We first recall the construction of a twisted pre-Lie algebra structure on the species of finite connected topological spaces. Then, we construct a corresponding non-coassociative permutative (NAP) coproduct on the subspecies of finite connected [Formula: see text] topological spaces, i.e. finite connected posets, and we prove that the vector space generated by isomorphism classes of finite posets is a free pre-Lie algebra and also a cofree NAP coalgebra. Furthermore, we give an explicit duality between the non-associative permutative product and the proposed NAP coproduct. Finally, we prove that the results in this paper remain true for finite connected topological spaces.