concentrations for 3He, 4He, 20Ne, and 84Kr were estimated. Correcting for the various sources of He, the tritiogenic helium‐3 (3Hetrit) concentration of inflowing groundwater was estimated at 8.3 tritium units (TU). The flow‐weighted groundwater concentration of 3H, determined from 22 stream water samples, was estimated at 9.8 TU. Assuming that the relationship between flow amount and transit time at Fischa‐Dagnitz is characterized by a hybrid dispersion–exponential age model, the 3Hetrit–3H ratio (8.3/9.8 = 0.85) defines a MTT of 8 years. The validity of this estimate was evaluated by comparison to a long‐term 3H time series that exists for Fischa‐Dagnitz. The likely range of MTT's derived from the measured 3H time series is 11 to 14 years.

Tracer test for the measurement of gas diffusion and non-aqueous phase liquid (NAPL) saturation in soil

During soil bioremediation, the diffusion of oxygen into the soil is an important prerequisite for aerobic biodegradation, and the decrease of petroleum products is the ultimate goal. Both processes need to be monitored. The aim of this work was to develop a gas tracer test that yields information on both, gas diffusion and residual saturation with non-aqueous phase liquids (NAPLs) in unsaturated soil heaps. One conservative tracer (methane) and 4 partitioning gas tracers (diethylether, methyl tert-butyl ether, chloroform and n-heptane) were injected as vapors into laboratory columns filled with unsaturated sand with increasing NAPL saturation. Breakthrough curves of gaseous compounds were measured at two points and compared to analytical solutions of an analytical diffusive-reactive transport equation. By fitting of methane data, robust results for effective diffusivity (tortuosity) were obtained. NAPL saturation was most accurately measured by the moderately water soluble tracers (ethers and chloroform). The hydrophobic tracer n-heptane did not partition into water-immersed NAPL. An easy and accurate way to assess air–NAPL partitioning constants from gas chromatography retention times is furthermore reported. It is concluded that gas tracer tests have the potential for measuring two important properties in soil bioremediation systems easily and quickly.