Formation Of Two-dimensional Electron Gas Research Articles

Achieving High Performance of ZnSnO Thin-Film Transistor via Homojunction Strategy.

The zinc-tin-oxide (ZTO) thin-film transistor (TFT) is one of the most promising candidates for advanced display applications, though its popularity is limited by its performances. In this work, a heterojunction channel strategy was adopted to regulate the electron transport behaviors and the TFT performances by manipulating the concentration and the distribution of oxygen vacancies, and a reasonable physical model was proposed based on experimental and simulation results. It is difficult to mediate the contradiction between mobility and threshold voltage for the single channel. Via a heterojunction channel strategy, desirable TFT performances, with mobility of 12.5 cm2/Vs, threshold voltage of 1.2 V and Ion/Ioff of 3 × 109, are achieved when the oxygen-vacancy-enriched layer gets close to the gate insulator (GI). The enhanced performances can be mainly attributed to the formation of two-dimensional electron gas (2DEG), the insensitive potential barrier and the reasonable distribution of oxygen vacancy. On the contrary, when the oxygen-vacancy-enriched layer stays away from GI, all the main performances degenerate due to the vulnerable potential well. The findings may facilitate the development and application of heterojunction channels for improving the performances of electronic devices.

Spin-polarized two-dimensional electron/hole gas at the interface of nonmagnetic semiconducting half-Heusler compounds: Modified Slater-Pauling rule for half-metallicity at the interface

Half-Heusler compounds with 18 valence electrons per unit cell are well-known nonmagnetic semiconductors. Employing first-principles electronic band-structure calculations, we study the interface properties of the half-Heusler heterojunctions based on FeVSb, CoTiSb, CoVSn, and NiTiSn compounds, which belong to this category of materials. Our results show that several of these heterojunction interfaces become not only metallic but also magnetic. The emergence of spin-polarization is accompanied by the formation of two-dimensional electron gas or hole gas at the interface. A qualitative analysis of the origin of the spin polarization at the interfaces suggests that strong correlations are responsible. For the cases of magnetic interfaces where half-metallicity is also present, we propose a modified Slater-Pauling rule similar to the one for bulk half-metallic half-Heusler compounds. Additionally, we calculate exchange parameters, Curie temperatures, and magnetic anisotropy energies for magnetic interfaces. Our study, along with recent experimental evidence confirming the presence of two-dimensional electron gas at CoTiSb/NiTiSn heterojunctions, may motivate future efforts to explore and realize device applications using these heterojunctions.

Simulation study on electrical properties of p-GaN gate normally-off HEMT devices affected by Al mole fraction in AlGaN barrier layer

The reason that p-GaN gate normally-off high electron mobility transistor (HEMT) device is able to draw prevail interests is not only for its outstanding electric properties of low on-resistance and high thermal conductivity, but also for its applications under high frequency and high voltage. In HEMT devices, the setting of Al component in the AlGaN barrier layer is a key parameter to affect the formation of two-dimensional electron gas (2DEG) at the AlGaN/GaN heterojunction, and therefore directly determines the performance of the devices. This paper uses the Atlas module of the Silvaco-TCAD software to design and simulate p-GaN gate normally-off HEMT devices to investigate the effect of Al mole fraction content in the AlGaN barrier layer on the electrical performance, as well as the causes in terms of the conduction band energy structure diagram. The results show that the threshold voltage of the HEMT device decreases, the maximum saturation drain current increases, and the peak transductance of the HEMT device increases with increasing the Al content. In the off-state (zero gate voltage), the AlGaN/GaN potential well depth becomes deeper as the Al mole fraction increases, resulting in a lower driven force to rebuild the minimized 2DEG concentration in the GaN layer for switching from off-state to on-state, and this leads to a lower threshold voltage. While, in the on-state (5 V gate voltage), the deeper AlGaN/GaN potential well depth as the Al mole fraction increases, the higher of the 2DEG concentration of the GaN layer, leading to a higher maximum saturation output drain current. After optimization, the integrated electrical performance of the HEMT devices has been found best when the Al mole fraction content is about 0.25. The results obtained from the simulations are helpful for the experimental design of p-GaN gate normally-off HEMT devices

Synergic strategies of composition-modified bilayer channel configuration and ozone-processed gate stacks for atomic-layer deposited In-Ga-Zn-O thin-film transistors

Composition-modified bilayer channel configuration was introduced for enhancing the device performance of In-Ga-Zn-O (IGZO) thin film transistors (TFTs), which was composed of 3-nm-thick In-rich prompt-IGZO and 12-nm-thick prime-IGZO layers for the formation of two-dimensional electron gas (2DEG) at interfaces. The cationic compositions of bilayer IGZO channels were designed by modulating the sub-cyclic ratios among the precursors during atomic-layer deposition process. To properly control the effect of modified compositions in bilayer channels, the oxidant for the formation of Al2O3 protection and gate insulator layers were chosen as ozone. The IGZO TFTs fabricated with bilayer channel configurations exhibited the carrier mobility of 45.5 cm2/Vs and the subthreshold swing of 0.24 V/dec, keeping the turn-on position at near 0 V of gate bias without performing additional heat treatments including post-annealing process at higher temperatures. From the investigations on the temperature-dependent variations in electrical conductivity and band alignments of bi-layered IGZO channels, composition controls of prime and prompt IGZO layers were found to be crucial for initiating the quantum confinement effect of 2DEG. Thus, the optimum compositions (In:Ga:Zn) of both layers were 1.4:1.0:2.0 and 5.0:1.0:3.4, respectively. The device using optimum bilayer channel composition exhibited excellent positive bias stress (PBS) stability due to the implementation of confinement barrier at interface between the prime and prompt layers, in which the threshold voltage shifts (∆VTH) were estimated to be as low as 1.34 V. Furthermore, it was found that the PBS instability was anomalously compensated even at higher temperature stresses owing to long-term hydrogen diffusion from the ozone-processed gate stacks. The ∆VTH was finally stabilized to 0.22 V at 80 °C with a lapse of stress time for 104 s.

Chemical mechanism of formation of two-dimensional electron gas at the Al2O3/TiO2 interface by atomic layer deposition

Two-dimensional electron gases (2DEGs) localized at oxide heterointerfaces can potentially be used in applications associated with the design of novel electronic device architectures. Recent studies have reported that atomic layer deposition (ALD) of Al2O3 on TiO2 substrates can generate 2DEG states, owing to in situ formation of interfacial oxygen vacancies (VO). However, the chemical mechanism governing the adsorption of the trimethylaluminum (TMA) precursor on the TiO2 surface remains unclear. In this work, an investigation aimed at elucidating the formation of the 2DEG state through the reaction of TMA on TiO2 was performed using periodic dispersion-corrected DFT + U calculations. Dimethylether, whose desorption leaves VO surrounded by Ti3+, can be formed via direct methylation of the lattice oxygen on the TiO2 surface. The experimentally observed dependence of the carrier density on the process temperature of Al2O3 ALD confirmed the endothermic nature of VO formation. Furthermore, the emergence of geometrically confined n-type electronic states corresponding to interfacial VO confirmed the formation of 2DEGs at the heterointerface. Our study provides a fundamental understanding of 2DEG formation in the Al2O3/TiO2 heterojunction interface.

(Invited) Ga2O3 Phase Control and Heterojunctions Using Plasma-Enhanced Atomic Layer Epitaxy

Ga2O3 has emerged as a promising material for next generation power electronics. While β-Ga2O3 (monoclinic) is the most stable and studied of six Ga2O3 polymorphs, the slightly less energetically favorable α-, ε-, and κ-Ga2O3 phases have unique characteristics that can be exploited such as larger bandgaps, alloying for dopant control, or polarization beneficial to the formation of two-dimensional electron gas (2DEG) channels. Specifically, α-Ga2O3 (rhombohedral, corundum) has the largest bandgap of ~5.3 eV and can be alloyed with α-Al2O3 (8.8 eV) and α-In2O3 (3.7 eV) for bandgap engineering. Both ε-Ga2O3 (hexagonal, P63mc) and κ-Ga2O3 (orthorhombic, Pna21 ) phases are polar, with a predicted spontaneous polarization strength up to 10 times larger than GaN and 3 times larger than AlN. Like the III-N system, polarization induced charges can lead to higher charge densities and mobilities in 2DEGs formed at heterojunctions, which would improve the viability of Ga2O3 electronic devices. Plasma-enhanced atomic layer deposition (PEALD) is a popular, conformal, energy-enhanced synthesis method for thin films due to its many advantages, including: deposition at reduced growth temperatures, access to metastable phases, improved crystallinity, and increased growth rates. In this work, we use PEALD to produce high-quality heteroepitaxial Ga2O3 and (AlxGa1-x)2O3 (AlGO) films and investigate materials properties such as phase selectivity, ternary solubility limits, and electrical and optical performance.All Ga2O3 films were deposited in a Veeco Fiji G2 reactor equipped with a load lock and turbo pump using trimethygallium, trimethylaluminum, and O2 plasma. Initial studies on c-plane sapphire substrates at 350°C and 8 mTorr show the phase could be altered from β to α by a varying the pure O2 flow during plasma pulse from 5-40 sccm [1]. Optical emission spectroscopy indicate that the changes in the relative concentration of atomic oxygen is crucial for phase selectivity while the high ion flux to the surface can contribute to the crystallinity at low Tg [2]. To grow ε(κ)-Ga2O3 on c-plane sapphire required going to a much higher temperature (500°C), pressure (100’s mTorr), and O2 flow (100sccm) [1]. Without modifications to the current ALD system, pure ε(κ)-Ga2O3 on sapphire was not achieved under any conditions. Using optimum growth conditions for the three phases on sapphire, films were deposited on GaN and diamond to determine the effect of substrate structure. Transmission electron microscopy was conducted to determine the specific phases (β, ε, and κ) present in each case, and showed the amount of each phase varied with PEALD parameters. While films on diamond resulted in mixed β/ε(κ) phases, pure ε(κ)-phase films were attained on GaN and the strain varied with pressure and Tg. Vertical breakdown measurements were taken for both β- and ε(κ)-Ga2O3/n+ GaN substrates. Breakdown fields varied between 3.8-7.0 MV/cm dependent on the phase and strained state of the Ga2O3 films. β-Ga2O3 films showed less variability in breakdown field from device to device than ε(κ)-Ga2O3 films, but neither showed a dependence on device size.While PEALD is beneficial for depositing thin films of metastable phases, practical devices often require much thicker barrier and active layers. For this reason, we investigated integrating PEALD metastable Ga2O3 films with traditional semiconductor deposition techniques, such as molecular beam epitaxy (MBE), capable of extending these layers beyond 100 nm in thickness. The same MBE conditions were used to deposit Ga2O3 films on GaN substrates with and without PEALD ε(κ)-Ga2O3 nucleation layers. Those deposited without the PEALD metastable nucleation layer resulted in stable β-phase films, while those with nucleation layers resulted in pure ε(κ)-phase films. This shows importance of PEALD for realizing practical device structures using metastable phases.Finally, to investigate heterojunctions for 2DEG formation, AlxGa1-xO films were developed. While the full stoichiometric range could be reached using a PEALD digital alloying method, crystallinity was lost above x = 0.2 for the β phase, x = 0.35 for the ε(κ) phase, and x=0.6 for the α phase. Initial device structures will be shown in order to establish the feasibility of these films in device applications.[1] Wheeler, et al. Chem. Mater. 2020, 32, 1140-1152[2] Boris, et al. JVST A 2019, 37(6), 060909 Figure 1

Integration of Indium Arsenide/Indium Phosphide Core-Shell Nanowire Vertical Gate-All-Around Field-Effect Transistors on Si

Among the III-V semiconductor materials, indium arsenide (InAs) nanowire (NWs) with high carrier mobility are expected to be alternative channels for high-performance and low-power field-effect transistors (FETs). However, there is a challenge in enhancing the on-state current for the InAs NW-channel vertical gate-all-around (VGAA) structures on Si. We investigated vertical InAs/InP core-shell (CS) NW-channels to enhance the current and demonstrated InAs/InP CS NW VGAA FETs. The InAs/InP CS NW-channel enhanced the on-state current while maintaining a small off-leakage current. The devices showed an on-state current of 40 $\mu \text{A}/\mu \text{m}$ , off-leakage current of 1 pA/ $\mu \text{m}$ , and subthreshold slope of 111 mV/dec at $\text{V}_{\text {DS}} =0.50$ V. The origin of the current enhancement suggests that there is a formation of two-dimensional electron gas (2DEG) in the InAs/InP CS NW-channel, and the characteristics of the InAs/InP CS NW VGAA FET revealed that the InP interlayer at draian edge and low source resistivity are important parameters to take advantage of 2DEG for CS NW VGAA FET.

Analysis of Two-Dimensional Electron Gas Formation in InGaAs-Based HEMTs

Analysis of Two-Dimensional Electron Gas Formation in InGaAs-Based HEMTs

Polarization induced two-dimensional electron gas in ZnO/ZnMgO Heterointerface for High-performance enhanced UV photodetector

The spontaneous formation of two-dimensional electron gas (2DEG) with a high carrier density (∼1018 cm−3) was achieved at a ZnO/Mg0.2Zn0.8O interface grown using a facile radio-frequency magnetron sputtering system on a quartz substrate. Compared with Mg0.2Zn0.8O ultraviolet (UV) photodetectors (PDs) with and without a ZnO buffer layer, the PD based on ZnO/Mg0.2Zn0.8O bilayer films exhibited not only sensitivity to dual wavelength in the UV region, but also significantly enhanced spectral responsivity, photocurrent-to-dark current ratio (107), specific detectivity (1014), and UV/visible rejection ratio of about four orders of magnitude at a low operating voltage bias. Induced by 2DEG, the external quantum efficiency (EQE) of photodetector reached 14858% at 10 V, indicating that a considered high gain was achieved in the device based on this heterojunction architecture. The gain mechanism was further demonstrated by polarization induction and band bending in detail. This application of 2DEG in a practical detector offers a novel and effective approach for the substantial improvement in the high-performance of ZnO/Mg0.2Zn0.8O dual-band UV PDs.

Unravelling oxygen-vacancy-induced electron transfer at SrTiO3-based heterointerfaces by transport measurement during growth

Numerous studies have shown that oxygen vacancies play an important role on the formation of two-dimensional electron gas (2DEG) at SrTiO3-based heterointerfaces. Previously, it is widely believed that the main mechanism is that the oxygen vacancies in SrTiO3 directly contribute electrons to the 2DEG. Here, we performed transport measurements during the creation of 2DEG for depositing amorphous LaAlO3 on SrTiO3 substrates and related heterostructures. Our result suggests that, unlike the previous viewpoint, in this kind of 2DEG the determinant mechanism is the electron transfer from the oxygen vacancies in the film grown on SrTiO3, rather than the oxygen vacancies in SrTiO3 themselves. This effect is so striking that an amorphous film of less than 10% monolayer coverage on SrTiO3, or equivalently 0.04 nm, can already generate a highly conducting 2DEG. The present result may have a general implication and provide a possible way to understand the long-standing debate on the origin of 2DEG at SrTiO3-based heterointerfaces.

Formation of Two-dimensional Electron Gas at Amorphous/Crystalline Oxide Interfaces

Experimentally, we found the percentage of low valence cations, the ionization energy of cations in film, and the band gap of substrates to be decisive for the formation of two-dimensional electron gas at the interface of amorphous/crystalline oxide (a-2DEG). Considering these findings, we inferred that the charge transfer from the film to the interface should be the main mechanism of a-2DEG formation. This charge transfer is induced by oxygen defects in film and can be eliminated by the electron-absorbing process of cations in the film. Based on this, we propose a simple dipole model that successfully explains the origin of a-2DEG, our experimental findings, and some important properties of a-2DEG.

Luminescence emission from nonpolar Al0.3Ga0.7N/GaN core-shell and core-multi-shell nanowires

In the present work, we theoretically study the possibility of luminescence emission from two systems of nonpolar Al0.3Ga0.7N/GaN Core-shell and core-multi-shell c-axis oriented nanowires with hexagonal cross section. To obtain energy levels and wave functions through the solution of Schrodinger-Poisson equations, numerical Self-consistent procedure has been employed. N-type doping has been considered to investigate the two-dimensional electron gas formation and its effect on luminescence. The detailed analysis of the results as a function of the various structural parameters has been carried out. The results presents an examination of the band to band luminescence feature and its changes with involved parameters. We found that the size of the system determines the feature of luminescence emission. As main finding, our calculations show that the intensity of luminescence spectrum in facet to facet route of NW cross section is significant than that of corner to corner route. In addition, no shift of the peak position is observed with changing the amount of doping. Our numerical calculations give more insights into the luminescence emission of nonpolar GaN/AlGaN core/shell nanowire and have many implications in experiment.

Luminescence related to two-dimensional gas in ZnO/ZnMgO heterostructures

In c-oriented (001) wurtzite ZnMgO/ZnO heterostructures the polarization induced electric field is the driving force for the formation of two-dimensional electron gas (2DEG) at the ZnMgO/ZnO interfaces. In this work we report on our results of photoluminescence (PL) studies of single ZnMgO/ZnO heterostructures with different thicknesses of top ZnO layers grown on a-plane sapphire by molecular beam epitaxy. We show that the PL spectrum of ZnO layers depends on their thicknesses. In particular, in thin ~5–8nm ZnO layers a broad emission band is observed at 3.1–3.3eV, which shifts to higher energies with increasing temperature and excitation power. We suggest that this PL involves 2D electrons confined in the triangular potential well at the ZnMgO/ZnO interface. We also observe an emission near 3.4eV, which we interpret as emission involving 2D electrons and holes from the ZnMgO barrier. The dependence of the PL on the thickness of the ZnO layer is discussed and we suggest that emission involving two dimensional 2D electrons reflects occupation of states in the triangular potential at the interface.

Виявлення початку формування двовимірного електронного газу на поверхні топологічного ізолятора

Виявлення початку формування двовимірного електронного газу на поверхні топологічного ізолятора

Publisher's Note: Effects of structural relaxation, interdiffusion, and surface termination on two-dimensional electron gas formation at theLaAlO3/SrTiO3(001) interface [Phys. Rev. B92, 155416 (2015)

Publisher's Note: Effects of structural relaxation, interdiffusion, and surface termination on two-dimensional electron gas formation at the<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mi>LaAlO</mml:mi><mml:mn>3</mml:mn></mml:msub><mml:mo>/</mml:mo><mml:msub><mml:mi>SrTiO</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:mrow></mml:math>(001) interface [Phys. Rev. B<b>92</b>, 155416 (2015)

Lattice parameters and electronic structure of BeMgZnO quaternary solid solutions: Experiment and theory

BexMgyZn1−x−yO semiconductor solid solutions are attractive for UV optoelectronics and electronic devices owing to their wide bandgap and capability of lattice-matching to ZnO. In this work, a combined experimental and theoretical study of lattice parameters, bandgaps, and underlying electronic properties, such as changes in band edge wavefunctions in BexMgyZn1−x−yO thin films, is carried out. Theoretical ab initio calculations predicting structural and electronic properties for the whole compositional range of materials are compared with experimental measurements from samples grown by plasma assisted molecular beam epitaxy on (0001) sapphire substrates. The measured a and c lattice parameters for the quaternary alloys BexMgyZn1−x with x = 0−0.19 and y = 0–0.52 are within 1%–2% of those calculated using generalized gradient approximation to the density functional theory. Additionally, composition independent ternary BeZnO and MgZnO bowing parameters were determined for a and c lattice parameters and the bandgap. The electronic properties were calculated using exchange tuned Heyd-Scuseria-Ernzerhof hybrid functional. The measured optical bandgaps of the quaternary alloys are in good agreement with those predicted by the theory. Strong localization of band edge wavefunctions near oxygen atoms for BeMgZnO alloy in comparison to the bulk ZnO is consistent with large Be-related bandgap bowing of BeZnO and BeMgZnO (6.94 eV). The results in aggregate show that precise control over lattice parameters by tuning the quaternary composition would allow strain control in BexMgyZn1−x−yO/ZnO heterostructures with possibility to achieve both compressive and tensile strain, where the latter supports formation of two-dimensional electron gas at the interface.

Determination of the depletion layer width and effects on the formation of double-2DEG in AlGaAs/GaAs heterostructures

In this work, the influence of the surface depletion layer on the formation of a two-dimensional electron gas in AlGaAs/GaAs modulated doped heterostructures is studied. The authors explore a method for estimating the depletion region inside of the GaAs-based heterostructures by using the longitudinal optical and L- amplitude modes observed in Raman spectra, which are supported by the modeling results. The authors found that the position of the topmost doping layer changes the electron distribution in the heterostructure and decreases the influence of the depletion layer. Similar effects are perceived when an optimized solution of (NH4)2SX and isopropanol is employed. The authors present a method to evaluate the formation of a double two-dimensional electron gas in a heterostructure by the adequate use of modulation line in the photoreflectance spectroscopy.

Self-consistent vertical transport calculations in AlxGa1–xN/GaN based resonant tunneling diode

The formation of two-dimensional electron gases (2DEGs) at AlxGa1−xN/GaN hexagonal double-barriers (DB) resonant tunneling diodes (RTD) is investigated by numerical self-consistent (SC) solutions of the coupled Schrödinger and Poisson equations. Spontaneous and piezoelectric effects across the material interfaces are rigorously taken into account. Conduction band profiles, band edges and corresponding envelope functions are calculated in the AlxGa1−xN/GaN structures and likened to those where no polarization effects are included. The combined effect of the polarization-induced bound charge and conduction band offsets between the hexagonal AlGaN and GaN results in the formation of 2DEGs on one side of the DB and a depletion region on the other side. Using the transfer matrix formalism, the vertical transport (J−V characteristics) in AlGaN/GaN RTDs is calculated with a fully SC calculation in the ballistic regime. Compared to standard calculations where the voltage drop along the structure is supposed to be linear, the SC method leads to strong quantitative changes in the J−V characteristics showing that the applied electric field varies significantly in the active region of the structure. The influences of the aluminum composition and the GaN(AlGaN) thickness layers on the evolution of the current characteristics are also self-consistently investigated and discussed. We show that the electrical characteristics are very sensitive to the potential barrier due to the interplay between the potential symmetry and the barrier height and width. More interestingly, we demonstrate that the figures of merit namely the peak-to-valley ratio (PVR) of GaN/AlGaN RTDs can be optimized by increasing the quantum well width.

Creating Two-Dimensional Electron Gas in Nonpolar/Nonpolar Oxide Interface via Polarization Discontinuity: First-Principles Analysis of CaZrO3/SrTiO3 Heterostructure.

We studied strain-induced polarization and resulting conductivity in the nonpolar/nonpolar CaZrO3/SrTiO3 (CZO/STO) heterostructure (HS) system by means of first-principles electronic structure calculations. By modeling four types of CZO/STO HS-based slab systems, i.e., TiO2/CaO and SrO/ZrO2 interface models with CaO and ZrO2 surface terminations in each model separately, we found that the lattice-mismatch-induced compressive strain leads to a strong polarization in the CZO film and that as the CZO film thickness increases there exists an insulator-to-metal transition. The polarization direction and critical thickness of the CZO film for forming interfacial metallic states depend on the surface termination of CZO film in both types of interface models. In the TiO2/CaO and SrO/ZrO2 interface models with CaO surface termination, the strong polarization drives the charge transfer from the CZO film to the first few TiO2 layers in the STO substrate, leading to the formation of two-dimensional electron gas (2DEG) at the interface. In the HS models with ZrO2 surface termination, two polarization domains with opposite directions are in the CZO film, which results in the charge transfer from the middle CZO layer to the interface and surface, respectively, leading to the coexistence of the 2DEG on the interface and the two-dimensional hole gas (2DHG) at the middle CZO layer. These findings open a new avenue to achieve 2DEG (2DHG) in perovskite-based HS systems via polarization discontinuity.

Reconstruction of electrostatic field at the interface leads to formation of two-dimensional electron gas at multivalent(110)LaAlO3/SrTiO3interfaces

Reconstruction of electrostatic field at the interface leads to formation of two-dimensional electron gas at multivalent<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:mrow><mml:mo>(</mml:mo><mml:mn>110</mml:mn><mml:mo>)</mml:mo></mml:mrow><mml:mspace width="0.28em" /><mml:mi>LaAl</mml:mi><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn>3</mml:mn></mml:msub><mml:mtext>/</mml:mtext><mml:mi>SrTi</mml:mi><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:mrow></mml:math>interfaces