Formation Of Elastomers Research Articles

Electrically Driven Artificial Muscles Using Novel Polysiloxane Elastomers Modified with Nitroaniline Push-Pull Moieties.

The synthesis of novel dielectric elastomers that show a muscle-like actuation when exposed to a low electric field represents a major challenge in materials science. Silicone elastomers modified with polar side groups are among the most attractive dielectrics for such a purpose because of their high polarizability over a wide temperature and frequency range. Nitroaniline (NA) has a strong dipole moment, and therefore, its incorporation into silicone networks should allow the formation of elastomers with increased dielectric permittivity. However, incorporation of a large amount of NA into silicone needed to increase the dielectric permittivity is still challenging. In this work, we present the synthesis of polysiloxane elastomers modified with a large fraction of the nitroaniline (NA) polar group, following two different synthetic strategies. Both approaches allowed the formation of homogenous elastomers at the molecular level. These yellowish materials have a dielectric permittivity three times higher as compared to the reported NA-modified silicones. Additionally, they have excellent mechanical properties with low viscoelastic losses and a strain at break reaching 300%. Furthermore, the mechanical properties of these elastomers can be easily tuned by the content of cross-linkers used. The developed elastomers are highly stable in electromechanical tests and show an actuation strain of 8% at unprecedentedly low electric fields of 7.5 V/μm. The combination of properties such as high dielectric permittivity, large strain at break, low viscoelastic losses, fast and reversible actuation, and actuation at low electric fields is crucial for the new generation of dielectric elastomer materials that will find their way in applications ranging from artificial muscles, soft robots, sensors, and haptic displays to electronic skin.

Improved Resilience by Formation of Elastomers inside Cotton Fibers

The introduction of elastomeric substances between the cellulose fibrils and/or histological elements of cotton fibers could lead to wrinkle-resistant cottons. Such substances, polyenes obtained by polymerization in situ after inclusion within the structure, are unable to penetrate the intermolecular structure, but are able to link together the elements of the fiber. This might result in a fiber with greater delayed elastic recovery and reduced permanent set, permitting wrinkle recovery of cotton fabrics to be increased. The study of optimum reaction parameters resulted in a reproducible process for including the polymer. The location of the polymer has been determined through the development of a new method for revealing the structure of cellulose. The desired mechanical properties of woven treated fabrics are improved, as indicated by various measurements. The first results concerning single fibers seem to corroborate the preceding.