Frequency Standards Research Articles

Neural-network approach to running high-precision atomic computations

Modern applications of atomic physics, including the determination of frequency standards and the analysis of astrophysical spectra, require prediction of atomic properties with exquisite accuracy. For complex atomic systems, high-precision calculations are a major challenge due to the exponential scaling of the involved electronic configuration sets. This exacerbates the problem of required computational resources for these computations and makes indispensable the development of approaches to select the most important configurations out of otherwise intractably huge sets. We have developed a neural-network (NN) tool for running high-precision atomic configuration interaction (CI) computations with iterative selection of the most important configurations. Integrated with the established atomic codes, our approach results in computations with significantly reduced computational requirements in comparison with those without NN support. We showcase a number of NN-supported computations for the energy levels of Fe16+ and Ni12+ and demonstrate that our approach can be reliably used and automated for solving specific computational problems for a wide variety of systems. Published by the American Physical Society 2024

Exploring the Impact of Developmental Clearance Saturation on Propylene Glycol Exposure in Adults and Term Neonates Using Physiologically Based Pharmacokinetic Modeling.

Propylene glycol (PG) is a pharmaceutical excipient which is generally regarded as safe (GRAS), though clinical toxicity has been reported. PG toxicity has been attributed to accumulation due to saturation of the alcohol dehydrogenase (ADH)-mediated clearance pathway. This study aims to explore the impact of the saturation of ADH-mediated PG metabolism on its developmental clearance in adults and neonates and assess the impact of a range of doses on PG clearance saturation and toxicity. Physiologically based pharmacokinetic (PBPK) models for PG in adults and term neonates were developed using maximum velocity (Vmax) and Michaelis-Menten's constant (Km) of ADH-mediated metabolism determined in vitro in human liver cytosol, published physicochemical, drug-related and ADH ontogeny parameters. The models were validated and used to determine the impact of dosing regimen on PG clearance saturation and toxicity in adults and neonates. The Vmax and Km of PG in human liver cytosol were 1.57 nmol/min/mg protein and 25.1 mM, respectively. The PG PBPK model adequately described PG PK profiles in adults and neonates. The PG dosing regimens associated with saturation and toxicity were dependent on both dose amount and cumulative in standard dosing frequencies. Doses resulting in saturation were higher than those associated with clinically observed toxicity. In individuals without impaired clearance or when PG exposure is through formulations that contain excipients with possible interaction with PG, a total daily dose of 100-200 mg/kg/day in adults and 25-50 mg/kg/day in neonates is unlikely to result in toxic PG levels or PG clearance saturation.

Analysis of poor work postures during morning care operations of intensive care unit nurses: a field research

BackgroundPoor working postures in morning care operations contribute significantly to work-related muscle fatigue and low back pain among ICU (Intensive Care Unit, ICU) nurses. However,there are few field studies on the relationship between Poor working postures and work-related muscle fatigue, low back pain among ICU nurses.ObjectiveThis study aims to assess the frequency and degree of posture hazards associated with poor working postures during morning care operations of ICU nurses.MethodsTwo ICUs in a Grade-A tertiary hospital in Hunan Province were randomly selected for the field study in May–June 2021 research. The image data of the participating nurses’ morning care work postures were collected by observation method and image recording method, and the postural hazard level was assessed by the two-person interpretation method of the work posture analysis system. The mean and standard deviation, frequency and percentage were used for the basic statistical description, and the general linear model multivariate Hotelling’s T2 test was used to calculate the Hotelling’s T2 and F statistics to explore the pattern of change in the postural hazard score curves.ResultsA total of 45 nurses were observed during morning care operations, resulting in 47.8 h of video data and 34,428 effective static operation posture pictures. Among these pictures, 21,166 (61.5%) depicted poor working postures. Nurses spent up to 7 min and 30 s maintaining a challenging posture during oral care, with the highest postural hazard score (M = 2.2, SD = 0.3) observed during defecation care. Each patient requires a total of 25–30 min of oral care per day.The Hotelling’s T2 test indicated that the change curve of the postural hazard score in each step revealed the largest second-order F value, F = 52.931, P < 0.001.DiscussionICU nurses frequently adopt poor working postures during morning care operations. Further research should focus on optimizing safe working postures to prevent or minimise detrimental occupational hazards resulting from poor working postures.Research on occupational low back pain among ICU nurses can help them work more efficiently, and thereby improving their nursing level.

Enhancing distribution system stability and efficiency through multi‐power supply startup optimization for new energy integration

AbstractThis paper addresses the challenge of maximizing power capture from new energy sources, including coal, wind, solar, and hydroelectric power, which often lack sufficient inertia support. This deficiency can lead to frequency instability and cascading failures within the power system. A cooperative optimization model for the start‐up of multiple power supplies, designed to enhance the integration of new energy sources while maintaining system stability is proposed. The model incorporates primary frequency modulation and the intrinsic inertia support capabilities of self‐synchronous voltage source field stations, considering dynamic frequency constraints. Additionally, it employs new energy units with primary frequency modulation to provide inertia support during curtailment, particularly when conventional units cannot meet frequency standards due to existing constraints. Extensive simulations and comparative analyses demonstrate that the proposed model improves new energy utilization by up to 37.5% and reduces operational costs by approximately 16%, enhancing overall operational efficiency in high energy consumption scenarios.

Efficacy of the Nutrition Education and Screening Tool as a Foundation for Exploring Perinatal Diet and Determinants in Aboriginal and Torres Strait Islander Women of Far North Queensland.

Assessing perinatal diet and its determinants in Australia's Aboriginal and Torres Strait Islander women remains challenging, given the paucity of tools that incorporate Aboriginal ways of knowing, being, and remembering within a quantitative framework. This study aimed to explore the determinants of perinatal nutrition in this population and to evaluate the efficacy of the Nutrition Education and Screening Tool (NEST) in collecting diet-related data in this population. This study employed a Participatory Action Research approach using the NEST as a foundation for structured research inquiry. Self-reported diet and determinants were collected from a cross-sectional cohort of Aboriginal and Torres Strait Islander women from Far North Queensland. Participants (n = 30) declared excess consumption of meat and alternatives, fruit, vegetables and legumes, and dairy and alternatives. Grain and cereal consumption aligned with recommendations; wild-harvested foods comprised a mean 19.75% of their protein intake. Food frequency data were supported by participants' descriptions of how they eat, combine, rotate, and cook these foods. Standard food frequency questionnaires are challenging for Aboriginal and Torres Strait Islanders as their concepts of time and ways of remembering are different from Western understanding. Use of the NEST allowed food frequency items to be explored, clarified, and cross-referenced; yarning provided a degree of support for quantitative data. The results of this study translate to future public health research, practice, and policy. Alternative quantitative measures to determine food frequency should be considered in future studies. These may include the cyclical approach to time that is well understood and integrated by Indigenous cultures.

Wireless transmission of audio signals and temperature data using an optoelectronic system.

This work presents an optoelectronic instrument designed for wireless visible light communication (WVLC) systems, operating within a wavelength range of 380-750nm and compatible with standard radio frequency (RF) communication. The instrument encompasses two distinct architectures. The first enables the transmission and reception of RF-processed audio signals through a three-stage process involving RF signal transmission via Bluetooth, signal multiplexing using acousto-optic modulation, a sinusoidal grating, a PIN photodetector array, and final audio playback. The second architecture focuses on the wireless transmission and reception of temperature data, utilizing a similar three-stage approach that includes temperature data measurements with an LM35 sensor, signal processing with Arduino UNO microcontrollers, and information transmission via Bluetooth. Experimental results for both architectures validate the effectiveness of this optoelectronic instrument, demonstrating its capability to integrate RF and WVLC technologies.

Full non-LTE spectral line formation

In the present paper we consider the full nonlocal thermodynamic equilibrium (non-LTE) radiation transfer problem. This formalism allows us to account for deviation from equilibrium distribution of both the radiation field and the massive particles. In the present study, two-level atoms with broadened upper level represent the massive particles. In the absence of velocity-changing collisions, we demonstrate the analytic equivalence of the full non-LTE source function with the corresponding standard non-LTE partial frequency redistribution (PFR) model. We present an iterative method based on operator splitting techniques that can be used to numerically solve the problem at hand. We benchmark it against the standard non-LTE transfer problem for a two-level atom with PFR. We illustrate the deviation of the velocity distribution function of excited atoms from the equilibrium distribution. We also discuss the dependence of the emission profile and the velocity distribution function on elastic collisions and velocity-changing collisions.

Interictal stereo-electroencephalography features below 45 Hz are sufficient for correct localization of the epileptogenic zone and postsurgical outcome prediction.

Evidence suggests that the most promising results in interictal localization of the epileptogenic zone (EZ) are achieved by a combination of multiple stereo-electroencephalography (SEEG) biomarkers in machine learning models. These biomarkers usually include SEEG features calculated in standard frequency bands, but also high-frequency (HF) bands. Unfortunately, HF features require extra effort to record, store, and process. Here we investigate the added value of these HF features for EZ localization and postsurgical outcome prediction. In 50 patients we analyzed 30 min of SEEG recorded during non-rapid eye movement sleep and tested a logistic regression model with three different sets of features. The first model used broadband features (1-500 Hz); the second model used low-frequency features up to 45 Hz; and the third model used HF features above 65 Hz. The EZ localization by each model was evaluated by various metrics including the area under the precision-recall curve (AUPRC) and the positive predictive value (PPV). The differences between the models were tested by the Wilcoxon signed-rank tests and Cliff's Delta effect size. The differences in outcome predictions based on PPV values were further tested by the McNemar test. The AUPRC score of the random chance classifier was .098. The models (broad-band, low-frequency, high-frequency) achieved median AUPRCs of .608, .582, and .522, respectively, and correctly predicted outcomes in 38, 38, and 33 patients. There were no statistically significant differences in AUPRC or any other metric between the three models. Adding HF features to the model did not have any additional contribution. Low-frequency features are sufficient for correct localization of the EZ and outcome prediction with no additional value when considering HF features. This finding allows significant simplification of the feature calculation process and opens the possibility of using these models in SEEG recordings with lower sampling rates, as commonly performed in clinical routines.

Rydberg-State Double-Well Potentials of Van der Waals Molecules

Recent progress in studies of Rydberg double-well electronic energy states of MeNg (Me = 12-group atom, Ng = noble gas atom) van der Waals (vdW) molecules is presented and analysed. The presentation covers approaches in experimental studies as well as ab initio-calculations of potential energy curves (PECs). The analysis is shown in a broader context of Rydberg states of hetero- and homo-diatomic molecules with PECs possessing complex ‘exotic’ structure. Laser induced fluorescence (LIF) excitation spectra and dispersed emission spectra employed in the spectroscopical characterization of Rydberg states are presented on the background of the diverse spectroscopic methods for their investigations such as laser vaporization–optical resonance (LV-OR), pump-and-probe methods, and polarization labelling spectroscopy. Important and current state-of-the-art applications of Rydberg states with irregular potentials in photoassociation (PA), vibrational and rotational cooling, molecular clocks, frequency standards, and molecular wave-packet interferometry are highlighted.

Continuous GPS PPP-AR frequency transfer links

Abstract In this paper, we show that the SPARK software of the Natural Resources Canada (NRCan) with their DCR (Decoupled Clock Rapid) products can be used to generate the PPP-AR continuous batch clock solutions of multiple days, which we use to build frequency transfer links between two remotely located GPS receivers. The reliability and confidence in forming the long-term frequency transfer links have been improved compared to reference~\cite{jian2023gps}. We compare the SPARK PPP-AR links to an optical fiber and TWSTFT links for hundreds of days. The ∽500-day-long comparisons with TWSTFT show no frequency bias for continental and cross-continental links. Frequency transfer links formed using the SPARK solutions have uncertainty of 1×10-15/T, where T is in days, without reaching the noise floor, a critical requirement for comparing optical frequency standards and for the redefinition of the SI second. The short latency of the NRCan DCR products enables the quick availability of the PPP-AR links presented in this paper marking it particularly relevant for time sensitive applications.

Geochemical baseline establishment and accumulation characteristics of soil heavy metals in Sabaochaqu watershed at the source of Yangtze River, Qinghai-Tibet Plateau

The establishment of soil geochemical baseline and heavy metal pollution assessment in the Qinghai-Tibet Plateau is of great significance for guiding environmental management in the high-cold and high-altitude regions. A total of 126 topsoil samples (0–20 cm) were collected and the contents of Cu, Pb, Zn, Ni, Cr, Cd, As and Hg were determined in the Sabaochaqu basin of the Tuotuo River, the source of the Yangtze River, in the Tibetan Plateau. The baseline values of 8 heavy metals were determined by mathematical statistics, iterative 2times standard deviation method, cumulative frequency and reference element standardization, and the soil heavy metal pollution in the study area was assessed by enrichment factor method and pollution index method. The results showed that the average contents of As, Cd, Cr, Cu, Hg, Ni, Pb and Zn were 31.84, 0.29, 66.07, 17.35, 0.021, 27.86, 49.35 and 88.56 mg/kg, respectively. Baseline values were 22.24, 0.217, 64.16, 15.69, 0.0191, 26.46, 34.91, and 68.62 mg/kg, respectively. There is a great difference between the baseline value of soil heavy metals in study area and the Xizang soil background value, especially the baseline value of Cd was 2.68 times of its background value. The results of the pollution evaluation based on the baseline values showed that the 8 heavy metals were slightly enriched, and the overall pollution status was light pollution, and measures should be taken to control and manage them. The research results can provide a reference value for the evaluation of soil heavy metal pollution in the source region of the Yangtze River, and also provide a theoretical basis for the construction of soil heavy metal baseline values in similar high-cold and high-altitude regions.

Atomic frequency standard based on direct frequency comb spectroscopy.

We have developed a high performance atomic frequency standard based on Doppler-free direct frequency comb excitation of a two-photon transition in 87Rb. We demonstrate equivalent performance compared to an identical system based on cw laser excitation of the clock transition. This approach greatly simplifies optical clock architecture and eliminates the need for cw lasers in many two-photon frequency standards. The clock transition linewidth and ac-Stark shift measured directly with the frequency comb are shown to be nearly identical to those obtained using a cw laser of equal average power. We directly count this reference via the frequency comb repetition rate, achieving instabilities of 1.9 × 10-13 at 1 s averaging down to 7.8(38) × 10-15 at 2600 s, currently limited by temperature dependent shifts.

Characterization of the GLONASS-K1+ atomic frequency standard

The fifth GLONASS-K1 satellite with space vehicle number R807 was launched in October 2022. It represents the first spacecraft of the K1+ generation, which offers various technical innovations. Compared to previous K1 satellites, R807 also transmits a code-division multiple access (CDMA) signal in the L2 frequency band in addition to L1 and L2 frequency-division multiple access (FDMA) and L3 CDMA signals. Thus, R807 is the first spacecraft of the K1+ generation. A geometry- and ionosphere-free triple carrier combination is used to analyze the GLONASS R807 clock consistency at different frequencies. Significant inconsistencies were found showing up as variations with a peak-to-peak amplitude of up to 40 cm and periods between 15 min and a few days. Whereas the ultimate explanation for these variations is not known, it is likely that they originate from cross-talk of two oscillators with similar frequency. A short-term clock analysis for integration times up to 100 s based on the one-way carrier phase (OWCP) method shows a superior stability of the R807 clock compared to all other GLONASS satellites including the new K2 generation. The Allan deviation computed from 5 s clock estimates confirms this finding for integration times up to 600 s but shows a significant bump at longer integration times due to the periodic variations mentioned above. Single-frequency OWCP processing confirms consistency of the L1 and L2 FDMA signals whereas the L3 CDMA signal shows a slight phase shift. Although the spurious variations mask the true performance of the K1+ atomic frequency standard, its behavior at short integration times points at a new type of GLONASS satellite clock.

Investigation of the Relationship between Topographic and Forest Stand Characteristics Using Aerial Laser Scanning and Field Survey Data

The article thoroughly investigates the relationships between terrain features and tree measurements derived from aerial laser scanning (ALS) data and field surveys in a 1067-hectare forested area. A digital elevation model (DEM) was generated from ALS data, which was then used to derive additional layers such as slope, aspect, topographic position index (TPI), and landforms. The authors developed a mathematical procedure to determine the radii for the topographic position index. The canopy height model was created, and individual trees were segmented using a novel voxel aggregation method, allowing for the calculation of tree height and crown size. Accuracy assessments were conducted between ALS-derived data and field-collected data. Terrain variability within each forest unit was evaluated using characteristics such as standard deviation, entropy, and frequency. The relationships between tree height and the derived topographic features within forest subcompartments, as well as the correlation between the height yield map for the entire area and the TPI layer, were analysed. The authors found strong correlation between the topographic position index and tree heights in both cases. The presented remote-sensing-based methodology and the results can be effectively used in digital forest site mapping, complemented by field sampling and laboratory soil analyses, and, as final goal, in carbon stock assessment.

Investigating the principle and application of high-frequency and high-voltage pulse AC equipment for oil–water separation of heavy crude oil

To address the challenges of oil–water separation encountered during the processing of heavy crude oil, this study meticulously examines the kinetics of demulsification under an electric field. Consequently, a cutting-edge high-frequency/high-voltage AC pulsed power supply has been innovatively developed. This device boasts a flexible voltage-adjustment mechanism, strategically enhancing the inverter output voltage incrementally throughout the pulse’s duration. This method effectively reduces the negative impact of current surges on the operational stability of crude oil desalination plants, especially during the commutation periods of the switching devices. Furthermore, it resolves the issue of premature power supply shutdowns to the desalination plant, caused by peak currents misinterpreted as critical short-circuit currents leading to pole plate breakdowns. An industrial application study conducted at Shandong Chambroad Petrochemicals Co., Ltd. Under identical operational conditions, the power supply designed in this research outperforms traditional electrical desalting transformers in several key aspects. These include a notably enhanced oil–water separation capability and significantly more stable performance. Remarkably, the desalting efficiency shows substantial improvement even at increased feed rates, under constant other conditions. The experimental findings indicate that the average rates of desalination and dehydration achieved by this power supply exceed 90%. Moreover, even when the feed rate is augmented by approximately 75% under constant operating conditions, the desalination efficiency remains 78.49% higher than that achieved by standard industrial frequency electric desalination transformers. Additionally, the desalting outcomes are predominantly unaffected by fluctuations in the initial salt content of the feedstock, demonstrating the robustness of the developed solution.

Octave-spanning Kerr soliton frequency combs in dispersion- and dissipation-engineered lithium niobate microresonators

Dissipative Kerr solitons from optical microresonators, commonly referred to as soliton microcombs, have been developed for a broad range of applications, including precision measurement, optical frequency synthesis, and ultra-stable microwave and millimeter wave generation, all on a chip. An important goal for microcombs is self-referencing, which requires octave-spanning bandwidths to detect and stabilize the comb carrier envelope offset frequency. Further, detection and locking of the comb spacings are often achieved using frequency division by electro-optic modulation. The thin-film lithium niobate photonic platform, with its low loss, strong second- and third-order nonlinearities, as well as large Pockels effect, is ideally suited for these tasks. However, octave-spanning soliton microcombs are challenging to demonstrate on this platform, largely complicated by strong Raman effects hindering reliable fabrication of soliton devices. Here, we demonstrate entirely connected and octave-spanning soliton microcombs on thin-film lithium niobate. With appropriate control over microresonator free spectral range and dissipation spectrum, we show that soliton-inhibiting Raman effects are suppressed, and soliton devices are fabricated with near-unity yield. Our work offers an unambiguous method for soliton generation on strongly Raman-active materials. Further, it anticipates monolithically integrated, self-referenced frequency standards in conjunction with established technologies, such as periodically poled waveguides and electro-optic modulators, on thin-film lithium niobate.

Matching males and females undergoing non mesh primary unilateral inguinal hernia repair: evaluating sex differences in preoperative and acute postoperative pain.

The objective was to compare pain and related psychological factors during the preoperative and acute postoperative period between male and female patients, who underwent non mesh primary unilateral inguinal hernia repair. After ethics approval, informed consent was obtained, and data were collected. Male and female participants were compared by manually matching one-to-one on 10 variables. Descriptive statistics (mean ± standard deviation and frequency) as well as numerical rating scales from 0 to 10 were used. Comparison tests were performed using Chi-square or Fisher's Exact test for categorical data and independent samples t-test or non-parametric equivalent tests for numerical scores. p < 0.05 is reported as statistically significant. To control type I error, Bonferroni correction was used. 72 participants with 36 matched pairs were included. Sex differences were found for operation length (p = .006), side of operation (p = .002), and hernia type (p = .013). Significant differences between the sexes were not found at the preoperative or postoperative time for resilience, pain interference or pain severity related measures, postoperative hernia pain incidence, pain catastrophizing, depression and anxiety symptoms, or return to normal activities. When controlling for known confounders and using a conservative Type I error rate, pain and related factors between the sexes did not differ significantly.

Photon Detectors and Emitters for Quantum Communication Systems and Quantum Frequency Standards

Photon Detectors and Emitters for Quantum Communication Systems and Quantum Frequency Standards

Dual-frequency optical-microwave atomic clocks based on cesium atoms

133Cs, the only stable cesium (Cs) isotope, is one of the most investigated elements in atomic spectroscopy and was used to realize the atomic clock in 1955. Among all atomic clocks, the cesium atomic clock has a special place, since the current unit of time is based on a microwave transition in the Cs atom. In addition, the long lifetime of the 6P3/2 state and simple preparation technique of Cs vapor cells have great relevance to quantum and atom optics experiments, which suggests the use of the 6S−6P D2 transition as an optical frequency standard. In this work, using one laser as the local oscillator and Cs atoms as the quantum reference, we realize two atomic clocks at the optical and microwave frequencies. Both clocks can be freely switched or simultaneously output. The optical clock, based on the vapor cell, continuously operated with a frequency stability of 3.9×10−13 at 1 s, decreasing to 2.2×10−13 at 32 s, which was frequency-stabilized by modulation transfer spectroscopy and estimated by an optical comb. Then, applying this stabilized laser to an optically pumped Cs beam atomic clock to reduce the laser frequency noise, we obtained a microwave clock with a frequency stability of 1.8×10−12/τ, reaching 6×10−15 at 105 s. This study demonstrates an attractive feature for the commercialization and deployment of optical and microwave clocks, and will guide the further development of integrated atomic clocks with better stability. Therefore, this study holds significant practical implications for future applications in satellite navigation, communication, and timing.

Composite Raman-Nath heterodyne interferometry with relevance for precise spectroscopy

Atomic state manipulation by laser radiation requires a stringent control of the light phase noise for precise spectroscopy and quantum computation. In this work we describe a novel interferometer recently employed to estimate the phase noise induced by an optical frequency shifter based on serrodyne modulation for optical frequency standards (Barbiero et al., 2023). The interferometer is generated by an acousto-optic actuator working in the Raman-Nath regime. Using the heterodyne detection between the unshifted optical mode with the first higher order optical components, we are able to detect the differential phase between the two optical path arms with a reduction of the phase noise induced by the actuator. We provide a theoretical treatment for the actuator phase suppression and we estimate the detectable phase noise limit of this interferometer. Finally, we discuss the possible applications in the field of precision measurements.