Polymer based waveguide amplifiers are the key devices to improve the performance of integrated communication systems. However, due to their comparatively low relative gain, their widespread practical application has been limited. In polymer based optical waveguide amplifiers, the size of inorganic compounds in the composite gain media has a significant impact on the gain performance of the amplifier. Up to now, there has been limited research on the size influence of inorganic compound on the gain variation in organic polymer based optical waveguide amplifiers. In this study, a series of NaLu0.8-xYxF4: Yb, Er-PMMA composite polymer were used as gain media to prepare organic waveguide amplifiers working in the C-band (1530–1565 nm). The size of NaLu0.8-xYxF4: Yb, Er compounds varies between 20 nm and 150 nm. In the polymer based optical waveguide amplifiers, variations in the size of the inorganic NaLu0.8-xYxF4:Yb,Er compound affects not only the C-band emission intensity but also the relative gain. When the size of the inorganic compound is 65 nm, the composite gain media exhibits the maximum emission peak intensity at 1550 nm and the corresponding device achieves a maximum relative gain of 19.3 dB/cm. Our results show that the size of inorganic compounds affects the variation of luminescence intensity and ultimately the gain of waveguide amplifiers. The gain of future polymer optical waveguide amplifiers can be improved by this method.
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