Trihalomethane Formation Research Articles

Trihalomethane Formation Potential at the Barekese Water Treatment Plant and the Related Cancer Risk to Consumers in the Kumasi Metropolis of Ghana

The prevalence of disinfection by-products in drinking water supplies is a global concern due to their carcinogenicity. However, the monitoring of DBPs such as trihalomethanes (THMs) and haloacetic acids (HAAs) in drinking water supplies is non-existent in many developing Asian, South American, and African countries. The formation of THMs during disinfection arises from a reaction between the disinfectant and natural organic matter in the water, particularly, dissolved organic carbon (DOC). This reaction is hastened by increases in temperature, high levels of disinfectant doses or residual, elevated water pH, long disinfection contact times, and high DOC concentrations. However, the inclusion of a granular activated carbon adsorption process in the water treatment process is the most effective method for the removal of the main precursor (DOC) for the formation of THMs in treated water. The Barekese WTP, which disinfects with chlorine, has no adsorption process for DOC removal, and supplies over 80% of pipe-borne water to the city of Kumasi in Ghana, was assessed for the THM formation potential (THMFP). A THM predictive model was used to determine the potential THM concentration in the final water. The THMFP at the Barekese WTP ranged between 22.42 and 38.94 µg/L, which was below the 100 µg/L threshold set by the WHO. The lifetime average daily doses were 3.9494 × 10−4 µg/Kg/d and 3.9294 × 10−4 µg/Kg/d for male and female consumers, respectively. The lifetime integrative cancer risks associated with consumption of the water were 1.817 × 10−5 and 1.808 × 10−5 for males and females, respectively. The cancer risk posed was acceptably low. However, direct measurement of DBPs is required to corroborate these findings and verify the cancer risk posed to the consumers of treated water from the Barekese WTP to inform policies, regulations, public health interventions, and investment.

Trihalomethanes (THMs) formation in chlorine-treated and -untreated wastewater and its horizontal and vertical distribution through the irrigation of agricultural fields

ABSTRACT This study examines the formation of trihalomethanes (THMs) in wastewater intended for crop irrigation. The presence of dissolved organic carbon (DOC) in the water and its release from the soil make it crucial to understand the relationship between THM formation, DOC aromaticity, and residual chlorine. The research takes a dual approach: assessing spatial distribution through field samples from canals now distributing treated, chlorinated wastewater and analysing vertical percolation of irrigation wastewater through soil previously irrigated with untreated, non-chlorinated water for over 100 years. Spatial analysis reveals that THMs are present in wastewater before treatment, with concentrations increasing post-treatment. Although DOC levels decrease after treatment, their aromaticity remains unchanged, suggesting the persistence of labile DOC. The presence of THMs in treated wastewater from irrigation canals may result from shorter travel distances or increased chlorine use during the COVID-19 pandemic. Vertical soil column experiments indicate a correlation between THM generation, water source, and soil type. Results show that THMs are retained in the soil, where labile DOC is trapped, reducing its concentration while potentially releasing DOC from humic substances. Despite this, THM concentrations do not pose a risk to aquifers, though ongoing monitoring is important should soil and/or treatment methods be altered.

Reduction of organic matter and disinfection by products formation at surface water treatment plants in Egypt

ABSTRACT Although the removal of colloidal particles continues to be an important reason for using coagulation, currently a newer approach, the removal of organic matter to reduce the formation of disinfection byproducts (DBPs) such as trihalomethanes (THMs) are suspected carcinogens. Inefficient removal of total organic carbon (TOC) leads to the formation of carcinogenic THMs. This motivates the research efforts to find a way to reduce them in potable water. The first objective of this research is monitoring the water quality (raw and produced) for selected three water treatment plants within Giza Governorate to reveal the most polluted site (high TOC in the raw water and THMs in the treated water) in the study areas. The second objective of this study is enhancing coagulation to reduce TOC and THMs from surface water treating. In this study, two different coagulants aluminum sulfate (alum), and ferric chloride were tested under different conditions of pH and coagulant concentration to determine their effectiveness for removal of TOC, THMs and turbidity. Optimum values for the mentioned conditions were used to achieve the maximum reduction for TOC and THMs in Al-Ayat drinking water treatment plant (DWTP) which recorded the highest concentration of TOC and THMs. Ferric chloride as a coagulant achieved the maximum removal percentage % of TOC, THMs and turbidity as 79%, 82% and 94%, respectively, at ferric chloride dose 100 mg/L, while alum as a coagulant recorded the maximum removal percentage % of TOC, THMs and turbidity as 46%, 52% and 91%, respectively, at alum dose 100 mg/L. The results indicated that ferric chloride as a coagulant has the highest efficiency reduction of TOC, THMs and turbidity if compared to alum with the same dose added.

Enhancing efficiency and quality control: The impact of Digital Twins in drinking water networks.

This paper showcases the successful development and implementation of two Digital Twin prototypes within the Lab Digital Twins project, designed to enhance the efficiency and quality control of Aigües de Barcelona's drinking water network. The first prototype focuses on asset management, using (near) real-time data and statistical models, and achieving a 70% success rate in predicting pump station failures 137 days in advance. The second prototype addresses water quality monitoring, leveraging machine learning to accurately forecast trihalomethane levels at key points in the distribution system, and enabling proactive water quality management strategies, ensuring compliance with stringent safety standards and safeguarding public health. The paper details the methodology of both prototypes, highlighting their potential to revolutionize water network management. PRACTITIONER POINTS: Digital representation of assets and processes in the drinking water treatment network Early fault detection in assets, and predictions of trihalomethane formation in the drinking water distribution network Reduction on monitoring time and incident response for target assets by means of Digital Twins Improvement in visualization, prediction, and proactive measures for asset management and water quality control Contribution to the growing knowledge on Digital Twins and their potential to revolutionize water network operations.

In-depth analysis of natural organic matter fractions in drinking water treatment performance: Fate and role of humic substances in trihalomethanes formation potential

In this study we investigate the compositional changes in dissolved organic matter (DOM) fractions across diverse water sources and treatment processes in three Drinking Water Treatment Plants (DWTPs). High-Performance Size Exclusion Chromatography coupled with Diode Array Detection and Organic Carbon Detection (HPSEC-DAD-OCD) was employed to characterize DOM fractions, offering insights into treatment optimization. We examine bulk water parameters, DOM distributions, and the efficiency of treatment trains in reducing DOM fractions. Results reveal distinct DOM composition profiles in river-sourced versus reservoir-sourced waters, with implications for treatment processes. Coagulation, Granular Activated Carbon (GAC) adsorption, Electrodialysis Reversal (EDR), and Ion Exchange (IEX) were evaluated for their efficacy in removing DOM fractions. The analysis highlights the effectiveness of coagulation in reducing high molecular weight (MW) fractions, while GAC filtration targets lower MW fractions. EDR shows significant removal of anions and aromatics, while IEX demonstrates high removal efficiencies for removing humic substances (HS) fractions. Spectroscopic analysis further elucidates changes HS sub-fractions and their role in disinfection by-products (DBP) formation. To quantitatively assess the relationship between HS sub-fractions and trihalomethane formation potentials (THMFP), Pearson correlation analysis were conducted, unveiling robust associations between HS sub-fractions and THM-FP that can be predicted by surrogate parameters such as A254.

Optimizing the number, locations, and chlorine dosages of booster chlorination stations in water distribution networks

ABSTRACT Safe and reliable drinking water is essential for sustaining life. Chlorination is widely used for disinfection in water distribution networks (WDNs). A higher dose of chlorine is required in an overhead service reservoir to maintain minimum residual chlorine at the farthest end in WDNs. However, delivering high dosages of chlorine from storage tanks can pose public health issues, especially for the residents living near overhead service reservoirs due to the formation of trihalomethanes, haloacetic acids, and chlorophenols. In addition, a higher dosage will lead to increased chlorine consumption and will accelerate pipe corrosion. Booster chlorination (BC) stations with smaller dosages are a solution to this problem. However, identifying the optimal number, locations, and dosage of each BC station in a cost-effective manner is challenging. This study proposes a methodology for determining the optimal number, locations, and chlorine dosages of BC stations in WDNs using a mixed integer linear programming problem. The methodology is illustrated through a simplified WDN in Holeta town, Ethiopia. The results indicate that if one adds two BC stations beyond the three dosage stations at the source, it will lead to a 49% reduction in chlorine use and a 27% decrease in the life cycle cost.

Trihalomethane formation potentials from the effluent of different wastewater treatment sources

Abstract Reused wastewater is commonly treated with disinfection to remove pathogenic microorganisms; however, this process generates disinfection byproducts (DBPs), such as trihalomethanes (THMs). This study aimed to investigate the levels of THMs and THM formation potential (THMFP) in treated wastewater originating from different sources i.e., domestic, food-processing industry and hospital. The samples from each source were collected three times between June and August 2023. Dissolved organic carbon (DOC) was evaluated from the samples prior to and after disinfection with chlorine over a period of 7 days. The results found that the concentration of DOC was highest in hospital effluent, with an average value of 5.60±0.16 mg/L followed by effluent from the food-processing industry and domestic, which had average DOC concentrations of 4.60±1.39 mg/L and 4.46±0.37 mg/L, respectively. The concentration of THMs in hospital effluent was found the highest at 6.91±0.88 µg/L followed by effluent from the domestic and food-processing industries, which exhibited amounts of 6.74±0.77 µg/L and 5.25±0.77 µg/L, respectively. In contrast, the food-processing factory had the highest concentration of THMFP at 299.39±26.54 µg/L, while the domestic and hospital effluent displayed a lower concentration of 133.64±36.86 µg/L and 51.48±9.01 µg/L, respectively.

Performance of Chitosan/Carbon Nanotube-Coated Ultrafiltration Membranes for Natural Organic Matter Removal from Drinking Water

The objective of this study is to improve the filtration efficiency of commercially available polyethersulfone (PES) ultrafiltration (UF) membranes, with a specific focus on removing natural organic matter (NOM) and preventing membrane fouling. The modification of UF membranes was accomplished by utilizing chitosan/multi-walled carbon nanotubes (CS/MWCNT-OH) and employing both dip and spin coating techniques. The membrane surface morphologies were evaluated using the Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR), Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM), and Energy-Dispersive X-ray Spectroscopy (EDX) techniques. Tests were carried out to assess the effectiveness of the membranes in a laboratory-scale system using two primary water sources from Istanbul, specifically the Melen River and Terkos Lake. Total organic carbon (TOC), UV254 absorbance, turbidity, and trihalomethane formation potential (THMFP) were all measured as part of a thorough analysis. The surface morphology investigations verified the effective deposition of MWCNT-OH nanoparticles onto the membrane surface. This was corroborated by the reduction in the water contact angle, showing an improvement in the hydrophilicity of the membrane. The modified membranes demonstrated much higher TOC removal rates compared to the original membranes. Specifically, the removal efficiencies for Melen River and Terkos Lake were 37.14% and 56.86%, respectively. Nevertheless, the alteration of the surface led to a decline in membrane flux as a result of the concurrent drop in pore size. To summarize, the results of this work highlights the considerable capability of surface modification using CS/MWCNT-OH to improve the performance and antifouling characteristics of commercial PES UF membranes.

Assessment of trihalomethanes formation during the treatment of surface water in coastal areas

Assessment of trihalomethanes formation during the treatment of surface water in coastal areas

Leaching of organic matter from cigarette butt filters as a potential disinfection by-products precursor

The study aimed to evaluate cigarette butt filters (CBFs) as a potential source of dissolved organic carbon (DOC) in water leading to the formation of disinfection by-products. Two different forms of CBFs – intact (I) and disintegrated (D), as they occur in the environment, were selected for leaching in chlorinated (CI, CD), non-chlorinated (NI, ND), and highly chlorinated (HCD) water samples. The UV absorbance profiles of the leachate samples showed that intact CBFs exhibited higher DOC leaching compared to the disintegrated ones, which was further accentuated in chlorinated samples (CI > CD > NI > ND). The Fourier Transform Infrared spectra of the leachates revealed the presence of characteristic functional groups of cellulose acetate and its chlorinated derivatives, indicating the potential degradation of the polymer. Moreover, trihalomethane (THM) formation in chlorinated samples was relatively higher in CI samples (2 – 11.5 times) compared to CD, consistent with the DOC leaching trends. Further, the speciation characteristics of different THMs in both CI and CD samples were similar. Although spectral and morphological analyzes of CI and CD samples revealed negligible variation, HCD samples depicted significant surface roughness characterized by the formation of pits and holes, along with the evolution of crystallinity. This suggested accelerated degradation of CBFs and disruption of acetyl groups as a factor of elevated chlorine concentrations.

Formation and health risk assessment of trihalomethanes in coastal wells impacted by seawater intrusion

The formation of trihalomethanes (THMs) in coastal wells impacted by seawater intrusion (SWI) is relatively understudied. Coastal wells, unlike typical groundwater sources, frequently exhibit elevated levels of chloride and bromide ions, potentially influencing the formation and speciation of THMs. The current study investigated the THM formation in coastal well water from a location affected by SWI. Samples were chlorinated with 2.5 mg L−1 and 5 mg L−1 chlorine doses to replicate field conditions. The THM concentration in the samples exceeded the maximum permissible limit for drinking water. The well with the highest chloride-to-bromide (Cl/Br) ratio (Cl/Br = 645) exhibited the highest total THM concentration (503.2 μg L−1). Samples with high bromide concentration had more brominated THMs over the 5-day reaction period. The bromine substitution factors for wells after 24 h with a chlorine dose of 2.5 mg L−1 were 1.89, 2.21, and 2.78, corresponding to bromide concentrations of 0.098, 0.109, and 1.275 mM, respectively. The average cancer risk associated with the well water was estimated to be 20.9 × 10−06 through dermal contact and 6.84 × 10−04 through inhalation. The study area had an estimated average cancer risk of 705 cases per million population. The study area's common diseases and cancer incidence data for the past four decades indicated a decreasing trend for waterborne diseases and a steep increase in cancers. While several factors may contribute to increasing cancer cases, our study highlights chlorinated coastal well water as an additional potential cancer risk agent.

Fungal and bacterial evaluation in drinking water distribution network and their association with physicochemical parameters

Preventing the growth of microorganisms in water distribution network (WDN) is an important public health priority. In this study, 98 water samples were collected from the Gorgan City (Iran) water distribution network (WDN) to assess fungal and bacterial contamination in WDN and their association with physicochemical parameters. All microbiological and physicochemical tests were performed as described in the standard method. The results showed that 15.3 %, 12.2 %, and 2 % of the sample had total coliforms, Clostridium perfringens and fecal coliforms, respectively; however, no Escherichia coli and fecal streptococci were found in samples. The average count of heterotrophic bacteria and fungi was 203.45 CFU/mL and 6.83 CFU/100 mL, respectively. Seven genera of fungi were isolated, of which Candida (19.4 %) and Aspergillus (11.2 %) were the most prevalent, followed by Penicillium (5.1 %), Rhodotorula (3.1 %), Cladosporium (2 %), Acremonium (2 %) and Alternaria (1 %). The mean and Standard deviation of free residual chlorine (FRC), pH, turbidity, temperature, total organic carbon and electrical conductivity were 0.22 ± 0.27 mg/l, 7.28 ± 0.22, 0.61 ± 0.68 NTU, 19.27 ± 2.83 °C, 0.45 ± 0.17 mg/l, and 953.49 ± 207.54 (µs/cm), respectively. The presence of pathogens fungus is a major public health concern for people with lowered immunity. The present study indicated that using microorganisms with different features provides a more reliable evaluation to assess the microbial growth in WDN. Amongst physicochemical parameters, FRC above 0.8 mg/l prevented the fungal and bacterial pathogens growth in WDN. However, further research is required to measure the risks of trihalomethane formation.

Point-of-use chlorine residuals and disinfection byproduct occurrences in rural households served by public water utilities in Appalachian Virginia

ABSTRACT We characterized concentrations of trihalomethanes (THMs), a measure of disinfection byproducts (DBPs), in tap water samples collected from households with utility-supplied water in two rural counties in Appalachian Virginia, and assessed associations with pH, free chlorine, and metal ions which can impact THM formation. Free chlorine concentrations in all samples (n = 27 homes) complied with EPA drinking water guidelines, though 7% (n = 2) of first draw samples and 11% (n = 3) of 5-min flushed-tap water samples exceeded the US Safe Drinking Water Act (SDWA) maximum contaminant level (MCL) for THM (80 ppb). Regression analyses showed that free chlorine and pH were positively associated with the formation of THM levels above SDWA MCLs (OR = 1.04, p = 0.97 and OR = 1.74, p = 0.79, respectively), while temperature was negatively associated (OR = 0.78, p = 0.38). Of the eight utilities serving study households, samples from water served by three different utilities exceeded the EPA MCL for THM. Overall, these findings do not indicate substantial exposures to DBPs for rural households with utility-supplied water in this region of southwest Virginia. However, given the observed variability in THM concentrations between and across utilities, and established adverse health impacts associated with chronic and acute DBP exposure, more research on DBPs in rural Central Appalachia is warranted.

Monitoring and Assessment of the Quality of Chlorinated Water in Schools

All water destined for human consumption must be subjected to disinfection processes via chlorination with the aim of eliminating the risk of the transmission of waterborne diseases. However, the treatment of water using this method leads to the formation of trihalomethanes (THMs), which are toxic compounds that may be ingested, inhaled, or absorbed by the skin, increasing the risk of carcinogenic and mutagenic processes. High trihalomethane concentrations in water may be directly related to physicochemical properties, such as temperature, pH, hardness, and potentially toxic metal concentrations. In this work, physicochemical characterization was performed and water quality was assessed with regard to the presence of trihalomethanes in 17 samples collected from points before and after storage in reservoirs. Atomic absorption spectroscopy to determine potentially toxic metals and the measurement of physicochemical properties demonstrated that all results were in accordance with the standards established by Brazilian legislation. Gas chromatography–mass spectrometry was used to determine levels of trihalomethanes in the water samples (trichloromethane, bromodichloromethane, chlorodibromomethane, and bromoform), which were also in accordance with the limits established by Brazilian legislation. Hierarchical clustering on principal components confirmed changes in the water quality depending on location. This work constitutes a paradigm for future studies on the monitoring of toxic organic compounds in water to avoid health problems in humans and animals.

Control of chlorination disinfection by-products in drinking water by combined nanofiltration process: A case study with trihalomethanes and haloacetic acids

Disinfection by-products (DBPs) are prevalent contaminants in drinking water and are primarily linked to issues regarding water quality. These contaminants have been associated with various adverse health effects. Among different treatment processes, nanofiltration (NF) has demonstrated superior performance in effectively reducing the levels of DBPs compared to conventional processes and ozone-biological activated carbon (O3-BAC) processes. In this experiment, we systematically investigated the performance of three advanced membrane filtration treatment schemes, namely "sand filter + nanofiltration" (SF + NF), "sand filter + ozone-biological activated carbon + nanofiltration" (SF + O3-BAC + NF), and "ultrafiltration + nanofiltration" (UF + NF), in terms of their ability to control disinfection by-product (DBP) formation in treated water, analyzed the source and fate of DBP precursors during chlorination, and elucidated the role of precursor molecular weight distribution during membrane filtration in relation to DBP formation potential (DBPFP). The results indicated that each treatment process reduced DBPFP, as measured by trihalomethane formation potential (THMFP) and haloacetic acid formation potential (HAAFP), with the SF + O3-BAC + NF process being the most effective (14.27 μg/L and 14.88 μg/L), followed by the SF + NF process (21.04 μg/L and 16.29 μg/L) and the UF + NF process (26.26 μg/L and 21.75 μg/L). Tyrosine, tryptophan, and soluble microbial products were identified as the major DBP precursors during chlorination, with their fluorescence intensity decreasing gradually as water treatment progressed. Additionally, while large molecular weight organics (60–100,000 KDa) played a minor role in DBPFP, small molecular weight organics (0.2–5 KDa) were highlighted as key contributors to DBPFP, and medium molecular weight organics (5–60 KDa) could adhere to the membrane surface and reduce DBPFP. Based on these findings, the combined NF process can be reasonably selected for controlling DBP formation, with potential long-term benefits for human health.

Adaptation of water treatment processes for controlling disinfection byproducts in supply waters to compensate the effects of climate change

The water treatment processes (WTPs) need adaptation to climate change. Safe water supply is being challenged by the deteriorating trend of water quality, which can increase disinfection byproducts and impose cancer/non-cancer risks to humans. In this study, implications of climate change and water quality deterioration on the formation of trihalomethanes' (THMs), and risks from 2020 to 2050 were predicted. In 2020, averages of temperature, dissolved organic carbon (DOC) and pH in source waters from Newfoundland (Canada) were 7.92 °C, 6.40 mg/L and 6.53 respectively, which were predicted to be 9.95 °C, 8.56 mg/L and 7.65, respectively in 2050. Three scenarios of free chlorine and bromide ions [(2.0 mg/L, 10 μg/L), (3.5 mg/L, 25 μg/L) and (5.0 mg/L, 50 μg/L)] were simulated. Two models (Model-1 and Model-2) were applied for predicting THMs, risks and allowable DOC for target risks. For Model-1, DOC in 2030, 2040 and 2050 were predicted to be in the ranges of 4.53–4.92, 3.32–3.84 and 2.49–3.06 mg/L respectively to impose similar risks as of 2020. For Model-2, DOC ranges were 5.02–5.95, 3.92–4.99 and 3.60–4.80 mg/L respectively. The lower ranges of DOC in future years were due to increased effects of pH and temperature. To maintain the risks of 2050 to the levels of 2020, WTPs need to reduce DOC by 64.3–70.9 % (Model-1) and 43.8–57.9 % (Model-2). The granular activated carbon filtration is widely used for reducing DOC, which can be further assessed for extensive applications in the WTPs.

Comparison of Fe‐based and Al‐based coagulants in the removal of organic and disinfection by‐product precursors

AbstractSurface water is renowned for its natural organic matter, constituting approximately 45% of total dissolved organic carbon (DOC) which can be removed in water treatment plants. However, residual DOC in water can react with chlorine to form several carcinogenic disinfectant by‐products (DBPs). This study aimed to examine the molecular weight of organic fractions dissolved in three different water sources that act as precursors to the formation of DBPs species. The coagulants used were Al‐ and Fe‐based, frequently used in water treatment plants to remove organic fractions. Characterization of DOC in source water served as the first step in determining the performance of both coagulants in terms of organic properties. The results showed that the selected surface waters had similar DOC characteristics, including biopolymers, humic substances, building blocks, and a low molecular weight. These fractions contributed to the formation of trihalomethanes (THMs) and haloacetic acids (HAAs). The Fe‐based coagulant was more effective than the Al‐based coagulant in removing all organic fractions and reducing THMs compared to HAAs. Furthermore, one‐way ANOVA analysis showed a significant difference in the average removal of organic fractions and DBP species between the Fe‐based and Al‐based coagulants. The Fe‐based coagulant showed higher efficiency in removing biopolymers, dibromochloromethane, and chlorodibromoacetic acid than the Al‐based coagulant. In contrast, the Al‐based coagulant had better performance in reducing dibromo HAA and tribromo HAA. Both coagulants had no significant difference in extracting other organic fractions or DBPs species.

Impact of source water quality on total organic carbon and trihalomethane removal efficiency in a water treatment plant: A case study of Upper Awash, Ethiopia.

This study addresses the limited understanding of factors affecting the efficiency of water treatment plants in reducing trihalomethane (THM) formation through total organic carbon (TOC) removal, highlighting significant challenges in improving treatment effectiveness. The aim of this study was to examine the influence of water quality on the efficiency of water treatment plants to remove TOC and reduce THM formation. Linear regression and correlation analyses were conducted to examine the relationship between water quality parameters and THM concentrations. The results showed that there was a negative relationship between turbidity, metals, and TOC concentration with TOC removal efficiency. Positive correlations were found between parameters and the formation of THMs in water. Of these parameters, water temperature was observed to have relatively less influence on THM formation. It was observed that seasonal variations in water quality affect the efficiency of TOC removal and THM content in treated water. THM levels in chlorinated water were found to be within the permissible range of the World Health Organization's drinking water quality guidelines. However, it is still important to maintain continuous monitoring and take measures to reduce THMs. The model demonstrated a strong correlation (R2 = 0.906) between predicted and measured THM values.

MONITORAMENTO DE TRIHALOMETANOS (THMs) E DA QUALIDADE DA ÁGUA PARA ABASTECIMENTO PÚBLICO DA CIDADE DE CAVALCANTE, GOIÁS

MONITORING OF TRIHALOMETHANES (THMs) AND WATER QUALITY FOR PUBLIC SUPPLY IN THE CITY OF CAVALCANTE, GOIÁS. Trihalomethanes (THMs) are organohalogens compounds formed from the reaction between free residual chlorine and natural matter organic (humic substances) present in raw water from surface sources. This study aimed to evaluate the formation of THMs resulting from the application of chlorine for disinfection, in the water treating process for public supply in the city of Cavalcante, GO, located in the region of Chapada dos Veadeiros (Brazil). The results of physical-chemical analyses apparent color, turbidity, pH, free residual chlorine, consumed oxygen, hardness, total alkalinity and THMs demonstrated a positive and strong correlation between the formation of THMs and the hardness of treated water, as well as the chlorine consumed during disinfection process. It was observed an increase in apparent color, turbidity and consumed oxygen in the rainy season. These parameters indicate the presence of organic matter and that present a positive and moderate correlation with the formation of THMs.

Modeling chloramine stability and disinfection byproduct formation in groundwater high in bromide

AbstractBromide can promote monochloramine decomposition and disinfection byproduct (DBP) formation. Monochloramine and total chlorine stability as well as total trihalomethane and haloacetic acid formation were examined in groundwater with high bromide levels (300–1700 μg/L) following chlorine or KMnO₄ preoxidation. An N,N‐Diethyl‐p‐phenylenediamine (DPD)‐based total chlorine method detected chloramines and brominated amines (e.g., NH2Br, NHBrCl). An indophenol‐based monochloramine method showed minimal interference from brominated amines. Differences between these methods' measurements likely indicated brominated amine concentrations. Substantial total chlorine demands (up to ~3.5 mg/L in 4 days) following chlorine preoxidation were observed due to the presence of brominated amines. Total chlorine measurements were more stable and DBP formation was limited following KMnO₄ preoxidation because ammonia was dosed before chlorine, which inhibited brominated amine formation. A kinetic model developed elsewhere for dissolved organic matter (DOM)‐free water generally tracked with experimental results but some deviations occurred possibly because DOM consumed bromochloramine or its reaction intermediates.