Freeze-thaw Research Articles

Impact of freeze-thaw cycles on the remobilization behaviors of microplastics in natural soils

Freeze-thaw (FT) cycle would greatly influence the fate of plastic particles (one of emerging contaminants with great concerns) in soils, yet its impacts and mechanisms remain unclear. The vertical migration/release behaviors of plastic particles (with diameters of 0.2 μm and 1 μm) in two natural soils and one model soil (i.e. quartz sand) without/with FT treatments (1 and 3 cycles) were examined. Owing to the presence of Fe/Al oxide minerals, finer pore structure, and uneven surfaces of natural soils, the breakthrough ratio of plastics in two natural soils was over 25% lower than in quartz sand. However, regardless of porous media type, FT processes (increasing cycles) significantly promoted the remobilization of plastics initially retained in three media during the subsequent water flushing processes. Via theoretical calculation, tracer experiments, and visible chamber experiments, the mechanisms driving plastics release from natural soils subjected to FT treatments during the water elution processes were determined to be different from those from pure quartz sand. The change of sand local configuration (the rearrangement of local sand pore spaces) during FT process mainly drove to plastics released from quartz sand columns. While the alteration in local soil configuration, the formation of preferential pathways, and increased release of soil particles contributed to plastics remobilization from soil columns subjected to FT. Clearly, FT processes significantly increased the vertical migration of plastics in soils potentially to groundwater, enhancing environmental risks of plastics.

Use of Wheat Fiber and Nanobentonite to Stabilize Clay Subgrades

Since clayey soils naturally present low mechanical strength, they pose direct challenges for engineering applications. Finding appropriate soil stabilizers to address the challenges posed by clayey soils is crucial for ensuring that the soil meets the necessary geotechnical requirements and fulfills economic and environmental issues. To this end, this research uses several stabilizers and techniques in clayey soils to improve their suitability for construction. The main objective of this study is to assess the use of wheat fiber and nanobentonite (NB) in soil stabilization, estimate their behavior in practices, outline their obstacles and potential for soil improvement, and consider their ecological and financial effects. This research also evaluates the behavior of the soil by incorporating NB (0.4, 0.8, and 1.2%) as a stabilizing agent. For this purpose, the randomly dispersed wheat fibers as a reinforcing agent at different dosages and lengths (0.3, 0.6, 0.9%, and 5, 10, and 15 mm) were combined to the soil matrix. The soil was characterized by conducting compaction, unconfined compressive strength (UCS), direct shear (DS), California bearing ratio (CBR), indirect tensile strength (ITS), freezing-thawing (F-T) tests, and microstructural analysis. The data were used to assess the effect of wheat fiber and NB on the soil’s geotechnical properties. The results revealed that incorporating 0.8% NB into the soil led to the best enhancement in compressive strength. This improvement is attributed to the dehydration and formation of a viscous-like film between the soil particles. In addition, 0.6% fibers with a length of 15mm increased the interaction and bonding forces between the particles of soil, resulting in a maximum increase in compressive strength. Combining fibers and NB improved the shear strength, tensile strength, and bearing capacity. Besides, the stabilized soil exhibited superior resistance to freezing-thawing cycles compared to the unreinforced clay. Overall, the results indicate that using wheat fibers and NB is a cost-effective and eco-friendly solution for stabilizing clay subgrades.

Freeze–Thaw Durability and Shrinkage of Calcium Sulfoaluminate Cement Concrete with Internal Curing

Freeze–Thaw Durability and Shrinkage of Calcium Sulfoaluminate Cement Concrete with Internal Curing

Strength Deterioration Mechanism of Interface between Soil–Rock Mixture and Concrete with Different Degrees of Roughness under Freeze–Thaw Cycles

Strength Deterioration Mechanism of Interface between Soil–Rock Mixture and Concrete with Different Degrees of Roughness under Freeze–Thaw Cycles

Relationship between soil structure and hydrological properties of the active layer in the permafrost region of the Qinghai–Tibet Plateau based on fractal theory

Soil structure and hydrological properties influence ecosystem stability and hydrological cycles. Fractal theory has been widely used in the quantitative analysis of soil particle-size distribution (PSD), aggregate and pore distribution, and evaluation of soil degradation, desertification, and wind erosion. However, the complex relationships between soil physiochemical properties and soil hydrological processes based on fractal theory have not been thoroughly investigated. This study focused on the correlation among soil structure, physicochemical properties, and hydrological properties in the active layers of various soil types and vegetation coverages in the permafrost region of the Qinghai–Tibet Plateau (QTP) using the principles of fractal theory. The results showed that the fractal dimension of soil PSD (DPSD) in the active layer of the QTP was predominantly within the range of 2.13–2.70, which is notably smaller than the fractal dimension of the soil water retention curve (DWRC: 2.72–2.93). With decreased vegetation coverage, the alpine soil particles exhibit gradual fineness, increasing the DPSD. Soil physicochemical properties were affected by the interactions among internal factors and the external environment, such as geographical locations, slope orientations, vegetation coverages, and soil freeze–thaw cycles. The results of correlation analysis indicated that the fractal dimension of PSD and the soil water retention curve (WRC) were significantly correlated with soil textural, physicochemical, and hydraulic properties, particularly in clay, silt, and very fine sand content. Finally, a fractal model of WRC in the permafrost region was established based on DPSD and WRC parameters of the Gardner and van Genuchten models. The study provides an improved perspective for revealing the transport process and influencing mechanism of soil water and salt in the active layer of the QTP and a more accurate prediction of soil physiochemical and hydrological properties for climate warming and wetting.

Mechanical Properties of Subgrade Soil Reinforced with Basalt Fiber and Cement under Freeze–Thaw Cycles

Mechanical Properties of Subgrade Soil Reinforced with Basalt Fiber and Cement under Freeze–Thaw Cycles

Lignin fiber reinforced gypsum-cement composite materials: Investigation of fracture properties and freeze–thaw behaviors

Lignin fiber reinforced gypsum-cement composite materials: Investigation of fracture properties and freeze–thaw behaviors

Identification of novel antifreeze peptides from yak skin gelatin ultrasound-assisted enzymatic hydrolysate

In this paper, a new type of antifreeze peptide was identified from the ultrasonic-assisted enzymolysis product of yak skin. First, the antifreeze peptides were obtained by ultrasonic-assisted enzymolysis of yak skin gelatin. The obtained peptides with 150 W ultrasound treatment could increase the survival rate of Lactobacillus plantarum from 16 % to 60 % after four freeze–thaw cycles. Then, the component with the highest antifreeze activity in the peptides’ ultrafiltration product was analyzed by LC-MS/MS to obtain 961 peptides. After screening of antifreeze activity and physical properties, three antifreeze peptide sequences were obtained (S1: GERGGPGGPGPQ, S2: PGGAEGPGRDAQQP, S3: VAPPGAPKKEH). DSC analysis, Lactobacillus plantarum cryoprotection experiments and molecular docking showed that the S1 sequence had the best antifreeze activity. This study provides a new idea for the high-value utilization of yak by-products and a potential candidate for food antifreeze agents.

Optimizing CLM4.5 simulations of the active layer: The role of gravel in Tibetan Plateau permafrost

Gravel is widely distributed in soils of the Tibetan Plateau (TP), where permafrost also occurs over approximately half of the total area. Gravel has different thermal and hydrological properties to those of fine-grained soils, which may have a considerable impact on hydrothermal transport within TP soils. However, few land models consider gravel. Here, we incorporated the thermal and hydraulic properties of gravel into the Community Land Model and explored the effect of differing gravel contents on land surface processes. We found that all parameters affecting soil hydrothermal transport were sensitive to gravel content. Soil thermal and hydraulic conductivities increased with increasing gravel content, ultimately leading to variations in soil temperature, soil water content, and radiation fluxes with changing gravel content. Soil containing gravel exhibited higher infiltration and greater total water storage capacities. We also compared different model schemes in an attempt to improve the simulation of active layers in permafrost regions with high gravel content on the TP. The scheme in which both gravel and freeze–thaw parameterizations were applied (i.e., SP3) improved both the latent heat flux and ground heat flux transfer. The SP3 scheme performed best in terms of soil temperature and soil moisture simulations at both the Nagqu and Madoi field stations, demonstrating a particular ability to better characterize soil moisture processes as a function of temperature during soil freezing and thawing.

Enhancement of Mechanical Properties and Freeze–Thaw Durability of Recycled Aggregate Concrete using Aggregate Pretreatment

Enhancement of Mechanical Properties and Freeze–Thaw Durability of Recycled Aggregate Concrete using Aggregate Pretreatment

Residual textile reinforced mortar‐to‐concrete bond after exposure to harsh environments

AbstractTextile reinforced mortars (TRM) are materials whose mechanical behavior has been extensively investigated during the last few years. However, studies on the behavior of these materials after exposure to various aggressive environments are still limited and, hence, their performance during their entire service life remains to be determined. The present study contributes to the knowledge pool regarding the behavior of concrete specimens furnished with TRM overlays post their exposure to various harsh environments, specifically through the analysis of shear bond tests. More specifically, 120 concrete substrates were reinforced with one and two layers of carbon textile which were embedded into a high and a low strength cementitious mortar and exposed to various harsh environments (carbonation, chlorides, carbonation and chlorides, different number of freeze–thaw cycles). It was concluded that: (i) a reduction of more than 25% is possible regarding failure stress; (ii) the number of textile layers plays an important role in TRM‐concrete bond behavior; and (iii) the influence of mortar strength is limited.

Performance Research and Engineering Application of Fiber-Reinforced Lightweight Aggregate Concrete

Low strength and low impact toughness are two of the main issues affecting the use of lightweight aggregate concrete in harsh cold environments. In this study, the strength of concrete was improved by adding high-strength fibers to bear tensile stress and organize crack propagation. Four sets of comparative experiments were designed with freeze–thaw cycles of 0, 50, 100, and 150 to study the mechanical properties of fiber-reinforced lightweight aggregate concrete under freeze–thaw conditions. A detailed study was conducted on the effects of freeze–thaw on the compressive strength, flexural strength, impact toughness, and microstructure of concrete with different fiber contents (3, 6, and 9 kg/m3). The results show that for ordinary lightweight aggregate concrete, under the freeze–thaw cycle, the internal pore water of the concrete froze and generated expansion stress, resulting in tensile cracks inside the concrete. The cracks gradually accumulated and expanded, ultimately leading to cracking and damage of concrete structures. After 150 cycles, the strength loss rate exceeded 25%. When adding a reasonable amount of fiber (6 kg/m3), the fiber took on the tensile stress and hindered the development of internal cracks, significantly enhancing the splitting tensile strength, flexural strength, and impact toughness of lightweight aggregate concrete. And the failure pattern of concrete was significantly improved. At the beginning of the freeze–thaw cycle, the internal tensile stress was less than the fiber tensile strength and the fiber–matrix bonding strength, and the strength reduction rate of the concrete was slow. Relying on the friction absorption capacity between the fiber and the matrix, the fiber used its own deformation to resist the tensile stress. In the late stage of the freeze–thaw cycle, due to the destruction of the fiber–matrix transition zone structure, the bond strength decreased, the crack resistance and toughening effect decreased, and the strength of the concrete decreased rapidly. Moreover, the reduction in impact toughness was greater than the compressive strength and flexural strength under static load.

Research on the Geosynthetic-Encased Gravel Pile Composite Highway Foundation in Low-Temperature Stable Permafrost Regions

In low-temperature stable permafrost regions, both active and passive cooling measures are commonly employed to ensure the long-term stability of highway structures. However, despite adopting these measures, various types of structural issues caused by permafrost degradation remain prevalent in high-grade highways. This indicates that in addition to preventing permafrost melting, structural reinforcement of the foundation is still necessary. Based on the analysis of the long-term foundation temperature field and settlement using the finite element method, which was validated through an indoor top-down freeze–thaw cycle test, this paper explores, for the first time, the feasibility of applying geosynthetic-encased gravel pile composite highway foundations—previously commonly used for permafrost destruction—in low-temperature stable permafrost areas where permafrost protection is the primary principle. By analyzing the long-term temperature field, settlement behavior, and pile–soil stress ratios of permafrost foundations influenced by both the highway structure and composite foundation, it was found that when the pile diameter is 0.5 m, pile spacing is 2 m, and pile length is 11 m, the mean monthly ground temperature of the permafrost foundation will not be significantly affected. Therefore, the properly designed geosynthetic-encased gravel pile composite highway foundation can be adopted in low-temperature stable permafrost regions where permafrost protection, rather than destruction, is required.

Water–Rock Interaction and Freeze–Thaw Cycles as Drivers of Acid Rock Drainage Generation by a Rock Glacier in the European Alps

Water–Rock Interaction and Freeze–Thaw Cycles as Drivers of Acid Rock Drainage Generation by a Rock Glacier in the European Alps

Comparative Analysis of Sewage Sludge Characteristics After Natural Deposition, Accelerated Aging, and Composting

This study investigated treatment methods for urban wastewater sludge, specifically examining natural drying over five years, accelerated freeze–thaw–drying cycles, and composting with and without a zeolite additive. The findings reveal that composting effectively stabilized the sludge while retaining essential nutrients crucial for agriculture. Notably, with the addition of 2% zeolite by total mass, approximately 40% of the total nitrogen was preserved. Adequate aeration during composting maintained acceptable levels of phosphorus compounds, with the phosphorus content expressed as P2O5 showing significant retention compared with the natural drying methods. Composting also demonstrated a substantial reduction in petroleum hydrocarbon concentrations, which decreased from 30 mg/kg to 3 mg/kg, thereby showcasing its potential for processing contaminated sludge. The inclusion of zeolite enhanced the nitrogen retention by an additional 10–20% compared with the composting without zeolite, aligning with previous studies on its effectiveness. While composting and thermal treatments, like accelerated freeze–thaw cycles, influenced the physical properties of the sludge—such as reducing the moisture content and altering the volatile substance concentrations—they did not significantly affect the heavy metal levels. Natural drying over five years resulted in reduced metal quantities, which possibly reflected changes in the wastewater characteristics over time. Given that the heavy metal concentrations remained largely unchanged, additional treatment methods are recommended when the initial sludge contains high levels of these contaminants to ensure the safe use of the final product as fertilizer. This study underscored the significant role of biochemical and microbiological processes during composting and natural drying in transforming sludge properties. Future research should focus on establishing upper contamination thresholds and exploring microbiological safety measures to enhance the viability of sludge reuse in agriculture, balancing nutrient preservation with environmental safety.

Effect of nano‐SiO2 dispersion on the mechanical properties and frost resistance of modified cement paste

AbstractThe dispersion of nano‐SiO2 (NS) in cement plays a critical role in enhancing the properties of cementitious materials. In this study, the combination of ultrasonic dispersion and polycarboxylic acid water reducing agent (PCE) was used to significantly improve the dispersion of NS. The effects of ultrasonic dispersion time, NS content, and PCE content on dispersion quality were investigated, alongside their impact on mechanical properties, electrical resistivity, and frost resistance. The results demonstrated that this synergistic method optimized the dispersion of NS, leading to superior mechanical properties and frost resistance. With an ultrasonic dispersion time of 40 min, NS content of 1.0 wt.%, and PCE content of 0.75 wt.%, the cement paste achieved its optimal performance. Compared to non‐dispersed samples, compressive strength increased by 33.7%. After 75 freeze–thaw cycles, the mass loss was 2%, the relative dynamic elastic modulus was 99.15%, and the strength loss was 13.74%.

Research on mechanical properties and pore structure evolution process of steam cured high strength concrete under freeze thaw cycles.

With the widespread use of high-strength concrete structures (HC), the impact of pore structure on their performance has become a current research focus. The mechanism by which different curing conditions and freeze-thaw cycles influence the evolution of pore structure remains unclear. Therefore, this study systematically investigated the frost resistance of high-strength concrete under different curing conditions, measured the mass loss rate, compressive strength, and relative dynamic elastic modulus of concrete under freeze-thaw cycles. Utilizing low-field nuclear magnetic resonance (NMR) technology, this study analyzed the evolution of pore structure in HC under freeze-thaw cycles. Additionally, the fractal dimension was used to evaluate the change of concrete internal pore structure, so as to reflect the influence of pore structure on the mechanical properties of concrete subjected to freeze-thaw cycles, and then evaluated the freeze-thaw damage of HC. The experimental results indicated that the steam curing regimes led to an increase in the porosity of HC, thereby influencing its frost resistance. Steam-cured high-strength concrete (SMHC) exhibited a higher degradation rate under freeze-thaw cycles, resulting in a greater level of deterioration compared to standard curing high-strength concrete (SDHC), even under the same number of freeze-thaw cycles.

Prediction of freeze–thaw and thermal shock weathering on natural stones through deep learning-based algorithms

Prediction of freeze–thaw and thermal shock weathering on natural stones through deep learning-based algorithms

The Effect of the Construction of a Tillage Layer on the Infiltration of Snowmelt Water into Freeze–Thaw Soil in Cold Regions

The snow melting and runoff process in the black soil area of Northeast China has led to soil quality degradation in farmland, posing a threat to sustainable agricultural development. To investigate the regulatory effect of tillage layer construction on the infiltration characteristics of snowmelt water, a typical black soil in Northeast China was selected as the research object. Based on field experiments, four protective tillage treatments (CK: control treatment; SB: sub-soiling treatment; BC: biochar regulation treatment; SB + BC: sub-soiling tillage and biochar composite treatment) were set up, and the evolution of soil physical structure, soil thawing rate, snow melting infiltration characteristics, and the feedback effect of frozen layer evolution on snowmelt infiltration were analyzed. The research results indicate that sub-soiling and the application of biochar effectively regulate soil aggregate particle size and increase soil total porosity. Among them, at the 0–10 cm soil layer, the soil mean weight diameter (MWD) values under SB, BC, and SB + BC treatment conditions increased by 6.25%, 16.67%, and 19.35%, respectively, compared to the CK treatment. Sub-soiling increases the frequency of energy exchange between the soil and the environment, while biochar enhances soil heat storage performance and accelerates the melting rate of frozen soil layers. Therefore, under the SB + BC treatment conditions, the maximum soil freezing rate increased by 21.92%, 5.67%, and 25.12% compared to the CK, SB, and BC treatments, respectively. In addition, sub-soiling and biochar treatment effectively improved the penetration performance of snowmelt water into frozen soil layers, significantly enhancing the soil’s ability to store snowmelt water. Overall, it can be concluded that biochar regulation has a good improvement effect on the infiltration capacity of surface soil snowmelt water. Sub-soiling can enhance the overall snowmelt water holding capacity, and the synergistic effect of biochar and deep tillage is the best. These research results have important guiding significance for the rational construction of a protective tillage system model and the improvement of the utilization efficiency of snowmelt water resources in black soil areas.

Hydrophobic treatments and their application with internal wall insulation

Hydrophobic (or water repellent) treatments have been proposed to mitigate moisture risks associated with internal wall insulation when applied to solid masonry walls. This can reduce risks associated with moisture accumulation within the structure such as mould growth or the deterioration of joist ends and other embedded timber. Where treatments perform well there is a net reduction of moisture content and risk. However, such treatments slow down drying processes, and therefore may result in a net increase in moisture if the treatment is bypassed by, for example, cracks. Some treatments may lead to damage to external masonry surfaces in some situations. Freeze–thaw and salt crystallisation are the two main causes. Hygrothermal simulations may give some indication of risks but techniques to assess the risk of surface damage are either simplistic, impractical outside of the research environment or both. This paper reviews the current field of assessing and predicting the risk of surface damage associated with surface treatments.