Garnet Clinopyroxenite Research Articles

Garnet clinopyroxenite formation via amphibole-dehydration in continental arcs: Evidence from Fe isotopes

Lower-crustal garnet clinopyroxenite (sometimes termed “arclogite”) fractionation in thick-crustal (>35 km) arc settings presents a compelling model to explain Fe-depletion trends, high oxygen fugacity, and evidence of recent delamination observed in many continental arcs. However, the origin of the garnet clinopyroxenites via igneous or metamorphic processes remains unclear. Due to the preferential incorporation of light Fe isotopes in garnet relative to clinopyroxene or amphibole, Fe isotopes are ideally suited for studying the effects of garnet fractionation on magmatic systems. Here, we present whole-rock and mineral Fe isotope data from a suite of lower to mid/upper-crustal Andean xenoliths from Mercaderes, Colombia. This data is combined with petrography, major and trace element mineral and whole-rock chemistry, geothermobarometry, and thermodynamic modeling to explore the xenoliths' petrogenesis and the Northern Andes' crustal structure. Whole-rock samples display a narrow range of Fe isotope compositions (δ56Fe = –0.02 to +0.11 ‰), which do not correlate with lithology, chemistry, or pressure-temperature conditions. This result is inconsistent with previous studies predicting the existence of an isotopically light Fe reservoir in the garnet-rich lower Andean crust. Through thermodynamic modeling, we show that the lack of isotopic fractionation in the Mercaderes xenoliths is more consistent with the suite representing a prograde metamorphic sequence, in which amphibole dehydration reactions drive metamorphism of mid/upper-crustal diorite protoliths. While our data do not preclude the presence of garnet clinopyroxenite cumulates at the base of the Andean crust, or that the delamination of such cumulates played an important role in the evolution of the Andes, they do indicate that not all garnet clinopyroxenites are cumulate in origin. Instead, the lower Andean crust represents an amalgamation of igneous and metamorphic rock, with metamorphism of mid-crustal lithologies and partial melting of mafic cumulate roots acting in tandem to drive densification and delamination of the lower crust in a self-feeding mechanism.

Metasomatic Interaction of Ultramafic Mantle Xenoliths with their Felsic HP–UHT Granulite Host (Moldanubian Domain, Bohemian Massif in Lower Austria)

Abstract The St. Leonhard granulite massif in Lower Austria, dominantly formed by kyanite-bearing felsic granulite, encloses countless up to 5 cm sized mantle xenoliths of garnet clinopyroxenite and peridotite. The mineralogical, textural and chemical consequences of a mutual metasomatic interaction at the contact between these xenoliths and the host orthopyroxene-bearing felsic granulite are described. Movement of Mg, Al and, especially, Ca from the garnet clinopyroxenite to the granulite and migration of K and Na in the opposite direction, caused the breakdown of clinopyroxene and formation of orthopyroxene–plagioclase symplectite coronae at the expense of the garnet clinopyroxenite xenoliths. Around the peridotite xenoliths, monomineralic orthopyroxene coronae have developed due to the supply of Si from the host granulite. The P–T conditions of this interaction were established to 900°C to 1000°C and 1.0 to 1.2 GPa by thermodynamic modelling. The duration of coronae growth was constrained to 13 to 532 ka based on modelling of Fe–Mg interdiffusion underlying secondary compositional zoning of garnet from the garnet clinopyroxenite xenolith extending to the coronae. The most significant change in the host granulite was caused by the supply of Ca from the garnet clinopyroxenite xenolith, which led to the breakdown of the Al2SiO5 phase—probably kyanite—and stabilization of orthopyroxene. K-feldspar-poor haloes surrounding mantle xenoliths formed due to the depletion of K in the granulite adjacent to the garnet clinopyroxenite. The observed origin of felsic–intermediate orthopyroxene-bearing granulite by transformation of felsic kyanite-bearing granulite through the metasomatic interaction with mantle xenoliths implies that the deep crustal chemical exchange between mantle- and crust-derived lithologies may have an important consequences on composition, thermal structure and geodynamic evolution of orogenic lower crust especially in hot collisional orogens, such as the European Variscides.

Zirconium stable isotope fractionation during intra-crustal magmatic differentiation in an active continental arc

Zirconium (Zr) stable isotope variations occur among co-existing Zr-rich accessory phases as well as at the bulk-rock scale, but the petrologic mechanism(s) responsible for Zr isotope fractionation during magmatic differentiation remain unclear. Juvenile magma generation and intra-crustal differentiation in convergent continental margins may play a crucial role in developing Zr isotope variations, and the Northern Volcanic Zone of the Andes is an ideal setting to test this hypothesis. To investigate the influence of these processes on Zr stable isotope compositions, we report δ94/90ZrNIST of whole rock samples from: 1) juvenile arc basalts from the Quaternary Granatifera Tuff, Colombia; 2) lower crust-derived garnet pyroxenites (i.e., arclogites), hornblendites, and gabbroic cumulates found in the same unit; and 3) felsic volcanic products from the Doña Juana Volcanic Complex, a dacitic composite volcano in close proximity to and partially covering the Granatifera Tuff. The basalts have δ94/90ZrNIST values ranging from −0.025 ± 0.018 ‰ to +0.003 ± 0.015 ‰ (n = 8), within the range of mid-ocean ridge basalts. The dacites have δ94/90ZrNIST values ranging from +0.008 ± 0.013 ‰ to +0.043 ± 0.015 ‰ (n = 14), slightly positive relative to the Granatifera and mid-ocean ridge basalts. In contrast, the (ultra)mafic cumulates have highly variable, predominantly positive δ94/90ZrNIST values, ranging from −0.134 ± 0.012 ‰ to +0.428 ± 0.012 ‰ (n = 15). Individual grains and mineral fractions of major rock-forming phases, including garnet (n = 21), amphibole (n = 9), and clinopyroxene (n = 18), were analyzed from 8 (ultra)mafic cumulates. The mineral fractions record highly variable Zr isotopic compositions, with inter-mineral fractionation (Δ94/90Zrgarnet-amphibole) up to 2.067 ‰. Recent ab initio calculations of Zr–O bond force constants in rock-forming phases predict limited inter-mineral Zr isotope fractionation in high-temperature environments, suggesting that the large fractionations we observe are not the product of vibrational equilibrium processes. Instead, we propose a scenario in which large Zr isotopic fractionations develop kinetically, induced by sub-solidus Zr diffusion between coexisting phases via changes in Zr distribution coefficients that arise from changes in temperature. Altogether, Zr isotope variability in this calc-alkaline continental arc setting exhibits no correlation with indices of magmatic differentiation (e.g., Mg#, SiO2), and is not a simple function of fractional crystallization. Furthermore, the garnet clinopyroxenite cumulates studied here represent density-unstable lower arc crust material; consequently, material with isotopically variable δ94/90Zr can be recycled into the mantle as a consequence of lower crustal foundering.

Probing the deep mantle wedge in an active subduction zone: Xenoliths from the Mercaderes Volcanic District, Southern Colombia

In subduction zones, the mantle wedge is the domain where liquid phases released by the oceanic subducting plates cause mantle hydration, metasomatism, and partial melting, producting the arc crust. However, direct petrologic information on mantle wedges overlying active subduction zones remains scarce. Here we constrain key aspects of the petrological evolution of the supra-subduction mantle underneath the active volcanic district of Southern Colombia (Mercaderes) by studying a unique suite of peridotite and pyroxenite xenoliths hosted by andesites and lamprophyres. These garnet-bearing peridotite, websterite, clino- and orthopyroxenite xenoliths equilibrated between 2.5 and 4 GPa and 1100–1200 °C. The studied rocks display considerable heterogeneity in terms of lithotypes, textures, mineral abundance and extent of metasomatic overprint. Most samples display fine-grained mylonitic textures overprinting coarse-grained peridotite and garnet pyroxenite precursors; the EBSD study of undeformed garnet websterite samples suggests crystallization from melts and/or melt-rock reaction processes. Modal enrichment in clinopyroxene as well as in the alkalis and LREE contents in some garnet peridotite implies interaction with alkaline basaltic melts, whereas enrichment in silica, Pb and Sr in the garnet-bearing orthopyroxenites records interaction with metasomatic, slab-derived liquids. Some garnet clinopyroxenite xenoliths display marked positive Sr anomalies and minor Eu anomalies, indicating derivation of these rocks from Mg-rich, plagioclase-bearing (and garnet-absent) low-pressure cumulates. Their equilibration in the garnet field implies that after crystallization these clinopyroxenites were transported to deeper levels in the mantle, as the result of foundering into the mantle of the dense arc roots, as already documented in Mercaderes and elsewhere in the Andes. In conclusion, the Mercaderes xenoliths probe a heterogeneous and chemically active domain of the Colombian mantle wedge, where deep sinking lower crustal rocks, melt metasomatism by distinct venues of chemically different melts, and deformation predate fast exhumation by volatile-rich melts.

Late Cretaceous bimodal volcanic rocks in Shuanghu induced by lithospheric delamination beneath the Southern Qiangtang, Tibet

The southern Qiangtang (SQT) in central Tibet is characterized by sporadic Late Cretaceous magmatic rocks whose petrogenesis and tectonic implications remain unclear. Here, new zircon UPb ages and Hf isotope compositions, together with whole-rock element and isotope data have been collected for the Duoma volcanic rocks from the SQT, central Tibet. Zircon UPb dating indicates that the Duoma volcanic rocks crystallized at ca. 98 Ma. The basalts of the Duoma volcanic rocks have low SiO2 (51.49–53.36 wt%), high total alkalis (4.65–6.25 wt%), and display OIB-like isotopic signatures (87Sr/86Sr)i = 0.7051 to 0.7058, εNd(t) = +0.04 to +1.10), overall similar to intra-plate alkali basalts. Moreover, basalts exhibit slight depletion of high-field-strength elements (HFSEs; e.g., Nb, Ta, and Ti), but enrichment of light rare earth (LaN/YbN = 6.7–7.6) with no negative Eu anomalies (Eu/Eu* = 0.91–0.99). These geochemical features, together with their high La/Nb (1.56–1.70) and Zr/Hf (44.70–45.87) but low La/Ba (0.08–0.09) and Ca/Al (0.43–0.65) ratios, suggest that the Duoma basalts originated from partial melting of garnet clinopyroxenite that was metasomatized by depleted mantle-derived melts. The coexisting rhyolites have high SiO2 (69.78–69.92 wt%) and exhibit significant enrichment in large-ion lithophile elements (LILEs) and depletion in HFSEs (Nb, Ta, and Ti). Furthermore, the Duoma rhyolites are characterized by the decoupled Nd (εNd(t) values ranging from −4.4 to −11.1) and Hf (ɛHf(t) values ranging from −0.7 to +2.7) compositions, that character indicates that they were probably derived from the partial melting of the lower continental crust. The compositional bimodality and heterogeneous source of the Late Cretaceous volcanism indicate that they were formed in an extension setting, presumably triggered by lithospheric delamination beneath the SQT.

Chromium isotope variations in garnet-facies mantle rocks and their minerals: Implications for Cr isotope behavior in high-temperature processes

Previous work on Cr isotope composition of the lithospheric mantle focused on shallow spinel-facies peridotites and invoked the effects of partial melting and metasomatism. However, little is known on the Cr isotope composition and behavior in the deeper and more voluminous garnet-facies mantle, notably during generation and passage of magmas and fluids. Here, we present Cr isotope data for 26 garnet and ten spinel whole-rock peridotite xenoliths (mainly harzburgites) from the Udachnaya kimberlite on the Siberian craton and minerals from five of them, as well as for minerals of 14 eclogites and four garnet clinopyroxenites from the Dabie orogen in eastern China. Garnet (Gt) and clinopyroxene (Cpx) are major Cr hosts in the mantle. Our ionic modeling suggests the following order of 53Cr/52Cr values in coexisting minerals: garnet ≈ spinel > Cpx > olivine. Cr isotopes are equally partitioned between garnet and Cpx in four peridotites, while garnet is enriched in heavy Cr in one peridotite and all the eclogites (Δ53CrGt-Cpx 0.01‰ to 0.27‰, av. 0.10‰), but depleted in heavy Cr in the pyroxenites (Δ53CrGt-Cpx −0.03‰ to −0.16‰, av. −0.10‰). The Δ53CrGt-Cpx variations are attributed to effects of chemical composition, equilibration temperature and oxygen fugacity on equilibrium Cr isotope fractionation. Further, the anomalous Δ53CrGt-Cpx values in the Dabie pyroxenites and one peridotite may indicate disequilibrium inter-mineral isotope fractionation via kinetic diffusion during phase transitions as a result of pressure-temperature (P-T) changes and metasomatism.The whole-rock δ53Cr range in the garnet peridotites (−0.27 to 0.13‰; average −0.08 ± 0.18‰, 2 SD, n = 25, excluding an outlier with −0.86‰) overlaps bulk silicate Earth estimates whereas the spinel peridotites tend to have higher δ53Cr (−0.12 to 0.16‰; av. 0.02 ± 0.20‰, 2 SD, n = 10). While these rocks are residues of high degrees (30–40%) of melt extraction, their range contrasts with limited equilibrium Cr isotope fractionation we calculated for melting residues of both spinel and garnet peridotites (Δ53Crresidue-source < 0.03‰). The δ53Cr values in the spinel peridotites show correlations with modal abundances of Cpx, garnet and spinel, as well as major and trace element composition. We posit that the Cr isotope variations in these peridotites are somehow linked to solid–melt and inter-mineral diffusive exchanges during P-T changes, deformation and ingress of metasomatic media previously documented in the Udachnaya peridotites. The average δ53Cr value (−0.09 ± 0.16‰, 2 SD, n = 31) for garnet peridotites (excluding U9) in this and previous studies is similar to those previously obtained for (mainly off-craton) spinel peridotites and komatiites, and appears to be representative of the Cr isotope composition for bulk mantle. Numerical modeling for mantle magmas derived at different depths and by different melting degrees of garnet and spinel peridotites and eclogites yields a narrow δ53Cr range, possibly affected by oxygen fugacity.

Xenoliths of High-Alumina Pyroxenites in the Basalts of the Sigurd Volcano, Spitsbergen Island (Svalbard Archipelago), as Indicators of the Paleozoic Geodynamics of the Regional Lithosphere

Abstract—Xenoliths of high-alumina pyroxenites in the Quaternary basalts of the Sigurd Volcano of West Spitsbergen are spinel and spinel–garnet clinopyroxenites, spinel–garnet websterites, and websterites. The granoblastic texture with relics of subhedral magmatic texture, the change of mineral assemblages, and the signs of partial melting in the xenoliths reflect their multistage formation. The goal of our study was to determine the sequence and thermodynamic conditions of the change of mineral assemblages and to establish their age by Re–Os, U–Pb, Sm–Nd, and Rb–Sr isotope dating. It has been established that the primary assemblage in the pyroxenites, which included high-alumina Opx, Cpx, and Spl, was transformed in several stages: (1) Spl→Grt replacement with the formation of garnet-containing websterites and clinopyroxenites, (2) development of kelyphitic Opx–Spl rims over Grt grains, (3) formation of Amph, (4) exsolution with the formation of Cpx and Opx, and (5) partial melting. Comparison of the obtained results with published data shows that the primary assemblage is similar in Al2O3/MgO ratio to Opx + Cpx ± Spl cumulates resulted from the crystallization of basaltic melts at 1.2 GPa and the degree of crystallization of ~15%, i.e., in the lower crust (at 2.0 GPa, Grt and Cpx crystallize from the solution). The equilibrium parameters of the Grt–Opx assemblage in the pyroxenites are 1060–1310 ºC and 2.2–3.3 GPa; in the P–T diagram, their points are localized below the Spl→Grt phase transition curve, in the system CaO–MgO–Al2O3–SiO2, thus corresponding to the model continental geotherm with a surface heat flow density of 60 mV/m2 and somewhat higher. This indicates the Spl→Grt replacement and the formation of garnet-containing pyroxenites in the shallow-depth upper mantle. The formation of kelyphitic Opx–Spl rims over the Grt grains indicates a subsequent temperature and pressure decrease to values above the Grt→Spl phase transition curve. This is confirmed by the presence of exsolution structures in pyroxene, which formed when the temperature decreased by 100–150 ºC. The Re and Os isotope composition in the bulk samples of Spl–Grt websterites that did not undergo partial melting corresponds to an age of 457.0 ± 3.5 Ma, which reflects the time of transformation of the primary Cpx–Opx–Spl assemblage into a garnet-including one. A similar value (488.6 ± 5.9 Ma) was obtained by U–Pb dating of zircon from Spl–Grt websterite, also without signs of melting. Zircon crystals from Spl–Grt clinopyroxenite with clear signs of partial melting have typomorphic features of autochthonous magmatic zircons. They form a single age cluster of 310.7 ± 3.3 Ma, which marks the age of melt crystallization in the pyroxenites. Thus, Spl pyroxenites are, most likely, Opx + Cpx ± Spl cumulates, products of crystallization of basaltic melts in the lower crust. The subsequent Spl→Grt replacement and the formation of garnet-containing websterites and clinopyroxenites in the shallow-depth upper mantle can be regarded as an indicator of the delamination of the continental crust into the mantle, and the Re–Os isochron date of 457.0 ± 3.5 Ma is the most likely upper age bound of the crust delamination into the mantle. The subsequent uplifting of the Spitsbergen lithosphere, which was expressed as the formation of kelyphitic Opx–Spl rims over garnet, exsolution in pyroxene, and partial melting, was not far in time from the delamination stage and lasted ≤ 300 Ma.

Petrogenesis of Garnet Clinopyroxenite and Associated Dunite in Hujialin, Sulu Orogenic Belt, Eastern China

The origin of ultramafic rocks, especially those in suture zones, has been a focus because they are not only important mantle sources of magma, but also provide substantial information on metamorphism and melt/fluid–peridotite interaction. Ultramafic rocks in Hujialin, in the central part of the Sulu orogen, include peridotite and pyroxenite. Although many papers on their origin and tectonic evolution have been published in the past few decades, these questions are still highly debated. Here, we present mineralogy, mineral composition, and bulk-rocks of these ultramafic rocks to evaluate their origin and tectonic evolution. The garnet clinopyroxenite is low in heavy rare-earth elements (HREE, 5.97–10.6 ppm) and has convex spoon-shaped chondrite-normalized REE patterns, suggesting the garnet formed later, and its precursor is clinopyroxenite. It is high in incompatible elements (i.e., Cs, Rb, Ba) and shows negative to positive U, Nb, and Ta anomalies, without pronounced positive Sr or Eu anomalies. Clinopyroxene in garnet clinopyroxenite contains high MgO (Mg# 0.90–0.97). The mineral chemistry and bulk-rock compositions are similar to those of reactive clinopyroxenite, suggesting that it originally formed via peridotite–melt interaction, and that such silicic and calcic melt might derive from the subducted Yangtze continent (YZC). Dunite contains olivine with high Fo (93.0–94.1), low NiO (0.11–0.29 wt.%) and MnO (≤0.1 wt.%), chromite with high Cr# (0.75–0.96), TiO2 (up to 0.88 wt.%), and Na2O (0.01–0.10 wt.%). It has negatively sloped chondrite-normalized REE patterns. Mineral chemistry and bulk rocks suggest dunite likely represent residual ancient lithosperic mantle peridotite beneath the North China Craton (NCC) that was overprinted by aqueous fluids. The lack of prograde and retrograde metamorphic minerals in dunite and irregular shaped mineral inclusions in chromite suggest dunite did not subduct to deep levels. Dunite mingled with garnet clinopyroxenite during exhumation of the latter at shallow depths. These ultramafic rocks, especially hydrated peridotite, may be important sources of Au for the Jiaodong gold province in the NCC.

High‐pressure granulite facies re‐equilibration and zoisite–biotite dehydration melting during decompression of an ultrahigh‐pressure garnet clinopyroxenite from the island of Fjørtoft, Norway

AbstractA garnet clinopyroxenite from the island of Fjørtoft, Western Gneiss Region (WGR) in Norway, has experienced a complex metamorphic evolution demonstrated by studies involving petrographic observations, mineral chemistry, phase equilibria modelling and geothermobarometry. This rock, originally an eclogite, documents ultrahigh‐pressure (UHP) conditions higher than 3.5 GPa (Stage 1), witnessed by Ca‐rich garnet inclusions in kyanite. The UHP assemblage was pervasively re‐equilibrated at high‐pressure (HP) granulite facies conditions around 1.75 GPa and 870°C, during which and/or somewhat before Ca‐poor garnet, sodian diopside, zoisite and biotite formed (Stage 2a). Dehydration melting of zoisite and biotite (Stage 2b) took place at similar pressure–temperature conditions. The produced melt was poor in Si and rich in alkalis and crystallized mainly to analcime + plagioclase + K‐feldspar. Oriented composite inclusions of quartz + amphibole + phengite ± garnet, found in clinopyroxene, are interpreted to have resulted from interaction between a fluid (hydrous melt and/or aqueous fluid) and clinopyroxene at the early retrogression Stage 3. Stage 1 resulted from deep subduction of the rock. Stage 2 followed after early exhumation probably due to stagnation at a hot and thickened orogenic root. Consequently, other HP granulite facies metabasites, which are similar to the studied garnet clinopyroxenite and widespread in the northwestern WGR, could have been transformed from former eclogite at this stage, too. In addition, this study provides a direct link between the generation of peralkaline melts and crustal anatexis in collision zones and new insights into the retrograde formation of oriented mineral inclusions in HP‐UHP minerals.

Sulphide Petrology and Contribution of Subducted Sulphur in Diamondiferous Garnet-Bearing Pyroxenites from Beni Bousera (Northern Morocco)

Abstract This paper explores the unusual sulphide–graphite association of a selection of Beni Bousera garnet clinopyroxenites that initially equilibrated within the diamond stability field. Compared with common graphite-free garnet pyroxenites analysed so far, these rocks display tenfold S enrichment with concentrations up to 5550 μg g–1. Fe–Ni–Cu sulphides (up to 1·5 wt%) consist of large (up to 3 mm across), low-Ni pyrrrhotite (&amp;lt;0·1 wt% Ni) of troilite composition, along with volumetrically minor chalcopyrite and pentlandite. Such assemblages are interpreted as low-temperature (&amp;lt;100 °C) subsolidus exsolution products from homogeneous monosulphide solid solution. Troilite compositions of the pyrrhotite indicate strongly reducing conditions that are estimated to be slightly above the iron–wüstite (IW) buffer. Bulk-sulphide compositions are closer to the FeS end-member (i.e. Cu- and Ni-depleted) than other sulphide occurrences in mantle-derived pyroxenites described so far. Moreover, troilite contains trace metal microphases (Pb and Ag tellurides, molybdenite) that have never been reported before from mantle-derived garnet pyroxenites but occur in diamond-hosted eclogitic sulphide inclusions. Beni Bousera sulphides also show strong similarities to diamond-hosted sulphide inclusions of eclogitic affinity for a wide range of chalcophile–siderophile trace element contents. In view of the widespread molybdenite exsolution, coupled with Mo and S/Se/Te systematics of sulphide compositions (7872 &amp;lt; S/Se &amp;lt; 19 776; 15 &amp;lt; Se/Te &amp;lt; 31), black-shale pyrite is a potential sedimentary component to contribute to the petrogenesis of Beni Bousera garnet clinopyroxenites. Black shales would have recycled along with cumulates from the oceanic crust in the mantle source of Beni Bousera pyroxenites. Pyrite underwent desulfidation and replacement by troilite during subduction and prograde metamorphism, releasing its fluid-mobile elements (As, Sb, Pb) while suffering minimum S loss because of the strongly reduced conditions. Taken as a whole, our body of data supports a common origin for carbon (−27 ‰ &amp;lt; δ13C &amp;lt; −17 ‰) and sulphur and concomitant formation of diamond and sulphides. Both elements were delivered by an extraneous sedimentary component mixed with the altered oceanic crust rocks that was involved in the genesis of Beni Bousera garnet pyroxenites, prior to a Proterozoic partial melting event.

Deep subduction and exhumation of micro-continents in the Proto-Tethys realm: Evidence from metamorphism of HP-UHT rocks in the North Qinling Orogen, central China

The North Qinling Orogen in central China contains a typical continental high- and ultrahigh-pressure (HP-UHP) metamorphic belt, but its metamorphic evolution remains controversial. We report a combined investigation on petrology, geochronology and phase modelling for felsic granulite (samples SN1504 & SN1517) and garnet clinopyroxenite (sample SN1505) from the Songshugou area. Four stages of metamorphic evolution are constrained: (i) A possible prograde from HP amphibolite facies to peak UHP eclogite facies stage (~3–8 GPa/700–1080 °C) recorded by the chemical zoning of garnet core and mantle in sample SN1504 and also the presence of supersilicic titanite in sample SN1505. (ii) A post-peak decompression evolution is recorded by the formation of coronary garnet and plagioclase around kyanite in sample SN1504 and high-Ti amphibole and plagioclase in sample SN1505, including the evolution from eclogite facies to HP–ultrahigh temperature (UHT) conditions of 1.3–2.2 GPa/900–980 °C for sample SN1504 and 1.0–2.1 GPa/960–1010 °C for SN1505, respectively. (iii) Further decompression is revealed from the growth of corundum + spinel in local domains in sample SN1504, suggesting a low-pressure (LP) condition of ~0.8 GPa/950 °C. (iv) A subsequent cooling evolution is recorded by thin films of K-feldspar + quartz + biotite in sample SN1504 and low-Ti amphibole in sample SN1505, indicative of melt crystallization towards the solidus with conditions of 830–770 °C/0.55–0.8 GPa and 880–820 °C/0.8–0.9 GPa, respectively. Zircon and monazite U-Pb dating yields three metamorphic ages of c. 521 Ma, c. 503 Ma and c. 500–480 Ma, which are interpreted to represent the prograde HP amphibolite facies stage, the peak eclogite facies stage and the late cooling stage, respectively. The metamorphic P–T–t path suggests a complete history of deep continental subduction to depths of >90–250 km, followed by rapid exhumation to crustal depths for the Qinling micro-continent during the early Proto-Tethys evolution.

Ultra-High Pressure Metamorphism and Geochronology of Garnet Clinopyroxenite in the Paleozoic Dunhuang Orogenic Belt, Northwestern China

Ultra-high pressure (UHP) metamorphism is recorded by garnet clinopyroxenite enclaves enclosed in an undeformed, unmetamorphosed granitic pluton, northeastern Paleozoic Dunhuang orogenic belt, northwestern China. The protoliths of the garnet clinopyroxenite might be basic or ultrabasic volcanic rocks. Three to four stages of metamorphic mineral assemblages have been found in the garnet clinopyroxenite, and clockwise metamorphic pressure–temperature (P-T) paths were retrieved, indicative of metamorphism in a subduction environment. Peak metamorphic P-T conditions (790–920 °C/28–41 kbar) of garnet clinopyroxenite suggest they experienced UHP metamorphism in the coesite- or diamond-stability field. The UHP metamorphic event is also confirmed by the occurrence of high-Al titanite enclosed in the garnet, along with at least three groups of aligned rutile lamellae exsolved from the garnet. Secondary ion mass spectrometry (SIMS) U-Pb dating of metamorphic titanite indicates that the post-peak, subsequent tectonic exhumation of the UHP rocks occurred in the Devonian period (~389–370 Ma). These data suggest that part of the Paleozoic Dunhuang orogenic belt experienced UHP metamorphism, and diverse metamorphic facies series prevailed in this Paleozoic orogen. It can be further inferred that most of the UHP rocks in this orogen remain buried.

Ultra-high pressure metamorphism and geochronology of gar-net clinopyroxenite in the Paleozoic Dunhuang Orogenic Belt, northwestern China

Ultra-high pressure metamorphism and geochronology of gar-net clinopyroxenite in the Paleozoic Dunhuang Orogenic Belt, northwestern China

In search for the missing arc root of the Southern California Batholith: P-T-t evolution of upper mantle xenoliths of the Colorado Plateau Transition Zone

Xenolith and seismic studies provide evidence for tectonic erosion and eastward displacement of lower crust-subcontinental mantle lithosphere (LC-SCML) underlying the Mojave Desert Region (i.e. southern California batholith (SCB)). Intensified traction associated with the Late Cretaceous flattening of the subducting Farallon plate, responsible for deforming the SW U.S., likely played a key role in “bulldozing” the tectonically eroded LC-SCML ∼500 km eastwards, to underneath the Colorado Plateau Transition Zone (CPTZ) and further inboard. The garnet clinopyroxenite xenoliths from two CPTZ localities, Chino Valley and Camp Creek (central Arizona), provide a rare glimpse of the material underlying the CPTZ. Thermodynamic modeling, in addition to major and trace element thermobarometry, suggests that the xenoliths experienced peak conditions of equilibration at 600-900°C and 12-28 kbar. These peak conditions, along with the composition of the xenoliths (type “B” garnet and diopsidic clinopyroxene) strongly suggest a continental arc residue (“arclogite”), rather than a lower plate subduction (“eclogite”), origin. A bimodal zircon U-Pb age distribution with peaks at ca. 75 and 150 Ma, and a Jurassic Sm-Nd garnet age (154 ± 16 Ma, with initial εNd value of +8) overlaps eastern SCB pluton ages and suggests a consanguineous relationship. Cenozoic zircon U-Pb ages, REE geochemistry of zircon grains, and partially re-equilibrated Sm-Nd garnet ages indicate that displaced arclogite remained at elevated PT conditions (>700°C) for 10s of Myr following its dispersal until late Oligocene entrainment in host latite. With a ∼100 Myr long thermal history overlapping that of the SCB and the CPTZ, these assemblages also contain evidence for late-stage hydration (e.g. secondary amphibole), potentially driven by de-watering of the Laramide slab.In light of these results, we suggest that the CPTZ arclogite originates from beneath the eastern half of the SCB, where it began forming in Late Jurassic time as mafic keel to continental arc magmas. The displacement and re-affixation of the arclogites further inboard during the Late Cretaceous flat slab subduction, might have contributed to the tectonic stability of the Colorado Plateau relative to adjacent geologic provinces through Laramide time and likely preconditioned the region to Cenozoic tectonism, e.g. present-day delamination beneath the plateau, high-magnitude extension and formation of metamorphic core complexes.

Eclogite and Garnet Pyroxenite Xenoliths from Kimberlites Emplaced Along the Southern Margin of the Kaapvaal Craton, Southern Africa: Mantle or Lower Crustal Fragments?

Abstract Eclogite xenoliths, together with garnet pyroxenites and some mafic garnet granulites, found in kimberlites located along the southern margin of the Kaapvaal craton in southern Africa have been analysed by electron microprobe and mass spectrometry techniques to determine their geochemical characteristics. The majority of eclogites are bimineralic with garnet and omphacitic clinopyroxene in subequal proportions, with rutile as the main accessory phase; a few contain kyanite. Based on K2O in clinopyroxene and Na2O in garnet, the eclogites can be classified as Group II eclogites, and the majority are high-Ca in character. Garnet pyroxenites comprise garnet clinopyroxenites and garnet websterites. Major and trace element concentrations and isotope ratios of reconstituted bulk rock compositions of the eclogites and garnet pyroxenites allow constraints to be placed on depth of origin and likely protolith history. Calculated Fe–Mg exchange equilibration temperatures for the eclogites range from 815 to 1000 °C, at pressures of 1·7 ± 0·4 GPa as determined by REE partitioning, indicating that they were sampled from depths of 50–55 km; i.e. within the lower crust of the Namaqua–Natal Belt. The garnet pyroxenites show slightly lower temperatures (686–835 °C) at similar pressures of equilibration. Initial 143Nd/144Nd and 87Sr/86Sr ratios (calculated to time of kimberlite emplacement) of both lithologies overlap the field for lower crustal samples from the Namaqua–Natal Belt. Further evidence for a crustal origin is found in the similar REE patterns shown by many of the associated garnet granulite xenoliths. Garnet pyroxenites are interpreted to have a similar origin as the associated eclogites but with the mafic protolith having insufficient Na (i.e. low modal plagioclase) to allow for development of omphacitic pyroxene. Metamorphism of the mafic protoliths to these eclogites and garnet pyroxenites is inferred to have occurred during crustal shortening and thickening associated with the collision of the Namaqua–Natal Belt with the Kaapvaal craton at 1–1·2 Ga.

Metamorphic Evolution of Garnet-Bearing Ultramafic Rocks in the Hujialin Area, Sulu Ultrahigh-Pressure Orogenic Belt, Eastern China

The Rizhao Hujialin area is located in the central Sulu ultrahigh-pressure orogenic belt, where garnet clinopyroxenite is exposed in the upper part of an ultramafic rock complex and serpentinized dunite is exposed in its lower part. Based on textural criteria, the garnet clinopyroxenites were divided into three types: Equigranular garnet, porphyroclastic garnet, and megacrystic garnet pyroxenites. The garnet clinopyroxenites have convex-upward chondrite-normalized rare earth element patterns, large positive Pb anomalies, and depletion of high-field-strength elements (e.g., Nb, Zr, and Ti), suggesting a mantle source protolith overprinted by fluid metasomatism. Petrographic, mineral chemistry, phase equilibrium modeling, and zircon U–Pb geochronology data show that the evolutionary stages of the Hujialin garnet clinopyroxenites were as follows: Stage I: formation of the magmatic protoliths; stage II: formation of megacrystic garnet pyroxenite accompanying subduction; stage III: formation of porphyroclastic or equigranular garnet clinopyroxenite with a mineral assemblage of garnet + clinopyroxene + ilmenite + humite accompanying initial exhumation at ~215.0 ± 5.7 Ma; stage IV = progressive cooling and decompression associated with the crystallization of water-bearing minerals such as clinochlore and pargasite at 206 Ma; and Stage V = late epidote amphibolite-facies retrograde metamorphism producing a mineral assemblage of garnet + clinopyroxene + amphibole + chlorite + epidote + ilmenite at ~180–174 Ma associated with fluid activity in shear–tensional fractures and/or pores. The P-T conditions of the peak metamorphism were estimated at 4.5 ± 0.5 GPa and 800 ± 50 °C. Retrograde metamorphism recorded conditions of 1.0 GPa and 710 ± 30 °C during the exhumation and cooling process. The mineral transformation from early high-Al clinopyroxene to garnet and to late diopside records the general metamorphic evolution during subduction and exhumation, respectively. One zircon U–Pb analysis presents the Palaeoproterozoic age of 1817 ± 40 Ma, which is coeval with widespread magmatic and metamorphic events in the North China Craton.

Cryptic metasomatic agent measured in situ in Variscan mantle rocks: Melt inclusions in garnet of eclogite, Granulitgebirge, Germany

AbstractGarnet of eclogite (formerly termed garnet clinopyroxenite) hosted in lenses of orogenic garnet peridotite from the Granulitgebirge, NW Bohemian Massif, contains unique inclusions of granitic melt, now either glassy or crystallized. Analysed glasses and re‐homogenized inclusions are hydrous, peraluminous, and enriched in highly incompatible elements characteristic of the continental crust such as Cs, Li, B, Pb, Rb, Th, and U. The original melt thus represents a pristine, chemically evolved metasomatic agent, which infiltrated the mantle via deep continental subduction during the Variscan orogeny. The bulk chemical composition of the studied eclogites is similar to that of Fe‐rich basalt and the enrichment in LILE and U suggest a subduction‐related component. All these geochemical features confirm metasomatism. In comparison with many other garnet+clinopyroxene‐bearing lenses in peridotites of the Bohemian Massif, the studied samples from Rubinberg and Klatschmühle are more akin to eclogite than pyroxenites, as reflected in high jadeite content in clinopyroxene, relatively low Mg, Cr, and Ni but relatively high Ti. However, trace elements of both bulk rock and individual mineral phases show also important differences making these samples rather unique. Metasomatism involving a melt requiring a trace element pattern very similar to the composition reported here has been suggested for the source region of rocks of the so‐called durbachite suite, that is, ultrapotassic melanosyenites, which are found throughout the high‐grade Variscan basement. Moreover, the Th, U, Pb, Nb, Ta, and Ti patterns of these newly studied melt inclusions (MI) strongly resemble those observed for peridotite and its enclosed pyroxenite from the T‐7 borehole (Staré, České Středhoři Mountains) in N Bohemia. This suggests that a similar kind of crustal‐derived melt also occurred here. This study of granitic MI in eclogites from peridotites has provided the first direct characterization of a preserved metasomatic melt, possibly responsible for the metasomatism of several parts of the mantle in the Variscides.

Decoupling of Lu-Hf and Sm-Nd Isotopic System in Deep-Seated Xenoliths from the Xuzhou-Suzhou Area, China: Differences in Element Mobility during Metamorphism

This paper presents whole-rock Hf isotopic data for a suite of eclogite and garnet clinopyroxenite xenoliths hosted in the Early Cretaceous dioritic intrusions from the Xuzhou-Suzhou area along the southeastern margin of the Eastern Block of the North China Craton (NCC). Six of the eight studied xenolith samples plot significantly above the terrestrial Hf-Nd isotopic array and have eHf(0) value up to +60. All the samples define a well correlated 147Sm/144Nd-143Nd/144Nd age of 2 081 Ma, which is considered to record the granulite-facies metamorphism. In contrast, the Lu-Hf isotope system faithfully records the protolith information. The mineralogical assemblage, especially garnet and/or zircon (rutile to some extent) mainly controlled the decoupling of Hf-Nd isotope. The metamorphic modification on protolith characteristics and the differences in element mobility during metamorphism may also reinforce the observed decoupling between the Sm-Nd and Lu-Hf isotope systems; i.e., the absence of the correlations in eNd-eHf and also 87Sr/86Sr-143Nd/144Nd diagram. The Lu/Hf isochron age of 2 424 Ma is similar to the zircon age peak of the studied xenoliths and the dominant age of NCC basement, indicating that the igneous protolith has an affinity to the Archean basement of the NCC. Furthermore, the positive eHf(t) values at 2 500 Ma indicate a crustal growth event of 2 500 Ma in the NCC.

Granitoid melt inclusions in orogenic peridotite and the origin of garnet clinopyroxenite

Research Article| October 08, 2018 Granitoid melt inclusions in orogenic peridotite and the origin of garnet clinopyroxenite Alessia Borghini; Alessia Borghini 1Institut für Erd- und Umweltwissenschaften, Universität Potsdam, 14476 Potsdam, Germany Search for other works by this author on: GSW Google Scholar Silvio Ferrero; Silvio Ferrero 1Institut für Erd- und Umweltwissenschaften, Universität Potsdam, 14476 Potsdam, Germany2Museum für Naturkunde (MfN), Leibniz-Institut für Evolutions- und Biodiversitätsforschung, 10115 Berlin, Germany Search for other works by this author on: GSW Google Scholar Bernd Wunder; Bernd Wunder 3Helmholtz-Zentrum Potsdam, Deutsches GeoForschungsZentrum (GFZ), D-14473 Potsdam, Germany Search for other works by this author on: GSW Google Scholar Oscar Laurent; Oscar Laurent 4Department of Earth Sciences, Eidgenössische Technische Hochschule (ETH) Zurich, 8092 Zurich, Switzerland Search for other works by this author on: GSW Google Scholar Patrick J. O’Brien; Patrick J. O’Brien 1Institut für Erd- und Umweltwissenschaften, Universität Potsdam, 14476 Potsdam, Germany Search for other works by this author on: GSW Google Scholar Martin A. Ziemann Martin A. Ziemann 1Institut für Erd- und Umweltwissenschaften, Universität Potsdam, 14476 Potsdam, Germany Search for other works by this author on: GSW Google Scholar Author and Article Information Alessia Borghini 1Institut für Erd- und Umweltwissenschaften, Universität Potsdam, 14476 Potsdam, Germany Silvio Ferrero 1Institut für Erd- und Umweltwissenschaften, Universität Potsdam, 14476 Potsdam, Germany2Museum für Naturkunde (MfN), Leibniz-Institut für Evolutions- und Biodiversitätsforschung, 10115 Berlin, Germany Bernd Wunder 3Helmholtz-Zentrum Potsdam, Deutsches GeoForschungsZentrum (GFZ), D-14473 Potsdam, Germany Oscar Laurent 4Department of Earth Sciences, Eidgenössische Technische Hochschule (ETH) Zurich, 8092 Zurich, Switzerland Patrick J. O’Brien 1Institut für Erd- und Umweltwissenschaften, Universität Potsdam, 14476 Potsdam, Germany Martin A. Ziemann 1Institut für Erd- und Umweltwissenschaften, Universität Potsdam, 14476 Potsdam, Germany Publisher: Geological Society of America Received: 25 Jun 2018 Revision Received: 17 Sep 2018 Accepted: 17 Sep 2018 First Online: 08 Oct 2018 Online Issn: 1943-2682 Print Issn: 0091-7613 © 2018 Geological Society of America Geology (2018) 46 (11): 1007–1010. https://doi.org/10.1130/G45316.1 Article history Received: 25 Jun 2018 Revision Received: 17 Sep 2018 Accepted: 17 Sep 2018 First Online: 08 Oct 2018 Cite View This Citation Add to Citation Manager Share Icon Share Facebook Twitter LinkedIn MailTo Tools Icon Tools Get Permissions Search Site Citation Alessia Borghini, Silvio Ferrero, Bernd Wunder, Oscar Laurent, Patrick J. O’Brien, Martin A. Ziemann; Granitoid melt inclusions in orogenic peridotite and the origin of garnet clinopyroxenite. Geology 2018;; 46 (11): 1007–1010. doi: https://doi.org/10.1130/G45316.1 Download citation file: Ris (Zotero) Refmanager EasyBib Bookends Mendeley Papers EndNote RefWorks BibTex toolbar search Search Dropdown Menu toolbar search search input Search input auto suggest filter your search All ContentBy SocietyGeology Search Advanced Search Abstract Granitic melt inclusions were found in layers of garnet clinopyroxenites from orogenic peridotites hosted in high-pressure felsic granulites of the Granulitgebirge, central Europe. The inclusions are both glassy and crystallized, and occur as clusters in the garnet. Microstructural features suggest that the inclusions formed while garnet was growing as a peritectic phase, likely alongside clinopyroxene. The chemistry of the melt, in particular its trace element signature, shows a crustal contribution, probably due to the involvement of phengite in the melt-producing reaction, most likely in the presence of a fluid. The presence of a granitoid melt in mantle rocks may be the result of localized melting of a phengite-bearing protolith either already present in the peridotites or, more likely, within the local deeply subducted crustal units. In the latter case, the melt would have infiltrated the peridotites and generated pyroxenite via metasomatism. In either case, the presence of granitoid inclusions in orogenic peridotite provides direct evidence for a genetic connection between a high-pressure crustal melt and garnet pyroxenites. The in situ characterization of these remnants of natural melt provides direct quantitative constraints on (one of) the agents responsible for the interaction between crust and mantle. You do not have access to this content, please speak to your institutional administrator if you feel you should have access.

Subducted Mg-rich carbonates into the deep mantle wedge

Recent studies have concluded that subducted calcium (Ca-) rich carbonates could be dissolved in slab-derived aqueous fluids and transported upwards into the shallow mantle wedge (75–120 km), while magnesium (Mg-) rich carbonates could be delivered to a greater depth (i.e., the mantle transition zone, ∼410 km), melted, and recycled into the convective upper mantle. However, it remains unknown whether or not Mg-rich carbonates can be transferred to the deep mantle wedge (>∼120 km) by subduction-zone fluids, which, if true, is important for tracing deep carbon. In this paper, we report a comprehensive mineralogical, geochemical, stable (Mg and O) and radiogenic isotopic (zircon U–Pb) study of garnet clinopyroxenites from the Maowu ultra-mafic massif (a slice of the mantle wedge) in the Dabie orogeny, Central China. Whole-rock and mineral trace elemental features and zircon U–Pb ages reveal evidence of mantle wedge metasomatism by a slab-derived melt or supercritical fluid from the subducted rutile-bearing eclogitic Paleo-Tethys oceanic crust, in addition to subsequent metamorphism occurring during the Triassic collision between the South and North China blocks. Combined with the results of previous works, the high Th/U ratios of both whole rocks and metasomatized zircons with no oscillatory zoning lead us to infer that a supercritical liquid rather than a melt was the metasomatic agent during oceanic subduction at peak conditions (5.3–6.3 GPa and ∼800 °C, 160–190 km). Abundant carbonate mineral inclusions (including calcite, dolomite and magnesite) and the high δ18OVSMOW values of the metasomatized zircons (up to 12.2‰) indicate that sedimentary carbonates were leached by the supercritical fluid. Furthermore, whole-rock δ26Mg values (−0.99‰ to −0.65‰) that are lower than normal mantle values (−0.25±0.07‰) imply that the incorporated carbonates contain not only calcites but also a certain amount of dolomites (approximately 1–10 wt.% of the metasomatic supercritical liquid). The dissolved Mg-rich carbonates in the slab-derived supercritical liquid could effectively modify the Mg isotope composition of the deep mantle wedge. Our study represents a critical step towards achieving a broad understanding of the behaviours of recycled carbonate during slab subduction.