It is imperative to minimize radioiodine release to the environment through gaseous emissions of spent fuel reprocessing facilities, thereby mitigating its potential impact on the general public. One effective and widely adopted strategy for achieving this objective is caustic scrubbing, a method that involves the absorption of molecular iodine from gaseous streams using caustic soda ( NaOH ) solution in a packed column. In-depth laboratory-scale experiments were conducted to ascertain the overall volumetric mass transfer coefficient K G a for the absorption of dilute iodine vapor from air into a caustic soda solution in a packed column and to establish optimum performance parameters for this process. The investigation yielded noteworthy findings: K G a increased proportionately to (Gas phase Reynolds number)1.0 at constant liquid flow rates across all types of packing tested. K G a displayed relative independence from liquid velocities for high and moderate NaOH concentrations. However, this coefficient varied proportionately to (Liquid phase velocity)0.26 to 0.42 at lower NaOH concentrations under conditions of high gas flow rates NaOH . As the height of the column increased, K G a was found to decrease slightly. The presence of NOx at an inlet concentration of 9000 ppm in the gaseous stream led to a reduction in the mass transfer coefficient of iodine, particularly at low NaOH concentrations. In summary, the study underscores the importance of caustic scrubbing as an effective means to minimize the release of radioiodine. The investigation’s results provide valuable insights into optimizing performance parameters for this process, contributing to enhanced environmental protection.
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