Gapless Spin Liquid Research Articles

Entangled unique coherent line in the ground-state phase diagram of the spin-1/2 XX chain model with three-spin interaction.

Entangled spin coherent states are a type of quantum states that involve two or more spin systems that are correlated in a nonclassical way. These states can improve metrology and information processing, as they can surpass the standard quantum limit, which is the ultimate bound for precision measurements using coherent states. However, finding entangled coherent states in physical systems is challenging because they require precise control and manipulation of the interactions between the modes. In this work we show that entangled unique coherent states can be found in the ground state of the spin-1/2 XX chain model with three-spin interaction, which is an exactly solvable model in quantum magnetism. We use the spin squeezing parameter, the l_{1}-norm of coherence, and the entanglement entropy as tools to detect and characterize these unique coherent states. We find that these unique coherent states exist in a gapless spin liquid phase, where they form a line that separates two regions with different degrees of squeezing. We call this line the entangled unique coherent line, as it corresponds to the almost maximum entanglement between two halves of the system. We also study the critical scaling of the spin squeezing parameter and the entanglement entropy versus the system size.

Generating Function for Projected Entangled-Pair States

Diagrammatic summation is a common bottleneck in modern applications of projected entangled-pair states, especially in computing low-energy excitations of a two-dimensional quantum many-body system. To solve this problem, here we extend the generating-function approach for tensor-network diagrammatic summation, a scheme previously proposed in the context of matrix product states. Taking the form of a one-particle excitation, we show that the excited state can be computed efficiently in the generating-function formalism, which can further be used in evaluating the dynamical structure factor of the system. Our benchmark results for the spin-1/2 transverse-field Ising model and Heisenberg model on the square lattice provide a desirable accuracy, showing good agreement with known results. We then study the spin-1/2J1-J2 model on the same lattice and investigate the dynamical properties of the putative gapless spin liquid phase. We conclude with a discussion on generalizations to multiparticle excitations. Published by the American Physical Society 2024

Gapless Spin Liquid and Nonlocal Corner Excitation in the Spin-1/2 Heisenberg Antiferromagnet on Fractal

Motivated by the mathematical beauty and the recent experimental realizations of fractal systems, we study the spin-1/2 antiferromagnetic Heisenberg model on a Sierpiński gasket. The fractal porous feature generates new kinds of frustration to exhibit exotic quantum states. Using advanced tensor network techniques, we identify a quantum gapless-spin-liquid ground state in fractional spatial dimension. This fractal spin system also demonstrates nontrivial nonlocal properties. While the extremely short-range correlation causes a highly degenerate spin form factor, the entanglement in this fractal system suggests a long-range scaling behavior. We also study the dynamic structure factor and clearly identify the gapless excitation with a stable corner excitation emerged from the ground-state entanglement. Our results unambiguously point out multiple essential properties of this fractal spin system, and open a new route to explore spin liquid and frustrated magnetism.

Quantum spin liquids of Rydberg excitations in a honeycomb lattice induced by density-dependent Peierls phases

We show that the nonlinear transport of bosonic excitations in a two-dimensional honeycomb lattice of spin-orbit-coupled Rydberg atoms gives rise to disordered quantum phases which are topological and may be candidates for quantum spin liquids. As recently demonstrated by Lienhard et al. [Phys. Rev. X 10, 021031 (2020)] the spin-orbit coupling breaks time-reversal and chiral symmetries and leads to a tunable density-dependent complex hopping of spin excitations which behave as hard-core bosons. Using exact diagonalization (ED), we numerically investigate the phase diagram resulting from the competition between density-dependent and direct transport terms as well as density-density interactions. In mean-field approximation there is a phase transition from a condensate to a ${120}^{\ensuremath{\circ}}$ phase when the amplitude of the complex hopping exceeds that of the direct one. In the full model a new phase emerges close to the mean-field critical point as a result of quantum correlations induced by the density dependence of the complex hopping. We show that without density-density interactions this phase is a genuine disordered one, has large spin chirality, and is characterized by a nontrivial many-body Chern number. The Chern number is found to be robust to disorder. ED simulations of small lattices with up to 30 lattice sites give indications for a nondegenerate ground state with finite spin and collective gaps and thus for a bosonic integer quantum Hall phase, protected by $\mathrm{U}(1)$ symmetry. On the other hand, while staying finite, the many-body gap varies substantially when different twisted boundary conditions are applied, which points to a gapless phase. For very strong negative nonlinear hopping amplitudes we find another disordered regime with vanishing spin gap. This phase also has a large spin chirality and could be a gapless spin liquid but lies outside the parameter regime experimentally accessible in the Rydberg system.

Machine learning approach to study quantum phase transitions of a frustrated one dimensional spin-1/2 system

Frustration-driven quantum fluctuation leads to many exotic phases in the ground state (GS) and the study of these quantum phase transitions is one of the most challenging areas of research in condensed matter physics. We study a frustrated Heisenberg model of spin-1/2 chain with nearest exchange interaction J 1 and next nearest exchange interaction J 2 using the principal component analysis (PCA) which is an unsupervised machine learning technique. In this method most probable spin configurations (MPSCs) of GS and first excited state (FES) for different are used as the input in PCA to construct the covariance matrix. The ‘quantified principal component’ of the largest eigenvalue of the covariance matrix is calculated and it is shown that the nature and variation of can accurately predict the phase transitions and degeneracies in the GS. The calculated from the MPSC of GS only exhibits the signature of degeneracies in the GS, whereas, calculated from the MPSC of FES captures the gapless spin liquid (GSL)-dimer phase transition as well as all the degeneracies of the model system. We show that the jump in of FES at , indicates the GSL-dimer phase transition, whereas its kinks give the signature of the GS degeneracies. The scatter plot of the first two principal components of FES shows distinct band formation for different phases. The MPSCs are obtained by using an iterative variational method (IVM) which gives the approximate eigenvalues and eigenvectors.

Magnetic field effects on the quantum spin liquid behaviors of NaYbS2

Spin-orbit coupling is an important ingredient to regulate the many-body physics, especially for many spin liquid candidate materials such as rare-earth magnets and Kitaev materials. The rare-earth chalcogenides (Ch = O, S, Se) is a congenital frustrating system to exhibit the intrinsic landmark of spin liquid by eliminating both the site disorders between and ions with the big ionic size difference and the Dzyaloshinskii-Moriya interaction with the perfect triangular lattice of the ions. The temperature versus magnetic-field phase diagram is established by the magnetization, specific heat, and neutron-scattering measurements. Notably, the neutron diffraction spectra and the magnetization curve might provide microscopic evidence for a series of spin configuration for in-plane fields, which include the disordered spin liquid state, 120° antiferromagnet, and one-half magnetization state. Furthermore, the ground state is suggested to be a gapless spin liquid from inelastic neutron scattering, and the magnetic field adjusts the spin orbit coupling. Therefore, the strong spin-orbit coupling in the frustrated quantum magnet substantially enriches low-energy spin physics. This rare-earth family could offer a good platform for exploring the quantum spin liquid ground state and quantum magnetic transitions.

Evidence for a spinon Kondo effect in cobalt atoms on single-layer 1T-TaSe2

Quantum spin liquids (QSLs) are highly entangled, disordered magnetic states that arise in frustrated Mott insulators and host exotic fractional excitations such as spinons and chargons. Despite being charge insulators some QSLs are predicted to exhibit gapless itinerant spinons that yield metallic behavior in the spin channel. We have deposited isolated magnetic atoms onto single-layer (SL) 1T-TaSe$_2$, a gapless QSL candidate, to experimentally probe how itinerant spinons couple to impurity spin centers. Using scanning tunneling spectroscopy we observe the emergence of new, impurity-induced resonance peaks at the 1T-TaSe$_2$ Hubbard band edges when cobalt adatoms are positioned to have maximal spatial overlap with the Hubbard band charge distribution. These resonance peaks disappear when the spatial overlap is reduced or when the magnetic impurities are replaced with non-magnetic impurities. Theoretical simulations using a modified Anderson impurity model integrated with a gapless quantum spin liquid show that these resonance peaks are consistent with a Kondo resonance induced by spinons combined with spinon-chargon binding effects that arise due to QSL gauge-field fluctuations.

Muon Spin Relaxation Study of Frustrated Tm3Sb3Mg2O14 with Kagomé Lattice

The structure and magnetic properties of rare-earth ions Tm3+ Kagomé lattice Tm3Sb3Mg2O14 are studied by x-ray diffraction, magnetic susceptibility and muon spin relaxation (μSR) experiments. The existence of a small amount of Tm/Mg site-mixing disorder is revealed. DC magnetic susceptibility measurement shows that Tm3+ magnetic moments are antiferromagnetically correlated with a negative Curie–Weiss temperature of –26.3 K. Neither long-range magnetic order nor spin-glass transition is observed by DC and AC magnetic susceptibility, and confirmed by μSR experiment down to 0.1 K. However, the emergence of short-range magnetic order is indicated by the zero-field μSR experiments, and the absence of spin dynamics at low temperatures is evidenced by the longitudinal-field μSR technique. Compared with the results of Tm3Sb3Zn2O14, another Tm-based Kagomé lattice with much more site-mixing disorder, the gapless spin liquid like behaviors in Tm3Sb3Zn2O14 can be induced by disorder effect. Samples with perfect geometrical frustration are in urgent demand to establish whether QSL exists in this kind of materials with rare-earth Kagomé lattice.

Quantum spin liquids bootstrapped from Ising criticality in Rydberg arrays

Arrays of Rydberg atoms constitute a highly tunable, strongly interacting venue for the pursuit of exotic states of matter. We develop a new strategy for accessing a family of fractionalized phases known as quantum spin liquids in two-dimensional Rydberg arrays. We specifically use effective field theory methods to study arrays assembled from Rydberg chains tuned to an Ising phase transition that famously hosts emergent fermions propagating within each chain. This highly entangled starting point allows us to naturally access spin liquids familiar from Kitaev's honeycomb model, albeit from an entirely different framework. In particular, we argue that finite-range repulsive Rydberg interactions, which frustrate nearby symmetry-breaking orders, can enable coherent propagation of emergent fermions between the chains in which they were born. Delocalization of emergent fermions across the full two-dimensional Rydberg array yields a gapless Z2 spin liquid with a single massless Dirac cone. Here, the Rydberg occupation numbers exhibit universal power-law correlations that provide a straightforward experimental diagnostic of this phase. We further show that explicitly breaking symmetries perturbs the gapless spin liquid into gapped, topologically ordered descendants: Breaking lattice symmetries generates toric-code topological order, whereas introducing chirality generates non-Abelian Ising topological order. In the toric-code phase, we analytically construct microscopic incarnations of non-Abelian defects, which can be created and transported by dynamically controlling the atom positions in the array. Our work suggests that appropriately tuned Rydberg arrays provide a cold-atoms counterpart of solid-state 'Kitaev materials' and, more generally, spotlights a new angle for pursuing experimental platforms for Abelian and non-Abelian fractionalization.

Tomonaga-Luttinger Spin Liquid and Kosterlitz-Thouless Transition in the Spin-1/2 Branched Chains: The Study of Topological Phase Transition.

In the present work, we provide a comprehensive numerical investigation of the magnetic properties and phase spectra of three types of spin-1/2 branched chains consisting of one, two and three side spins per unit block with intra-chain interaction and a uniform inter-chain interaction in the presence of an external magnetic field. In a specific magnetic field interval, the low-temperature magnetization of these chains shows a step-like behavior with a pronounced plateau depending on the strength and the type of intra-chain interaction being ferromagnetic or antiferromagnetic. We demonstrate that when inter-chain interaction is antiferromagnetic and intra-chain interaction is ferromagnetic, the magnetization of the models manifests a smooth increase without a plateau, which is evidence of the existence of a Luttinger-like spin liquid phase before reaching its saturation value. On the other hand, when is ferromagnetic and is antiferromagnetic, the low-temperature magnetization of the chain with two branches shows an intermediate plateau at one-half of the saturation magnetization that breaks a quantum spin liquid phase into two regions. The magnetization of the chain with three branches exhibits two intermediate plateaus and two regions of a quantum spin liquid. We demonstrate that the chains with more than one side spin illustrate in their ground-state phase diagram a Kosterlitz–Thouless transition from a gapful phase to a gapless spin liquid phase.

Thermodynamics of the spin-half square kagome lattice antiferromagnet

Over the last decade, the interest in the spin-$1/2$ Heisenberg antiferromagnet (HAF) on the square kagome (also called shuriken) lattice has been growing as a model system of quantum magnetism with a quantum paramagnetic ground state, flat-band physics near the saturation field, and quantum scars. A further motivation to study this model comes from the recent discovery of a gapless spin liquid in the square kagome magnet $\mathrm{K}{\mathrm{Cu}}_{6}\mathrm{Al}\mathrm{Bi}{\mathrm{O}}_{4}{(\mathrm{S}{\mathrm{O}}_{4})}_{5}\mathrm{Cl}$ [M. Fujihala et al., Nat. Commun. 11, 3429 (2020)]. Here, we present large-scale numerical investigations of the specific heat $C(T)$, the entropy $S(T),$ as well as the susceptibility $\ensuremath{\chi}(T)$ by means of the finite-temperature Lanczos method for system sizes of $N=18,24,30,36,42,48$, and $N=54$. We find that the specific heat exhibits a low-temperature shoulder below the major maximum which can be attributed to low-lying singlet excitations filling the singlet-triplet gap, which is significantly larger than the singlet-singlet gap. This observation is further supported by the behavior of the entropy $S(T)$, where a change in curvature is present just at about $T/J=0.2$, the same temperature where the shoulder in $C$ sets in. For the susceptibility the low-lying singlet excitations are irrelevant, and the singlet-triplet gap leads to an exponentially activated low-temperature behavior. The maximum in $\ensuremath{\chi}(T)$ is found at a pretty low temperature ${T}_{\mathrm{max}}/J=0.146$ (for $N=42$) compared to ${T}_{\mathrm{max}}/J=0.935$ for the unfrustrated square-lattice HAF signaling the crucial role of frustration also for the susceptibility. We find a striking similarity of our square kagome data with the corresponding ones for the kagome HAF down to very low $T$. The magnetization process featuring plateaus and jumps and the field dependence of the specific heat that exhibits characteristic peculiarities attributed to the existence of a flat one-magnon band are discussed as well.

Quantum criticality and spin liquid phase in the Shastry-Sutherland model

Using the density-matrix renormalization group method for the ground state and excitations of the Shastry- Sutherland spin model, we demonstrate the existence of a narrow quantum spin liquid phase between the previously known plaquette-singlet and antiferromagnetic states. Our conclusions are based on finite-size scaling of excited level crossings and order parameters. Together with previous results on candidate models for deconfined quantum criticality and spin liquid phases, our results point to a unified quantum phase diagram where the deconfined quantum-critical point separates a line of first-order transitions and a gapless spin liquid phase. The frustrated Shastry-Sutherland model is close to the critical point but slightly inside the spin liquid phase, while previously studied unfrustrated models cross the first-order line. We also argue that recent heat capacity measurements in SrCu2(BO3)2 show evidence of the proposed spin liquid at pressures between 2.6 and 3 GPa.

Thirty-Year Anniversary of κ-(BEDT-TTF)2Cu2(CN)3: Reconciling the Spin Gap in a Spin-Liquid Candidate

In 1991 the layered organic compound κ-(BEDT-TTF)2Cu2(CN)3 with a triangular lattice was synthesized for the first time. Although, originally, the focus was on the superconducting properties under pressure, this frustrated Mott insulator has been the most promising quantum-spin-liquid candidate for almost two decades, widely believed to host gapless spin excitations down to T→0. The recent observation of a spin gap rules out a gapless spin liquid with itinerant spinons and puts severe constraints on the magnetic ground state. This review evaluates magnetic, thermal transport, and structural anomalies around T⋆=6 K. The opening of a spin gap yields a rapid drop of spin susceptibility, NMR Knight shift, spin-lattice relaxation rate, and μ-SR spin fluctuation rate, but is often concealed by impurity spins. The concomitant structural transition at T⋆ manifests in thermal expansion, THz phonons and 63Cu NQR relaxation. Based on the field dependence of T⋆, a critical field of 30–60 T is estimated for the underlying spin-singlet state. Overall, the physical properties are remarkably similar to those of spin-Peierls compounds. Thus, a strong case is made that the ‘6K anomaly’ in κ-(BEDT-TTF)2Cu2(CN)3 is the transition to a valence-bond-solid state and it is suggested that such a scenario is rather the rule than the exception in materials with strong magnetic frustration.

Rise and fall of plaquette order in the Shastry-Sutherland magnet revealed by pseudofermion functional renormalization group

The Shastry-Sutherland (SS) model as a canonical example of frustrated magnetism has been extensively studied. The conventional wisdom has been that the transition from the plaquette valence bond order to the Neel order is direct and potentially realizes a deconfined quantum critical point beyond the Ginzburg-Landau paradigm. This scenario, however, was challenged recently by improved numerics from density matrix renormalization group which offers evidence for a narrow gapless spin liquid between the two phases. Prompted by this controversy and to shed light on this intricate parameter regime from a fresh perspective, we report high-resolution functional renormalization group analysis of the generalized SS model. The flows of over 50 million running couplings provide a detailed picture for the evolution of spin correlations as the frequency/energy scale is dialed from the ultraviolet to the infrared to yield the zero-temperature phase diagram. The singlet dimer phase emerges as a fixed point, the Neel order is characterized by divergence in the vertex function, while the transition into and out of the plaquette order is accompanied by pronounced peaks in the plaquette susceptibility. The plaquette order is suppressed before the onset of the Neel order, lending evidence for a finite spin liquid region for ${J}_{1}/{J}_{2}\ensuremath{\in}(0.77,0.82)$, where the flow is continuous without any indication of divergence.

Theory of the Kitaev model in a [111] magnetic field

Recent numerical studies indicate that the antiferromagnetic Kitaev honeycomb lattice model undergoes a magnetic-field-induced quantum phase transition into a new spin-liquid phase. This intermediate-field phase has been previously characterized as a gapless spin liquid. By implementing a recently developed variational approach based on the exact fractionalized excitations of the zero-field model, we demonstrate that the field-induced spin liquid is gapped and belongs to Kitaev’s 16-fold way. Specifically, the low-field non-Abelian liquid with Chern number C = ±1 transitions into an Abelian liquid with C = ±4. The critical field and the field-dependent behaviors of key physical quantities are in good quantitative agreement with published numerical results. Furthermore, we derive an effective field theory for the field-induced critical point which readily explains the ostensibly gapless nature of the intermediate-field spin liquid.

Gapless spin liquid and pair density wave of the Hubbard model on three-leg triangular cylinders

We study the ground state properties of the Hubbard model on three-leg triangular cylinders using large-scale density-matrix renormalization group simulations. At half-filling, we identify an intermediate gapless spin liquid phase, which has one gapless spin mode and algebraic spin–spin correlations but exponential decay scalar chiral–chiral correlations, between a metallic phase at weak coupling and Mott insulating dimer phase at strong interaction. Upon light doping the gapless spin liquid, the system exhibits power-law charge-density-wave (CDW) correlations but short-range single-particle, spin–spin, and chiral–chiral correlations. Similar to CDW correlations, the superconducting correlations also decay in power-law but oscillate in sign as a function of distance, which is consistent with the striped pair-density wave. When further doping the gapless spin liquid phase or doping the dimer order phase, another phase takes over, which has similar CDW correlations but all other correlations decay exponentially.

Gutzwiller projected states for the J1−J2 Heisenberg model on the Kagome lattice: Achievements and pitfalls

We assess the ground-state phase diagram of the $J_1$-$J_2$ Heisenberg model on the kagome lattice by employing Gutzwiller-projected fermionic wave functions. Within this framework, different states can be represented, defined by distinct unprojected fermionic Hamiltonians that include hopping and pairing terms, as well as a coupling to local Zeeman fields to generate magnetic order. For $J_2=0$, the so-called U(1) Dirac state, in which only hopping is present (such as to generate a $\pi$-flux in the hexagons), has been shown to accurately describe the exact ground state [Y. Iqbal, F. Becca, S. Sorella, and D. Poilblanc, Phys. Rev. B 87, 060405 (2013); Y.-C. He, M. P. Zaletel, M. Oshikawa, and F. Pollmann, Phys. Rev. X 7, 031020 (2017)]. Here, we show that its accuracy improves in presence of a small antiferromagnetic super-exchange $J_2$, leading to a finite region where the gapless spin liquid is stable; then, for $J_2/J_1=0.11(1)$, a first-order transition to a magnetic phase with pitch vector ${\bf q}=(0,0)$ is detected, by allowing magnetic order within the fermionic Hamiltonian. Instead, for small ferromagnetic values of $|J_2|/J_1$, the situation is more contradictory. While the U(1) Dirac state remains stable against several perturbations in the fermionic part (i.e., dimerization patterns or chiral terms), its accuracy clearly deteriorates on small systems, most notably on $36$ sites where exact diagonalization is possible. Then, upon increasing the ratio $|J_2|/J_1$, a magnetically ordered state with $\sqrt{3} \times \sqrt{3}$ periodicity eventually overcomes the U(1) Dirac spin liquid. Within the ferromagnetic $J_{2}$ regime, evidence is shown in favor of a first-order transition at $J_2/J_1=-0.065(5)$.

Theoretical study of quantum spin liquids in S=12 hyper-hyperkagome magnets: Classification, heat capacity, and dynamical spin structure factor

Recent experiments suggest a quantum spin liquid ground state in the material PbCuTe$_2$O$_6$, where $S=1/2$ moments are coupled by antiferromagnetic Heisenberg interactions into a three dimensional structure of corner sharing triangles dubbed the hyper-hyperkagome lattice. It exhibits a richer connectivity, and thus likely a stronger geometric frustration, than the relatively well studied hyperkagome lattice. Here, we investigate the possible quantum spin liquids in the $S=1/2$ hyper-hyperkagome magnet using the complex fermion mean field theory. Extending the results of a previous projective symmetry group analysis, we identify only two $\mathbb{Z}_2$ spin liquids and a $U(1)$ spin liquid that are compatible with the hyper-hyperkagome structure. The $U(1)$ spin liquid has a spinon Fermi surface. For the $\mathbb{Z}_2$ spin liquids, one has a small excitation gap, while the other is gapless and proximate to the $U(1)$ spin liquid. We show that the gapped and gapless spin liquids can in principle be distinguished by heat capacity measurements. Moreover, we calculate the dynamical spin structure factors of all three spin liquids and find that they highly resemble the inelastic neutron scattering spectra of PbCuTe$_2$O$_6$. Implications of our work to the experiments, as well as its relations to the existing theoretical studies, are discussed.

Frustrated Kondo impurity triangle: A simple model of deconfinement

The concepts of deconfinement and topological order are of great current interest for quantum information science and for our understanding of quantum materials. Here, we introduce a simple model of three antiferromagnetically coupled Kondo impurities, a Kondo triangle, which can be used to further extend the application of these concepts to electronic systems. We show that, by tuning the magnetic frustration, the Kondo triangle undergoes a quantum phase transition between two phases of unbroken symmetry, signaling a phase transition beyond the Landau paradigm. We demonstrate that the frustrated spin liquid phase is described by a three-channel Kondo (3CK) fixed point and thus displays an irrational ground state degeneracy. Using an Abrikosov pseudofermion representation, this quantum state is categorized by an emergent U(1) gauge field and its projective symmetry group. The gauge theory is deconfining in the sense that a miniature Wilson loop orders and topological defects (instantons in the gauge field) are expelled. This phase persists in the presence of moderate Kondo screening until proliferation of topological defects leads to a quantum phase transition to an unfrustrated Fermi liquid phase. Based on this evidence, we propose that the 3CK phase displays topological order in a similar sense as gapless spin liquids.

Effects of spin-phonon coupling in frustrated Heisenberg models

The existence and stability of spin-liquid phases represent a central topic in the field of frustrated magnetism. While a few examples of spin-liquid ground states are well established in specific models (e.g. the Kitaev model on the honeycomb lattice), recent investigations have suggested the possibility of their appearance in several Heisenberg-like models on frustrated lattices. An important related question concerns the stability of spin liquids in the presence of small perturbations in the Hamiltonian. In this respect, the magnetoelastic interaction between spins and phonons represents a relevant and physically motivated perturbation, which has been scarcely investigated so far. In this work, we study the effect of the spin-phonon coupling on prototypical models of frustrated magnetism. We adopt a variational framework based upon Gutzwiller-projected wave functions implemented with a spin-phonon Jastrow factor, providing a full quantum treatment of both spin and phonon degrees of freedom. The results on the frustrated $J_1-J_2$ Heisenberg model on one- and two-dimensional (square) lattices show that, while a valence-bond crystal is prone to lattice distortions, a gapless spin liquid is stable for small spin-phonon couplings. In view of the ubiquitous presence of lattice vibrations, our results are particularly important to demonstrate the possibility that gapless spin liquids may be realized in real materials.