Fraction Of Suspended Particulate Matter Research Articles

Source apportionment of suspended particulate matter (PM1, PM2.5 and PM10) collected in road and tram tunnels in Krakow, Poland.

Here, we present the results of a comprehensive study of air quality in two tunnels located in the city of Krakow, southern Poland. The study comprised three PM fractions of suspended particulate matter (PM1, PM2.5 and PM10) sampled during campaigns lasting from March 14 to April 24, 2016 and from June 28 to July 18, 2016, in the road tunnel and the tram tunnel, respectively. The collected samples had undergone comprehensive chemical, elemental and carbon isotope analyses. The results of these analyses gave the basis for better characterization of urban transport as a source of air pollution in the city. The concentrations of particulate matter varied, depending on the analysed PM fraction and the place of sampling. For the tram tunnel, the average concentrations were 53.2µg·m-3 (PM1), 73.8µg·m-3 (PM2.5), 96.5µg·m-3 (PM10), to be compared with 44.2µg·m-3, 137.7µg·m-3, 221.5µg·m-3, respectively, recorded in the road tunnel. The isotope-mass balance calculations carried out separately for the road and tram tunnel and for each PM fraction, revealed that 60 to 79% of carbon present in the samples collected in the road tunnel was associated with road transport, to be compared with 15-33% obtained in the tram tunnel. The second in importance were biogenic emissions (17-21% and 41-49% in the road and tram tunnel, respectively. Sixteen different polycyclic aromatic hydrocarbons (PAHs) have been identified in the analysed samples. As expected, much higher concentrations of PAHs were detected in the road tunnel when compared to the tram tunnel. Based on the analysed PAHs concentrations, health risk assessment was determined using 3 different types of indicators: carcinogenic equivalent (CEQ), mutagenic equivalent (MEQ) and toxic equivalent (TEQ).

Transition metals concentration within the PM10 fraction of atmospheric suspended particulate matter – case study, Craiova, 2021

The current case study had the main purpose of determining and reporting the concentrations of the most toxic transition metals present in the composition of the particles suspended in the atmosphere, namely: lead, nickel, arsenic and cadmium. In the collection of experimental data, the fraction of suspended particulate matter represented by inhalable particles with an aerodynamic diameter smaller than 10 microns (PM10) was studied, by taking, during two weeks within different seasons of the year 2021, two set of seven filters, each used for one day – from an area of heavy traffic, on one of the main arteries of the municipality of Craiova, near a continuous air quality monitoring station capable of monitoring PM10. Thus, it was possible to permanently compare the results obtained through this application with the official data – registered during the same time intervals – by the local division of the EPA, founding a remarkable data concordance.

Pesticides in a temperate coastal lagoon in southwest Europe (Ria de Aveiro, Portugal) – Risk assessment and acute assays with Artemia and Daphnia

The Ria de Aveiro lagoon has been considered one of the most important Southern European long-term monitoring sites (LTER-site) concerning climate change and anthropogenic pollution. Nevertheless, studies concerning pesticide contamination herein are few and mostly outdated. Here, 56 pesticides dissolved in the aqueous phase (DAP) and suspended particulate matter (SPM) were examined to fill the knowledge gap, considering the hydrophobic nature of most evaluated compounds. Water samples were taken seasonally from eight sites, and both DAP and SPM fractions were analysed by gas-chromatography-mass spectrometry. The annual average concentrations of fungicides, herbicides and insecticides were ≈57 ng/L, ≈409 ng/L and ≈1058 ng/L in DAP and ≈7 μg/g, ≈28 μg/g and ≈67 μg/g in SPM. These pesticides and the excessive phosphate concentrations suggest that the lagoon's water quality may be hazardous to biota and humans. Invertebrates were identified as the most threatened trophic level using deterministic risk assessment, with chlorpyriphos and chlorfenvinphos being the primary culprits. Acute experiments with Artemia and Daphnia supported the suppositions.

Typhoon triggers estuarine heavy metal risk by regulating the multifractal grainsize of resuspended sediment

The turbulent boundary layer generated by wind in the estuarine surface water serves as a main factor affecting the distribution of suspended particulate matter (SPM) and suspended sediment concentration (SSC). In this study, representative typhoon-induced variation of surface fine SPM (<63 μm) was simulated in the Yangtze River Estuary (YRE) under two time scenarios. Each scenario contained four grainsize SPM fractions named Fraction 1 (<8 μm), Fraction 2 (8–16 μm), Fraction 3 (16–32 μm), Fraction 4 (32–63 μm). The typhoon-induced resuspended multifractal SSC quantification (TRMSQ) based on the relationship between SPM grainsize and heavy metal adsorption capacity was proposed to assess the variation in the resuspended threat of heavy metal to 6 key estuarine protected objects (three reservoirs & three national reserves) between Scenarios 1 and 2. The results presented that Fraction 3 exhibited the maximum increment in SSC resuspension mass and longest regression time from typhoon. Combined with TRMSQ, chromium (Cr) was calculated to be the riskiest typhoon-induced factor. The integrated resuspended risk of heavy metals for each protected object tends to increase from the northwest of Chongming Island (1.2) towards the maximum turbidity zone (>9) downstream, with an estuary-wide mean of 3.3.

Cu and Zn stable isotopes in suspended particulate matter sub-fractions from the northern Bay of Biscay help identify biogenic and geogenic particle pools

Marine suspended particulate matter (SPM) plays a pivotal role in the marine biogeochemical cycling of trace elements. This study investigates metal distributions and copper (Cu) and zinc (Zn) stable isotope ratios in different size fractions of SPM from two sampling stations on the inner continental shelf of northern Bay of Biscay (NE Atlantic), a zone highly influenced by the macrotidal Loire estuary, the outlet of a major European river. The objective of this study is to test stable isotopes as tools to infer the origins of particles and their formation processes, and to infer relevant Cu and Zn biogenic pools involved in marine trophic transfers of these metals. SPM samples were nearly quantitatively mineralized (i.e., without HF) to determine metals and Cu and Zn isotopes in their more labile and reactive phases. Their δ65CuSRM-976 values ranged from −0.45 to +0.51‰, with higher Cu concentrations accompanying particle size decreasing. The δ66ZnJMC-Lyon values in SPM sub-fractions varied from +0.14 to +0.76‰, and were uncorrelated to both Zn concentrations and particle size. Compared to larger size fractions, increased Al and Fe levels (proxies for terrigenous materials) and enrichments in lighter Cu and Zn isotopes observed in the smaller size SPM sub-fractions suggest that a major proportion of SPM Cu and Zn is associated with geogenic particles. Conversely, the relative enrichment of heavy isotopes in coarser particles is attributable to an increase of Cu and Zn metabolically incorporated into biogenic organic particles (e.g., plankton), and by surface adsorption onto organic detrital particles. The higher δ-values attributed to biogenic particles likely represents the isotope composition of the local marine organic matter available to primary consumers like filter-feeders (oysters). Thus, this study shows that targeting particles of specific size classes allows to identify relative dominances of biogenic and geogenic carrier phases. Identifying these pools and their isotopic composition may help to track Cu and Zn transfers through marine food-web in future studies.

Evaluation of Fine and Ultrafine Particles Proportion in Airborne Dust in an Industrial Area.

The health impacts of suspended particulate matter (SPM) are significantly associated with size—the smaller the aerosol particles, the stronger the biological effect. Quantitative evaluation of fine and ultrafine particles (FP and UFP) is, therefore, an integral part of ongoing epidemiological studies. The mass concentrations of SPM fractions (especially PM2.5, PM1.0, PM0.25) were measured in an industrial area using cascade personal samplers and a gravimetric method, and their mass ratio was determined. The results of PM2.5, PM1.0 were also compared with the reference measurement at stationary stations. The mean ratios PM2.5/SPM, PM1.0/SPM, and PM1.0/PM2.5 were 0.76, 0.65, and 0.86, respectively. Surprisingly, a mass dominance of UFP with an aerodynamic diameter <0.25 μm (PM0.25) was found with mean ratios of 0.43, 0.57, 0.67 in SPM, PM2.5 and PM1.0. The method used showed satisfactory agreement in comparison with reference measurements. The respirable fraction may consist predominantly of UFP. Despite the measures currently being taken to improve air quality, the most biologically efficient UFP can escape and remain in the air. UFP are currently determined primarily as particle number as opposed to the mass concentration used for conventional fractions. This complicates their mutual comparison and determination of individual fraction ratios.

Reactivity of particulate element concentrations: apportionment assessment of suspended particulate matter sources in the Upper Rhône River, France

Suspended particulate matter (SPM) transport through rivers is a major vector of nutrients and pollutants to continental shelf areas. To develop efficient sediment management strategies, there is a need to obtain quantitative information on SPM sources. For many years, the geochemical properties of SPM have been commonly used as tracers to identify sediment sources. In large watersheds, with numerous sources, the expected alteration of tracers during their transport requires that their reactivity be taken into account. To overcome this issue, we tested the use of major and trace element signatures in the residual fraction of SPM, using two different extraction methods. This original fingerprinting approach was applied to the Upper Rhône River basin (~20,000 km2) in order to assess the respective SPM contributions of its main five tributaries (Arve, Ain, Fier, Guiers, and Bourbre Rivers) for contrasted hydrological conditions (base flow periods, flood events and dam flushing). By incorporating element concentrations previously corrected from particle size distribution in a mixing model coupled to Monte Carlo simulations, we estimated the associated uncertainties of the SPM contributions from each tributary. The relative SPM contributions obtained using this fingerprinting approach were compared with those calculated with a 1-D hydro-sedimentary model. The use of element concentrations, such as Zn, P, Cu, Pb, Mn, or Sr, in the total fraction of SPM as conservative fingerprinting properties was not suitable, since they are mainly bound (> 50%) to reactive carrier phases. By using Ba, Ni, Fe, Mg, Cu, Sr, and V concentrations in the SPM residual fraction, the apportionment modeling of SPM sources was successfully assessed. The fingerprinting approach showed that, in base flow conditions, SPM originated mainly from the Arve River. During dam flushing event, the fingerprinting approach consistently estimated that re-suspended sediments came from the Arve River, while the 1-D hydro-sedimentary model estimated a proportion of re-suspended sediment originating within the Rhône River. This original fingerprinting approach highlighted the relevance of using geochemical properties in the non-reactive fraction of SPM in order to obtain reliable information on spatial sources of SPM in a large river basin. This methodology opens up promising perspectives to better track SPM sources in highly reactive environments such as estuaries/delta or in historical sediment archives.

Complex responses of suspended particulate matter in eutrophic river and its indicative function in river recovery process

Water environment and hydrodynamic condition of a river exerts a powerful influence on Suspended Particulate Matter (SPM) in rivers. Complex responses of SPM in rivers under changing water quality and hydrodynamic condition remain unclear and its indicative role in river recovery process is neglected. In this paper, twenty SPM samples were collected in June 2017 (rainy season) in Ziya River Mainstream (ZRM). The eutrophication levels of ZRM, sedimentation property and P fractions of SPM, and P-buffering intensity of the ZRM were investigated and compared with our previous research in arid season. The results showed eutrophication level was lower in rainy season than in arid season with mean Eutrophication Index (EI) values of 90.02 (seriously eutrophied) and 103.48 (extremely eutrophied), respectively. SPM in arid season has higher Loss On Ignition (LOI) content and was easier to remain suspension. The total amount of NaOH extracted Phosphorus (NaOH-P) and Organic Phosphorus (OP) fractions in SPM and Phosphorus (P) buffering intensity of ZRM were higher in arid season than in rainy season. Differences in water quality of a river can induce complex responses of SPM in its microstructure, P buffering ability and can act as a positive yet negative role in river eutrophication control. We put forward a P based river recovery process and suggest two-step river restoration measures, we point out rainy season is the reasonable timing to conduct measures in decreasing SPM concentration under the premise of mitigating P input. These results deepen our understanding on the role of SPM in P cycling in fluvial system and provide a new idea for river restoration work worldwide.

The impact the atmospheric air dust fractions and toxic metals on external respiratory function among chronic obstructive pulmonary disease patients

The study is dedicated to the potential risk determination of external respiratory function (ERF) disorders among chronic obstructive pulmonary disease (COPD) patients under dust fractions and toxic metals influence in Vladivostok atmosphere. The risk assessment included the environmental ERF trigger factors identification among COPD patients by regression analysis, the number of patients responding to factor exposure determination and the analysis of the possible ERF disorders individual risk among COPD patients. It is found that Vladivostok air pollution by dust aerosols and toxic metals directly affects COPD patients’ ERF. The most significant effect on the bronchial mucosa, aggravating bronchial patency (r=11.6%) and lung hyperinflation (r=10.7%) have ultrafine suspended particulate matter (SPM) fractions (0-1 μm). Fine SPM fractions (1-10 μm) affect ERF parameters characterizing bronchial patency only and less than ultrafine fractions (r=10.2%). Toxic metals (Ni, Zn) equally influence bronchial patency and lung tissue hyperinflation indicators among COPD patients (r=29.8% and r=29.1% respectively).

The role of microbially-mediated exopolymeric substances (EPS) in regulating Macondo oil transport in a mesocosm experiment

Large-scale exopolymeric substances (EPS) formation was observed in contaminated surface waters of the Gulf of Mexico, after the Deepwater Horizon oil spill. The conditions under which EPS are produced can cause variations in their physico-chemical properties, affecting the fate of the oil through either emulsification or coagulation with particles, followed by aggregation and marine oil snow (MOS) sedimentation. Here, we report results from a four-day mesocosm experiment that examined EPS production, the change in the bulk chemical composition (mainly polysaccharides and proteins), as well as the partitioning into different size fractions (suspended particulate matter (SPM), colloidal fraction, and sinking MOS). The treatments included 1) natural coastal seawater (Control), 2) a water accommodated fraction of oil (WAF), 3) a chemically-enhanced WAF with addition of oil dispersant Corexit (CEWAF), and 4) a diluted CEWAF (DCEWAF). Generally, the presence of WAF stimulated more extracellular polysaccharide production, whereas the addition of Corexit promoted more protein production. Moreover, marine aggregates changed from a terrestrial signature (higher aromaticity, lower EPS content and more uniform monosaccharide distribution) in the early stages of the experiment, to a fresher autochthonous signature (less aromatic, higher EPS content and glucose-dominated monosaccharide distribution) in the later stage of the mesocosm experiment. Corexit promoted the association between oil and proteins, assisting to emulsify the oil in colloids and SPM and delay the settling of EPS and oil (MOS) for the duration of the mesocosm. Furthermore, when oil, especially Corexit-dispersed oil, was present, extracellular polysaccharides were preferentially incorporated into sinking MOS relative to proteins, as evidenced from a lower protein-C/carbohydrate-C ratio of the sinking MOS than those of SPM and colloidal fraction in WAF, CEWAF and DCEWAF, respectively. This is in contrast to a higher protein-C/carbohydrate-C ratio in the sinking marine snow than those of SPM and colloidal fraction in the control. Likely, microbially-mediated extracellular polysaccharides are the key component that anchors the mineral ballast until the aggregates become dense enough and overcome the buoyancy added to the aggregates as a result of their association with oil/Corexit. We conclude that interactions between Corexit and EPS components regulate petroleum hydrocarbon distribution between the water column and sinking MOS.

Characterizing fluxes of trace metals related to dissolved and suspended matter during a storm event: application to a karst aquifer using trace metals and rare earth elements as provenance indicators

The origin of suspended matter and colloids in karst aquifers during storm events is not well understood in spite of their potentially important role in the transport of poorly soluble inorganic, organic, and microbiological pollutants. This work aims to characterize the fluxes of trace metals related to dissolved and suspended matter during a storm event at the spring of a karst aquifer in the Jura Mountains in France that is mainly recharged by diffuse infiltration. Various natural tracers, including rare earth elements (REE), were used to identify the origin of the contributing dissolved and suspended fractions. The storm event was characterized by the temporally delayed arrival of two different fractions of suspended particulate matter (SPM). A first SPM peak corresponded to autochthonous conduit sediment mobilized by a piston effect at the beginning of the event. A second SPM peak, related to the arrival of allochthonous soil particulates, was characterized by elevated turbidity and high concentrations of K, Al, Fe, and Mn. In the dissolved fraction, this second SPM peak was accompanied by various poorly soluble trace elements, which were interpreted by the presence of nanoparticles and colloids (NPCs). The REE distribution patterns demonstrated that both the NPCs and the SPM were derived from soil particles whatever the storm stage. This suggests that the SPM of the first stage was reworked cave sediment from previous storms composed of residual clays and soil particles, which excludes authigenic precipitates (such as Fe-Mn oxyhydroxides and speleothems) as a significant source for autochthonous sediments.

Unsteady Peristaltic Transport of a Particle-Fluid Suspension: Application to Oesophageal Swallowing

Abstract This model characterises the flow behaviour of suspended particles when swallowing through oesophagus. Transport of particle-fluid mixture induced by dilating peristaltic waves on a circular cylindrical tube was considered for investigation. Unsteady closed-form solutions for pressure gradient, velocity and stream function are obtained by applying regular perturbation technique up to the first order of wavenumber (the ratio of the tube radius to the wavelength). It is observed that the axial velocity of the fluid is greater than that of the solid particles almost everywhere. However, at the wall the axial velocity of the fluid is zero due to the no-slip condition imposed on it; but the suspended particulate material has non-zero positive axial velocity. Thus, the axial velocity of the suspended particles near the tube wall is more than that of the fluid velocity. It is further observed that the axial velocity is negative in the regions close to maximum occlusions giving way to instantaneous backward flow. It is also inferred that the maximum axial velocity of the particle-fluid suspension with non-zero wavenumber is more than that of the particle-free fluid with zero wavenumber. We examined the effect of volume fraction of suspended particulate matter on pressure gradient and velocity. An increase in the volume fraction diminished the pumping performance and also the axial and radial velocities. The results are also compared with those which were obtained for zero wavenumber. The outcome of the investigation endorses the doctors’ advice to patients suffering from achalasia, oesophageal stricture and oesophageal tumors to take liquid or food items with lesser solid contents. Streamline patterns are changed by increasing the flow rate while trapping occurs at high flow rates.

Polybrominated diphenyl ethers in the dissolved and suspended phases of seawater from Sanggou Bay, east China

The levels and profiles of polybrominated diphenyl ethers (PBDEs) in dissolved phase (DP) and suspended particulate matter (SPM) in seawater of Sanggou Bay (SGB) in four seasons were determined. The distribution and potential sources of these compounds were analyzed, and the ecological risk was assessed. The total concentrations of 14 PBDEs (∑14PBDE) in DP and SPM in the surface water ranged from 0.10 ng L−1 to 2.20 ng L−1 and from 0.51 ng L−1 to 6.15 ng L−1, respectively. The highest value was obtained in August. The concentrations of ∑14PBDE in the surface water were higher than those in the bottom water, and PBDEs were mainly partitioned into the SPM fraction. BDE209 was the most dominant PBDE congener, having average relative contributions of 86.5%–94.8% in DP and 40.5%–56.5% in SPM, followed by BDE47. The profiles of PBDEs in seawater of SGB were different from those of commercial PBDE products. The concentrations of ∑14PBDE were higher in the inner bay than in the outer bay, suggesting that the terrestrial input and human activities affected the PBDE distribution in SGB. Results of nonparametric multidimensional scaling suggested that BDE209 and BDE47 were important congeners discriminating PBDE contamination in SGB. The potential sources of PBDEs in SGB included commercial PentaBDE and DecaBDE products from the land, the atmospheric transport of commercial OctaBDE, and the degradation of high brominated congeners. The ecological risks from PentaBDE and OctaBDE were low, and those from DecaBDE were moderate in seawater of SGB.

Optical properties of size fractions of suspended particulate matter in littoral waters of Québec

Abstract. Mass-specific absorption (ai∗(λ)) and scattering (bi∗(λ)) coefficients were derived for four size fractions (i = 0.2–0.4, 0.4–0.7, 0.7–10, and &gt; 10 µm, λ = wavelength in nm) of suspended particulate matter (SPM) and with samples obtained from surface waters (i.e., 0–2 m depth) of the Saint Lawrence Estuary and Saguenay Fjord (SLE-SF) during June of 2013. For the visible–near-infrared spectral range (i.e., λ = 400–710 nm), mass-specific absorption coefficients of total SPM (i.e., particulates &gt; 0.2 µm) (hereafter aSPM∗) had low values (e.g., &lt; 0.01 m2 g−1 at λ = 440 nm) in areas of the lower estuary dominated by particle assemblages with relatively large mean grain size and high particulate organic carbon and chlorophyll a per unit of mass of SPM. Conversely, largest aSPM∗ values (i.e., &gt; 0.05 m2 g−1 at λ = 440 nm) corresponded with locations of the upper estuary and SF where particulates were mineral-rich and/or their mean diameter was relatively small. The variability of two optical proxies (the spectral slope of particulate beam attenuation coefficient and the mass-specific particulate absorption coefficient, hereafter γ and Svis, respectively) with respect to changes in particle size distribution (PSD) and chemical composition was also examined. The slope of the PSD was correlated with bi∗(550) (Spearman rank correlation coefficient ρs up to 0.37) and ai∗(440) estimates (ρs up to 0.32) in a comparable way. Conversely, the contribution of particulate inorganic matter to total mass of SPM (FSPMPIM) had a stronger correlation with ai∗ coefficients at a wavelength of 440 nm (ρs up to 0.50). The magnitude of γ was positively related to FSPMi or the contribution of size fraction i to the total mass of SPM (ρs up to 0.53 for i = 0.2–0.4 µm). Also, the relation between γ and FSPMPIM variability was secondary (ρs = −0.34, P &gt; 0.05). Lastly, the magnitude of Svis was inversely correlated with aSPM∗(440) (ρs = −0.55, P = 0.04) and FSPMPIM (ρs = −0.62, P = 0.018) in sampling locations with a larger marine influence (i.e., lower estuary).

Multi-matrix quantification and risk assessment of pesticides in the longest river of the Iberian peninsula

The distribution of pesticides in dissolved aqueous phase (DAP), suspended particulate matter (SPM) and Scrobicularia plana soft tissues from the Tagus River estuary was determined to evaluate the chemicals pollution status and their hazard potential in this area. Samples were collected in 6 campaigns (December 2012–October 2013), from 3 strategical sites, and analysed via different extraction procedures followed by gas chromatography tandem mass spectrometry (GC–MS/MS) determination. The contamination profile among matrices (DAP, SPM, and soft tissue from bivalves (STB)) was marked by average concentrations of 345ng/L, 0.51mg/kg, and 0.02mg/kg, respectively, with several samples above the 2013/39/EU Directive of environmental quality standards (EQS); no differences were observed between sex. A wider range of pesticides was present in STB (n=53) than in SPM (n=36) and DAP (n=19) matrices. Sediment–water partition coefficient, bioaccumulation factor in both DAP and SPM fraction were estimated ranging between 2.5 and 4.4 and 0.008–2799, respectively. The spatial distribution of most pesticides and physicochemical parameters were consistent, indicating a pollution pattern primarily near the Trancão River mouth. Due to the presence of the target compounds, calculated risk quotients pointed out potential hazards for aquatic organisms, mainly to invertebrates. The estimated average daily intake, theoretical maximum daily intake, and hazard quotient of the studied pesticides–via bivalve ingestion–indicated no risk for human health, although it is important to note possible biomagnification processes that may happen along the estuarine food-chain.

Polybrominated diphenyl ethers in dissolved and suspended phases of seawater and in surface sediment from Jiaozhou Bay, North China

The concentration and distribution of polybrominated diphenyl ethers (PBDEs) in the dissolved phase (DP) and suspended particulate matter (SPM) of seawater and in surface sediment obtained from Jiaozhou Bay (JZB) were determined. The potential sources of these compounds were evaluated. The total concentrations of 14 PBDEs (∑14PBDE) in DP and SPM were 0.09–1.35 and 1.17–5.45ng/L, respectively, indicating that the PBDE congeners are predominantly partitioned into the SPM fraction. The ∑14PBDE concentrations in sediment ranged from 2.18ng/g to 10.59ng/g with a mean value of 6.59ng/g. BDE-209 was dominant among 14 PBDE congeners, and BDE-47 was another abundant congener in the SPM and sediment samples. The PBDE concentration in SPM showed a significantly positive correlation with chlorophyll a level (r2=0.496, p<0.05), and that in the sediment exhibited a significantly positive correlation with clay proportion (r2=0.846, p<0.01). This result suggests that the phytoplankton or debris in the suspended particulates play an important role in PBDE accumulation and transportation and that PBDEs are preferentially enriched in clays in the sediment. PBDE concentrations were higher in the inner and mouth regions than in the outer and middle regions, and decreased with water depth in the water column. Non-parametric multidimensional scaling ordination showed that BDE-209 and BDE-47 are the important products discriminating PBDE contamination. This result is associated with industrial waste discharge from urban areas and with heavy ship traffic, indicating that DecaBDE and PentaBDE products are the potential sources of PBDEs. PBDE concentrations were lower in the sediment in JZB than in other coastal areas in South China, although the PBDE concentrations in DP were higher than those in some coastal areas worldwide. Moreover, the PBDE concentrations in DP and sediment increased in the last decade.

Distribution of arsenic between the particulate and aqueous phases in surface water from three freshwater lakes in China.

Total arsenic (As) in suspended particulate matter (SPM) of lacustrine ecosystems has been extensively documented, but knowledge on the distribution of As between the particle and aqueous phases in freshwater lakes remains largely unknown. The present study employed a rapid method to determine the total and dissolved As and As in SPM at sites covering the entire areas of three large shallow lakes in China, e.g., Taihu, Chaohu, and Dianchi, to obtain a "representative" mean value of the As concentration in various phases. The average concentrations of total and dissolved As were below 6.0 and 3.3μg/L, respectively. Arsenic in SPM was much higher than that in waters, as ranging from 24.7 to 516μg/g. Lake Taihu exhibited extensive seasonal variation both in total and dissolved As, while little difference was observed in SPM concentration, with an average value of 54.2 and 49.3mg/L in winter and summer, respectively. Among the algae in the three lakes, Cyanophyta dominated in both cell abundance and biomass. Algae mass occupied significant parts of SPM, especially in Dianchi; the proportions of algae in the SPM fractions were measured as 10.4 and 7.1% in Taihu in winter and summer, 4.5% in Chaohu, and 53.3% in Dianchi, both in summer season. The total As in SPM had a significant positive relationship with total As in water and a high distribution coefficient (Kd) between SPM and dissolved fraction of As at all three lakes. The high proportions of Algae, especially Cyanophyta in the composition of SPM in the three large shallow lakes, might play an important role in affecting the As distribution between the aqueous and particulate phases in aquatic ecosystem.

Occurrence and seasonal loads of pesticides in surface water and suspended particulate matter from a wetland of worldwide interest--the Ria Formosa Lagoon, Portugal.

Two novel methods were developed to extract and quantify 56 pesticides in surface waters, considering their content in both dissolved aqueous phase (DAP) and suspended particulate matter (SPM) fractions. These procedures were applied to coastal samples taken seasonally during 2012-2013, from three strategic sampling sites along the Ria Formosa Lagoon (south of Portugal). Briefly, 500 mL of water samples were filtrated, separating both fractions. The DAP fraction was extracted and pre-concentrated by solid-phase extraction (SPE), while the SPM was extracted using ultrasonic extraction technique (USE). Both fractions were then analyzed, and the pesticides were quantified and identified, within 35 min, by gas chromatography (GC) coupled to mass spectrometry (GC-MS and GC-MS/MS), respectively. The extraction of pesticides from the SPM fraction showed average recoveries of 102%, detection limits below 2.2 ng/L, and quantification limits ranging from 0.3 to 6.6 ng/L. Considering the real water samples, 73% of the selected pesticides were quantified in both DAP and SPM fractions (ΣDAP+SPM 2.3 μg/L) and their maximum levels were measured in autumn and winter. By category, the global loads of fungicides, herbicides, and insecticides were ≈407, ≈323, and ≈1.6 μg/L, respectively. Thirty-one percent of the quantified pesticides exceeded the European directives levels (2008/105/EC and 98/83/EC). From the total loads, the SPM fraction contribution was 32%, showing the importance of measuring pesticides in that fraction. The water physicochemical parameters revealed that the total nitrogen amounts were very high relatively to the legal required values, mainly close to the city of Faro (2.6 mg/L). In light of the above, measures are in need to meet European directives and protect both fauna and humans that use this area for leisure.

Elemental Composition and Source Apportionment of Suspended Particulate Matters and Health Risk Assessment in Mining and Nonmining Areas of Odisha, India

AbstractAtmospheric particulate matter was sampled synchronously during a monitoring campaign from January–December 2010 in mining and nonmining areas in Odisha, India. In this study, 14 elements were observed in suspended particulate matter (SPM) samples. The SPM average concentration and SD were found to be 169±7 and 128±10 μg m−3, respectively, in mining and nonmining areas. The observed elements were more highly enriched in mining than nonmining areas. Four trace metals, i.e., Pb, Cu, Cd, and Hg were found to be highly enriched in SPM samples in study areas; however, enrichment factors for Pb, Cd, and Hg were 2–4 times higher in mining than nonmining areas. In mining areas more than 91 and 78% of the total variance, based on the observed elements in nonmining area, were explained by five component factors in SPM fractions, which have an eigenvalue greater than 1. The measured source of observed elements originated from sea sprays. High inhalation doses were observed in summer rather than winter and r...

THE LONGITUDINAL PERTURBATED FLUID VELOCITY OF THE DUSTY FLUID IN THE INCOMPRESSIBLE FLOW IN CYLINDRICAL POLAR COORDINATE

The effect of finite volume fraction of suspended particulate matter on axially symmetrical jet mixing of incompressible dusty fluid has been considered. However, this assumption is not justified when the fluid density is high or particle mass fraction is large Here we are assuming the velocity and temperature in the jet to differ only slightly from that of surrounding stream, a perturbation method has been employed to linearized the equation those have been solved by using Laplace Transformation technique. Numerical computations have been made to discuss the longitudinal perturbated fluid velocity.