Decreasing Gas Pressure Research Articles

Thermal dynamics in deep shale reservoirs: Influences of the kerogen microstructural behavior on the gas adsorption/desorption capacity

In shale gas extraction projects, an investigation into the mechanisms of energy/mass transfer associated with shale gas adsorption/desorption in organic matter (kerogen) microstructure under high temperature and stress condition is crucial for improving the efficiency of shale gas production. This study presents a coupling thermo-hydro-mechanical model based on an improved fractal method that could explain the microstructural evolution of the kerogen system and the resultant alterations during the gas adsorption/desorption process under varying thermal conduction, gas seepage, and stress conditions. The influence of porosity, diameter, and tortuosity on the abundance, length, and complexity of kerogen networks under coupled multi-field effects is evaluated. The significance of this study is it could address the following aspects quantitively: (1) the spatiotemporal evolution of kerogen fractal dimensions following various extraction timelines; (2) the influence of shale temperatures on kerogen structures; (3) the influence of the kerogen fractal dimension on the shale gas desorption capacity and production efficiency; and (4) under different temperatures, when the fractal dimension/tortuosity fractal dimension of kerogen changes due to extraction disturbances, the volumetric deformation induced by gas adsorption increases by a maximum of 26.1%/decreases by 28.1% and in the later stages of extraction, the maximum gas pressure decreases by 44.7%/increases by 47.1%. The proposed fractal method adeptly reveals shale gas desorption behaviors under multi-field coupling conditions from a microscopic perspective, which cannot be found in the literature.

Microscopic Mechanism and Percolation Model of Dynamic Deposition of Elemental Sulfur Particles in Acidic Gas Reservoirs.

The dissolution of elemental sulfur in acidic gas leads to its precipitation as gas pressure decreases, thereby causing potential damage to the formation due to the deposition of sulfur particles. Previous sulfur deposition prediction models often relied on the solubility of sulfur in acidic gas and the stress state of sulfur particles to determine the occurrence of deposition, thus establishing predictive models. However, in the presence of complex geological conditions, the multiphase flow through porous media and the adsorption of particles on pore throat walls can also influence sulfur particle deposition to some degree. It is well known that sulfur particle deposition during gas reservoir development exhibits instability, with multiple factors influencing the deposited sulfur particles. Particularly noteworthy is the influence of airflow velocity, which can resuspend sulfur particles that are physically adsorbed on pore throat surfaces, thereby reintegrating them into the gas phase. Additionally, the dynamic deposition of larger sulfur particles involves a dynamic process. This study elucidates the dynamic process of sulfur deposition by considering the diverse transport dynamics of sulfur particles. Physical adsorption and desorption behaviors of sulfur particles are determined based on variations in reservoir conditions. The desorption status of sulfur particles with different particle sizes within the formation is established by evaluating the equilibrium between the force exerted on the pore throat wall and the suspension force generated by gas flow. The critical conditions for sulfur deposition in Yuanba gas reservoir were obtained by substituting on-site parameters into calculations. Moreover, a mathematical model is proposed to describe the dynamic deposition and migration of sulfur particles, adopting principles from continuous porous media porous flow theory, fluid flow mass conservation, as well as sulfur particle desorption and migration. The formulated model is solved, and its resulting solution process and outcomes hold significant implications for numerical simulation and predictive assessment of the development impact on gas reservoirs, particularly in later stages.

Investigation effects of different calorific values and operating conditions on biogas flame: a CFD study

ABSTRACT This study investigates different biogas fuels’ and operating conditions’ effects on flame temperatures and emissions (CO, CO2, NOx, and soot). Different calorific values (15.580, 17.880, 20.430, 23.080, and 26.230 MJ/kg) were obtained by changing methane content. Furthermore, various gas pressure (0.5, 1, 2, and 3 atm), excess air coefficient (1.4, 1.8, 2.5, and 4), and oxygen values (21, 23, 25, and 27%) were simulated for 8.6 kW thermal capacity furnace. Increasing the calorific value of biogas fuels, CO, NOx, and soot emissions and flame length tend to increase, while CO2 decreases. Increasing gas pressure, flame temperature, and CO2, CO, and NOx decrease, while soot emissions tend to increase. As a result of the decrease in the air excess coefficient from 4.0 to 1.4, there is a increase in the flame temperature, flame length, and soot, CO, CO2, and NOx emissions. On the other hand, oxygen content from 21% to 27% oppositely affected these parameters, excluding flame length.

Analysis of the influence of temperature on the adsorption characteristics of coal: Insights into low-temperature outburst prevention

To investigate the impact of temperature reduction on the adsorption characteristics of coal gas, isothermal adsorption experiments were conducted with environmental temperature and moisture content as variables. The changing patterns of coal gas adsorption characteristics, adsorption theories, and the temperature response of gas expansion were analyzed. Furthermore, engineering measures for preventing gas outbursts in low-temperature frozen coal seams were discussed. The research findings indicate that the gas adsorption capacity of coal samples increases with decreasing temperature. When the temperature decreases from 20 to −20 °C, the gas adsorption capacity decreases from 34.48 to 19.90 cm3/g. At the same pressure, the adsorption capacity of coal is negatively correlated with temperature. The Langmuir theoretical model better reflects the adsorption law of coal gas under different environmental temperature conditions, wherein the adsorption constant “a” gradually decreases with the increase in environmental temperature. In a closed space, the gas pressure decreases with the decrease in coal sample temperature. Under the new adsorption equilibrium, the gas pressure in the coal sample tank decreases linearly with temperature. Coal samples with different moisture contents exhibit varying degrees of decrease in gas pressure at the same temperature, with higher moisture content resulting in a smaller decrease in gas pressure. Gas expansion energy decreases linearly with the decrease in coal temperature, indicating a proportional relationship between gas expansion energy and coal gas release pressure. As the temperature decreases, the gas pressure decreases. Based on the experimental results, a synergistic approach for preventing gas outbursts through low-temperature freezing is proposed.

Analysis of the pressure drop of sulfur hexafluoride (sf6) gas in a circuit breaker 150 KV Siemens 3AQ1EG

Abstract. The development of technology in the current era is very rapid and has an impact on increasing electrical energy which is a major need for large industries and households. One of the electrical energy delivery equipment in the transmission system is a PMT or High Connection Breaker. This PMT is a mechanical equipment equipped with sulfur hexafluoride (SF6) gas arc extinguishing media. The process of extinguishing the arc occurs due to contact due to work from the movement that causes the contact to cause an arc. This decrease in SF6 gas pressure greatly affects reliability when operating, because the arc extinguishing process is not perfect. This is determined by the age of the equipment and the number of operating breakers. The results showed that SF6 gas which is in accordance with the standard normal pressure of 6.4 bar with an ambient temperature of 34°C can minimize the occurrence of equipment damage because it is able to approach arc pressure with SF6 gas velocity of 58 cm/s.kA, with a contact gap of 3,61224. cm, while the PMT cannot be operated at a pressure of 5.2 bar with an ambient temperature of 34°C because the speed of SF6 gas is 82 cm/s.kA with a contact gap of 5.10696. It is concluded that the higher the pressure affects the speed and distance when extinguishing the arc. several factors that affect the decrease in SF6 gas pressure using the FMEA method based on the highest value of the Risk Priority Number (RPN) of 810. Keywords: fire arc, Breakdown, Voltage breaker, SF6 . gas pressure

Экспериментальное исследование гидравлических характеристик сферических насадок для массообменных аппаратов

A critical analysis of the trends in the development of nozzles for mass transfer devices is given, some designs are described in which the transfer of heat and mass is organized from the standpoint of today technically the most perfect. It is shown that the specific surface, the free specific volume of the nozzle and the hydraulic resistance of the layer are determined as the main characteristics of irregular type packing bodies. The scheme and description of an experimental setup for determining the hydrodynamic characteristics of nozzles in laboratory conditions are given. The results of studies of the hydrodynamic parameters of a layer consisting of a spherical hollow irregular nozzle for a dry and irrigated column are presented. The singular velocities of the gas flow corresponding to the transition points (points of deceleration, suspension, inversion or choking) to different hydrodynamic modes of operation of the filling mass transfer columns (film, intermediate, turbulent) and corresponding pressure drops have been experimentally determined. The dependences of the hydraulic resistance of the nozzle layer on the gas velocity in the column for dry and irrigated nozzles with a 1 m high layer are determined. The main reasons for the decrease in gas pressure in the layer of the irrigated nozzle are indicated. The singular gas flow velocities and their corresponding pressure drops are calculated using known empirical dependencies for dry and irrigated nozzles. The results of experimental studies and engineering calculations were compared, thereby proving the possibility of using computational equations with satisfactory accuracy (up to 15%). The study of the hydrodynamics of the layer and its hydraulic characteristics has shown that the spherical, hollow nozzle design with evenly spaced holes on the surface provides an effective redistribution of working phases in the mass transfer apparatus.

Optimizing unconventional gas extraction: The role of fracture roughness

In unconventional reservoir engineering, such as coalbed methane and shale gas extraction, fracture behavior is pivotal in gas accumulation, migration, and extraction, acting as a primary channel for gas flow. Current research inadequately addresses the quantitative impact of fracture roughness on gas extraction. In this study, we introduce a novel interdisciplinary model that quantitatively characterizes shale fracture roughness and correlates it with shale permeability. This model comprehensively considers factors affecting shale extraction, including fracture roughness, in situ stress, reservoir deformation, and adsorption-desorption dynamics. It provides a thorough analysis of how fracture roughness influences gas seepage, extraction efficiency, and reservoir stability under various physical conditions. Our validated findings reveal that fracture roughness significantly affects shale permeability, stress responses, and displacement. As the fracture roughness coefficient χ increases from 0.2 to 1.0, the maximum reduction in gas pressure within the hydraulically fractured region is 4.7%, while the maximum increase in reservoir stress is 2.8%. In shale reservoirs near extraction well, particularly in hydraulically fractured zones, the maximum decrease in shale gas pressure is 11.1%, and the maximum increase in stress is 3.2%, which offer a groundbreaking approach for optimizing extraction rates and ensuring project safety in the industry.

Optimization of drilling parameters for coal seam gas extraction considering fluid–solid coupling and field application

AbstractAffect gas extraction efficiency to find out the optimum well location parameters, based on the gray correlation analysis of borehole diameter, borehole spacing, and extraction pressure three boreholes parameters that influence efficiency of gas extraction from the design of orthogonal experiment, using COMSOL simulate the effective radius of extraction under different experiments, and the effective radius of extraction for optimizing index quantitative gas extraction efficiency. The results showed that: factors affecting the gas extraction efficiency of the correlation between high and low aperture drilling, borehole spacing, and extraction from extraction negative pressure, it is concluded that the influence parameters of optimal layout parameter values, respectively, borehole diameter 8 cm and 3 m borehole spacing, extraction pressure 50 kPa, combined with the numerical simulation analysis using the optimal layout of gas drilling extraction from about 30 days. The decrease in gas pressure is about 45%, which basically meets the extraction standard, and the decreasing trend of gas pressure is obviously slowed down when the extraction time is longer than 30 days. The engineering experiment is carried out in the 9306 transport lane of a mine in Guizhou Province, and the results are basically consistent with the simulation results, which verify the rationality of the gray correlation analysis method to optimize the drilling parameters, and provide a theoretical basis for the optimization of drilling parameters.

Three-dimensional fluid simulation of a planar coil inductively coupled argon plasma source for semiconductor processes

In this paper, the effect of the coil structure, as well as the gas pressure, on the spatial distribution of an inductively coupled argon plasma is numerically investigated based on our developed three-dimensional fluid model. The model is based on a modified ambipolar diffusion model, in which the electron density is solved under the quasi-neutral condition, the ion density and neutral particle density are obtained by solving continuity equations, and the ion flux is achieved by solving the full momentum balance equation. In addition, the inductive electric field is governed by the Maxwell equations, which are solved in the frequency domain. The results show that the electron density is nonuniform along the azimuthal direction due to the asymmetry of the coil structure, and the uniformity becomes better as gas pressure decreases. Besides, the plasma azimuthal uniformity can also be improved by reducing the opening of the coil. As the coil radius increases, the plasma density decreases, while the radial uniformity of the plasma improves, and the azimuthal uniformity deteriorates. In addition, the influence of the current amplitude ratio between the inner coil and outer coil on the plasma uniformity in dual-coil discharge is also investigated. It is found that the plasma radial uniformity becomes better by reducing the inter-to-outer coil current amplitude ratio. The results obtained in this work demonstrate that the plasma uniformity can be improved by optimizing the coil structure and adjusting the discharge parameters, which is of significant importance in etching and deposition processes.

Study on the Coupling Effect of Stress Field and Gas Field in Surrounding Rock of Stope and Gas Migration Law

In the process of working face mining, the permeability of the coal seam and the crack evolution characteristics of overlying strata are very important for efficient gas drainage. In this study, the distribution characteristics of the stress field and crack field in the working face and their relations are analyzed mainly by 3DEC numerical simulation. Furthermore, combined with the on-site measurement of coal seam stress, gas pressure, and gas seepage in front of the working face and the gas seepage in overlying strata before and after mining, the coupling effect of stress field and gas field and the law of gas migration and distribution in the working face are deeply explored. The results show that the changing trend of gas seepage and gas pressure is controlled by the stress change of the working face, and with the increase of stress, gas pressure and gas seepage also increase. The peak position of gas pressure is the farthest from the coal wall, about 22.5~25 m, followed by the peak of stress and gas seepage. When the permeability of coal and rock mass increases, the gas seepage increases and the gas pressure decreases. The coal seam stress and gas seepage in the working face and gas seepage in the overlying strata fracture zone along the tailgate side are generally greater than those on the headgate side, but the gas pressure is the opposite. Mining cracks and strata separation provide a good channel and space for gas migration and accumulation. Along the strike and tendency of the working face, gas is mainly concentrated in the overlying strata crack space above the separation zone and the roof and overlying strata crack space on the side of the tailgate, respectively. Based on this, the directional borehole gas drainage technology and borehole layout scheme in the fractured zone are put forward, which effectively reduce the gas concentration in the working face by 30~36%.

Influence of the ambipolar field on the formation of electron phase flows in the positive column of a glow discharge in a nitrogen-like gas

The formation of the electron energy distribution function (EEDF) and phase flows of electrons in the plasma of a positive column of a glow discharge in a model gas with strong vibrational excitation, similar to molecular nitrogen, is analyzed in a wide pressure range. It is found that the traditional local approximation for calculating the EEDF can only be used at medium gas pressures, when the characteristic size of the plasma volume exceeds electron energy relaxation length in the entire range of electron energies. With a decrease in gas pressure, a new phenomenon is discovered—merging the phase flow streamlines into a single line on the coordinate-energy phase plane in the energy region of the of vibrational excitation threshold. It is shown that the combination of a strong electron sink at the threshold of vibrational excitation and the deceleration of electrons in an ambipolar field lead to a practical ‘vanishing’ of the component of the phase electron flux upward in energy. As a result, the streamlines of electron phase flow approach to some approximately straight line of constant kinetic energy close to the threshold energy of vibrational excitation. The formation of this feature on the phase plane correlates with the predominant escape to the walls of electrons with kinetic energy equal to the threshold of vibrational excitation.

Spatiotemporal measurements of striations in a glow discharge’s positive column using laser-collisional induced fluorescence

We have observed the behavior of striations caused by ionization waves propagating in low-pressure helium DC discharges using the non-invasive laser-collision induced fluorescence (LCIF) diagnostic. To achieve this, we developed an analytic fit of collisional radiative model (CRM) predictions to interpret the LCIF data and recover quantitative two-dimensional spatial maps of the electron density, ne, and the ratios of LCIF emission states that can be correlated with Te with the use of accurate distribution functions at localized positions within striated helium discharges at 500 mTorr, 750 mTorr, and 1 Torr. To our knowledge, these are the first spatiotemporal, laser-based, experimental measurements of ne in DC striations. The ne and 447:588 ratio distributions align closely with striation theory. Constriction of the positive column appears to occur with decreased gas pressure, as shown by the radial ne distribution. We identify a transition from a slow ionization wave to a fast ionization wave between 750 mTorr and 1 Torr. These experiments validate our analytic fit of ne, allowing the implementation of an LCIF diagnostic in helium without the need to develop a CRM.

Experimental and theoretical research on the debrining process in sediments for a gas storage salt cavern

The sediments account for a large part of the total mined volume of the cavern in high impurity salt mines. This paper was aimed at the scientific problem of gas storage in the pore space of the sediments, and expanded the storage capacity of salt cavern in high impurity salt mines. Debrining in the mined space of salt caverns (contained sediments) is a vital step to complete the gas storage. To experimentally observe the debrining process, debrining experiments are carried out using a self-developed experimental device. The debrining process can be divided into four typical stages, e.g., rapid increase of injection gas pressure, discharging the upper brine, i.e. the brine free of sediments, discharging the brine in sediments, and rapid decrease of injection gas pressure. A mathematical model is proposed for calculating debrining parameters of a salt cavern including sediments based on the pressure equilibrium principle at the gas-brine interface. A numerical method is established for calculating the total debrining time of irregular salt caverns including sediments. The effective cross-sectional area of debrining process is calculated by using the porosity of the sediments. A linear function of the porosity of the transition zone of the sediment surface is put forward. Therefore, the porosity of the upper brine space can gradually transition to the sediments, avoiding the error of sudden increase of the gas-brine interface and debrining rate, which is consistent with the practical debrining process. The porosity of sediments is considered to be a decaying exponential function of depth based on the accumulation of sediment particles. The cross-sectional area at any depth can be obtained through the interpolation of the sonar scanning data. The Jianghan salt cavern is selected for the applications of the proposed model, and the descending speed and depth of the gas-brine interface, and injection gas pressure with debrining time are analyzed. Results show that the greater the debrining rate, the shorter the time to reach the final sediment surface. The descending speed of the gas-brine interface shows a U-shaped curve, which is significantly affected by the cavern shape and porosity of sediments. The increment of the debrining rate has little effect on the ultimate injection gas pressure but has a significant effect on the increasing rate of injection gas pressure. These results can provide a reference for enhancing gas storage by using the sediment pore space of the mined volume and thereby expanding the effective gas storage volume of salt caverns.

Heat transfer and pyrolysis gas flow characteristics of light-weight ablative thermal protection system in the blunt body

Thermal protection system (TPS) is the critical system to protect the structure and electronic components of hypersonic vehicles from aerodynamic heating. Since the blunt body suffers the most severe thermal environment in a flight vehicle, the design of TPS for the blunt body is crucial. To investigate the thermal performance of the light-weight ablative material in the blunt body, a multi-dimensional thermal response model is proposed considering heat transfer, pyrolysis gas flow, and gas blowing effect. The characteristics of heat diffusion, pyrolysis process, gas flow, and the effect of pyrolysis gas blowing are investigated. It shows that the developed model can accurately predict temperature and gas flow. The temperature and charred thickness at the stagnation point are the largest, decrease along the surface of the sphere nose, and keep almost the same at the cone. Due to the surface pressure distribution, a large part of the pyrolysis gas in the sphere nose flows through the ablative material and injects into the air at the sphere-cone junction. In contrast, the gas at the cone flows vertically to the cone surface. The gas flow rate and pressure decrease as time elapses. Moreover, gas blowing mainly influences the thermal response near the sphere-cone junction, leading to a minimum blowing factor of 0.965 and a max temperature reduction of 7.4% at 100s. The effect of gas blowing is enhanced with the increase of phenolic resin content. This study deepens the understanding of the thermal performance of light-weight ablative material in the blunt body and guides the ablative thermal protection design.

Experiment, Model, and Mechanism of Multiscale Dynamic Diffusion-Permeability in Coal under Different Fluids.

The permeability of coal exhibits multiscale characteristics in space and time, which is caused by the presence of micro and nanopores in coal. Water, free gas, and adsorbed gas are common engineering fluids in coal seams during gas extraction. Thus, it is of significance to study the multiscale characteristics and mechanisms of seepage-diffusion of different fluids in coal for gas extraction engineering. Experiments of seepage-diffusion for He, CH4, and water are carried out using ϕ50 × 100 mm cylindrical coal. It is found that the apparent diffusion coefficient for He, CH4, and water are not a constant but a variable that decays dynamically with time. The phenomenon is independent of fluid properties and determined only by the multiscale characteristics of pores in coal, and then a novel model of multiscale dynamic apparent diffusion that can accurately describe the full-time process of flow in various fluids is proposed. The mechanism of dynamic seepage-diffusion for different fluids in coal is elucidated based on a new proposed geometrical model of multiscale pores. At the early stage of flow, fluids first flow in or out of the largest pores outside coal, and at the later stage of flow, fluids flow in the micro and nanopores inside the coal matrix. The pore sizes through which the fluid flows decrease with time, which leads to a dynamic attenuation of the apparent diffusion-permeability with time. The initial apparent permeability K 0 for He/CH4 shows a "U"-shaped pattern of decreasing and then increasing with the decrease of gas pressure. When the gas pressure is lower than the turning point, the slip effect dominates, making the initial apparent permeability K 0 decrease with the increase of gas pressure. When the gas pressure is higher than the turning point, the effect of the pressure difference of the gas dominates, and K 0 increases with the increase of gas pressure. When water flows in multiscale pores, it occupies the space of large pores, making the homogeneity of pores increase, and the decay coefficient of apparent permeability becomes smaller. The multiscale permeability can explain the reason for the rapid attenuation of coalbed methane production in the late stage. It is of great significance for coalbed methane productivity prediction.

Experimental study on stress and permeability response with gas depletion in coal seams

The gas extraction environment in coal seam exhibits uniaxial strain condition with constant overlying strata stress and horizontal strain. Simulating this environment in laboratory often ignores true triaxial stress state, so the difference in horizontal stresses reduction and the accompanying permeability evolution remain ambiguous. Therefore, this study conducted the true triaxial stress and permeability response tests simulating gas extraction environment under shallow and deep in-situ stress conditions. To quantify gas adsorption effect, the adsorbed (CO2) and non-adsorbed (He) gases were also used. The results indicated that the intermediate and minimum principal stresses, i.e., σ2 and σ3, exhibited a linear decreasing trend during gas depletion, but showed more decreases in stress when the intermediate and minimum principal strains, i.e., ε2 and ε3, recover under high gas pressure depletion. High true triaxial stress enhanced the compressibility of pores and fractures in coal, resulting in low horizontal deformation and stress reduction gradient during gas depletion. Similarly, the reduction gradient of σ2, mσ2, was less than that of σ3. This suggested that the difference between horizontal stresses also increased during coalbed methane (CBM) extraction, which exacerbated the risk of coal body damage. For different gas depletion, the stress reduction gradient exhibited mHe < 1 and mCO2 > 1, which was related to the relative affinity of different gas species for the adsorption medium. A significant matrix shrinkage effect resulted in a more pronounced stress reduction. For permeability, the permeability increased exponentially during CO2 depletion, while the permeability of helium exhibited a decreasing followed by an increase with decreasing gas pressure. This is related to the competing mechanism and synergistic effect of the adsorptive gas desorption, effective stress effect, and slippage effect. We quantified the contribution and mechanism of the three to the permeability separately. The permeability anisotropy ratio (Ar) decreased exponentially during gas depletion.

Research on the gas migration trend and mechanism of the transition flow regime in coal based on MRT-LBM simulation

In order to reveal the process and mechanism of gas flow in a low-permeability coal seam, a new multiple-relaxation-time lattice Boltzmann method (MRT-LBM) model of gas migration in coal micro/nanopores based on Langmuir monolayer adsorption theory, the slip boundary scheme and Bosanquet effective viscosity was established. The software MATLAB was used to carry out the simulation study of uniform pore gas flow based on the MRT-LBM model, and the results were compared and verified with the porous anodic alumina membrane gas flow experimental results. On this basis, the gas flow in coal pores with different micro/nanopore sizes considering adsorption was simulated. The results show that the dimensionless permeability coefficient increases with decreasing pore size under the same pressure, which reflects the subsequent enhancement of the microboundary constraint effect and reveals that the pore system becomes the main controlling factor of coal seam permeability within the coal matrix in the middle and late stages of coal seam gas extraction, while the role of the microboundary constraint effect needs to be considered. The gas adsorption layer weakens the pore gas flow capacity, but for pores with a radius greater than 16 nm, the apparent change in permeability caused by the adsorption layer is less than 5%, and the adsorption effect can be ignored. N2, CH4, and CO2 enter the transition flow regime under different pressure conditions; with gas extraction, the gas pressure decreases, and the difference in the gas flow characteristics of the three gases increases.

Gas Permeability Behavior in Frozen Sand Controlled by Formation and Dissociation of Pore Gas Hydrates

Formation and dissociation of pore gas hydrates in permafrost can change its properties, including fluid flow capacity. Permeability is one of the most significant parameters in the study of hydrate-containing rocks, especially in the case of gas burial or extraction. Gas permeability variations in frozen sand partially saturated with CO2 or CH4 hydrates are studied experimentally at a constant negative temperature of −5 °C, as well as during freezing–thawing cycles. The gas permeability behavior is controlled by the formation and dissociation of pore gas hydrates in frozen sand samples. The samples with an initial ice saturation of 40 to 60% become at least half as permeable, as 40% of pore ice converts to hydrate. The dissociation process of accumulated hydrates was modeled by both depressurizing methane or CO2 to atmospheric pressure and by stepwise injection of gaseous nitrogen up to 3 MPa into a frozen sample. In sand samples, with a decrease in gas pressure and without subsequent injection of nitrogen, a decrease in pore hydrate dissociation due to self-preservation was noted, which is reflected by a deceleration of gas permeability. Nitrogen injection did not lead to a decrease in the rate of dissociation in the frozen hydrate-containing sample, respectively, as there was no decrease in the rate of gas permeability.

The dynamics of magnetized viscous-resistive ADAFs under a self-similar evolution

In this paper, we explore the self-similarity time evolution of a hot accretion flow around a compact object in the presence of a toroidal magnetic field. We focus on a simplified model which is axisymmetric, rotating, unsteady viscous-resistive under an advection-dominated stage. In this work, we suppose that both the kinematic viscosity and the magnetic diffusivity to be a result of turbulence in the accretion flow. To describe such a flow, we apply magneto-hydrodynamics equations in spherical coordinates, [Formula: see text] and adopt unsteady self-similar solutions. By neglecting the latitudinal dependence of the flow, we obtain a set of one-dimensional differential equations governing the accretion system. In this research, we encounter two parameters related to the magnetic field; one of them is, [Formula: see text], defined as the ratio of the magnetic pressure to the gas pressure and the other one, [Formula: see text] applied in the magnetic diffusivity definition. Our results show that [Formula: see text] is a function of position, and increases towards outer layers. On the other hand, we examine different strength of magnetic field by choosing different value of [Formula: see text] which is the value of [Formula: see text] at the inner edge of disc. We see that both [Formula: see text] and [Formula: see text] have positive effect on growing the radial infall velocity but density and gas pressure decrease by larger values of these parameters. Moreover, the rotational velocity and temperature of accreting material reduce considerably under the influence of a stronger magnetic field. We also focus on the behavior of the mass accretion rate appearing as a descending function of position. Finally, our solutions confirm that the radial trend of the physical quantities in a dynamical accretion flow is different from the ones in a steady flow. However, the effect of various parameters on the physical quantities in our model is qualitatively consistent with similar steady models.

Electron density and temperature of dual-frequency capacitively coupled argon plasma in two-dimensional distribution obtained and studied in experiment

Behaviors of plasma in spatial distributions are vital for understanding physical mechanisms of low pressure capacitively coupled discharges. However, due to the lack of simple and reliable diagnostic techniques, few experimental studies have focused on two-dimensional distributions of plasma. Recently, we have developed a new method for rapid two-dimensional plasma diagnosis. With this method, the dual-frequency capacitively coupled plasma, an important plasma commonly used in etching, is systematically studied. Three circumstances are presented here: In case I, the plasma discharge was driven by a radio-frequency source; in case II, two radio-frequency sources were applied to one electrode; and in case III, such sources were applied to two separate electrodes. Results show that both the emission intensity and electron density in case III are higher than those in case II, and because the absolute value of the DC self-bias voltage is smaller, the structure of axial discharge is more symmetric in case III. For the asymmetrically capacitive discharges (cases I and II), the position of the maximum axial electron density is close to the powered electrode due to the presence of the DC self-bias voltage. As the low-frequency power increases or gas pressure decreases, the position of the maximum axial electron density moves gradually toward the grounded electrode because of the enlarged thickness of the sheath. However, high-frequency power has a limited influence on the position of the maximum axial electron density. The radial distribution of plasma is more uniform when plasma density is relatively low. For a higher plasma density situation, the center-peaked density profile results from the higher power deposition at the electrode center and/or more local charged particle dynamics. In addition, under the same discharge conditions, a lower electrode gap is favorable for the occurrence of the α-γ mode transition.