Energy transition drives the energy sector to renewable energy and electrification, being the critical minerals key players in the industrial development map. They comprise rare-earth elements and 35 other elements, including lithium, which holds 60% of its world reserves in the so-called lithium triangle located in Argentina, Bolivia, and Chile. The low electrical resistivities, variations in salt concentrations, low acoustic impedances, and dynamics of the hydrogeologic system make brine monitoring a complex geophysical exploratory problem. So, the objective is to find a suitable combination of geophysical techniques that fit the lithium exploration objectives, which are the characterization of the salt flat in-depth, fluid detection, basement delineation, definition of the main structures and main faults, and detection of semifresh water aquifers that contribute to its recharge and that are key to the reservoir water balance of an endorheic basin, which has the resource in solution. For this purpose, the evaluation of several prospecting methods in different salt flats was executed, concluding that full tensor magnetotellurics (MT), electrical resistivity tomography, and gravity comprise a toolkit that fits the objectives set. The methodology was validated at the Pozuelos salt flat. The results show that the fresh water-brines contact and the recharge system were well-defined and imaged by ERT. The full tensor MT detected two ultraconductive units: a shallower multilayer system saturated with brines, has a 400 m thickness, whereas the deeper unit has a 500 m thickness. Both MT and gravity characterized the basement, and gravity successfully delineated the main structures. The geophysical interpretation is in concordance with shallow and deep exploration wells. Finally, the integration of geophysical and well data allowed the construction of a 3D static reservoir model that finds the deepest basement area at approximately 900 m depth and discriminates eight lithofacies.
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