The present study focuses on the analysis of the effect of the phase change material (PCM) cavity size on the melting and solidification processes for application to thermal energy densification in a hot water tank through latent heat thermal energy storage in cylindrical annular cavities. A 2D axisymmetric composite geometrical pattern is considered, formed by a phase change material surrounded by a conductive and an insulating material. A parametric study is conducted on the phase change material cavity size, and the results are presented using non-dimensional numbers: Fourier number, Rayleigh number, and aspect ratio. Two approaches have been developed based on local and global analyses. The local one showed the predominance of the conductive or convective heat transfer process concerning the influence of the phase change material size, and thus the Rayleigh number, on the evolution of the solid/liquid interface and streamline shapes. The global one allowed correlations for melting and solidification Fourier numbers with respect to the Rayleigh number and aspect ratio to be built from simulation data. Two parameters for each process have been identified and defined from the present study: the critical Fourier number and the aspect ratio constant. The critical Fourier number corresponds to the maximum Fourier number that the phase change material needs to achieve for a melting or solidification process. The aspect ratio constant provides information on the phase change material aspect ratio value where the Rayleigh number no longer influences the process. In the case of the melting process, this parameter is an indication that convection has reached a maximum intensity and no longer influences the process. Finally, this study proposes a suitable aspect ratio for optimizing the melting process: 19.32, and another for optimizing the solidification process: 16.29.
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