The higher-order effects play an important role in the wave propagations of ultrashort (e.g. subpicosecond or femtosecond) light pulses in optical fibres. In this paper, we investigate anyn-component fourth-order nonlinear Schrödinger (n-FONLS) system with non-zero backgrounds containing then-Hirota equation and then-Lakshmanan–Porsezian–Daniel equation. Based on the loop group theory, we find the multi-parameter family of novel rational vector rogue waves (RVRWs) of then-FONLS equation starting from the plane-wave solutions. Moreover, we exhibit the weak and strong interactions of some representative RVRW structures. In particular, we also find that the W-shaped rational vector dark and bright solitons of then-FONLS equation as the second- and fourth-order dispersion coefficients satisfy some relation. Furthermore, we find the higher-order RVRWs of then-FONLS equation. These obtained rational solutions will be useful in the study of RVRW phenomena of multi-component nonlinear wave models in nonlinear optics, deep ocean and Bose–Einstein condensates.
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