PurposeThe aim of this work is to study the frequency response of linear and nonlinear piezoelectric vibration energy harvester (pVEH) based on Duffing-type nonlinearity and Kirchhoff’s law, and the effect of the effective electromechanical coupling on the frequency response of nonlinear pVEH.MethodsThe analytical technique based on the harmonic balance method (HBM) is used to obtain the mechanical and electrical frequency responses of linear and nonlinear pVEH, and the Jacobian matrix is used to analyze the solutions’ stability. The Runge–Kutta fourth-order method as a numerical technique is used to solve the ordinary differential equations of pVEH.ResultsThe analytical calculations are completed, and the frequency response solution of displacement of pVEH is contained in real and complex values and those of electrical responses are presented. The harmonic balance results are compared with numerical simulations for various hardening nonlinear springs. Simple analytical expressions for the jump points are suggested for the sweep-up and sweep-down frequencies of pVEH.ConclusionsThe analytical analysis shows that the jump-down frequency ratios have definite behaviors for each low and high effective electromechanical coupling of hardening-nonlinear pVEHs. Moreover, the jump-up frequency ratio is directly proportional to the effective electromechanical coupling of hardening nonlinear pVEHs.