Excess Fraction Research Articles

Application of hydrogen storage in polygeneration microgrids: Case study of wind microgrid in India

Renewable energy based stand-alone microgrids are highly promising to supply electricity to isolated communities and remote locations. However, both buffer and long-term energy storage are essential due to the highly intermittent nature of renewable sources. By employing hydrogen energy storage with fuel cell and electrolyser in these microgrids, multiple outputs such as electricity, heat, water, and fuel, can be achieved. Design, development and optimization of efficient energy storage system remain a key challenge for the stand-alone microgrid technology. One must ensure that the microgrid satisfies the required electric load but is not over-designed, which is achieved by limiting the two performance parameters i.e., unmet electrical load fraction and excess electricity fraction. The capacities of wind turbine, electrolyser and hydrogen storage are optimized corresponding to the limiting values of unmet electrical load (fUL) and excess electricity (fEX) below 10 %. For the location of Ladakh which has rich availability of wind resource, the optimum size of microgrid is observed to be smallest as WT-20 kW, El-20 kW, H2-15 kg with fUL and fEX as 6.4 % and 8.9 % respectively. The Levelised Cost of Energy (LCOE) is also minimum as 0.89 $/kWh for the location of Ladakh. The distribution of wind resource has significant impact on the size of hydrogen storage. Uniform wind energy with higher velocity round the year reduces the capacity of hydrogen energy storage. Kanyakumari has non-uniform wind resource across different months of the year corresponding to which the capacity of H2 storage is as high as 370 kg.

Temperature-mortality associations by age and cause: a multi-country multi-city study.

Heterogeneity in temperature-mortality relationships across locations may partly result from differences in the demographic structure of populations and their cause-specific vulnerabilities. Here we conduct the largest epidemiological study to date on the association between ambient temperature and mortality by age and cause using data from 532 cities in 33 countries. We collected daily temperature and mortality data from each country. Mortality data was provided as daily death counts within age groups from all, cardiovascular, respiratory, or noncardiorespiratory causes. We first fit quasi-Poisson regression models to estimate location-specific associations for each age-by-cause group. For each cause, we then pooled location-specific results in a dose-response multivariate meta-regression model that enabled us to estimate overall temperature-mortality curves at any age. The age analysis was limited to adults. We observed high temperature effects on mortality from both cardiovascular and respiratory causes compared to noncardiorespiratory causes, with the highest cold-related risks from cardiovascular causes and the highest heat-related risks from respiratory causes. Risks generally increased with age, a pattern most consistent for cold and for nonrespiratory causes. For every cause group, risks at both temperature extremes were strongest at the oldest age (age 85 years). Excess mortality fractions were highest for cold at the oldest ages. There is a differential pattern of risk associated with heat and cold by cause and age; cardiorespiratory causes show stronger effects than noncardiorespiratory causes, and older adults have higher risks than younger adults.

A Census of the β Pic Moving Group and Other Nearby Associations with Gaia* * Based on observations made with the Gaia mission, the Two Micron All Sky Survey, the Wide-field Infrared Survey Explorer, the NASA Infrared Telescope Facility, Cerro Tololo Inter-American Observatory, the Southern Astrophysical Research Telescope, Gemini Observatory, the Spitzer Space Telescope, and the eROSITA instrument on the

I have used the third data release of the Gaia mission to improve the reliability and completeness of membership samples in the β Pic moving group (BPMG) and other nearby associations with ages of 20–50 Myr (Sco Body, Carina, Columba, χ 1 For, Tuc-Hor, IC 2602, IC 2391, NGC 2547). I find that Carina, Columba, and χ 1 For are physically related and coeval, and that Carina is the closest fringe of a much larger association. Similarly, Tuc-Hor and IC 2602 form a coeval population that is spatially and kinematically continuous. Both results agree with hypotheses from Gagné et al. I have used the new catalogs to study the associations in terms of their initial mass functions, X-ray emission, ages, and circumstellar disks. For instance, using the model for Li depletion from Jeffries et al., I have derived an age of 24.7−0.6+0.9 Myr for BPMG, which is similar to estimates from previous studies. In addition, I have used infrared photometry from the Wide-field Infrared Survey Explorer to check for excess emission from circumstellar disks among the members of the associations, which has resulted in a dramatic increase in the number of known disks around M stars at ages of 30–50 Myr and a significant improvement in measurements of excess fractions for those spectral types and ages. Most notably, I find that the W3 excess fraction for M0–M6 initially declines with age to a minimum in BPMG (<0.015), increases to a maximum in Carina/Columba/χ 1 For ( 0.041−0.007+0.009 , 34 Myr), and declines again in the oldest two associations (40–50 Myr). The origin of that peak and the nature of the M dwarf disks at >20 Myr are unclear.

The VISCACHA Survey – XI. Benchmarking SIESTA: a new synthetic CMD fitting code

ABSTRACT We present a novel code, named SIESTA (Statistical matchIng between rEal and Synthetic sTellar popuLations), designed for performing statistical isochrone fitting to colour–magnitude diagrams (CMDs) of single stellar populations by leveraging comparisons between the observed stellar distribution and predictions from synthetic populations, simulated on top of a grid of isochrones. These synthetic populations encompass determinant factors such as the cluster’s initial mass function (IMF), the presence of non-resolved binaries, as well as the expected photometric errors, and observational completeness (or the observed luminosity function). Employing Markov Chain Monte Carlo within a Bayesian framework, SIESTA allows for the determination of a cluster’s age, metallicity, distance, colour excess, and binary fraction (with masses exceeding a certain ratio). In this study, we rigorously benchmark the SIESTA code utilizing synthetic populations and evaluate its performance against observations from the VISCACHA Survey in the Small Magellanic Cloud, focusing on five star clusters: Lindsay 114, NGC 152, Lindsay 91, Lindsay 113, and NGC 121. These clusters were chosen for their diverse age range, spanning from 0.04 to 10 Gyr. Our findings demonstrate the capability of the SIESTA code to accurately represent the observed CMDs of these clusters. Furthermore, we compare the results obtained with SIESTA to previous characterizations of these clusters, highlighting the consistency between the derived metallicity and spectroscopic determinations from various sources.

Capillary blood parameters are gestational age, birthweight, delivery mode and gender dependent in healthy preterm and term infants.

The measurement of blood pH and gas analytes (BPGA), soon after birth, constitutes the first-line standard of care procedure in high-risk newborns. However, no data is available in capillary blood on perinatal bias such as gestational age (GA), weight at birth (BW), delivery mode, and gender. The aims of the present study were to investigate whether in a cohort of healthy preterm (PT) and term (T)infants BPGA were GA, BW, delivery mode and gender dependent, thus affecting BPGA reliability as diagnostic test. We performed a prospective case-control study in 560 healthy infants (PT: n=115, T: n=445). BPGA was measured within 24-h from birth. Perinatal characteristics, outcomes, and clinical examination were also recorded. PT infants showed higher (p<0.001) carbon dioxide partial pressure (pCO2), fraction of fetal hemoglobin (HbF), base excess (BE), bicarbonate (HCO3), and lower lactate (Lac) levels. When corrected for delivery mode, higher (p<0.001) HbF, BE, HCO3, and lower Lac levels were found. Similarly, higher (p<0.05, for all) pCO2, HbF, BE, HCO3 and lower Lac levels were found between female and male PT and T infants. Repeated multiple logistic regression analysis showed that BPGA was GA, BW, delivery mode and gender dependent. The present results showing that BPGA can be affected by a series of perinatal outcomes open the way to further investigations providing longitudinal BPGA reference curves in the transitional phase, thus empowering BPGA role as a reliable diagnostic and therapeutic strategies efficacy marker.

Carpal tunnel syndrome and occupational hand exposures: a Danish nationwide cohort study

ObjectivesThe aim was to examine exposure–response relations between occupational hand exposures and carpal tunnel syndrome (CTS) and to compare the relation between surgery-treated and non-surgery-treated CTS. The secondary aim was...

All-cause, cardiovascular, and respiratory mortality and wildfire-related ozone: a multicountry two-stage time series analysis

Wildfire activity is an important source of tropospheric ozone (O3) pollution. However, no study to date has systematically examined the associations of wildfire-related O3 exposure with mortality globally. We did a multicountry two-stage time series analysis. From the Multi-City Multi-Country (MCC) Collaborative Research Network, data on daily all-cause, cardiovascular, and respiratory deaths were obtained from 749 locations in 43 countries or areas, representing overlapping periods from Jan 1, 2000, to Dec 31, 2016. We estimated the daily concentration of wildfire-related O3 in study locations using a chemical transport model, and then calibrated and downscaled O3 estimates to a resolution of 0·25° × 0·25° (approximately 28 km2 at the equator). Using a random-effects meta-analysis, we examined the associations of short-term wildfire-related O3 exposure (lag period of 0-2 days) with daily mortality, first at the location level and then pooled at the country, regional, and global levels. Annual excess mortality fraction in each location attributable to wildfire-related O3 was calculated with pooled effect estimates and used to obtain excess mortality fractions at country, regional, and global levels. Between 2000 and 2016, the highest maximum daily wildfire-related O3 concentrations (≥30 μg/m3) were observed in locations in South America, central America, and southeastern Asia, and the country of South Africa. Across all locations, an increase of 1 μg/m3 in the mean daily concentration of wildfire-related O3 during lag 0-2 days was associated with increases of 0·55% (95% CI 0·29 to 0·80) in daily all-cause mortality, 0·44% (-0·10 to 0·99) in daily cardiovascular mortality, and 0·82% (0·18 to 1·47) in daily respiratory mortality. The associations of daily mortality rates with wildfire-related O3 exposure showed substantial geographical heterogeneity at the country and regional levels. Across all locations, estimated annual excess mortality fractions of 0·58% (95% CI 0·31 to 0·85; 31 606 deaths [95% CI 17 038 to 46 027]) for all-cause mortality, 0·41% (-0·10 to 0·91; 5249 [-1244 to 11 620]) for cardiovascular mortality, and 0·86% (0·18 to 1·51; 4657 [999 to 8206]) for respiratory mortality were attributable to short-term exposure to wildfire-related O3. In this study, we observed an increase in all-cause and respiratory mortality associated with short-term wildfire-related O3 exposure. Effective risk and smoke management strategies should be implemented to protect the public from the impacts of wildfires. Australian Research Council and the Australian National Health and Medical Research Council.

The short-term effects of individual and mixed ambient air pollutants on suicide mortality: A case-crossover study

It is critical to explore intervenable environmental factors in suicide mortality. Based on 30,688 suicide cases obtained from the Mortality Surveillance System of the Jiangsu Provincial Centre for Disease Control and Prevention, we utilized a case-crossover design, and found that the OR of suicide deaths increased by a maximum of 0.71 % (95 % CI: 0.09 %, 1.32 %), 0.68 % (95 % CI: 0.12 %, 1.25 %), 0.77 % (95 % CI: 0.19 %, 1.37 %), 2.95 % (95 % CI: 1.62 %, 4.29 %), 4.18 % (95 % CI: 1.55 %, 6.88 %), and 0.93 % (95 % CI: 0.10 %, 1.77 %), respectively, for per 10 μg/m3 increase in the particulate matter (PM) with diameters ≤ 2.5 µm (PM2.5), PM with diameters ≤ 10 µm (PM10), ozone (O3), nitrogen dioxide (NO2), sulfur dioxide (SO2), and per 0.1 mg/m3 increase in carbon monoxide (CO) concentrations with the conditional logistic regression analysis. People living in county-level cities were more susceptible. Particularly, a significant positive association was found between air pollutant mixture exposure and suicide deaths (OR=1.04,95 % CI: 1.01, 1.06). The excess fraction of suicide deaths due to air pollution reached a maximum of 8.07 %. In conclusion, we found associations between individual and mixed ambient air pollutants and suicide deaths, informing the development of integrated air pollution management and targeted measures for suicide prevention and intervention. Environmental ImplicationAs a major contributor to the global burden of disease, air pollution was confirmed by accumulating studies to have adverse impact on mental health, and potentially lead to suicide deaths. However, systematic studies on the association between air pollution and suicide mortality are lacking. We explored the associations of multiple air pollutants and pollution mixtures with suicide deaths and assessed excess suicide mortality due to air pollution, emphasizing the importance of air pollution control on suicide prevention. Our study provides evidence to support mechanistic studies on the association between air pollution and suicide, and informs comprehensive air pollution management.

Effects of Excess Air and Energy Fraction on Heat Transfer for Co-firing of Eucalyptus Bark and Peanut Shell Blended Fuel in a Twin-Cyclonic Swirling Fluidized-Bed Combustor

Effects of Excess Air and Energy Fraction on Heat Transfer for Co-firing of Eucalyptus Bark and Peanut Shell Blended Fuel in a Twin-Cyclonic Swirling Fluidized-Bed Combustor

Different Source Contributions of Bioactive Trace Metals in Sinking Particles in the Northern South China Sea

Time-series samples intercepted via three synchronized moored sediment traps, deployed at 1000 m, 2150 m, and 3200 m in the northern South China Sea (NSCS) during June 2009–May 2010, were analyzed to quantify the bioactive trace metal fluxes in sinking particles and investigate their different source contributions. Iron (Fe) primarily originated from lithogenic sources. Manganese (Mn), cobalt (Co), nickel (Ni), copper (Cu), and zinc (Zn) exhibited various degrees of enrichment over their continental crustal ratios. Since the sources of bioactive trace metals in sinking particles can be divided into lithogenic, biogenic, and excess fractions, mass conservation calculations were used to quantify the contribution of each source. The results showed that Fe, Mn, and Co had extremely low biogenic proportions (0.1–3.3%), while Ni, Cu, and Zn had higher proportions (2.7–17.3%), with the biogenic fraction decreasing with the depth. Moreover, excess sources accounted for a significant proportion of Mn (68–75%), Co (34–54%), Ni (60–62%), Cu (59–74%), and Zn (56–65%) in sinking particles at the three sampling depths. The excess fractions of Mn, Co, and Cu in sinking particles can be affected by authigenic particles. This is supported by their similar scavenging-type behavior, as observed via the increase in their fluxes and enrichment patterns with the increasing depth. Furthermore, the excess fractions of Ni, Cu, and Zn may have significant contributions from anthropogenic sources. The variability of Fe in sinking particles was mainly controlled via lithogenic matter. Notably, organic matter and opal were found to be pivotal carriers in the export of excess bioactive trace metals (Mn, Co, Ni, and Cu) via the water column, accompanied with the elevated ballast effect of lithogenic matter with the depth. However, the transportation of excess Zn was more complicated due to the intricate processes involved in Zn dynamics. These findings contribute to our understanding of the sources and transport mechanisms of bioactive trace metals in the marine environment.

Development of long-acting injectable suspensions by continuous antisolvent crystallization: An integrated bottom-up process

Our present work elucidated the operational feasibility of direct generation and stabilization of long-acting injectable (LAI) suspensions of a practically insoluble drug, itraconazole (ITZ), by combining continuous liquid antisolvent crystallization with downstream processing (i.e., centrifugal filtration and reconstitution). A novel microchannel reactor-based bottom-up crystallization setup was assembled and optimized for the continuous production of micro-suspension. Based upon the solvent screening and solubility study, N-methyl pyrrolidone (NMP) was selected as the optimal solvent and an impinging jet Y-shaped microchannel reactor (MCR) was selected as the fluidic device to provide a reproducible homogenous mixing environment. Operating parameters such as solvent to antisolvent ratio (S/AS), total jet liquid flow rates (TFRs), ITZ feed solution concentration and the maturation time in spiral tubing were tailored to 1:9 v/v, 50 mL/min, 10 g/100 g solution, and 96 h, respectively. Vitamin E TPGS (0.5% w/w) was found to be the most suitable excipient to stabilize ITZ particles amongst 14 commonly used stabilizers screened. The effect of scaling up from 25 mL to 15 L was evaluated effectively with in situ monitoring of particle size distribution (PSD) and solid-state form. Thereafter, the suspension was subjected to centrifugal filtration to remove excess solvent and increase ITZ solid fraction. As an alternative, an even more concentrated wet pellet was reconstituted with an aqueous solution of 0.5% w/w Vitamin E TPGS as resuspending agent. The ITZ LAI suspension (of 300 mg/mL solid concentration) has the optimal PSD with a D10 of 1.1 ± 0.3 µm, a D50 of 3.53 ± 0.4 µm and a D90 of 6.5 ± 0.8 µm, corroborated by scanning electron microscopy (SEM), as remained stable after 548 days of storage at 25 °C. Finally, in vitro release methods using Dialyzer, dialysis membrane sac were investigated for evaluation of dissolution of ITZ LAI suspensions. The framework presented in this manuscript provides a useful guidance for development of LAI suspensions by an integrated bottom-up approach using ITZ as model API.

A multi-approach framework for developing feasible, viable, and sustainable hybrid energy systems in remote areas: The case of Con Dao island in Vietnam

In remote communities, hybrid energy systems are increasingly used to improve the reliability and renewability of power supply. The techno-economic analysis is often used to develop these promising energy systems, ignoring some performance indicators and environmental factors. This study proposes a multi-approach framework for developing operationally feasible, economically viable, and environmentally sustainable hybrid energy systems in remote areas. A case study is conducted on Con Dao Island in Vietnam to supply its electricity demand using six on-grid and off-grid hybrid energy systems. After finding the best techno-economic configurations of the six developed systems, they are subjected to multi-approach analysis and exhaustive comparison using a set of performance, economic, and environmental indicators. An off-grid hybrid energy system comprising photovoltaics, wind turbines, lead-acid batteries, and diesel generators has the lowest net present cost (109.7 million USD) to supply the predicted island's electricity consumption (with a total on-site electricity generation of 184.1 GWh/yr). However, this off-grid system indicates the highest excess energy fraction (55%), while the on-grid systems with the ability to export excess energy to the grid have no excess energy fraction. In terms of eco-friendliness, an on-grid hybrid energy system consisting of a high level of photovoltaics and wind turbines shows the best results, with a negative total environmental impact and CO2-eq emissions. This on-grid system shows the best cost of energy (0.1 USD/kWh) with approximately 450% less total environmental impact than the best off-grid system investigated, offsetting about 48.2 kilotonnes of CO2-eq/yr by exporting net emission-free electricity. Overall, the proposed framework can assist decision-makers in finding feasible, viable, and sustainable hybrid energy systems.

Quantitative analysis of phase fraction and mechanical behaviour of friction stir processed carbon steels

Duplex phase microstructure was produced by friction stir processing (FSP) in two steel plates of low and medium carbon wt.%. FSP at the same rotational and traverse velocity resulted in two different combinations of micro constituent phases. For processed low carbon steel (PLCS), it is the combination of 65.9% Ferrite, 9.6% Bainite, and 23% Martensite and for processed medium carbon steel (PMCS), it is 21.7% Ferrite and 74.3% Martensite. Microstructure and X-ray diffraction analyses confirm the presence of Retained austenite in both cases. In addition, it reveals the effect of carbon wt.% of base material on martensitic transformation in the form of lath size, volume fraction, and strength of Martensite. Further, the tensile response (yield strength) is found to be in good agreement with rule of mixture for PLCS only. However, by fixing the volume fraction of Martensite (fM) to 0.60 and neglecting the adverse effect of excess fraction of Martensite, contribution of micro constituent phases to yield strength satisfies the rule of mixture for PMCS too. Finally, yield strength contribution of different constituent phases is 43.5% by Ferrite, 29.4% by Bainite, and 31.2% by Martensite including an negligible error of 0.43% for PLCS, while it is 9.8% by Ferrite and 96.8% by Martensite including an error of 6.6% for PMCS.

On the Generation of Excess Solid Fraction in the RheoMetal Process

Aluminium can be essential in reducing climate impacts as weight reduction is critical. Rheocasting is getting more and more attention from the electronics and automotive industries. The solid fraction in Rheocasting determines the processing outcome. The RheoMetal process is one of the leading processes with the most significant deviation from equilibrium, making presetting the slurry-making parameters difficult. A deeper analysis of the physics of the solid fraction deviation from equilibrium is made based on literature data using a simplistic mathematical model. The developed model confirms that the process is far from equilibrium and that the growth conditions of the freeze-on layer on the cooling agent used in the process determine the slurry temperature and cause the formation of excess solid fraction.

Greenness and excess deaths from heat in 323 Latin American cities: Do associations vary according to climate zone or green space configuration?

Green vegetation may protect against heat-related death by improving thermal comfort. Few studies have investigated associations of green vegetation with heat-related mortality in Latin America or whether associations are modified by the spatial configuration of green vegetation. We used data from 323 Latin American cities and meta-regression models to estimate associations between city-level greenness, quantified using population-weighted normalized difference vegetation index values and modeled as three-level categorical terms, and excess deaths from heat (heat excess death fractions [heat EDFs]). Models were adjusted for city-level fine particulate matter concentration (PM2.5), social environment, and country group. In addition to estimating overall associations, we derived estimates of association stratified by green space clustering by including an interaction term between a green space clustering measure (dichotomized at the median of the distribution) and the three-level greenness variable. We stratified analyses by climate zone (arid vs. temperate and tropical combined). Among the 79 arid climate zone cities, those with moderate and high greenness levels had modestly lower heat EDFs compared to cities with the lowest greenness, although protective associations were more substantial in cities with moderate versus high greenness levels and confidence intervals (CI) crossed the null (Beta: −0.41, 95% CI: −1.06, 0.25; Beta −0.23, 95% CI: −0.95, 0.49, respectively). In 244 non-arid climate zone cities, associations were approximately null. We did not observe evidence of effect modification by green space clustering. Our results suggest that greenness may offer modest protection against heat-related mortality in arid climate zone Latin American cities.

Short-term exposure to sulfur dioxide and daily mortality in Brazil: A nationwide time-series study between 2003–2017

Sulfur dioxide (SO2), despite its ubiquitousness, there is relatively less epidemiological evidence regarding the health risks associated with SO2 compared to other pollutants, especially in low-income countries where there are high levels of SO2 emissions. In this study, we estimated the association between ambient SO2 exposure and daily mortality in Brazil over a period of 15 years (2003–2017). We used an extension of the two-stage time-series design in a time-series analytic approach with a distributed lag model. The study population consisted of 2,872,084 death records, with a higher proportion of male deaths observed across all-cause mortality (58%). The majority of the individuals were aged above 65 years. The mean SO2 concentration across the study period was 1.5 μg/m³ (range: 0.0 to 71.0). The national meta-analysis for the whole dataset (without stratification by sex and age) showed an uncertain association, in which a 10 μg/m3 increase in daily SO2 was associated with an RR of mortality of 1.015 (95%CI: 0.992; 1.037). Robust associations were observed only for the subgroup analysis of people 46–65 years old [RR = 1.050 (95%CI: 1.004; 1.096)] and men 46–65 years old [RR = 1.064 (95%CI: 1.005; 1.122)]. We found moderate heterogeneity in the national analysis, with an I2 of 21% for the subgroup of people 46–65 years old. Excess mortality fraction for people between 46 and 65 years old attributable to per 10 μg/m3 increase in SO2 was 2.93% (95% eCI: 0.29%–6.78%). These results highlight the need for targeted air pollution control policies to reduce the health burden of SO2 exposure in Brazil. Further research is needed to fully understand the mechanisms behind the age-specific and regional effects of SO2 on mortality.

Effects of drought and nutrient deficiencies on the allocation of recently fixed carbon in a plant-soil-microbe system.

Carbon (C) allocation plays an important role in plant adaptation to water and nutrient stresses. However, the effects of drought and nutrient deficiencies on the allocation of recently fixed C in the plant-soil-microbe system remain largely unknown. Herein, we studied the response of C allocation of Sophora moorcroftiana (an indigenous pioneer shrub in Tibet) to drought, nitrogen (N) deficiency and phosphorus (P) deficiency using a microcosm experiment. The 13CO2 continuous labeling was used to trace C allocation in the plant-soil-microbe system. We found that drought significantly reduced plant 13C, but it increased 13C accumulation in soil. The decreased plant 13C under drought was attributed to the decrease of 13C in stem and root rather than that in leaf. The excess 13C fraction in the microbial biomass (MB13C) was reduced by N deficiency, but it was not affected by the combination of drought and N deficiency, indicating that drought weakened the effects of N deficiency on MB13C. By contrast, MB13C increased under the combination of drought and P deficiency, suggesting that drought enhanced the effects of P deficiency on MB13C. Drought and nutrient deficiencies regulated the belowground 13C allocation. Specifically, drought and P deficiency increased the allocation of 13C to root and N deficiency regulated the allocation of 13C to microbial biomass C and dissolved organic C in soil. Notably, soil 13C decreased with increasing plant 13C, while MB13C first decreased and then increased with increasing plant 13C. Overall, our study demonstrated that drought and nutrient deficiencies interactively affected C allocation in a plant-soil-microbe system and provided insights into C allocation strategies in response to multiple resource (water and nutrient) stresses under environmental changes.

Temporal dynamics and controlling factors of CO2 and CH4 variability in the urban atmosphere of Wroclaw, Poland

Temporal and spatial distribution of both biogenic and anthropogenic components of atmospheric carbon dioxide (CO2) and methane (CH4) is crucial for understanding the environmental impacts of climate change over urban areas. This research focuses on applying stable isotope source-partitioning studies to determine the interactions between biogenic and anthropogenic CO2 and CH4 emissions in an average-sized city environment. Study signifies the weight of instantaneous variability and diurnal averaging as compared with seasonal records of variations of the atmospheric CO2 and CH4 at a variety of typical urban sites in the city of Wroclaw, conducted during a one-year period from June 2017 to August 2018.The findings reveal distinct temporal variations in atmospheric CO2 and CH4 mole fractions and their isotopic composition. The average atmospheric CO2 and CH4 mole fractions during the study period were 416.4 ± 20.5 ppm, and 1.95 ± 0.09 ppm, respectively. The study highlights the high variability of driving forces, including current energy use patterns, natural carbon reservoirs, planetary boundary layer dynamics, and atmospheric transport. Additionally, the relationship between the evolution of the convective boundary layer depth and the CO2 budget was analyzed using the CLASS model with input parameters based on field observations, resulting in insights such as an increase in the range of 25–65 ppm of CO2 during stable nocturnal boundary layers.The observed changes in stable isotopic signatures of air samples allowed for the identification of two main source categories in the city area: fuel combustion and biogenic processes. The δ13C-CO2 values of collected samples suggest that biogenic emissions dominate (up to 60 % of CO2 excess mole fraction) during the growing season, but are reduced by plant photosynthesis during summer afternoons. In contrast, local fossil-fuel CO2 contribution (up to 90 % of excess CO2 mole fraction) from domestic heating, vehicle emissions, and heat and power plants predominantly influence the urban GHG budget during winter. The δ13C-CH4 values indicate anthropogenic sources related to fossil fuel combustion during winter, with values ranging from −44.2 ‰ to −51.4 ‰, while slightly more depleted values, between −47.1 ‰ and −54.2 ‰, reflect a larger input of biological processes in the methane urban budget during summer.Overall, instantaneous and hourly variability of the above-mentioned readings of gas mole fraction and isotopic composition, have shown higher variability than seasonal amplitudes. Hence, respecting this granularity is the key to alignment and understanding significance of such localized atmospheric pollution studies. Additionally, the changing overprint of the system's framework, such as variability of wind and atmospheric layering patterns, weather events, provides context of sampling and data analysis at different frequencies.

The fate of biodegradable plastic during the anaerobic co-digestion of excess sludge and organic fraction of municipal solid waste

Co-digestion of the organic fraction of municipal solid waste (OFMSW) and excess sludge has several benefits especially related to improved methane production and better process stability. In recent years, the presence of biodegradable plastics is increasingly common in OFMSW especially since, as in Italy, biodegradable bags are used for its collection. In this paper, the influence and the fate of biodegradable bags during anaerobic co-digestion of excess sludge and OFMSW are assessed. The best results in terms of methane yield (about 180 NmL/gVS) have been obtained with the 50:50 (VS basis) co-digestion of excess sludge and OFMSW with an organic loading rate of 2 kgVS/m3·d. Bioplastic degradation is very limited during the co-digestion but it does not influence methane production or digestate chemical characteristics. However, the feeding of bioplastic bags seems to induce a higher phytotoxicity and the presence of undigested fragments is anyway a problem for further treatment or direct utilization of digestate.

Improved Algorithms of Data Processing for Dispersive Interferometry Using a Femtosecond Laser

Two algorithms of data processing are proposed to shorten the unmeasurable dead-zone close to the zero-position of measurement, i.e., the minimum working distance of a dispersive interferometer using a femtosecond laser, which is a critical issue in millimeter-order short-range absolute distance measurement. After demonstrating the limitation of the conventional data processing algorithm, the principles of the proposed algorithms, namely the spectral fringe algorithm and the combined algorithm that combines the spectral fringe algorithm with the excess fraction method, are presented, together with simulation results for demonstrating the possibility of the proposed algorithms for shortening the dead-zone with high accuracy. An experimental setup of a dispersive interferometer is also constructed for implementing the proposed data processing algorithms over spectral interference signals. Experimental results demonstrate that the dead-zone using the proposed algorithms can be as small as half of that of the conventional algorithm while measurement accuracy can be further improved using the combined algorithm.