Using time-dependent wave packet method, the dynamics studies of the S+ + D2(v0 = 2, j0 = 0) → SD+ + D reaction were carried out based on the potential energy surface (PES) reported by Zhu et al., (Phys. Chem. Chem. Phys.23 4757–4767 (2021)). The isotope effect is very obvious. When the H atom is replaced by the D atom, the reaction probability at total angular momentum equal to zero has a threshold of about 0.28 eV and it decreases significantly in the collision energy range studied. The total and rovibrational state-resolved integral cross section were reported and the results indicate that the distribution of integral cross section is mainly concentrated in the ground state. The forward biased differential cross sections show that the stripping mechanism due to high total angular momentum plays a dominant role in the reaction.
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