The article presents the results of approbation of the complex method of three-dimensional characterization of radioactive contamination, which allows to build maps with the fields of radioactive contamination of areas and objects in real time. The proposed γ-spectrometric method is optimized for the conditions of necessity to carry out prompt primary assessment of radiation situation at NFC enterprises and consists in carrying out γ-spectrometric measurements using horizontal and angular collimating protection for the detector. Measurements in this case are a successive set of γ spectra in the control measuring points that form a network of radiation survey of the facility.