Frost Point Hygrometer Measurements Research Articles

The SPARC Water Vapor Assessment II: assessment of satellite measurements of upper tropospheric humidity

Abstract. Nineteen limb-viewing data sets (occultation, passive thermal, and UV scattering) and two nadir upper tropospheric humidity (UTH) data sets are intercompared and also compared to frost-point hygrometer balloon sondes. The upper troposphere considered here covers the pressure range from 300–100 hPa. UTH is a challenging measurement, because concentrations vary between 2–1000 ppmv (parts per million by volume), with sharp changes in vertical gradients near the tropopause. Cloudiness in this region also makes the measurement challenging. The atmospheric temperature is also highly variable ranging from 180–250 K. The assessment of satellite-measured UTH is based on coincident comparisons with balloon frost-point hygrometer sondes, multi-month mapped comparisons, zonal mean time series comparisons, and coincident satellite-to-satellite comparisons. While the satellite fields show similar features in maps and time series, quantitatively they can differ by a factor of 2 in concentration, with strong dependencies on the amount of UTH. Additionally, time-lag response-corrected Vaisala RS92 radiosondes are compared to satellites and the frost-point hygrometer measurements. In summary, most satellite data sets reviewed here show on average ∼30 % agreement amongst themselves and frost-point data but with an additional ∼30 % variability about the mean bias. The Vaisala RS92 sonde, even with a time-lag correction, shows poor behavior for pressures less than 200 hPa.

Investigation and amelioration of long-term instrumental drifts in water vapor and nitrous oxide measurements from the Aura Microwave Limb Sounder (MLS) and their implications for studies of variability and trends

Abstract. The Microwave Limb Sounder (MLS), launched on NASA's Aura spacecraft in 2004, measures vertical profiles of the abundances of key atmospheric species from the upper troposphere to the mesosphere with daily near-global coverage. We review the first 15 years of the record of H2O and N2O measurements from the MLS 190 GHz subsystem (along with other 190 GHz information), with a focus on their long-term stability, largely based on comparisons with measurements from other sensors. These comparisons generally show signs of an increasing drift in the MLS “version 4” (v4) H2O record starting around 2010. Specifically, comparisons with v4.1 measurements from the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) indicate a ∼ 2 %–3 % per decade drift over much of the stratosphere, increasing to as much as ∼ 7 % per decade around 46 hPa. Larger drifts, of around 7 %–11 % per decade, are seen in comparisons to balloon-borne frost point hygrometer measurements in the lower stratosphere. Microphysical calculations considering the formation of polar stratospheric clouds in the Antarctic winter stratosphere corroborate a drift in MLS v4 water vapor measurements in that region and season. In contrast, comparisons with the Sounding of the Atmosphere using Broadband Emission Radiometry (SABER) instrument on NASA's Thermosphere Ionosphere Mesosphere Energetics and Dynamics (TIMED) mission, and with ground-based Water Vapor Millimeter-wave Spectrometer (WVMS) instruments, do not show statistically significant drifts. However, the uncertainty in these comparisons is large enough to encompass most of the drifts identified in other comparisons. In parallel, the MLS v4 N2O product is shown to be generally decreasing over the same period (when an increase in stratospheric N2O is expected, reflecting a secular growth in emissions), with a more pronounced drift in the lower stratosphere than that found for H2O. Comparisons to ACE-FTS and to MLS N2O observations in a different spectral region, with the latter available from 2004 to 2013, indicate an altitude-dependent drift, growing from 5 % per decade or less in the mid-stratosphere to as much as 15 % per decade in the lower stratosphere. Detailed investigations of the behavior of the MLS 190 GHz subsystem reveal a drift in its “sideband fraction” (the relative sensitivity of the 190 GHz receiver to the two different parts of the microwave spectrum that it observes). Our studies indicate that sideband fraction drift accounts for much of the observed changes in the MLS H2O product and some portion of the changes seen in N2O. The 190 GHz sideband fraction drift has been corrected in the new “version 5” (v5) MLS algorithms, which have now been used to reprocess the entire MLS record. As a result of this correction, the MLS v5 H2O record shows no statistically significant drifts compared to ACE-FTS. However, statistically significant drifts remain between MLS v5 and frost point measurements, although they are reduced. Drifts in v5 N2O are about half the size of those in v4 but remain statistically significant. Scientists are advised to use MLS v5 data in all future studies. Quantification of interregional and seasonal to annual changes in MLS H2O and N2O will not be affected by the drift. However, caution is advised in studies using the MLS record to examine long-term (multiyear) variability and trends in either of these species, especially N2O; such studies should only be undertaken in consultation with the MLS team. Importantly, this drift does not affect any of the MLS observations made in other spectral regions such as O3, HCl, CO, ClO, or temperature.

Understanding balloon-borne frost point hygrometer measurements after contamination by mixed-phase clouds

Abstract. Balloon-borne water vapour measurements in the upper troposphere and lower stratosphere (UTLS) by means of frost point hygrometers provide important information on air chemistry and climate. However, the risk of contamination from sublimating hydrometeors collected by the intake tube may render these measurements unusable, particularly after crossing low clouds containing supercooled droplets. A large set of (sub)tropical measurements during the 2016–2017 StratoClim balloon campaigns at the southern slopes of the Himalayas allows us to perform an in-depth analysis of this type of contamination. We investigate the efficiency of wall contact and freezing of supercooled droplets in the intake tube and the subsequent sublimation in the UTLS using computational fluid dynamics (CFD). We find that the airflow can enter the intake tube with impact angles up to 60∘, owing to the pendulum motion of the payload. Supercooled droplets with radii > 70 µm, as they frequently occur in mid-tropospheric clouds, typically undergo contact freezing when entering the intake tube, whereas only about 50 % of droplets with 10 µm radius freeze, and droplets < 5 µm radius mostly avoid contact. According to CFD, sublimation of water from an icy intake can account for the occasionally observed unrealistically high water vapour mixing ratios (χH2O > 100 ppmv) in the stratosphere. Furthermore, we use CFD to differentiate between stratospheric water vapour contamination by an icy intake tube and contamination caused by outgassing from the balloon and payload, revealing that the latter starts playing a role only during ascent at high altitudes (p < 20 hPa).

Comparisons of temperature, pressure and humidity measurements by balloon-borne radiosondes and frost point hygrometers during MOHAVE-2009

Abstract. We compare coincident, in situ, balloon-borne measurements of temperature (T) and pressure (P) by two radiosondes (Vaisala RS92, Intermet iMet-1-RSB) and similar measurements of relative humidity (RH) by RS92 sondes and frost point hygrometers. Data from a total of 28 balloon flights with at least one pair of radiosondes are analyzed in 1-km altitude bins to quantify measurement differences between the sonde sensors and how they vary with altitude. Each comparison (T, P, RH) exposes several profiles of anomalously large measurement differences. Measurement difference statistics, calculated with and without the anomalous profiles, are compared to uncertainties quoted by the radiosonde manufacturers. Excluding seven anomalous profiles, T differences between 19 pairs of RS92 and iMet sondes exceed their measurement uncertainty limits (2 σ) 31% of the time and reveal a statistically significant, altitude-independent bias of 0.5 ± 0.2 °C. Similarly, RS92-iMet P differences in 22 non-anomalous profiles exceed their uncertainty limits 23% of the time, with a disproportionate 83% of the excessive P differences at altitudes >16 km. The RS92-iMet pressure differences increase smoothly from −0.6 hPa near the surface to 0.8 hPa above 25 km. Temperature and P differences between all 14 pairs of RS92 sondes exceed manufacturer-quoted, reproducibility limits (σ) 28% and 11% of the time, respectively. About 95% of the excessive T differences are eliminated when 5 anomalous RS92-RS92 profiles are excluded. Only 5% of RH measurement differences between 14 pairs of RS92 sondes exceed the manufacturer's measurement reproducibility limit (σ). RH measurements by RS92 sondes are also compared to RH values calculated from frost point hygrometer measurements and coincident T measurements by the radiosondes. The influences of RS92-iMet Tand P differences on RH values and water vapor mixing ratios calculated from frost point hygrometer measurements are examined.

Accuracy assessment and correction of Vaisala RS92 radiosonde water vapor measurements

Relative humidity (RH) measurements from Vaisala RS92 radiosondes are widely used in research and operational applications, but their accuracy is not well characterized as a function of height, RH, and time of day (or solar altitude angle). This study compares RS92 RH measurements to simultaneous water vapor measurements from three reference instruments of known accuracy. Cryogenic frost point hygrometer measurements are used to characterize the RS92 accuracy above the 700‐mbar level, microwave radiometer measurements characterize the RS92 accuracy averaged over essentially the lower troposphere, and the RS92 accuracy at the surface is characterized by a system of 6 RH probes with National Institute of Standards and Technology–traceable calibrations. The three RS92 accuracy assessments are combined to yield a detailed estimate of RS92 accuracy for all RH conditions from the surface to the lowermost stratosphere. An empirical correction is derived to remove the mean bias error, yielding corrected RS92 measurements whose bias uncertainty is independent of height or RH and is estimated to be ±4% of the measured RH value for nighttime soundings and ±5% for daytime soundings, plus an RH offset uncertainty of ±0.5% RH that is significant for dry conditions. The accuracy of an individual RS92 sounding is further characterized by the 1‐σ “random production variability,” estimated to be ±1.5% of the measured RH value. The daytime bias correction must be used with caution, as it is only accurate for clear‐sky or near‐clear conditions owing to the complicated effect of clouds on the solar radiation error.

Trends and variability of midlatitude stratospheric water vapour deduced from the re-evaluated Boulder balloon series and HALOE

Abstract. This paper presents an updated trend analysis of water vapour in the lower midlatitude stratosphere from the Boulder balloon-borne NOAA frostpoint hygrometer measurements and from the Halogen Occulation Experiment (HALOE). Two corrections for instrumental bias are applied to homogenise the frostpoint data series, and a quality assessment of all soundings after 1991 is presented. Linear trend estimates based on the corrected data for the period 1980–2000 are up to 40% lower than previously reported. Vertically resolved trends and variability are calculated with a multi regression analysis including the quasi-biennal oscillation and equivalent latitude as explanatory variables. In the range of 380 to 640 K potential temperature (≈14 to 25 km), the frostpoint data from 1981 to 2006 show positive linear trends between 0.3±0.3 and 0.7±0.1%/yr. The same dataset shows trends between −0.2±0.3 and 1.0±0.3%/yr for the period 1992 to 2005. HALOE data over the same time period suggest negative trends ranging from −1.1±0.2 to −0.1±0.1%/yr. In the lower stratosphere, a rapid drop of water vapour is observed in 2000/2001 with little change since. At higher altitudes, the transition is more gradual, with slowly decreasing concentrations between 2001 and 2007. This pattern is consistent with a change induced by a drop of water concentrations at entry into the stratosphere. Previously noted differences in trends and variability between frostpoint and HALOE remain for the homogenised data. Due to uncertainties in reanalysis temperatures and stratospheric transport combined with uncertainties in observations, no quantitative inference about changes of water entering the stratosphere in the tropics could be made with the mid latitude measurements analysed here.

Validation of Aura Microwave Limb Sounder water vapor by balloon‐borne Cryogenic Frost point Hygrometer measurements

Here we present extensive observations of stratospheric and upper tropospheric water vapor using the balloon‐borne Cryogenic Frost point Hygrometer (CFH) in support of the Aura Microwave Limb Sounder (MLS) satellite instrument. Coincident measurements were used for the validation of MLS version 1.5 and for a limited validation of MLS version 2.2 water vapor. The sensitivity of MLS is on average 30% lower than that of CFH, which is fully compensated by a constant offset at stratospheric levels but only partially compensated at tropospheric levels, leading to an upper tropospheric dry bias. The sensitivity of MLS observations may be adjusted using the correlation parameters provided here. For version 1.5 stratospheric observations at pressures of 68 hPa and smaller MLS retrievals and CFH in situ observations agree on average to within 2.3% ± 11.8%. At 100 hPa the agreement is to within 6.4% ± 22% and at upper tropospheric pressures to within 23% ± 37%. In the tropical stratosphere during the boreal winter the agreement is not as good. The “tape recorder” amplitude in MLS observations depends on the vertical profile of water vapor mixing ratio and shows a significant interannual variation. The agreement between stratospheric observations by MLS version 2.2 and CFH is comparable to the agreement using MLS version 1.5. The variability in the difference between observations by MLS version 2.2 and CFH at tropospheric levels is significantly reduced, but a tropospheric dry bias and a reduced sensitivity remain in this version. In the validation data set a dry bias at 177.8 hPa of −24.1% ± 16.0% is statistically significant.

The increase in stratospheric water vapor from balloonborne, frostpoint hygrometer measurements at Washington, D.C., and Boulder, Colorado

Stratospheric water vapor concentrations measured at two midlatitude locations in the northern hemisphere show water vapor amounts have increased at a rate of 1–1.5% yr−1 (0.05–0.07 ppmv yr−1) for the past 35 years. At Washington, D.C., measurements were made from 1964–1976, and at Boulder, Colorado, observations began in 1980 and continue to the present. While these two data sets do not comprise a single time series, they individually show increases over their respective measurement periods. At Boulder the trends do not show strong seasonal differences; significant increases are found throughout the year in the altitude range 16–28 km. In winter these trends are significant down to about 13 km.

A humidity climatology for Halley, Antarctica, based on frost-point hygrometer measurements

Measurements of humidity at a height of 4 m were made at Halley Research Station between 1995 and 1997 using a frost point hygrometer. Relative humidities were usually close to ice saturation, particularly during the winter, but ice supersaturations of up to 20% were frequently measured. Supersaturation with respect to liquid water was rarely observed. During the summer, diurnal variation in temperature drove a daily cycle in relative humidity, although corresponding variations in mixing ratio were comparatively small. It is suggested that the high frequency of ice supersaturations and almost total absence of water supersaturation results from the high abundance of condensation nuclei relative to ice nuclei.

Lidar observations of polar stratospheric clouds at the South Pole: 1. Stratospheric unperturbed conditions, 1990

Observations of polar stratospheric clouds (PSCs) carried out at the Amundsen Scott South Pole Station by lidar in the winter of 1990 are reported. Echoes attributable to PSCs began to appear in late May, were a persistent feature till early September, and from that time until the end of October were sporadically observed. Values of the backscatter ratio as high as 16 were recorded in late August at 13 km. Analyses based on the sensitivity of the backscattering to temperature confirm that the attribution of the echoes to PSC type I or II is possible in some cases. Those that could be ascribed to type II were observed mostly during July and August, while those attributable to type I appeared only at the beginning of the winter. The comparison of water vapor mixing ratios derived from PSC type II occurrence temperatures and frost point hygrometer measurements indicates a fast dehydration in the beginning of the winter.