Gas Mixture Research Articles

Flow assurance analysis in Front End Engineering Design (FEED) of Subsea Flowline and Riser

Innovative subsea production systems (SPS) are required for deep-water oil and gas exploration in order to transport multiphase fluids—a complex mixture of water, gas, and oil—across long distances under challenging conditions. Significant technological challenges confront these systems, such as flow assurance, which ensures continuous fluid flow through pipelines, flowlines, and wells. Flow assurance issues can significantly impact production and incur costly downtime. This paper emphasizes the critical role of flow assurance analysis during the crucial Front-End Engineering Design (FEED) stage of SPS development. By utilizing industry-standard simulation tools like PIPESIM™, engineers can proactively identify and mitigate potential flow assurance problems that could hinder productivity. These analyses are crucial as FEED decisions significantly impact project cost-effectiveness. To illustrate the practical application of flow assurance principles, the paper presents a case study of a subsea architecture design for a specific manifold system. Considering operator requirements, flow assurance simulations were employed to guide critical decisions regarding material selection and optimal sizing of risers and flowlines. This demonstrates how flow assurance considerations during FEED directly influence cost-effective and optimized SPS design.

Reduction of MRONJ risk after exodontia by virtue of ozone infiltration: A randomized clinical trial.

Exodontia is commonly considered as a risk factor for the development of medication-related osteonecrosis of the jaw (MRONJ) in individuals exposed to bone modifying agents. This study was aimed at assessing the efficiency and safety of a gaseous oxygen-ozone mixture as an adjuvant to a standard exodontia to reduce the risk of MRONJ development. A randomized, open-label, phase II, single-center clinical trial involving 117 patients at risk of MRONJ was conducted. The study protocol tested injections of an oxygen-ozone mixture in the post-extraction site. Participants were randomly assigned to two groups: oxygen-ozone therapy, and standard tooth extraction protocol. Post-extraction wound healing was assessed using the Inflammatory Proliferative Remodeling (IPR) Wound Healing Scale. The oxygen-ozone therapy group exhibited a significant improvement in wound healing post-extraction during the inflammatory and proliferative phases, as indicated by the IPR scale scores at 3-5 days (p = 0.006) and 14 days (p < 0.001) respectively. Oxygen-ozone therapy shows promise in improving post-extraction healing in patients at risk of MRONJ. Future studies with larger sample sizes and multicenter collaborations are recommended to confirm the validity of these findings and explore the long-term efficacy of ozone therapy.

The Creation of a New Model of a Gas-Turbine Electric Power-Generating Device

A hypothesis on the possibility of creating an electric power gas turbine device running on fuel gas is proposed, and the results of preliminary research experiments are given to evaluate the validity of this hypothesis. The assessment criteria for mixing fuel gas and air and the quality of combustion have been identified. In particular, it has been found that the burning of fuel gas with a blue flame in a combustion chamber of a particular, proposed design, is an indication that the content of the fuel gas mixture was optimal, the mixing process is perfect, and the exhaust gas is completely expelled from the combustion chamber. It has also been revealed that the criteria for quantitative assessment of the quality of the fuel gas combustion process is the force of the exhaust gas blown out of the combustion chamber acting on the blade of the gas turbine. It is shown that the optimal content of the propane-air mixture at atmospheric pressure is 92% air + 8% propane, and the force of the exhaust gas flow acting on the air turbine blade was 5 dekanewtons.The calculation shows that the action of total force of two chambers on the gas turbine blade can overcome the reaction force of the generator armature with a capacity of at least 1000 W.As is seen from the given approximate, simple calculations, a large amount of electricity can be generated by the proposed gas turbine devices if they are equipped with an electric generator of appropriate capacity and the appropriate number of combustion chambers.To determine the parameters of the proposed design of the combustion chamber of the gas turbine device, such as diameter, height, and volume, materials are provided based on the experiment, and an image is obtained that establishes a relationship between the force of the combustion chamber acting on the gas turbine blade and the mentioned parameters.

The Influence of Selected Process Parameters on the Efficiency of the Process of Gas Nitriding of AISI 1085 Steel

The main aim of the manuscript was to investigate the impact of modifying the parameters of the gas nitriding process of samples made from AISI 1085 steel on the course and results of the process carried out in a chemical reactor allowing for thermogravimetric measurements. The tested steel was subjected in a chemical reactor to the process of gas nitriding in the temperature range of 490–580 °C, using different sample heating rates (in the range of 1–25 °C/min) and various mixtures of nitriding gases (pure NH3, or NH3 with the addition of H2 or N2). To assess the impact of the tested process parameters on its efficiency, the thickness of the nitrided layers produced, the change in sample mass, the structure of the phases produced, the phase composition and the microhardness were examined. For the research methodology used, it was found that reducing the amount of NH3 and/or using H2 or N2 admixtures adversely affects the thickness of the nitride layers produced. At the same time, the use of a lower maximum process temperature with the same gas mixture resulted in a significant difference in the thickness of the layers. It was also found that the use of pure NH3 or a gas mixture (NH3 + H2) with higher NH3 contents resulted in higher surface microhardnesses of the samples and that for these samples, the hardness increased to a greater depth.

Formation of Black Silicon in a Process of Plasma Etching with Passivation in a SF6/O2 Gas Mixture

This article discusses a method for forming black silicon using plasma etching at a sample temperature range from −20 °C to +20 °C in a mixture of oxygen and sulfur hexafluoride. The surface morphology of the resulting structures, the autocorrelation function of surface features, and reflectivity were studied depending on the process parameters—the composition of the plasma mixture, temperature and other discharge parameters (radical concentrations). The relationship between these parameters and the concentrations of oxygen and fluorine radicals in plasma is shown. A novel approach has been studied to reduce the reflectance using conformal bilayer dielectric coatings deposited by atomic layer deposition. The reflectivity of the resulting black silicon was studied in a wide spectral range from 400 to 900 nm. As a result of the research, technologies for creating black silicon on silicon wafers with a diameter of 200 mm have been proposed, and the structure formation process takes no more than 5 min. The resulting structures are an example of the self-formation of nanostructures due to anisotropic etching in a gas discharge plasma. This material has high mechanical, chemical and thermal stability and can be used as an antireflective coating, in structures requiring a developed surface—photovoltaics, supercapacitors, catalysts, and antibacterial surfaces.

Global existence of weak solutions and weak–strong uniqueness for nonisothermal Maxwell–Stefan systems *

The dynamics of multicomponent gas mixtures with vanishing barycentric velocity is described by Maxwell–Stefan equations with mass diffusion and heat conduction. The equations consist of the mass and energy balances, coupled to an algebraic system that relates the partial velocities and driving forces. The global existence of weak solutions to this system in a bounded domain with no-flux boundary conditions is proved by using the boundedness-by-entropy method. A priori estimates are obtained from the entropy inequality which originates from the consistent thermodynamic modelling. Furthermore, a conditional weak–strong uniqueness property is shown by using the relative entropy method.

Flame spray pyrolyzed carbon-encapsulated Au/Fe3O4 nanoaggregates enabled efficient photothermal therapy and magnetic hyperthermia of esophageal cancer cells

Multifunctional magneto-plasmonic nanoparticles with magnetic hyperthermia and photothermal therapy could kill cancer cells efficiently. Herein, carbon-encapsulated Au/Fe3O4 (Au/Fe3O4@C) was fabricated using an enclosed flame spray pyrolysis. The nanostructures, including an Fe3O4 core (51.9–55.2 nm) with a decreasing carbon shell thickness and an Au core (4.68–8.75 nm) coated with 2–4 graphite layers, were tailored by tuning the C2H4 content in the reacting gas mixture. Saturation magnetization (33.7–48.2 emu/g) and optical absorption were determined. The carbon shell facilitated the dispersion of Au/Fe3O4 and restrained their laser-induced and magnetic field-induced coalescence and growth. Au/Fe3O4@C exhibited excellent magnetic resonance imaging capability (91.4 mM−1 s−1) and photothermal performance (65.4°C for 0.8 mg/mL Au/Fe3O4@C at a power density of 1.0 W/cm2 after 300 s near-IR laser irradiation (808 nm)). Moreover, the combined application of photothermal and magnetic-heating properties reduced the required intensity of both laser and magnetic field compared to the intensity of separate situations. Our work provides a unique, intriguing approach to preparing multicomponent core/shell nanoaggregates that are promising candidates for esophageal cancer cell therapy.

Numerical Simulation and Consequence Analysis of Full-Scale Jet Fires for Pipelines Transporting Pure Hydrogen or Hydrogen Blended with Natural Gas

The use of existing natural gas pipelines for the transport of hydrogen/natural gas mixtures can achieve large-scale, long-distance and low-cost hydrogen transportation. A jet fire induced by the leakage of high-pressure pure hydrogen and hydrogen-blended natural gas pipelines may pose a severe threat to life and property. Based on the Abel–Nobel equation of state and a notional nozzle model, an equivalent pipe leakage model is established to simulate high-pressure pipeline gas leakage jet fire accidents. Large-scale high-pressure hydrogen and natural gas/hydrogen mixture jet fires are simulated, showing the jet impingement process and obtaining an accurate and effective simulation framework. This framework is validated by comparing the simulated and experimental measured results of flame height, flame appearance and thermal radiation. Several combustion models are compared, and the simulated data show that the non-premixed chemical equilibrium combustion model is superior to other combustion models. The influence of the pipe pressure and the hydrogen blending ratio on the consequences of natural gas/hydrogen mixture pipeline leakage jet fire accidents is explored. It is found that when the hydrogen blending ratio is lower than 22%, the increase in the hydrogen blending ratio has little effect on the decrease in the thermal radiation hazard distance.

In-flight iron ore reduction and nanoparticle formation in an atmospheric pressure hydrogen microwave plasma

Abstract The in-flight reduction of iron ore particles using an atmospheric pressure hydrogen plasma is investigated. Iron ore particles with a size less than 75 µm are aerosolized and carried with an argon-hydrogen (90%-10%) gas mixture through an atmospheric pressure microwave plasma. After the treatment, the collected particles are observed to follow three distinct populations: (i) fully reduced nanoparticles, (ii) partially reduced spheres, larger than the feedstock, and (iii) partially melted, partly reduced agglomerates. A model is developed to explain the possible mechanism for the origin of the three populations. The nanoparticles (i) are found to be likely formed from the previously evaporated material whereas the particles (ii) and (iii) result from the partial/complete melting of the particles and agglomerates flowing through the reactor. The gas temperature is estimated to be more than 2000 K, which enables the rapid melting, evaporation, and reduction of these particles within residence times of only a few 10 ms.

High aspect ratio SiO2/SiN (ON) stacked layer etching using C3HF5, C4H2F6, and C4H4F6

Abstract High aspect ratio SiO2/SiN (ON) stacked layer etching using hydrofluorocarbon gases was conducted with various ratios of H, F, and C to achieve higher etching rates and precise profile control. The experimental gases were C3HF5, C4HF5, C4H2F4, C4H2F6, C4H4F6 and C5H2F10. The oxygen gas flow rate and mixing ratio were optimized to maximize mask selectivity while avoiding clogging at the top of the mask. For comparison, C4F6/CH2F2/Ar/O2, and C4F6/C4F8/CH2F2/Ar/O2 were used as reference gas mixtures. The initial screening narrowed the candidate pool to 3 gases: C3HF5, C4H2F6, and C4H4F6. At equivalent power, the C3HF5 condition achieved a 15% faster ON etch rate, and C4H2F6 achieved a 9% faster ON etch rate compared to the reference condition. Only C4H4F6 showed a worse ON etch rate than the reference (~33%) due to severe mask clogging. Furthermore, C3HF5 achieved a 29% faster ON etch rate under high power conditions. It also achieved a 57% faster ON etch rate without excessively compromising selectivity or bow CD expansion after optimization. We report detailed comparisons of etch rate and clogging while controlling the CD profile in the ON stack process.

Hardness and Microstructure of TiN Coating on Aluminum Alloy with DC Sputtering

Titanium Nitride coating has attracted much interest in increasing the hardness of aluminum alloys. This study aims to investigate the effect of Ar: N gas mixture and time on increasing the hardness of aluminum alloys using DC sputtering. Preparation of TiN thin films on aluminum alloy substrates using flowing gas mixture parameters and time. First, the layer of TiN was deposited on the sample with a gas mixture of 90Ar:10N; 80Ar:20N; 70Ar:30N; and 60Ar:40N (%) for 60 minutes. Then the optimum gas mixture that produces the highest surface hardness is used in the second process with time variations of 30, 60, 90, and 120 minutes. The results showed that the highest hardness was achieved in a gas mixture of 70Ar:30N and 60 minutes. The TiN phase formed on the aluminum surface was identified by XRD, while the surface morphology was observed by SEM. Compared with untreated samples, the hardness of treated samples increased significantly.

Construction of a Biogas Digester Using Gas and Temperature Sensor

The construction of a biogas digester is the main emphasis of this project. Biogas is a mixture of gases created during the anaerobic decomposition of organic material, including food waste, animal waste, sewage, and waste from farms and plants. One of the major causes is environmental degradation, which has emerged to be the greatest threat to the health of the environment and the economy of the underdeveloped areas. But with the discovery and application of biogas which is a gaseous fuel obtained from biomass by the process of anaerobic digestion, most problems are resolved. The project’s aim is to create a biogas digester that leverages animal manure to generate biogas for usage at Covenant University. The digester selected for construction is a barrel drum digester for the production of biogas using cow dung. The cow dung was tested for a total of 14 days, during which the days of gas production and digestion were observed, and the biogas was then tested with the gas and temperature sensor and was confirmed to detect gas and temperature.

Experimental Combustion and Flame Characterization of a Chemical Looping-Based Oxidative Dehydrogenation Byproduct Fuel Mixture Containing High CO2 Dilution

Abstract This study investigates the combustion performance of a CO2-rich fuel mixture containing ethane and methane as active species using a constant volume combustion chamber. This fuel is obtained as a byproduct of a chemical looping-based oxidative dehydrogenation (Cl-ODH) process ethylene production. The byproduct gas mixture has 40.79% CO2, 39.49% ethane, and 4.88% methane by weight with other minor compounds. Using this fuel for energy extraction would improve the process efficiency of the ethane to ethylene conversion. After initial combustion modeling, the gas fuel mixture was reduced to just the major species: CO2, ethane, and methane. The mixture was then tested for flammability limits and combustion performance under spark-ignition conditions. Effects of ambient conditions like temperatures between 300 and 400 K with initial pressures from 1 to 10 bar were tested. The effects of stoichiometry were tested to understand flame velocities and heat release. The fuel mixture showed an overall reduced flame velocity compared to gasoline. Instability in combustion was believed to be caused by the dissociation of ethane under elevated conditions. At higher pressures, the flame produces lower cumulative heat release. Simulations were also performed using a model tuned to replicate the operations of the combustion chamber used in the experiments. Heat release and unburnt fuel mass data were calculated to identify the discrepancies in the combustion completeness at elevated pressures. The effects of CO2 quenching the flame coupled with the increased dissociation of the fuel species can lead to up to more than 75% of the fuel mixture being unburnt. Data from this study were used to modify a small-scale spark-ignition engine to use this fuel and produce usable energy.

Simulation Analysis of Arc-Quenching Performance of Eco-Friendly Insulating Gas Mixture of CF3I and CO2 under Impulse Arc

Due to its superior insulating qualities, SF6 gas is extensively used in the power sector. However, because of its poor environmental protection properties, finding ecologically acceptable insulating gas has become a critical challenge in the power sector in the context of pursuing green electricity. This work simulates the arc-quenching performance of a gas mixture of CF3I and CO2, which is thought to be a workable substitute for SF6 gas. The COMSOL software is used to build a two-dimensional model of a single-pipe arc-quenching chamber based on the concepts of magnetohydrodynamics (MHD) theory. The lightning impulse current is made by applying electrical stimulation to pure CO2 gas, gas mixtures with 10% CF3I and 90% CO2, and gas mixtures with 30% CF3I and 70% CO2 in the single-pipe arc-quenching chamber. During the first stage of arc formation, the results show that CF3I/CO2 gas mixtures with 10% and 30% CF3I have lower electrical conductivity than pure CO2 gas. An 8/20 μs lightning impulse current waveform with a magnitude of 4 kA is used for this observation. The highest airflow velocity for pure CO2 is 1744 m/s, but the mixture of 10%/90% CF3I/CO2 has a maximum airflow velocity of 1593 m/s. The 30%/70% CF3I/CO2 mixture has the highest maximum airflow velocity at 1840 m/s. Airflow velocity increases and the overpressure in the arc-quenching chamber is prolonged when there is a greater concentration of CF3I gas in the gas mixture. Consequently, these factors greatly reduce the duration of the arc-extinguishing time. The arc-quenching chamber’s overpressure is extended when the amount of CF3I gas in the gas mixture is increased, which increases the velocity of the airflow. As a result, these factors significantly decrease the duration of the arc-extinguishing time.

Effect of the component and the concentration ratio on the removal of volatile organic compound mixtures by non-thermal plasma

The feasibility and efficiency of the degradation of volatile organic compounds (VOCs) by non-thermal plasma (NTP) has been extensive investigated and proved in laboratory experiments with single target component. In practical, multicomponent VOCs are emitted during industrial production. It is urgent need to study the abatement of multicomponent VOCs to evaluate the effectiveness of NTP technology in application, and explore the impact of interactions between VOCs components on degradation efficiency. This study focused on the degradation of VOCs mixtures composed of toluene (TOL), acetone (AC), and ethyl acetate (EA) by dielectric barrier discharge (DBD) plasma in room temperature. Through changing the target gas in turn and the concentration ratio of additive gas in binary mixture, the influence of the composition and the concentration ratio of the additive gases on the target gas degradation have been investigated by comparing the decomposition of the single compound. The results showed that AC and EA had little or no inhibitory effect on degradation of TOL. When AC was added and degraded together with TOL, the degradation rate of TOL remained almost unchanged with slight fluctuations in the range of 75.3 ± 1.0% as the ratio of added AC increased. However, TOL significantly inhibited the degradation of EA and AC, and more seriously on AC. When the ratio of added TOL increased, the degradation rates of EA or AC changed from 41.1% or 34.5% to 29.8% or 12.2%, which were 11.3% or 22.3% reduced respectively. It is indicated that there was a mutual inhibitory effect between the AC and EA when they were degraded together, and a stronger inhibitory effect of EA on AC was observed. When the ratio of added AC to EA changed from 0:1 to 3:1, the degradation rate of EA decreased by 9.5%, from 49.8% to 40.3%. When the ratio of added EA to AC changed from 0:1 to 3:1, the degradation rate of AC decreased by 16.0%, from 37.9% to 21.9%.

Piezoelectric and elastic properties of Al0.60Sc0.40N thin films deposited on patterned metal electrodes

Sc-doped aluminum nitride (AlScN) allows for piezoelectric devices with large electromechanical coupling and the benefits increase with larger Sc doping in the film. However, with a larger Sc concentration, the process window narrows, and it is necessary to fine-tune the deposition parameters to achieve a good film. In this paper, we investigate depositions of highly doped AlScN (40% Sc) on unpatterned and patterned metal layers, to show how it is possible to maintain a good film quality on a metal electrode. We find how high-temperature deposition of the metal improves the AlScN film quality, how the gas mixture allows to reduce defects, and how film quality changes with thickness. We show that extreme care must be taken in the apparently trivial step of photoresist cleaning. Finally, we extract the mechanical, electrical, and piezoelectric properties of our optimized layer from a batch of fabricated resonators, obtaining a 5× improvement of piezoelectric coupling compared to undoped AlN and a 1.5× improvement from 32% doped AlScN.

Sensitive Detection of OCS Using Thermal Conversion Combined with Spectral Reconstruction Filtering Differential Optical Absorption Spectroscopy.

Carbonyl sulfide (OCS) is a toxic gas produced during industrial processes that poses risks to both human health and industrial equipment. Therefore, detecting OCS concentrations plays a crucial role in early hazard warning. This paper presents an online system for detecting OCS at the ppb level using thermal conversion and spectral reconstruction filtering differential optical absorption spectroscopy (SRF-DOAS). First, OCS, which is not suitable for DOAS due to its weak absorption characteristics, is completely transformed into SO2 with strong absorption characteristics under high-temperature conditions. Then, the spectral reconstruction filtering method (SRF) is proposed to eliminate the noise and interference. The core idea of the method is to arrange the spectrum according to the spectral intensity from small to large rather than wavelength, reconstructing the spectrum into a new spectrum with linear characteristics. The reconstructed spectrum can remove noise and interference by linear fitting and retain the characteristic of SO2 oscillation absorption. Next, we demonstrate the ability of the reconstructed spectral method to remove noise and interference by comparing the spectra of the inverse-reconstructed gas mixture and SO2. The relative deviation of 0.88% at 100 ppb and detection limit of 7.26 ppb*m for OCS were obtained using the SRF-DOAS method. Finally, the reliability of the system was confirmed by measurements of OCS concentrations in mixture gas of OCS and air, as well as in human exhaled breath.

Efficient detection of nitric oxide a biomarker associated with COVID19 via N, P co-doped C60 fullerene: a computational study.

Coronavirus (COVID-19) is a novel respiratory viral infection, causing a relatively large number of deaths especially in people who underly lung diseases such as chronic obstructive pulmonary and asthma, and humans are still suffering from the limited testing capacity. In this article, a solution is proposed for the detection of COVID-19 viral infections through the analysis of exhaled breath gasses, i.e., nitric oxide, a prominent biomarker released by respiratory epithelial, as a non-invasive and time-saving approach. Here, we designed a novel and low-cost N and P co-doped C60 fullerene-based breathalyzer for the detection of NO gas exhaled from the respiratory epithelial cells. This breathalyzer shows a quick response to the detection of NO gas by directly converting NO to NO2 without passing any energy barrier (0kcal/mol activation energy). The recovery time of breathalyzer is very short (0.98 × 103s), whereas it is highly selective for NO sensing in the mixture of CO2 and H2O gasses. The study provides an idea for the synthesis of low-cost (compared to previously reported Au atom decorated nanostructure and metal-based breathalyzer), efficient, and highly selective N and P co-doped C60 fullerene-based breathalyzer for COVID-19 detection. The geometries of N and P-doped systems and gas molecules are simulated using spin-polarized density functional theory calculations.

Simultaneous Reconstruction of Gas Concentration and Temperature Using Acoustic Tomography.

Acoustic tomography utilizes sensor arrays to collect sound wave signals, enabling non-contact measurement of physical parameters within an area of interest. Compared to optical technologies, acoustic tomography offers the advantages of low cost, low maintenance, and easy installation. Current research in acoustic tomography mainly focuses on reconstruction algorithms for temperature fields, while monitoring the composition and concentration of gases is significant for ensuring safety and improving efficiency, such as in scenarios like boiler furnaces and aviation engine nozzles. In excitable gases, the speed of sound exhibits an S-shaped curve that changes with frequency, a characteristic that could be potentially useful for acoustic tomography. Therefore, this study primarily discusses the quantitative calculation of gas concentration and temperature based on the dispersion of the speed of sound. By employing graphic processing and pattern matching methods, a coupled relationship of the dispersion of the speed of sound with gas concentration and temperature is established. The projection intersection method is used to calculate the concentration and temperature of binary and ternary gas mixtures. Combined with the inversion method, a joint reconstruction method for gas concentration fields and temperature fields based on the dispersion of the speed of sound is developed. The feasibility of the proposed simultaneous reconstruction method for temperature and concentration fields is validated using numerical simulations. Additionally, an acoustic tomography experimental system was set up to conduct reconstruction experiments for binary gas concentration fields and temperature fields, confirming the effectiveness of the proposed method.

On the CO2 Harvesting from N2 Using Grazyne Membranes.

Separation of carbon dioxide (CO2) from nitrogen (N2) is central to any global warmingremediation technology aimed at reducing atmospheric CO2 content. Chemicalmembranes designed to differentially permeate both molecules are appealing due totheir simple use, being environmentally friendly, with high surface areas, compact,easy to maintain and cost-effective, still, the field is growing due to the difficulties inCO2/N2 separation. The present study poses grazynes, two-dimensional stripe-basedC-based materials with sp and sp2 C atoms, as suited membranes for CO2/N2separation. The combination of density functional theory and molecular dynamicssimulations allow tackling the energetics, kinetics, and dynamics of the membraneeffectiveness of pore-engineered grazynes in a holistic fashion. The explored grazynesare capable of physisorbing CO2 and N2, thus avoiding material poisoning bymolecular decoration, while the diffusion of CO2 through the pores is found to be rapid,yet easier than that of N2, in the rate order of the s-1 in the 100-500 K temperaturerange. In particular, low-temperature CO2 separation even for CO2 contents below0.5% are found for [1],[2]{2}-grazyne when controlling the membrane exposure contactto the gases mixture, paving the way for exploring and using grazynes for air CO2remediation.