Food Industry Wastewater Research Articles

Investigating the treatability of prepared food industry wastewater using the chemical process of coagulation and flocculation

Investigating the treatability of prepared food industry wastewater using the chemical process of coagulation and flocculation

Treating waste with waste: Treatment of textile wastewater using upcycled food waste as a pore-forming agent in the fabrication of ceramic membranes employing DOE/FFD design

This study investigates a novel method for food waste management by using it as a sustainable replacement for conventional pore-forming agents in ceramic membrane production. The membranes were analyzed using various techniques, including X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), and a universal testing machine. The morphologies of the membranes were observed using scan electron microscopy (SEM). The effects of particle size (45–125 μm), pore-forming agent (5–20 wt%), and sintering temperature (900–1150 °C) on the porosity and mechanical strength of the membranes were investigated using the Design of Experiments (DoE) and Response Surface Methodology (RSM). The optimized membrane was evaluated for its performance in filtering industrial textile wastewater. It achieved impressive results, with approximately 98.4 % removal of turbidity and 71.3 % removal of chemical oxygen demand. This research paves the way for optimizing ceramic membrane fabrication using upcycled food waste, promoting sustainability and offering potential solutions for both food waste management and industrial wastewater treatment challenges.

Colour and COD Removal from Food and Beverages Industrial Wastewater by using Spent Alkalis Carbide Lime (SACL)

The abundant amount of water used in the food & beverages (F&B) industry has caused the wastewater from this industry to be one of the major sources of water pollution, due to its high content of colour and chemical oxygen demand (COD). In this study, spent alkalis carbide lime (SACL) was used in treating the colour and COD simultaneously from the F&B industrial wastewater. SACL was used to reduce the amount of landfill waste and because of its similar characteristic to lime. The SACL was characterized using X-ray Diffractometer (XRD) X-ray Fluorescence (XRF), Scanning Electron Microscope (SEM), and Fourier-Transform Infrared Spectroscopy (FTIR) while the F&B industrial wastewater was characterized by using HACH DR6000 and UV-Vis Spectrophotometers. Several series of chemical precipitation experiments were conducted through jar tests to evaluate the effects of SACL dosing, pH value, and contact time on the percentage removal of colour and COD. The optimum conditions obtained from this study are pH 7 and 20 minutes, with percentage removal of 99.5% and 89.8% for colour and COD. However, the percentage removal of colour and COD decreased as contact time increased. With the same value of pH and contact time, SACL managed to remove more colours compared to lime, which is 93.6% compared to 88.54%, respectively. According to the analyses of FTIR and UV-Vis, the wastewater sample was cleaner when using SACL compared to using lime during the treatment. Thus, the study proves that SACL is a reliable alternative to treat colour and COD from F&B industrial wastewater.

Valorization of residual ashes from boiler combustion process into activated carbon for adsorption of food industry wastewater

Valorization of residual ashes from boiler combustion process into activated carbon for adsorption of food industry wastewater

Identifying leverage points using material flow analysis to circularise resources from urban wastewater and organic waste

Anthropogenic systems are synonymous with linear economies that cause widespread resource waste and environmental degradation. Urban areas are hotspots for this behaviour due to their high population density and resource consumption. Changing this situation is limited by the lack of a holistic but sufficiently detailed understanding of system units where resource waste occurs. The objectives of this study were: (1) to develop and apply a model of the material and substance (nitrogen, phosphorus, and carbon) flows of organic waste and wastewater systems at a local scale, taking Christchurch, New Zealand, as a study case, and (2) to identify leverage points within the system to achieve resource circularisation. Results show that groundwater, infiltrated water, and industrial wastewater are the predominant material flows into the system. Nitrogen and phosphorus inputs predominantly come from food products, detergents, green waste, and industrial wastewater. The Christchurch wastewater system is a prime example of a linear economy, where ∼66 % of the nitrogen and ∼63 % of the phosphorus entering the wastewater system is discharged to the ocean. Leakage from the water supply system reduces water resource efficiency, while water infiltration into the wastewater network inflates the quantity of wastewater treated at the centralised treatment plant, limiting nutrient recovery. In the compost facility, 86 % of the waste is composted, with 33% of the nitrogen and all the phosphorus exiting as compost, while ∼66 % of the nitrogen treated exits through volatilisation. The remaining 14 % of the organic waste entering the treatment plant is deemed unsuitable for composting and is landfilled. The material and substance flow analysis allowed the identification of flows with leverage points in the system where there are opportunities to reduce, reuse, or recover materials and substances to encourage circularisation. These flows include food products, detergents, unsuitable materials for composting, domestic water supply leakages, wastewater network infiltration, and wastewater treatment plant's nutrient recovery.

Using a novel bio-based cationic flocculant for food industry wastewater treatment

Wastewater from the food industry is considered harmful to human health and aquatic life, as well as polluting water and soil. This research is centered around finding an affordable and easy physicochemical method for dealing with waste generated by the food industry. To accomplish this goal, a new bio-based flocculant called 4-benzyl-4-(2-oleamidoethylamino-2-oxoethyl) morpholin-4-ium chloride was created using sustainable sources, specifically crude olive pomace oil. Its chemical structure was confirmed using various spectroscopic techniques such as FTIR, 1H-NMR, mass spectra, and 13C-NMR. This new bio-based cationic flocculant was combined with alum to act as a coagulant in the waste treatment process. Also, a study was conducted to determine the optimal conditions for the coagulation-flocculation process parameters, namely, pH and alum dosage, on COD and removal efficiency. The results showed that the optimal conditions for flocculation were achieved at pH 5.8, with 680 mg/L alum and 10 mg/L of commercial flocculant dose compared to only 5 mg/L of a new bio-based cationic flocculant. A comparison was made between the new bio-cationic flocculant and a commercial CTAB one for treating wastewater in the food industry. The study found that the new bio-based cationic flocculant was more effective in reducing the chemical oxygen demand, achieving a reduction of 61.3% compared to 54.6% for using a commercial cationic flocculant. Furthermore, using a new bio-based cationic flocculant costs only 0.49 $/g, which is less than the present cationic flocculant, which costs 0.93 $/g. The adoption of this new flocculant provides a sustainable alternative to existing industrial wastewater treatment processes

Assessment of Nutrient Removal Efficiency of Marine Microalgae Dunaliella salina in Saline Food Industry Wastewater

Industrial wastewater release into the environment is a critical global challenge leading to severe water pollution, adversely impacting terrestrial and aquatic ecosystems requiring effective solutions. The treatment, disposal, and recirculation of saline wastewater from food containing nitrate and phosphate poses significant health and environmental risks. This research aims to address the challenge by investigating the potential of using the marine microalgae Dunaliella salina for treating saline food industry wastewater, both in laboratory and pilot-scale settings using raceway tanks. In the laboratory study, a mixture of wastewater and F/2 medium was inoculated with Dunaliella salina to assess its potential for growth in saline wastewater, rich in nitrate and phosphate. The study observed a cell density of 5.5 x 105 cells/ml. Subsequently, a pilot-scale study was conducted, where the maximum cell density of 6.2 x 105 cells/ml was achieved. The efficacy of Dunaliella salina in removing nitrate and phosphorus from the culture was evaluated by measuring the levels of these compounds. A significant reduction in nitrate concentration from 146 to 22.16 mg/l was observed, with a removal efficiency of 84.82%; similarly, the phosphate concentration decreased from 55.3 to 10.79 mg/l, with a removal efficiency of 80.49 %. The reductions in nitrate and phosphate concentrations, along with the demonstrated growth of Dunaliella salina in saline industrial wastewater, confirmed the feasibility of employing these microalgae for bioremediation treatment in a sustainable way.

Electrochemical Characteristics of Microbial Fuel Cells Operating with Various Food Industry Wastewaters

In the present work, four different wastewaters from the food industry were used in parallel, in four identical dual-chamber MFCs, with graphite granules as anodic electrodes. Specifically, a mixture of hydrogenogenic reactor effluents (effluents from a dark fermentation reactor fed with cheese whey (CW), for hydrogen production), CW, and a mixture of expired fruit juices and wastewater from the confectionery industry were simultaneously used in MFCs to evaluate the effect of the type of effluent/wastewater on their efficiency. An electrochemical characterization was performed using electrochemical impedance spectroscopy measurements under open- (OCP) and closed-circuit conditions, at the beginning and end of the operating cycle, and the internal resistances were determined and compared. The results showed that the highest OCP value, as well as the highest power density (Pmax) and Coulombic efficiency (εcb) at the beginning of the operating cycle, was exhibited by the MFC, using a sugar-rich wastewater from the confectionery industry as substrate (sugar accounts for almost 92% of the organic content). This can be correlated with the low internal resistance extracted from the Nyquist plot at OCP. In contrast, the use of CW resulted in a lower performance in terms of OCP, εcb and Pmax, which could be correlated to the high internal resistance and the composition of CW, a substrate rich in lactose (disaccharide), and which also contains other substances (sugars account for almost 72% of its organic content, while the remaining 28% is made up of other soluble compounds).

Development of alginate beads loaded with bioactive ingredients from Chlorella vulgaris cultivated in food industry wastewaters

Microalgae are increasingly recognized for their potential in the food sector due to their rapid growth and rich content in proteins, carbohydrates, and pigments. The extraction of pigments from microalgal biomass holds promise for their utilization as natural colorants and antioxidants. To address the economic challenges associated with microalgae cultivation, particularly high nutrient costs, this study focused on cultivating Chlorella vulgaris in a mixture of food industry wastewaters (brewery wastewater, expired orange juice and cheese whey). This resulted in a microalgae-bacteria consortium with a concentration of 2.2 g·L−1 dry weight after 5 days of cultivation. The wastewater bioremediation ranged between 23 and 77 %, and the produced microalgae biomass contained 21.68 ppm lutein, 36.47 ppm a-chlorophyll and 11.19 ppm b-chlorophyll. The extraction process employed a solvent screening strategy with food industry-accepted solvents used to extract high-value compounds efficiently. Ethanol was the most effective solvent, outperforming acetone, ethyl acetate, and hexane. An upscaled extraction process was conducted using 10 g lyophilized microalgae. After ethanol evaporation, the microalgal extract was re-diluted in sunflower oil and encapsulated in alginate beads, achieving an encapsulation yield of 93.3 %. Lutein, identified as one of the main compounds in the extract, exhibited a satisfactory encapsulation efficiency of 55 %. The efficient encapsulation of the microalgae components in alginate beads was verified by the alteration of the colorimetric parameters of these alginate beads compared to those loaded with pure sunflower oil as well as empty beads. These findings highlight the potential of microalgae as a valuable tool for transforming food industry wastewater into high-value products, especially when microalgal extract is encapsulated in alginate beads. This strategy presents substantial prospects for the food industry, merging effective wastewater valorization with biomass production and bioactive compound extraction. It exemplifies a circular bioeconomy, showcasing sustainable resource management and value creation.

Ammonium ion removal from aqueous solutions in the presence of organic compounds, using biochar from banana leaves. Competitive isotherm models

BackgroundIndustrial, e.g. food industrial and domestic wastewaters contain huge amount of compounds causing eutrophication, and should be removed with high cost during wastewater treatment. However, these compounds could be utilized as fertilizers too. Biochar can remove a wide range of pollutants from water, such as ammonium, which can be found in relatively high concentration in dairy wastewaters. However, adsorption performance may be affected by the presence of other wastewater pollutants. Thus, this study aims to determine the efficiency of biochar as an adsorbent of ammonium in aqueous solutions in the presence of some selected organic compounds of typical dairy wastewaters such as bovine serum albumin (BSA), lactose, and acetic acid. Methods: The biochar was produced from banana leaves at 300 °C, modified with NaOH, and characterized by Scanning Electron Microscope – Energy Dispersive X-Ray Spectroscopy (SEM-EDX), Fourier-transform infrared spectra (FTIR) analysis, and specific surface area measurements. Batch experiments were carried out to investigate the ammonium adsorption capacity and the ion competitive adsorption mechanism. Significant Findings: Results show that the surface structure of the biochar derived from banana leaves is different from other biochars previously studied; although the specific surface area is not very considerable and despite having nitrogen within the elemental composition, the biochar studied is capable of adsorbing 2.60 mg NH4+/m2, the highest ammonium removal in 2 h occurs at pH 9 and 500 mg biochar dose. Langmuir model in the monolayer phase analysis fits better for all scenarios and the maximum NH4+ adsorption capacity was 0.97 mg/g without organic compounds. In the multilayer adsorption phase, the isotherm model that best fits the data obtained is the Harkins-Jura model without organic compounds. The presence of organic compounds in the aqueous solution significantly impacts the adsorption of ammonium by biochar since it improves the adsorption capacity (1.132 mg/g BSA, 0.975 mg/g lactose, and 1.874 mg/g acetic acid). The Aranovich-Donohue isotherm model fitted the data obtained during ion competitive adsorption experiments well.

Consequential LCA of NPK fertilizers from microbial, animal, plant, and mineral origin highlights resource constraints and environmental impacts

The production and use of mineral fertilizers lead to severe environmental impacts, therefore initiatives such as the European Green Deal promote organic farming and nutrient circularity. However, many organic fertilizers (those containing organic carbon and nutrients of exclusively biological origin) face constraints due to resource availability, and it is paramount to understand their environmental impacts to prevent unforeseen effects. This study employed a consequential life cycle assessment (LCA) to compare the environmental impact of mineral fertilizer to three types of organic fertilizers: animal-, plant-, and innovative microbe-based, considering market constraints and marginal suppliers. Organic fertilizers were complemented with mineral products to yield NPK compound fertilizers containing 1 t of nitrogen, 0.44 t of phosphorus, and 0.83 t of potassium (multi-substance functional unit). The findings reveal that 9 out of the 17 studied organic fertilizers are constained products, and that their demand is met through the supply of mineral fertilizers, soybean meal, and maize or barley grain. Consequently, for the transition to a circular and organic agrifood system, the focus should shift toward untapped resources like microbial fertilizers sourced from food and beverage industry wastewater, and sewage sludge. Constrained markets vary with time and geographical location, emphasizing the importance of context-specific decision-making. The impact of mineral fertilizers is relatively low across impact categories, but the gap between them and energy-intensive organic fertilizers narrows in an industrial symbiosis scenario where waste heat is available. An additional assessment of soil organic carbon estimated the contribution of organic fertilizers to the “4 per 1000" initiative's goal for soil carbon storage. Organic fertilizer application alone only achieves this goal in one scenario (rapeseed meal), but combining it with other management practices like crop rotation offers a promising strategy. The scenario that included fertilizer transport showed the potential for reduced environmental impacts by applying locally available by-products as organic fertilizer instead of imported mineral fertilizers. Overall, the results call for caution when transitioning from mineral to organic fertilizers as their availability and environmental impact are not self-evident.

Comparison among OH, N and P functionalized carbon quantum dots/TiO2 nanocomposites for food industry wastewater remediation

TiO2 nanoparticles present limited efficiency under visible light in photocatalytic for food and agriculture wastewater remediation. Hence, the exploration of modifications to enhance their photocatalytic activity has been studied. Carbon Quantum Dots (CQDs) have recently gained attention as functional coatings for TiO2, but a comparison between different types of CQDs has not been performed before. In this study, TiO2 nanoparticles coated with CQD treated with NaOH, HNO3, and H3PO4 were synthesized and named OHTiO2, NTiO2 and PTiO2. The materials were characterized for the photocatalytic degradation of glucose, representing jam industry wastewater and showed enhanced photocatalytic activity under visible light irradiation when compared to bare TiO2 nanoparticles. The type of functional groups on the CQDs played a crucial role in determining the photocatalytic performance of the composites. In one case, they reduce the band gap, as observed in the NTiO2, while in another case, they mitigate the influence of interferents, as observed in the PTiO2. This research provides valuable insights into the design and optimization of functionalized quantum dots for photocatalytic applications.

Employing Spent Frying Oil as a Feedstock to Produce Short-Chain Organic Acids Using Mixed Microbial Cultures

Food industry waste and wastewater have been explored in relation to acidogenic fermentation as sources of non-competing food carbohydrates and mixed microbial cultures (MMCs), respectively, with the aim of producing short-chain organic acids (SCOAs) with general applications in polyhydroxyalkanoates (PHAs) production. However, studies on acidogenic fermentation using lipidic substrates are scarce. In this work, it was hypothesized that spent frying oil (SFO) could be used as a substrate for SCOA production via MMCs. In this study, oleic acid was used as a model molecule. The characterization of SFO revealed that it is mainly composed of oleic acid (81%), with minor amounts of palmitic, linoleic, and stearic acids. Different MMCs and food-to-microorganism (F/M) ratios were tested. MMCs collected in the aerobic tank of a municipal wastewater treatment plant (AES), at a 1:1 F/M, allowed to obtain the highest SCOA concentration (1.50 g COD/L) and the most diverse profile of SCOAs, with the production of acetic, propionic, butyric, iso-butyric, and valeric acids at 48:17:9:13:13% on a molar basis, respectively. This variety of odd and even SCOAs is of upmost importance, with potential applications in producing PHAs. This work can be considered a starting point for future acidogenic fermentation studies using lipid-based substrates and for the future production of PHAs.

Nanoparticle-assisted biohydrogen production from pretreated food industry wastewater sludge: Microbial community shifts in batch and continuous processes

Biohydrogen production from industrial waste has gained a significant attention as a sustainable energy source. In this study, the enrichment of biohydrogen production from pretreated dissolved air flotation (DAF) sludge, generated from food industry wastewater treatment plants, was investigated using SiO2@Cu-Ag dendrites core–shell nanostructure (NS). The effect of NS on the changes of the microbial community and biohydrogen yield was evaluated through batch and continuous tests. In batch mode, various nanomaterial doses were investigated with several concentrations ranging from 20 to 50 mg/L for hydrogen production using glucose as a substrate. The optimum core–shell NS amount was 40 mg/L, achieving a maximum H2 yield of 163 mL/g volatile solids (VS) compared to the control's 79 mL/g VS. However, 50 mg/L NS inhibited most bacteria in the sludge. The continuous experiment used a continuous stirring tank reactor (CSTR) with 40 mg/L SiO2@Cu-Ag core–shell NS and pretreated industrial sludge as substrate. The H2 yield increased to 115 L/kg VS compared to the control reactor's 89 L/kg VS. The gas analysis showed compositional proportions of 83 % H2, 7 % CO2, and 4.5 % methane, while the microbial community analysis indicated the development of hydrogen-producing species such as Clostridium. In conclusion, SiO2@Cu-Ag core–shell NS addition enhanced anaerobic degradation of organic matter and its conversion to biohydrogen. The selected nanomaterial can be used for an effective continuous treatment system for industrial sludge while promoting dark fermentation.

Applicability of hybrid treatment to reduce the footprint of domestic and industrial wastewater of developing countries

Wastewater pollution is a serious concern, especially in developing countries such as Pakistan. The untreated domestic and industrial wastewater is typically discharged into sewers, natural drains, or water bodies. There is a dire need to evaluate the applicability of low-cost treatment technologies. Hybrid wastewater treatment (HWWT), comprising of chemically enhanced primary treatment (CEPT) and intermittent sand filter (ISF), was adopted to treat domestic, process and manufacturing, and food industry wastewaters. The wastewater pollution and contamination were assessed in terms of biochemical oxygen demand (BOD), chemical oxygen demand (COD), and total suspended solids (TSS). The removal efficiency (RE) performance of HWWT was compared with the CEPT system only. Considering the CEPT only, the RE of BOD was ≈70 % for domestic, >80 % for process and manufacturing, and ≈50 % for the food industry. For COD, the RE was high in process & manufacturing (RE ≈ 81 %), followed by food (RE ≈ 55 %) and domestic wastewater (RE ≈ 17 %). Furthermore, the CEPT provided >95 % TSS removal in all wastewater types. The HWWT increased TSS removal by ≈2 %, BOD removal by ≈13 %, and COD removal by ≈27 % compared to the CEPT system. Therefore, HWWT proved more efficient in treating both domestic and industrial wastewater. The HWWT reduced the greywater footprint (GWF) by 50–60 % when compared to the CEPT system. This study provided knowledge of the characteristics of domestic and industrial wastewater. Furthermore, provides a basis to assess the applicability and performance of various wastewater treatment systems under given settings.

Efektivitas Penggunaan Serbuk Cangkang Telur Ayam Sebagai Penetralisir Derajat Keasaman dan Kekeruhan Pada Air Limbah Industri Makanan

Chicken egg shells are food waste that is usually produced from household activities, which has an impact on environmental pollution. Chicken egg shells are known to have a high calcium carbonate (CaCO3) content that can be utilized. The purpose of this study was to determine the pH and turbidity of food industry waste water and to determine the best mass of chicken eggshell flour as a filter media. This research was conducted in a filter column where the wastewater samples that entered the filter column would pass through the prepared chicken egg shell filter media with several mass variations, namely 50 g, 100 g, 150 g, 200 g, and 250 g

Cultivation of Chlorella sp. HS2 using wastewater from soy sauce factory

Incorporation of wastewater from industrial sectors into the design of microalgal biorefineries has significant potential for advancing the practical application of this emerging industry. This study tested various food industrial wastewaters to assess their suitability for microalgal cultivation. Among these wastewaters, defective soy sauce (DSS) and soy sauce wastewater (SWW) were chosen but DSS exhibited the highest nutrient content with 13,500 ppm total nitrogen and 3051 ppm total phosphorus. After diluting DSS by a factor of 50, small-scale cultivation of microalgae was conducted to optimize culture conditions. SWW exhibited optimal growth at 25–30 °C and 300–500 μE m−2 s−1, while DSS showed optimal growth at 30–35 °C. Based on a 100-mL lab-scale and 3-L outdoor cultivation with an extended cultivation period, DSS outperformed SWW, exhibiting higher final biomass productivity. Additionally, nutrient-concentrated nature of DSS is advantageous for transportation at an industrial scale, leading us to select it as the most promising feedstock for microalgal cultivation. With further optimization, DSS has the potential to serve as an effective microalgal cultivation feedstock for large-scale biomass production.

Production of microbial carotenoid using innate inherent of the food industry wastewater

Yeast is considered as the leading participant in natural pigment production, which has a wide application in the industries relevant to food, medicine and health. This study is aimed to focus on producing carotenoids from food industry waste. The food industry waste's innate microbe (Rhodotorula mucilaginosa) is used for the bioremediation of the same waste, and it was also used as the precursor for carotenoid production. The nutritional supplement (different carbon sources) and their effect on carotenoid production were also studied in this research, revealing glucose could be a good carbon source for carotenoid production. The solvent effect on carotenoid separation was studied, which revealed that methanol, combined with ultrasonication, is the best solvent system for carotenoid extraction from Rhodotorula mucilaginosa. The batch study of this conjoint bioremediation and carotenoid production process was studied for its persuading parameters (pH, temperature, light, time and agitation) effects. The maximum carotenoid production (810 µg/g) was achieved at 72 hr with the pH 6 and 27 °C in light irradiation (White light), agitation (200 rpm) and with ethanol + ultrasonication recovery system in carotenoid extraction. HPLC, FTIR and UV analysis were performed to confirm the presence of β-carotene. The analytical studies revealed that the extracted pigment contains 32.5 % of β-carotene, 54 % of torulene and 13.5 % of torularhodin, respectively. The characteristic property of the treated water was analyzed and compared with the raw wastewater, which was also found to be within the limit for discharge and reusability. These results prove that the innate yeast of food industry wastewater could be a potential candidate for wastewater remediation and carotenoid production.

Physical and Chemical Treatability Assessment for Food Industry Wastewater in Wastewater Treatment Plant Design

Food industry wastewater has characteristics that contain high organic matter and suspended solids. Most of the methods used are physical and chemical treatment because these methods have high efficiency and effectivity. In designing a new wastewater treatment plant, the treatability assessment is essential to any consideration or reference in planning the treatment process to be implemented. This research aims to obtain treatability assessment results that will be used as consideration in planning treatment units in WWTP according to the characteristics of wastewater tested. The removal results of the sedimentation test with Imhoff Cone were able to remove 51.2% COD, 64.04% BOD, and 95.21% TSS with the optimum settling time of 40 minutes. The samples test continued to the rapid-slow mixing test using the jar test, resulting that by adding coagulant at the optimum dose of PAC 120 mg/L, it was capable to remove 68.21% of COD, 73.22% of BOD, and up to 98.07% of TSS at the end of the process. Based on the assessment results, the physical and chemical treatment can remove suspended solids pollutant parameters with high efficiency so it will be considered to be used in planning Wastewater Treatment Plants for this food industry.

Yeast Isolated from Pulque for Application in Microbial Fuel Cells: Use of Food Industry Wastewater as Substrate

Yeast Isolated from Pulque for Application in Microbial Fuel Cells: Use of Food Industry Wastewater as Substrate