Young Water Fractions Research Articles

Effects of Short‐Term Climate Variations on Young Water Fraction in a Small Pre‐Alpine Catchment

AbstractContinuous and extended observations of hydrometeorological parameters, alongside the analysis of the isotopic composition across diverse waters within catchments, can significantly enhance our understanding of the potential ramifications of climate change on the hydrological response. In this study, a comprehensive analysis of hydrometeorological and isotopic data was conducted over 10 hydrological years (October 2012–September 2022) within a small, forested catchment in the Italian pre‐Alps, aiming to investigate the impacts of short‐term climatic changes on the isotopic composition of waters and the young water fraction (Fyw). The results showed that the catchment experienced climate conditions with rapid warming and drying trends. Significant isotopic enrichments were observed in all sampled water sources, driven primarily by air temperature. Fyw was estimated to be 0.64 ± 0.06, 0.45 ± 0.07, and 0.16 ± 0.03 for stream water, soil water, and shallow groundwater based on the whole‐period sinusoidal fittings, respectively. Comparative analyses comprising different approaches for the estimation of Fyw showed that time‐windows scenarios and detrending corrections yielded smaller Fyw than approaches based on the whole‐period fitting and discharge‐sensitivity modeling. Such differences can be attributed to an uneven temporal distribution of stream water isotopic data, the difficulties in capturing high flows in a humid catchment characterized by a fast runoff response during rainfall‐runoff events, and the presence of isotopic trends. Our findings underscore the imperative of integrating interannual isotopic trends and adopting appropriate sampling strategy and methodological approaches to ensure a robust Fyw estimation.

Can the young water fraction reduce predictive uncertainty in water transit time estimations?

Transit time distributions (TTDs) of streamflow are informative descriptors of catchment hydrological functioning and solute transport mechanisms. Conventional methods for estimating TTDs generally require model calibration against extensive tracer data time series, which are often limited to well-studied experimental catchments. We challenge this limitation and propose an alternative approach that uses the young water fraction (Fywobs), an increasingly used water age metric which represents the proportion of streamflow with a transit time younger than 2-3 months, and that can be robustly estimated with sparsely measured tracer data. To this end, we conducted a proof of concept study by modelling TTDs using StorAge Selection (SAS) functions with oxygen isotopes (δ18O) measurements for 23 diverse catchments in Germany. In a Monte-Carlo approach, we computed the (averaged) marginal TTDs of a prior parameter distribution and derived a model-based Fyw (Fywsim). We compared Fywsim with Fywobs, obtained from δ18O measurements, and constrained the prior SAS parameters distribution. Subsequently, we derived a posterior distribution of parameters and resulting model simulations. Our findings showed that using Fywobs to constrain the model effectively reduced parameter equifinality and simulation uncertainty. However, the value of Fywobs on reducing model uncertainty varied across sites, with larger values (Fywobs≥0.10) leading to simulations with a narrower uncertainty band and higher model efficiency, whilst smaller values (Fywobs≤0.05) had limited influence on reducing model output uncertainty. We discussed the potential and limitations of combining SAS functions with Fywobs, and considered broader implications of this approach for enhancing our understanding of catchment functioning and water quality status.

Potential Amplifiers of Hydrological Drought: A Deep Dive into the Seasonal Variations of New, Young, and Old Water Fractions in the Stream Discharge of a Pre-Alpine Catchment

This study examines runoff generation processes by focusing on new, young, and old water fractions in the stream discharge within the Swiss pre-Alpine Alp catchment and its smaller tributaries, Erlenbach and Vogelbach. Young water represents a contribution from the three most recent rainfall-runoff events. This research utilises a four-year time series of daily stable water isotope data from stream water and precipitation to investigate seasonal variations. An extended two-component hydrograph separation method is applied to analyse the catchment water and tracer mass balance across both the event and pre-event time axes. The calculated new, young and old water components in stream discharge help estimate time-varying backward travel time distributions. Factors such as air temperature, snow depth, and evapotranspiration data are considered to understand isotope fractionation because of phase changes. The results suggest that discharge generated in autumn and winter may have longer backward travel times compared with spring or summer discharge. Additionally, forest cover influences water fractions older than 40 days. The study identifies a nivo-pluvial runoff regime, with new water fractions peaking in August (Erlenbach, Vogelbach) and January (Alp). Young water fractions reach their highest levels at the start of winter and during snowmelt, while old water fractions peak towards the end of snowmelt and in mid-autumn. The Alp catchment and its tributaries exhibit higher new and young water components than old water following a month of low precipitation and high evapotranspiration in July. These findings are significant in light of the projected drier summers in Central Europe.

Monthly new water fractions and their relationships with climate and catchment properties across Alpine rivers

Abstract. The Alps are a key water resource for central Europe, providing water for drinking, agriculture, and hydropower production. Thus, understanding runoff generation processes of Alpine streams is important for sustainable water management. It is currently unclear how much streamflow is derived from old water stored in the subsurface and how much stems from more recent precipitation that reaches the stream via near-surface quick flow processes. It is also unclear how this partitioning varies across different Alpine catchments in response to hydroclimatic forcing and catchment characteristics. Here, we use stable water isotope time series in precipitation and streamflow to quantify the young water fractions (Fyw; i.e., the fraction of water younger than approximately 2–3 months) and new water fractions (Fnew; here, the fraction of water younger than 1 month) in streamflow from 32 Alpine catchments. We contrast these measures of water age between summer and winter and between wet and dry periods and then correlate them with hydroclimatic variables and physical catchment properties. New water fractions varied between 3.5 % and 9.6 %, with values of 9.2 % in rainfall-dominated catchments, 9.6 % in hybrid catchments, and 3.5 % in snow-dominated catchments (mean across all catchments of 7.1 %). Young water fractions were approximately twice as large (reflecting their longer timescale) and ranged between 10.1 % and 17.6 %, with values of 17.6 % in rainfall-dominated catchments, 16.6 % in hybrid catchments, and 10.1 % in snow-dominated catchments (mean across all catchments of 14.3 %). New water fractions were negatively correlated with catchment size (Spearman rank correlation, rS, of −0.38), q95 baseflow (rS=-0.36), catchment elevation (rS=-0.37), total catchment relief (rS=-0.59), and the fraction of slopes steeper than 40° (rS=-0.48). Large new water fractions, implying faster transmission of precipitation to streamflow, are more prevalent in small catchments, at low elevations, with small elevation differences, and with large fractions of forest cover (rS=0.36). New water fractions averaged 3.3 % following dry antecedent conditions, compared with 9.3 % after wet antecedent conditions. Our results quantify how hydroclimatic and physical drivers shape the partitioning of old and new waters across the Alps, thus indicating which landscapes transmit recent precipitation more readily to streamflow and which landscapes tend to retain water over longer periods. Our results further illustrate how new water fractions may find relationships that remained invisible with young water fractions.

Nitrate trend reversal in Dutch dual-permeability chalk springs, evaluated by tritium-based groundwater travel time distributions

Historical use of fertilizer and manure on farmlands is known to have a lasting impact on ecosystems and water resources, but few studies assess the legacy of nitrate pollution on groundwater and surface water after farming applications were reduced. We studied the response of nitrate in spring water to a reduction of nitrogen fertilizer applications in agriculture realized since the mid-1980s. We assessed the travel time distribution of groundwater based on a time series of tritium measurements for 90 springs and small brooks that drain a dual porosity chalk aquifer. The travel time distributions were constrained using the tritium data in combination with time series of nitrate concentrations, applying a shape-free travel time distribution model. A clear trend reversal of nitrate concentrations was observed and simulated for springs with a large fraction of young water (< 30 years old) whereas the nitrate response in springs with relatively older water was attenuated and delayed. We conclude that obtaining a time series of tritium data helps to constrain age distributions of water that is discharged from dual permeability aquifers. The fraction of water aged <30 years was a meaningful parameter to distinguish between different types of springs. Nitrate trends in springs that drain large fractions of young water (> 0.6) show higher peak concentrations, shorter lag-time between leaching and outflow peaks and steeper declines after trend reversal, relative to trends in springs which are dominantly fed by older groundwater. The study thus shows that the nitrate legacy of groundwater systems is strongly determined by the range of their travel time distributions, and trend reversal in receiving springs and surface waters may appear within 10 to 15 years after measures to reduce nitrate losses from farming.

Saturated hydraulic conductivity (Ksat) and topographic controls on baseflow contribution in high-altitude aquifers with complex geology

Mountains in general are important sources of water resources and correspondingly, the Upper Indus Basin (UIB) in the Himalayas provides water for hundreds of millions of users. During low-flow periods, streamflow is fed by a combination of groundwater (baseflow), snow/glacier melt and recent precipitation. However, the proportion of stream baseflow generated by different sources and the factors that control these contributions remain poorly understood. In this paper, we focus on the Western Himalayan Liddar watershed (1243 km2) in the UIB and use a multi-method approach to characterize aquifers and baseflow generation in three nested catchments which represent varying geology and topography. Our multi-method approach includes geophysical surveys, slug tests, stable isotope compositions, young water fraction (Fyw) estimation and a Bayesian end member mixing model. Specifically, we hypothesize that Ksat of the subsurface plays a critical role in the contribution of groundwater to baseflow. The watershed is subdivided into three nested catchments (Limestone, hardrock and alluvium). Our results indicate that the upstream, steep, high-permeability limestone catchment has the relatively largest groundwater contribution to streamflow (63–78 %) and a low Fyw (38 %) than the other two sites. The mid-elevation hard rock catchment has a lower permeability on average but is highly variable due to fracture networks and geologic contacts, allowing a substantial groundwater contribution to streamflow (38–66 %) and a similar Fyw (36 %) to the limestone catchment. The downstream, low-slope catchment underlain by alluvium has a highly variable hydraulic conductivity and a substantially lower groundwater contribution to streamflow (26–45 %) and a higher Fyw (55 %). We find that both hydraulic conductivity and topography exert control on the magnitude of baseflow contribution to the stream. However, Ksat acts as a key control in groundwater contribution to baseflow as observed in headwaters and downstream region of the watershed. While unconsolidated deposits are often thought of as important high-porosity mountain aquifers, our results point to the importance of fractured and karstified bedrock in baseflow generation in high mountains. As climate change alters the snow- and ice-melt regimes of UIB rivers, our study underscores the critical importance of improving our understanding of baseflow sources.

Mechanisms of Suprapermafrost Groundwater Recharge Streamflow in Alpine Permafrost Regions: Insights From Young Water Fraction Analysis

AbstractThis study investigates the temporal processes of suprapermafrost groundwater (SPG)‐supplied streamflow in alpine permafrost regions, aiming to fill the gap in understanding this process from a water‐age perspective. Precipitation, streamflow, and SPG samples were collected from the Three‐Rivers Headwaters Region (TRHR). We defined the physical meaning of Fyw (the young water fraction) of the SPG and calculated it for the first time. The results showed that in the TRHR, the SPG mean travel time (MTT) was 159 days, and approximately 46.4% of SPG was younger than 77 days, whereas the streamflow MTT was 342 days, and approximately 12.2% of the streamflow was younger than 97 days. The correlation analysis revealed that various climatic factors played dominant roles in the recharge time variations of the SPG‐supplied streamflow within the TRHR. The SPG recharge rate did not significantly affect the streamflow Fyw; however, the thickness of the active layer ultimately controlled the SPG transit time distribution. Regression analysis further demonstrated the nonlinear impact of precipitation, average temperature, and average freezing days on SPG Fyw, which is closely related to seasonal freeze–thaw heat conduction and groundwater heat advection in the active layer. During the initial ablation period, the streamflow was primarily recharged by young SPG, resulting in a short‐tail travel time distribution. Our findings provide valuable insights into runoff generation and concentration processes in permafrost regions and have important implications for water resource management.

Technical note: Two-component electrical-conductivity-based hydrograph separation employing an exponential mixing model (EXPECT) provides reliable high-temporal-resolution young water fraction estimates in three small Swiss catchments

Abstract. The young water fraction represents the portion of water molecules in a stream that have entered the catchment relatively recently, typically within 2–3 months. It can be reliably estimated in spatially heterogeneous and nonstationary catchments from the amplitude ratio of seasonal isotope (δ18O or δ2H) cycles of stream water and precipitation, respectively. Past studies have found that young water fractions increase with discharge (Q), thus reflecting the higher direct runoff under wetter catchment conditions. The rate of increase in the young water fraction with increasing Q, defined as the discharge sensitivity of the young water fraction (Sd*), can be useful for describing and comparing catchments' hydrological behaviour. However, the existing method for estimating Sd*, which only uses biweekly isotope data, can return highly uncertain and unreliable Sd* when stream water isotope data are sparse and do not capture the entire flow regime. Indeed, the information provided by isotope data depends on when the respective sample was taken. Accordingly, the low sampling frequency results in information gaps that could potentially be filled by using additional tracers sampled at a higher temporal resolution. By utilizing high-temporal-resolution and cost-effective electrical conductivity (EC) measurements, along with information obtainable from seasonal isotope cycles in stream water and precipitation, we develop a new method that can estimate the young water fraction at the same resolution as EC and Q measurements. These high-resolution estimates allow for improvements in the estimates of the Sd*. Our so-called EXPECT (Electrical-Conductivity-based hydrograph separaTion employing an EXPonential mixing model) method is built upon the following three key assumptions: We construct a mixing relationship consisting of an exponential decay of stream water EC with increasing young water fraction. This has been obtained based on the relationship between flow-specific young water fractions and EC. We assume that the two-component EC-based hydrograph separation technique, using the above-mentioned exponential mixing model, can be used for a time-source partitioning of stream water into young (transit times &lt; 2–3 months) and old (transit times &gt; 2–3 months) water. We assume that the EC value of the young water endmember (ECyw) is lower than that of the old water endmember (ECow). Selecting reliable values from measurements of ECyw and ECow to perform this unconventional EC-based hydrograph separation is challenging, but the combination of information derived from the two tracers allows for the estimation of endmembers' values. The two endmembers have been calibrated by constraining the unweighted and flow-weighted average young water fractions obtained with the EC-based hydrograph separation to be equal to the corresponding quantities derived from the seasonal isotope cycles. We test the EXPECT method in three small experimental catchments in the Swiss Alptal Valley using two different temporal resolutions of Q and EC data: sampling resolution (i.e. we only consider Q and EC measurements during dates of isotope sampling) and daily resolution. The EXPECT method has provided reliable young water fraction estimates at both temporal resolutions, from which a more accurate discharge sensitivity of the young water fraction (SdEXP) could be determined compared with the existing approach. Also, the method provided new information on ECyw and ECow, yielding calibrated values that fall outside the range of measured EC values. This suggests that stream water is always a mixture of young and old water, even under very high or very low wetness conditions. The calibrated endmembers revealed a good agreement with both endmembers obtained from an independent method and EC measurements from groundwater wells. For proper use of the EXPECT method, we have highlighted the limitations of EC as a tracer, identified certain catchment characteristics that may constrain the reliability of the current method and provided recommendations about its adaptation for future applications in catchments other than those investigated in this study.

Lessons learned from the spatiotemporal analysis of long‐term and time‐variable young water fractions of large central European river basins

AbstractThe transit time of precipitation entering a catchment and leaving it as streamflow spatiotemporally varies according to the flow paths that precipitation takes. However, investigating influences of hydrometeorological variables and catchment characteristics on time‐variable transit times is challenging due to the complex water flow through heterogeneous landscapes. Recent studies investigated the fraction of streamflow younger than approximately 3 months (Fyw) using multi‐year data (long‐term Fyw) or one‐year calculation windows to investigate its time‐variability (time‐variable Fyw). Nonetheless, it is still unclear if the inter‐annual variability of one‐year Fyw is due to hydrological influences or its uncertainty, and no minimum time series length for the long‐term Fyw was defined yet. Here, we investigated the impact of catchment characteristics and hydrometeorological variables on the long‐term Fyw, the time‐variable Fyw, and the Fyw depending on discharge of nine river basins in Central Europe. All methods of estimating Fyw led to similar results, with Fyw depending on discharge deemed unreliable due to the monthly sampling interval of streamflow isotopes. Danube and Rhine had the lowest Fyw (0.06), medium Fyw (0.20) were found in eastern basins (e.g., Oder), and the western ones (e.g., Mosel) had the highest Fyw (0.33). Spatial analysis indicated a negative relationship between Fyw and altitude. Contradicting or lacking spatiotemporal relationships to other variables pointed to unknown influential factors controlling the runoff process. Using flow duration curves, it was found that basins with a low flow variability had low Fyw, indicating that the old water of their runoff stems from large subsurface storage. With increasing calculation window size, the within‐basin variability of time‐variable Fyw decreased. Long‐term Fyw depended on the method used to define ‘long‐term’ and the time series length and start and end date. We thus recommend future studies to calculate long‐term and time‐variable Fyw to facilitate comparability between different catchments, and to account for this source of uncertainty. Further, more studies are needed in diverse catchments to investigate the hydrometeorological impacts on Fyw and thus on runoff generation processes.

Changes in Water Age During Dry‐Down of a Non‐Perennial Stream

AbstractNon‐perennial streams, which lack year‐round flow, are widespread globally. Identifying the sources of water that sustain flow in non‐perennial streams is necessary to understand their potential impacts on downstream water resources, and guide water policy and management. Here, we used water isotopes (δ18O and δ2H) and two different modeling approaches to investigate the spatiotemporal dynamics of young water fractions (Fyw) in a non‐perennial stream network at Konza Prairie (KS, USA) during the 2021 summer dry‐down season, as well as over several years with varying hydrometeorological conditions. Using a Bayesian model, we found a substantial amount of young water (Fyw: 39.1–62.6%) sustained flows in the headwaters and at the catchment outlet during the 2021 water year, while 2015–2022 young water contributions estimated using sinusoidal models indicated smaller Fyw amounts (15.3% ± 5.7). Both modeling approaches indicate young water releases are highly sensitive to hydrological conditions, with stream water shifting to older sources as the network dries. The shift in water age suggests a shift away from rapid fracture flow toward slower matrix flow that creates a sustained but localized surface water presence during late summer and is reflected in the annual dynamics of water age at the catchment outlet. The substantial proportion of young water highlights the vulnerability of non‐perennial streams to short‐term hydroclimatic change, while the late summer shift to older water reveals a sensitivity to longer‐term changes in groundwater dynamics. Combined, this suggests that local changes may propagate through non‐perennial stream networks to influence downstream water availability and quality.

Topographic influence on ecohydrology in volcanic watersheds of the western Pacific monsoon area: evidence from water stable isotope composition of meteoric water, thermal water, and plants

ABSTRACT In Taiwanese volcanic watersheds, we investigated stable water isotopes in meteoric water, plants, and thermal water. Meteoric water exhibited a seasonal cycle, with heavier isotopes in winter and lighter ones in summer, especially in the southern region. The northern monsoon signal lagged the south by two weeks. In the Tatun mountains, young water fractions indicated prevalent old water sources. In the northern watershed, streamwater mainly came from the winter monsoon, while the southern one was influenced by alternating monsoons. Both indices indicated that winter plants depended on summer rainfall. Streamwater and plants had distinct sources in winter, supporting ecohydrological separation. Thermal spring water’s d-excess helped identify water–rock interactions, with low d value signaling such interactions. The topographic wetness index showed a higher summer monsoon contribution to southern streamwater but a lower one to plants. The mean linear channel direction significantly affected the monsoon contribution fraction, with northeast-oriented channels vulnerable to northeastward winter monsoons. Finally, we developed a model illustrating hydrological processes on short and long timescales. Our findings enhance our understanding of hydrological disturbances’ impact on water resources and ecosystems.

The age and sources of stream water in a boreal forest watershed in the permafrost region: a case study of a watershed in northeast China

Determining the age and sources of stream water is critical for understanding the watershed hydrological processes and biogeochemical cycle. In this study, daily isotope data of rainfall and runoff, as well as continuously monitored conductivity data from June to October in 2019 in-Laoyeling(LYL) watershed located in permafrost region of northeastern China were used to separate streamflow components through the application of two independent methods: isotope-based hydrograph separations (IHS) and the conductivity mass balance (CMB) methods. The results showed that stream water in a boreal forest watershed with permafrost of the Daxing’an Mountains is mainly composed of pre-event water. Although the IHS method is more sensitive and provides more details than the CMB method, the results of both methods show a similar trend. The average value of the young water fractions (Fyw) for those aged less than 65 days is 5.6%, while the mean transit time (MTT) was calculated to be 3.33 years. These findings enhance our understanding of the fundamental characteristics of runoff generation mechanisms and changes in runoff components in permafrost regions. Such knowledge is crucial for effective regional water resource management under the context of climate change, such as construction of water conservancy facilities and prediction of flood and drought disasters.

Mean transit time of water bodies in a typical soil-plant-atmosphere continuum of the subtropical monsoon region

The mean transit time (MTT) is a good indicator of water cycle processes. We know little about the MTT of different water bodies within the soil-plant-atmosphere continuum (SPAC) in the subtropical monsoon region. We estimated the MTT of stratified soil water at different depths as well as the xylem water and leaf water in typical Cinnamomum camphora woodland located in Changsha City from March 2017 to October 2019. The main methods used in this study included the stable isotope technology, the linear mixed model and the sine wave fitting method. The results showed that the stable isotopes were more depleted in summer and enriched in winter for different water bodies within the SPAC. The δ2H values of soil water gradually decreased as depth increased. The δ2H values of xylem water closely resembled those of soil water, but the δ2H values of leaf water were more positive and exhibited larger variation. Results of the linear mixed model indicated that the lower MTT values of soil water and plant water occurred between June and September, while the higher values were often observed around January and from April to May. The precipitation replenishment exhibited a significant negative correlation with the MTT. The MTT of soil water generally increased with depth, although preferential flow could enhance the replenishment of deeper soil water and subsequently reduce the MTT. The mean MTT values of xylem water and leaf water were similar. Results of the sine wave fitting method showed that the young water fraction (Fyw) of soil water gradually decreased as depth increased, while the MTT of soil water gradually increased as depth increased. The Fyw and MTT of xylem water were lower and higher than those of leaf water, respectively. Both the mean MTT values of soil water based on the linear mixed model or the sine wave fitting method increased from the surface to the deeper soil layers. The former exhibited a smaller variation range and the latter showed a larger variation range. The mean MTT value of xylem water based on the linear mixed model was 2.4 days less than that of leaf water, while the MTT value of xylem water in the sine wave fitting method was 87.4 days higher than that of leaf water. These differences may be due to the parameterization of "new/young water", the uncertainty of results, and the effect of evaporative fractionation. This study contributes to a better understanding of water transport and consumption processes within the SPAC and provides valuable insights for agricultural production and water resources management in the subtropical monsoon region.

The seasonal origins and ages of water provisioning streams and trees in a tropical montane cloud forest

Abstract. Determining the sources of water provisioning streams, soils, and vegetation can provide important insights into the water that sustains critical ecosystem functions now and how those functions may be expected to respond given projected changes in the global hydrologic cycle. We developed multi-year time series of water isotope ratios (δ18O and δ2H) based on twice-monthly collections of precipitation, lysimeter, and tree branch xylem waters from a seasonally dry tropical montane cloud forest in the southeastern Andes mountains of Peru. We then used this information to determine indices of the seasonal origins, the young water fractions (Fyw), and the new water fractions (Fnew) of soil, stream, and tree water. There was no evidence for intra-annual variation in the seasonal origins of stream water and lysimeter water from 1 m depth, both of which were predominantly comprised of wet-season precipitation even during the dry seasons. However, branch xylem waters demonstrated an intra-annual shift in seasonal origin: xylem waters were comprised of wet-season precipitation during the wet season and dry-season precipitation during the dry season. The young water fractions of lysimeter (&lt; 15 %) and stream (5 %) waters were lower than the young water fraction (37 %) in branch xylem waters. The new water fraction (an indicator of water ≤ 2 weeks old in this study) was estimated to be 12 % for branch xylem waters, while there was no significant evidence for new water in stream or lysimeter waters from 1 m depth. Our results indicate that the source of water for trees in this system varied seasonally, such that recent precipitation may be more immediately taken up by shallow tree roots. In comparison, the source of water for soils and streams did not vary seasonally, such that precipitation may mix and reside in soils and take longer to transit into the stream. Our insights into the seasonal origins and ages of water in soils, streams, and vegetation in this humid tropical montane cloud forest add to understanding of the mechanisms that govern the partitioning of water moving through different ecosystems.

Relationship between isotope ratios in precipitation and stream water across watersheds of the National Ecological Observation Network

AbstractThe timescales associated with precipitation moving through watersheds reveal processes that are critical to understanding many hydrologic systems. Measurements of environmental stable water isotope ratios (δ2H and δ18O) have been used as tracers to study hydrologic timescales by examining how long it takes for incoming precipitation tracers become stream discharge, yet limited measurements both spatially and temporally have bounded macroscale evaluations so far. In this observation driven study across North American biomes within the National Ecological Observation Network (NEON), we examined δ18O and δ2H stable water isotope in precipitation (δP) and stream water (δQ) at 26 co‐located sites. With an average 54 precipitation samples and 139 stream water samples per site collected over 2014–2022, assessment of local meteoric water lines and local stream water lines showed geographic variation across North America. Taking the ratio of estimated seasonal amplitudes of δP and δQ to calculate young water fractions (Fyw), showed a Fyw range from 1% to 93% with most sites having Fyw below 20%. Calculated mean transit times (MTT) based on a gamma convolution model showed a MTT range from 0.10 to 13.2 years, with half of the sites having MTT estimates lower than 2 years. Significant correlations were found between the Fyw and watershed area, longest flow length, and the longest flow length/slope. Significant correlations were found between MTT and site latitude, longitude, slope, clay fraction, temperature, precipitation magnitude, and precipitation frequency. The significant correlations between water timescale metrics and the environmental characteristics we report share some similarities with those reported in prior studies, demonstrating that these quantities are primarily driven by site or area specific factors. The analysis of isotope data presented here provides important constraints on isotope variation in North American biomes and the timescales of water movement through NEON study sites.

Stable isotopes reveal the surface water-groundwater interaction and variation in young water fraction in an urbanized river zone

Based on 30 sampling campaigns on precipitation, river water and groundwater in Qingbaijiang urban catchment, southwest China, this study reports the spatio-temporal evolution of water isotopes under the impacts of human activities. The seasonal variation of groundwater-surface water interaction is quantitatively evaluated by isotope-aid hydrograph separation, and the young water fraction (Fyw) in river water at different spatial locations is estimated based on the seasonal periodicity of isotopes. The results show that the stable isotopes in river water and groundwater in Qingbaijiang urban catchment grow enriched from upstream to downstream, reflecting the transformation of the dominant water source from plateau river water to local precipitation and the influence of evaporation. The operation of water conservancy projects and construction of impervious surface in urban areas increase the evaporation intensity of river water. The results of the end-member mixing analysis (EMMA) demonstrates that the average annual contributions of river water to near-bank groundwater are 60.17%, 23.55% and 24.90% in the upper, middle and lower parts, respectively. The periodic storage and release of water led by the water conservancy projects enhances the groundwater recharge in the upstream river, while the water exchanges between river water and groundwater in the middle and lower parts of the catchment are reduced. The Fyw at 8 river sections of Qingbaijiang River estimated by the isotopic amplitude ratio method ranges from 0.067 to 0.194, with an overall increasing trend from upstream to downstream. The young water fraction is negatively correlated with mean elevation, mean slope and vegetation coverage, while positively correlated with the proportion of anthropogenic land use and the proportion of low-permeable soil. The construction of impervious surfaces and drainage systems in urban and rural areas is an important driver for the elevated young water fraction.

Isotope-derived young water fractions in streamflow across the tropical Andes mountains and Amazon floodplain

Abstract. The role of topography in determining water transit times and pathways through catchments is unclear, especially in mountainous environments – yet these environments play central roles in global water, sediment, and biogeochemical fluxes. Since the vast majority of intensively monitored catchments are at northern latitudes, the interplay between water transit, topography, and other landscape and climatic characteristics is particularly underexplored in tropical environments. To address this gap, here we present the results of a multiyear hydrologic sampling campaign (twice-monthly and storm sampling) to quantify water transit in seven small catchments (&lt;1.3 km2 area) across the transition from the Andes mountains to the Amazon floodplain in southern Peru. We use the stable isotope composition of water (δ18O) to calculate the fraction of streamflow comprised of recent precipitation (“young water fraction”) for each of the seven small catchments. Flow-weighted young water fractions (Fyw) are 5 %–26 % in the high-elevation mountains, 22 %–52 % in the mid-elevation mountains, and 7 % in the foreland floodplain. Across these catchments, topography does not exert a clear control on water transit; instead, stream Fyw is apparently controlled by a combination of hydroclimate (precipitation regime) and bedrock permeability. Mid-elevation sites are posited to have the highest Fyw due to more frequent and intense rainfall; less permeable bedrock and poorly developed soils may also facilitate high Fyw at these sites. Lowland soils have low Fyw due to very low flow path gradients despite low permeability. The data presented here highlight the complexity of factors that determine water transit in tropical mountainous catchments, particularly highlighting the role of intense orographic precipitation at mountain fronts in driving rapid conveyance of water through catchments. These results have implications for the response of Earth's montane “water towers” to climate change and for water–rock reactions that control global biogeochemical cycles.

Interactive effects of catchment mean water residence time and agricultural area on water physico-chemical variables and GHG saturations in headwater streams

Greenhouse gas emissions from headwater streams are linked to multiple sources influenced by terrestrial land use and hydrology, yet partitioning these sources at catchment scales remains highly unexplored. To address this gap, we sampled year-long stable water isotopes (δ18O and δ2H) from 17 headwater streams differing in catchment agricultural areas. We calculated mean residence times (MRT) and young water fractions (YWF) based on the seasonality of δ18O signals and linked these hydrological measures to catchment characteristics, mean annual water physico-chemical variables, and GHG % saturations. The MRT and the YWF ranged from 0.25 to 4.77 years and 3 to 53%, respectively. The MRT of stream water was significantly negatively correlated with stream slope (r2 = 0.58) but showed no relationship with the catchment area. Streams in agriculture-dominated catchments were annual hotspots of GHG oversaturation, which we attributed to precipitation-driven terrestrial inputs of dissolved GHGs for streams with shorter MRTs and nutrients and GHG inflows from groundwater for streams with longer MRTs. Based on our findings, future research should also consider water mean residence time estimates as indicators of integrated hydrological processes linking discharge and land use effects on annual GHG dynamics in headwater streams.

Towards a conceptualization of the hydrological processes behind changes of young water fraction with elevation: a focus on mountainous alpine catchments

Abstract. The young water fraction (Fyw*), defined as the fraction of catchment outflow with transit times of less than 2–3 months, is increasingly used in hydrological studies that exploit the potential of isotope tracers. The use of this new metric in catchment intercomparison studies is helpful to understand and conceptualize the relevant processes controlling catchment functioning. Previous studies have shown surprising evidence that mountainous catchments worldwide yield low Fyw*. These low values have been partially explained by isolated hydrological processes, including deep vertical infiltration and long groundwater flow paths. However, a thorough framework illustrating the relevant mechanisms leading to a low Fyw* in mountainous catchments is missing. The main aim of this paper is to give an overview of what drives Fyw* variations according to elevation, thus clarifying why it generally decreases at high elevation. For this purpose, we assembled a data set of 27 study catchments, located in both Switzerland and Italy, for which we calculateFyw*. We assume that this decrease can be explained by the groundwater storage potential, quantified by the areal extent of Quaternary deposits over a catchment (Fqd), and the low-flow duration (LFD) throughout the period of isotope sampling (PoS). In snow-dominated systems, LFD is strictly related to the snowpack persistence, quantified through the mean fractional snow cover area (FSCA). The drivers are related to the catchment storage contribution to the stream that we quantify by applying a cutting-edge baseflow separation method to the discharge time series of the study sites and by estimating the mean baseflow fraction (Fbf) over the PoS. Our results suggest that Quaternary deposits could play a role in modulating Fyw* elevation gradients via their capacity to store groundwater, but subsequent confirmation with further, more detailed geological information is necessary. LFD indicates the proportion of PoS in which the stream is sustained and dominated by stored water coming from the catchment storage. Accordingly, our results reveal that the increase of LFD at high elevations, to a large extent driven by the persistence of winter snowpacks and the simultaneous lack of a liquid water input to the catchments, results in lower Fyw*. In our data set, Fbf reveals a strong complementarity with Fyw*, suggesting that the latter could be estimated as Fyw*≃1-Fbf for catchments without stable water isotope measurements. As a conclusion, we develop a perceptual model that integrates all the results of our analysis into a framework for how hydrological processes control Fyw* according to elevation. This lays the foundations for an improvement of the theory-driven models.

Land cover influence on catchment scale subsurface water storage investigated by multiple methods: Implications for UK Natural Flood Management

Study regionUnited Kingdom (UK). Study Focus‘Natural flood management’ (NFM) schemes manipulating land use and other catchment features to control runoff are increasingly promoted across the UK. Catchment water storage and mixing processes influence runoff, but our understanding of the effects of land cover change on these processes is still limited. This study combined hydrometric, isotopic and geochemical measurements to investigate land cover versus potential topographic, soil and geological controls. It compared storage-discharge dynamics in nine nested catchments within a 67 km2 managed upland catchment in southern Scotland. Storage and mixing dynamics were characterised from hydrometric data using recession analysis and from isotopic data using mean transit time and young water fraction estimates. To give information on water sources, groundwater fraction was estimated from end member mixing analysis based on acid neutralising capacity. New hydrological insightsThe analysis showed low but variable sub-catchment scale dynamic storage (16–200 mm), mean transit times (134–370 days) and groundwater fractions (0.20–0.52 of annual stream runoff). Soil hydraulic conductivity was most significantly positively correlated with storage and mixing measures, whilst percentage forest cover was inversely correlated. Any effects of forest cover on increasing catchment infiltration and storage are masked by soil hydraulic properties even in the most responsive catchments. This highlights the importance of understanding dominant controls on catchment storage when using tree planting as a flood management strategy.