Fraction Of Stream Sediments Research Articles

The Relationship between Particle Size and Element Distribution in Stream Sediments from the Dongyuan W-Mo Deposit, Eastern China

Particle size exerts significant control on the concentration of elements in stream sediments and is therefore critical in stream sediment-based geochemical exploration, which has proved important in China’s National Geochemical Mapping Project. There are various geographical landscapes in China with different distribution characteristics of stream sediments. Therefore, we studied the relationship between particle size and element distribution in stream sediments, which is always a crucial but challenging issue in geochemical surveys. The distributions of minerals and elements in eight size fractions of stream sediments (2–0.84, 0.84–0.42, 0.42–0.25, 0.25–0.177, 0.177–0.125, 0.125–0.096, 0.096–0.074, and <0.074 mm) from the Dongyuan W-Mo deposit in eastern China were studied. The results show that the 2–0.25 mm particle size fraction of stream sediments is composed mainly of rock debris and various minerals from broken bedrock upstream, while the <0.25 mm fraction is composed mainly of clay, individual minerals, and organic matter. The pilot survey results prove that using 2–0.25 mm as the sampling particle size fraction is better than using <0.25 mm, especially in geochemical prospecting and geological body delineation. Sampling the 2–0.25 mm particle size fraction of stream sediments can help to delineate proven ore bodies, ore-related anomalies, and geological bodies more effectively and more credibly. The suggested sampling particle size fraction for a stream sediment geochemical survey in a humid to semi-humid low mountain landscape in eastern China is therefore 2–0.25 mm, rather than the particle size fraction of <0.25 mm that was used for sampling in this area before. This paper depicts a successful example for determining the optimal sampling particle size fraction for stream sediment-based geochemical exploration.

Integration of Detrital Gold Microchemistry, Heavy Mineral Distribution, and Sediment Geochemistry to Clarify Regional Metallogeny in Glaciated Terrains: Application in the Caledonides of Southeast Ireland

Regional exploration for rare and precious metal enrichment traditionally uses multielement geochemical analysis of the fines (<150 μm) fraction of stream sediments; however, these data can be misleading in glaciated regions with complex geology. Here, we compare the spatial distributions of data from sediment fines with distributions of heavy mineral concentrates, including detrital gold, in the same region. Gold grains are characterized according to abundance and morphology plus a microchemical signature from the combination of alloy analysis and systematic identification of mineral inclusions revealed in polished sections. These inclusions survive indefinitely and are indicative of hypogene mineralogy, whereas the metal loadings of fines may be affected by weathering or anthropogenic activity. All three approaches are mutually supportive: sediment fines analyses provide a basis for more labor-intensive targeted gold-grain studies, which in turn highlight specific gold-element associations useful for interpretation of geochemical data sets. Spatial distributions of resistate heavy mineral suites constrain the directions and extents of glacial transport, which facilitates more confident interpretations of placer-lode relationships from gold-grain studies. Characterization of 2,160 gold grains from 40 localities in the auriferous region of southeast Ireland provided a clear indication of proximity of gold to source and identified gold derived from different episodes of mineralization. A distinction is apparent between gold in the south of the region (Wexford), likely derived from widespread stratabound Au-As-Fe-S mineralization, and that in the north (Wicklow), where the historical placer mining district of the Goldmines River yielded gold with inclusions exhibiting a distinctive Pb-Bi-As association. The Goldmines River placers formed by the efficient accumulation and preservation of detrital gold derived from several discrete intravalley sources. We recommend that a combination of classic stream-sediment geochemistry, heavy mineral analysis, and gold-grain studies is used more widely to provide additional insights on the location and nature of gold mineralization and regional metallogeny in regions of poor exposure and complex geology.

Indicator mineral and geochemical signatures associated with the Sisson W–Mo deposit, New Brunswick, Canada

An indicator mineral and geochemical case study was carried out around the Sisson W–Mo deposit to test modern indicator mineral and analytical methods and document glacial and fluvial dispersal from a significant W–Mo source. Indicator minerals in the 0.25 – 2.0 mm non-ferromagnetic heavy mineral fraction of till and stream sediments include the primary ore minerals scheelite, wolframite and molybdenite, as well as chalcopyrite, joseite, native Bi, bismutite, bismuthinite, galena, sphalerite, arsenopyrite, pyrrhotite and pyrite. Indicator minerals in c. 12 – 14 kg samples define glacial dispersal of at least 10 km down ice (SE) of the deposit and fluvial dispersal at least 4 km downstream. The presence of very coarse (0.5 – 2.0 mm) indicator minerals in till and stream sediments marks proximity (&lt;1 km) to the mineralized source. Indicator elements for the deposit in the &lt;0.063 mm fraction of till, the &lt;0.177 mm fraction of stream sediments, and in stream water include W and Mo, and various combinations of pathfinder elements Ag, As, Bi, Cd, Cu, In, Pb, Te and Zn. This list of elements is more extensive than previously identified for the Sisson deposit or other studies around W mineralization in glaciated terrain. The study demonstrates that indicator mineral methods, so well known for diamond and gold exploration, have a broader application that includes W–Mo exploration.

Temporal evaluation of Cu, Mn, Pb and Zn potential mobilities in stream sediments of a copper mining area in South Brazil

Sequential extractions were applied to the silt-clay fraction of stream sediments to evaluate temporal modifications on Cu, Mn, Pb and Zn potential mobilities, during different stages of copper mining activities, in September, 1993 and September, 1996. Cu and Pb partitioning, obtained from a five-step extraction scheme showed the oxidizable phase as the most important for Cu and Pb, while the so-called carbonatic and the exchangeable phases were significant in the Zn and Mn partitionings. Cu presented the greatest variability between both, sites and sampling periods. The results suggest that metal partitioning, especially that of Cu, can be reflecting sulfide oxidation processes, probably enhanced by tailings exposure.

Use of a sensitive analytical method and the silt-clay (< 53 μm) fraction of stream sediments in exploration for gold in northern Thailand

Heavy mineral concentrates (SG ⪢ 3.3) from the Huai Hin Laep, a tributary of the Huai Kho Lo River in northern Thailand, contain strongly anomalous concentrations of gold. In contrast, the gold content of the associated < 149 μm and <53 μm fractions of the sediment is generally less than the 5 ppb detection limit obtained by a conventional fire assay-atomic absorption spectrometry method. To test for the presence of a gold anomaly at concentrations < 5 ppb, we have used an aqua-regia digestion followed by an Amberlite XAD-8 column preconcentration technique that, when used with a spectrometer that enables full display of the analytical spectrum to optimize baseline analysis, gives a detection limit of 0.1 ppb Au. Gold content of the < 53 μm sediment fraction ranges from 1.0 to 3.1 ppb compared to concentrations that typically range from 1000 to more than 100,000 ppb in the heavy mineral concentrates. However, despite gold concentrations in the sediment being several orders of magnitude lower than those in the heavy mineral concentrates, the downstream dispersion patterns are similar, with gold concentrations increasing at high energy sites and downstream away from the assumed source. These results identify the presence of a greatly diluted gold anomaly in the < 53 μm fraction of the sediments and suggest that transport and deposition of this fine grained gold is controlled by the same sedimentological factors that control the behavior of gold in the sand-size range, between 53 μm and 425 μm. Most important from an exploration standpoint, is that by using a sufficiently sensitive analytical method, meaningful gold dispersion patterns can be recognized at concentrations below 5 ppb.

Heavy metals and manganese oxides in the genesee watershed, New York state: effects of geology and land use

Manganese oxide coatings on gravels from 255 sites on tributary streams in the Genesee River Watershed were analyzed for Mn, Fe, Zn, Cd, Co, Ni, Pb, and Cu. The results were compared with data on bedrock geology, surficial geology and land use, using factor analysis and stepwise multiple regression. All metals except Pb show strong positive correlation with Mn. This association results from the well-known tendency of Mn oxide precipitates to adsorb and incorporate dissolved trace metals. Pb may be present in a separate phase on the gravel surfaces; alternatively Pb abundance may be so strongly influenced by environmental factors that the effect of varying abundance of the carrier phase becomes relatively unimportant. When the effects of varying Mn abundance are allowed for, Pb and to a lesser extent Zn and Cu abundances are seen to be related to commercial, industrial and residential land use. In addition to this pollution effect, all the trace metals, Cd and Ni most strongly, tend to be more abundant in oxide coatings from streams in the forested uplands in the southern part of the area. This probably reflects increased geochemical mobility of the metals in the more acid soils and groundwater of the southern region. A strong Zn anomaly is present in streams draining areas underlain by the Lockport Formation. Oxide coatings in these streams contain up to 5% Zn, originating from disseminated sphalerite in the Lockport and secondary Zn concentrations in the overlying muck soils. The same group of metals, plus calcium and loss on ignition, were determined in the silt and clay (minus 230 mesh) fraction of stream sediments from 129 of the same sites, using a hot nitric acid leach. The amounts of manganese in the sediments are low (average 1020 ppm) and manganese oxides are, at most, of relatively minor significance in the trace-metal geochemistry of these sediments. The bulk of the trace metals in sediment appears to be associated with iron oxides, clays and organic matter.