Increase In Flux Research Articles

Atmospheric particulates over the northwestern Pacific during the late Holocene: Volcanism, dust, and human perturbation.

Mineral aerosols form a key component of Earth's dynamic biogeochemical systems, yet their composition and mass are variable in time. We reconstruct patterns in mineral aerosol flux from East Asia, the second largest global dust source, in a peat mire in northern Japan. Using geochemical fingerprinting, we show for the past ~3600 years that high but variable tephra flux dominated regional aerosol loads. A human signal was discernible as elevated pollutant metals, along with East Asian mainland dust, identifiable by its geochemical signature. After ~700 years before the present, dust flux increased as the westerly jet intensified and moved south, the summer monsoon strength reduced, and agriculture expanded. From the 20th century, dust flux increased by two times. Attributable largely to human activity, this demarks a major change in aerosol export to the northwestern Pacific with accompanying increases in fluxes for key micronutrients and increased pollution flux by 16 times.

Improvement of superconducting, morphological, and flux pinning ability of YBa2Cu3O7-y matrix with oxygen and Mn2O3 impurity

Abstract In the current work, the influence of oxygen and Mn2O3 impurity levels intervals 0.00≤x≤0.30 on various key properties such as electrical resistivity, superconducting, flux pinning ability, stabilization of ceramic system, and morphological properties of YBa2Cu3O7-y (Y-123) superconductor were examined by electrical resistivity, critical current density, and scanning electron microscopy (SEM), electron dispersive X-ray (EDX) measurements. The EDX test results indicated that all the Y-123 ceramics produced possessed different composition distributions on the sample surface. SEM photomicrographs also confirmed the improvement in the appearance of surface morphology and crystallinity quality of the YBa2Cu3O7-y system. Moreover, the development in the interaction quality between grains, pinning ability and strength quality of 2D coupled vortices was obtained with the oxygen ambient and optimum manganese impurity addition highly dispersing throughout the intra grain and inter-grain boundary couplings due to the increase in the artificial flux pinning nucleation sites in the Y-123 system. Thus, the best sample with the highest Jc value of 98 A/cm2 showed the most resistance to the applied magnetic field and current. Similarly, the same sample exhibited the greatest superconductive offset (98.320 K) and onset (100.504 K) temperatures values based on the development of the Cu-O coordination and stability of the crystal structure. In conclusion, this comprehensive study based on the analysis of oxygen and Mn2O3 impurity addition mechanism through the YBa2Cu3O7-y ceramic matrix may open a new and applicable field for advanced engineering, heavy industry technology and large-scale applications.

A new validated TRNSYS module for phase change material-filled multi-glazed windows

Incorporating phase change materials (PCM) into multi-glazed windows (MW) has been recognized as an effective way to regulate the indoor thermal environment and reduce the energy consumption of buildings. However, the design and calculation of PCM-filled multi-glazed windows (MW + PCM) remain challenging due to the lack of general transient simulation methods and integrated tools. To address this issue, the present study developed a dynamic coupled thermal and optical model for MW + PCM based on the enthalpy-temperature and interface energy balance methods. Then, the model was implemented in C++ and integrated into the TRNSYS software as a new module (Type 2602). In parallel, a test platform comprising two test chambers was established to evaluate the effect of PCM on the thermal and optical properties of the window and to validate the newly proposed module. It was found that compared to the traditional triple-glazed window (TW), the PCM-filled triple-glazed window (TW + PCM) effectively reduces the irradiance through the window by 34.17 % and the maximum temperature of the inner surface by approximately 5.56 °C. While the increase in external surface radiation flux density from 600 to 1200 W/m2 has a diminishing effect on the heat flux variation rate during the heat dissipation process for TW + PCM, it effectively shortens the latent heat absorption time by 0.50 h and increases the temperature difference between the inner and outer surfaces by 3.02 °C. The new module demonstrates satisfactory accuracy through experimental validation and simulation comparisons, with the maximum heat flux coefficient of variance of the root mean square error (CV(RMSE)) less than 6.35 % and 11.25 % under TW and TW + PCM configurations.

Deciphering the properties of UV upturn galaxies in the Virgo cluster

Abstract The UV upturn refers to the increase in UV flux at wavelengths shorter than 3000 Å observed in quiescent early-type galaxies (ETGs), which still remains a puzzle. In this study, we aim to identify ETGs showing the UV upturn phenomenon within the Virgo galaxy cluster. We utilized a color-color diagram to identify all potential possible UV upturn galaxies. The Spectral Energy Distributions (SED) of these galaxies were then analyzed using the CIGALE software; we confirmed the presence of UV upturn in galaxies within the Virgo cluster. We found that the SED fitting method is the best tool to visualize and confirm the UV upturn phenomenon in ETGs. Our findings reveal that the population distributions regarding stellar mass and star formation rate properties are similar between UV upturn and red sequence galaxies. We suggest that the UV contribution originates from old stellar populations and can be modeled effectively without a burst model. Moreover, by estimating the temperature of the stellar population responsible for the UV emission, we determined it to be 13,000 K to 18,000 K. These temperature estimates support the notion that the UV upturn likely arises from the contribution of low mass evolved stellar populations (extreme horizontal branch stars). Furthermore, the Mg2 index, a metallicity indicator, in the confirmed upturn galaxies shows higher strength and follows a similar trend to previous studies. This study sheds light on the nature of UV upturn galaxies within the Virgo cluster and provides evidence that low-mass evolved stellar populations are the possible mechanisms driving the UV upturn phenomenon.

Development and Optimization of a Micro-Baffle for the Enhancement of Heat Transfer in Film Boiling

This study represents the development and optimization of a micro-baffle design to enhance heat transfer in film boiling. Numerical simulations are performed using an open-source computational fluid dynamics (CFD) model, which incorporates the Lee model for momentum source associated with the phase change, and the Volume of Fluid (VOF) method to capture bubble dynamics. A comparison of the numerical results with the previous numerical and experimental data confirmed the validity of the numerical model. The influence of key design parameters was systematically investigated. The results revealed that a vertical baffle provided the maximum performance. The optimal baffle design achieved a 57.4% improvement in the Nusselt number and a 66.4% increase in critical heat flux (CHF). Furthermore, the proposed design facilitated continuous bubble formation, even with a reduced temperature difference between the heated surface and the subcooled liquid, which is crucial for energy-efficient thermal management in engineering systems. Ultimately, this study demonstrates the potential of micro-baffle designs in controlling bubble dynamics and improving heat transfer in film boiling, thereby aiding the design of efficient thermal systems.

Surface Transformation Of Ultrahigh-Temperature Ceramics HfB2-SiC-C(graphene) Under The Influence Of High-Speed Disossociated Nitrogen Jets

In order to study the promising potential of HfB2–30 vol % SiC ultrahigh-temperature ceramic materials modified with low amounts of reduced graphene oxide for the creation of aerospace equipment intended for use in N2-based atmospheres, the effect of high-speed dissociated nitrogen flow on it has been investigated. It has been established that under the chosen conditions of exposure during the stepwise increase of the anode power supply of plasma torch and, accordingly, the influencing heat flux, at certain parameters there is a sharp increase in the surface temperature from ~1750 to 2000-2100°C. At the same time, further increase of the heat flux has no obvious and proportional effect on the temperature of the sample surface, which may indicate its high catalyticity with respect to the reactions of surface recombination of atomic nitrogen. It is shown that the surface layers of the material undergo chemical transformation (removal of silicon-containing substances, formation of a new phase based on HfN), which is accompanied by a significant change in the microstructure (formation of dendrite-like structures), which affects the optical and catalytic characteristics of the surface.

Highly inhomogeneous interactions between background climate and urban warming across typical local climate zones in heatwave and non-heatwave days

Abstract Urban heat island (UHI) in conjunction with heatwave (HW) leads to exacerbation of thermal stress in urban areas. Prior research on UHI and HW has predominantly concentrated on examining the thermal conditions at the surface and near-surface, with few investigations extending to the radiative and dynamical interactions of UHI and HW, particularly with a focus on the inhomogeneities across local climate zones (LCZs). Here, we analyse the temperature disparity between HW and non-HW conditions across LCZs in the Sydney area by quantifying the contributions of individual radiative and dynamical processes using the coupled surface-atmosphere climate feedback-response analysis method (CFRAM). Three moist HW events in 2017, 2019, and 2020 are simulated using the Weather Research and Forecasting (WRF) model coupled with the single-layer urban canopy model (SLUCM). It is found that the maximum surface and 900 hPa temperature difference between HW and non-HW days may reach up to 10 K, with the increased net solar radiation during HWs being comparable to the typical level of anthropogenic heat flux in urban areas. It is also found that the reduction of clouds, the presence of vapour, and the increase of sensible heat contribute to the warming effect to various degrees, with the contribution of clouds being the most dominant. Conversely, the generation of dry convection and the increase of latent heat flux lead to cooling effects, with the latter being more dominant and capable of causing up to 10 K surface temperature difference between LCZ1 (compact high-rise) and LCZ9 (sparsely built). The differences in the contributions of climate feedback processes across different LCZs become more evident during more severe and humid HWs. These findings underscore the necessity of implementing LCZ-tailored heat mitigation strategies.

The decoupled effect of oxidizer mass flux and combustion pressure on turbulent combustion characteristics of finite-length solid fuel

Combustion pressure and oxidizer mass flux are key factors influencing the performance of hybrid rocket motors. In the present work, the decoupled effects of oxidizer mass flux and combustion pressure on turbulent combustion characteristics were investigated. First, a finite-length combustion theory of fuel grains was developed to identify the main sensitive parameters, including flame structure and the recirculation zone, which affect the combustion of solid fuel. Then, a two-dimensional transient numerical model, based on the coupling characteristics of the heat transfer process in solid fuel grains and dynamic combustion flow, was developed and validated through fire experiments under a wide range of inflow conditions. A quantitative analysis was conducted to assess the impact of flame structure and the recirculation zone on the dynamic combustion characteristics of finite-length solid fuel. The results showed that the fuel characteristic temperatures of the front and central parts are negatively correlated with flame height, while the characteristic temperature of the rear part is positively correlated with the recirculation zone temperature. Both the mass flow rate and combustion pressure are negatively correlated with flame height and positively correlated with the temperature of the recirculation zone. Compared to combustion pressure, the influence of mass flow rate is more significant. The transient processes of the solid fuel regression rate under different inflow conditions exhibit a consistent tendency: an increase in mass flow flux and combustion pressure results in faster attainment of peak regression rate and stabilization.

Aripiprazole, but Not Olanzapine, Alters the Response to Oxidative Stress in Fao Cells by Reducing the Activation of Mitogen-Activated Protein Kinases (MAPKs) and Promoting Cell Survival.

Prolonged use of atypical antipsychotics (AAPs) is commonly associated with increased cardiovascular disease risk. While weight gain and related health issues are generally considered the primary contributors to this risk, direct interference with mitochondrial bioenergetics, particularly in the liver where these drugs are metabolized, is emerging as an additional contributing factor. Here, we compared the effects of two AAPs with disparate metabolic profiles on the response of Fao hepatoma cells to oxidative stress: olanzapine (OLA), which is obesogenic, and aripiprazole (ARI), which is not. Results showed that cells treated with ARI exhibited resistance to H2O2-induced oxidative stress, while OLA treatment had the opposite effect. Despite enhanced survival, ARI-treated cells exhibited higher apoptotic rates than OLA-treated cells when exposed to H2O2. Gene expression analysis of pro- and anti-apoptotic factors revealed that ARI-treated cells had a generally blunted response to H2O2, contrasting with a heightened response in OLA-treated cells. This was further supported by the reduced activation of MAPKs and STAT3 in ARI-treated cells in response to H2O2, whereas OLA pre-treatment enhanced their activation. The loss of stress response in ARI-treated cells was consistent with the observed increase in the mitochondrial production of O2•-, a known desensitizing factor. The physiological relevance of O2•- in ARI-treated cells was demonstrated by the increase in mitophagy flux, likely related to mitochondrial damage. Notably, OLA treatment protected proteasome activity in Fao cells exposed to H2O2, possibly due to the better preservation of stress signaling and mitochondrial function. In conclusion, this study highlights the underlying changes in cell physiology and mitochondrial function by AAPs. ARI de-sensitizes Fao cells to stress signaling, while OLA has the opposite effect. These findings contribute to our understanding of the metabolic risks associated with prolonged AAP use and may inform future therapeutic strategies.

Horizontal Heat Flux Spread in an Inner Corner of Buildings

This study investigates fire separation distances as essential means of passive fire protection in building design. The focus is on the inner corner configuration of building exterior walls, which represents the worst-case scenario for façade fire spread outside of a building. The inner-corner configuration appears to increase the intensity of the radiative heat flux due to reflection and reradiation of heat. Comprehensive approaches for determining fire separation distances around the various façade geometries can be found, but none of them is focused on detailed descriptions of the unprotected area in an inner corner. A medium-scale scenario was chosen and was experimentally validated with a radiant panel for a better understanding of heat flux spread. This paper compares the experiment with analytical and numerical models. The analytical model is based on the Stefan–Boltzmann law and the calculated configuration factor as per Eurocode 1. The numerical model combines radiative and convective components of the heat flux because convection is non-negligible near the heat source. Experimental data confirm the prediction based on the numerical and analytical model and show agreement. The final increase in heat flux due to the corner configuration investigated at the medium scale reaches up to 29%.

Experimental investigation at reduced scale of the effect of a ceiling on the burning rate of a pool fire

This study examines the influence of the proximity of a ceiling on the burning rate of a fire in enclosures. The parameters included the pool diameter, distance to the ceiling and fuel type. The analysis focused on the average mass loss rate. The results confirmed the increase in mass loss rate with the elevation for all fuel types. This increase in the mass loss rate appears from a distance to the ceiling that is correlated with the flame height. It is caused by an increase in the heat flux emitted by the flame, which changes shape, and the temperature of the ceiling, which increases with the fire elevation. A correlation is proposed to predict the increase in mass loss rate as a function of the enthalpy ratio Δ H/ Lv and flame height. A comparison of the results with previous experimental studies demonstrated consistency between the different tests.

Effect of relative humidity on passive spore release from substrate surfaces

Fungal spores are abundant in ambient air and exposure to this type of bioaerosols are found to cause significant health and climatic effects. In this study, we investigated the influence of air relative humidity (RH) on the passive release of spores from solid substrates. Preliminary investigations into the effect of RH on fungal spore release indicated an increase in spore flux with reduced air RH. The change in spore emission flux occurred very quickly in response to a change in ambient RH. To verify the hypothesis of extremely rapid drying under lower RH, experiments were conducted using a quartz crystal microbalance with dissipation (QCM-D) to understand the timescales of spore moisture uptake and drying. The analysis of mass transfer of water to and from the spores indicated that the bulk of the transfer occurred within a minute of exposure to any RH. The effect of the ambient RH was explained using a mathematical model with the spotlight on the parameter, E, that represented the energy required to aerosolise one spore. This study demonstrates the application of QCM-D to study interaction between ambient aerosol particles and various vapor phase and gas phase environments. The study enhances the overall understanding and capability to characterise passive fungal spore release under varying humidity conditions in the natural environment.

Fabrication of ultrafiltration membrane with antibacterial properties by blending Ag/UiO-66-NH2 and bamboo cellulose

Cellulose is a widely available organic substance that forms membranes with excellent hydrophilicity and biocompatibility. However, it is prone to biological contamination because its surface is conducive towards the accumulation of biologically active substances, which has hindered its application potential. In this work, an antimicrobial cellulose-based membrane (Ag/UiO-66-NH2@BCM) with high water flux, high retention rate, and good hydrophilicity was prepared. At an optimal blend ratio of 1 wt% Ag/UiO-66-NH2, the membrane exhibited significant improvements, including a 31% increase in pure water flux, a Bovine Serum Albumin retention rate of 99.6%, and a water flux recovery of 97.4%. Crucially, the membrane demonstrated potent antibacterial, showcasing its broad-spectrum antimicrobial properties. Investigations into the ability of Ag/UiO-66-NH2@BCM to remove Pb2+, Cd2+, and Cr6+ ions from a water column revealed that the maximum adsorption capacity of the monolayer was 405, 390, and 328 mg/g, respectively. The composite membrane demonstrated broad-spectrum and highly effective antimicrobial properties, along with efficient removal of heavy metal ions. The proposed method can be utilized to prepare other composite membranes for water treatment and other fields of membrane separation technology.

Pre-ozonation coupled with forward osmosis with fertilizer as draw solution for simultaneous wastewater treatment and agricultural irrigation

Membrane-based processes have emerged as effective solutions for treating tannery wastewater. Persistent membrane fouling remains a significant obstacle to long-term operational sustainability, and residual pollutants often persist in the treated effluent. To address these challenges, we investigated an integrated ozone-forward osmosis (O3-FO) process, with a focus on evaluating the efficacy of pre-ozonation in alleviating membrane fouling, as well as exploring the possibilities of this integrated process for the reuse of tannery wastewater. Fertilizer, specifically 2 M Ca(NO3)2, served as the draw solution (DS) in this process. The findings reveal that the integrated system demonstrated remarkable pollutant retention capabilities. Notably, no metal was detected in the fertilizer. Therefore, the integrated process not only dilutes the fertilizer but also minimizes the risk of heavy metal contamination to both crops and soil. Furthermore, pre-ozonation effectively mitigated membrane fouling, resulting in an increase in membrane flux with a maximum increase of 20.98 % at 0.6 L/min. Orthogonal partial least squares-discriminant analysis (OPLS-DA) revealed pre-ozonation has the most significant impact on four parameters: water flux (Jw), chemical oxygen demand (COD), fouling resistance (Rf) and oxidation reduction potential (ORP). Meanwhile, ammonium nitrogen (NH4-N) variation, dissolved organic carbon (DOC) variation and ORP played an important role in the four systems. Multi-criteria decision analysis (MCDA) showed that the 0.2 L/min O3-FO system achieved the highest score (0.66), followed by 0.6 L/min (0.53), 0.4 L/min (0.41) and 0 L/min (0.29). This research offers a theoretical framework for the synergistic integration of advanced oxidation and membrane technology in the treatment of industrial wastewater.

Melt sensitivity of irreversible retreat of Pine Island Glacier

Abstract. In recent decades, glaciers in the Amundsen Sea Embayment in West Antarctica have made the largest contribution to mass loss from the entire Antarctic Ice Sheet. Glacier retreat and acceleration have led to concerns about the stability of the region and the effects of future climate change. Coastal thinning and near-synchronous increases in ice flux across neighbouring glaciers suggest that ocean-driven melting is one of the main drivers of mass imbalance. However, the response of individual glaciers to changes in ocean conditions varies according to their local geometry. One of the largest and fastest-flowing of these glaciers, Pine Island Glacier (PIG), underwent a retreat from a subglacial ridge in the 1940s following a period of unusually warm conditions. Despite subsequent cooler periods, the glacier failed to recover back to the ridge and continued retreating to its present-day position. Here, we use the ice-flow model Úa to investigate the sensitivity of this retreat to changes in basal melting. We show that a short period of increased basal melt was sufficient to force the glacier from its stable position on the ridge and undergo an irreversible retreat to the next topographic high. Once high melting begins upstream of the ridge, only near-zero melt rates can stop the retreat, indicating a possible hysteresis in the system. Our results suggest that unstable and irreversible responses to warm anomalies are possible and can lead to substantial changes in ice flux over relatively short periods of only a few decades.

Magma recharge at Manam volcano, Papua New Guinea, identified through thermal and SO2 satellite remote sensing of open-vent emissions

Manam is one of the most frequently active volcanoes in Papua New Guinea and is a top contributor to global volcanic volatile emissions due to its persistent open-vent degassing. Here, we present a multi-year time series (2018–2021) of thermal and SO2 emissions for Manam from satellite remote sensing, which we interpret in the context of open-vent feedback between magma supply, reservoir pressure, and outgassing. We classify the time series into four phases based on the varying SO2 flux and observe a transient, yet substantial, increase in time-averaged SO2 flux from background levels of ~ 0.6 to ~ 4.72 kt day−1 between March and July 2019. We also identify a transition from temporally coupled to decoupled gas and thermal emissions during this period which we explain in the context of a magma recharge event that supplied new, volatile-rich magma to the shallow plumbing system beneath Manam. We infer that the arrival of this recharge magma triggered the series of eruptions between August 2018 and March 2019. These explosive events collectively removed 0.18 km3 of degassed residual magma and signalled the onset of a renewed period of unrest that ultimately culminated in a major eruption on 28 June 2019. We quantify the magnitude of “excess” degassing at Manam after the removal of the inferred residual magma. SO2 emissions reveal that ~ 0.18 km3 of magma was supplied, but only ~ 0.08 km3 was erupted between April 2019 and December 2021. We highlight how multi-parameter remote sensing observations over months to years enable the interpretation of open-vent processes that may be missed by short-duration campaign measurements.

3D topology optimization design of air natural convection heat transfer fins

This study focuses on the fin-tube heat exchanger and utilizes topology optimization methods to design a completely new fin structure. In this optimization process, complete Navier-Stokes (N-S) equations were used to describe the steady-state incompressible flow, and the Boussinesq model was employed to simulate natural convection. The flow equations were coupled with the heat convection–diffusion equation to achieve topology optimization for natural convection heat transfer. Topology optimization was conducted using density-based optimization methods, and interpolation was performed on the permeability and conductivity of the distributed materials. Given the initial fin structure, an interpolation progressive approach was adopted to obtain a new “ airfoil-shaped” optimized structure through density-based topology optimization method for natural convection. The new structure enhances the convective heat transfer by perforating the fins. The perforations are mainly concentrated in the central region of the heat exchanger and the upper half of the fins. The new structure, compared to the prototype structure, not only has a reduced volume but also exhibits a decrease in convective thermal resistance within a larger range of heat flux densities, as revealed by CFD simulations. Moreover, as the heat flux density increases, the rate of reduction in convective thermal resistance shows an upward trend for the new structure compared to the prototype structure.

Improving oral absorption of a rapidly crystallizing parent drug using prodrug strategy: Comparison of phosphate versus glycine based prodrugs

With an increasing number of Biopharmaceutical Classification System (BCS) II/IV pipeline compounds, solubilizing and supersaturating formulation strategies are becoming prevalent. Beyond formulation and solid form strategies, prodrugs are also employed to overcome solubility-limited absorption of poorly water-soluble compounds. Prodrugs can potentially yield supersaturated systems upon conversion to the parent drug intraluminally and thus enhance absorption. However, supersaturation also increases the driving force for crystallization, resulting in low solution concentrations, which can potentially negate the advantage of prodrugs. In this work, two unique solubility-enhancing prodrugs, phosphate and glycine esters, were investigated for a rapidly crystallizing parent drug. Ex vivo absorption studies using rat tissue and in vivo studies in dogs were performed. Conversion rate of the phosphate prodrug to the parent was dependent on the milieu and increased ∼24-fold in the presence of intestinal contents as medium and tissue relative to neat buffer. In contrast, conversion of the glycine prodrug was minimal under any conditions tested, suggesting that the conversion occurs after absorption into the enterocytes. Phosphate prodrug showed a non-linear increase in parent drug absorptive flux across rat intestinal tissue with concentration when intestinal contents were used as donor media. This was attributed to rapid conversion and high supersaturation of the parent drug which subsequently resulted in crystallization at high doses in the donor chamber. Glycine prodrug did not undergo complete conversion at high doses and was absorbed unchanged on the basolateral side, indicating saturation of the converting enzymes in the enterocytes. The combined flux (parent drug and glycine) showed a linear increase with dose and crystallization was not observed. Under physiological conditions, glycine prodrug that is absorbed unchanged from the intestine can potentially undergo complete conversion in hepatocytes after absorption and make the parent drug systemically available. Thus, glycine prodrug provided overall higher absorption compared to phosphate prodrug. The observed flux levels for both the prodrugs were higher compared to the parent drug alone, highlighting an advantage to use of a prodrug strategy to improve absorption of such compounds. Oral dosing in a dog PK study revealed that the bioavailability using the phosphate prodrug was ∼50% whereas, it was ∼100% with glycine prodrug, supporting the in vitro observations.

Rising CO2 and land use change amplify the increase in terrestrial and riverine export of dissolved organic carbon over the past four decades

The lateral transport of dissolved organic carbon (DOC) from land to rivers and oceans is a significant but overlooked component of the global carbon cycle. However, there are still large uncertainties in the magnitude and trend of global DOC export fluxes, as well as their response to environmental change. In this study, several simulations were conducted using a developed land surface model that considered riverine DOC transport and anthropogenic disturbance to investigate the terrestrial DOC loading and riverine DOC export, and to quantify the relative contributions of natural and anthropogenic factors over the past four decades (1981–2016). These factors include climate change, nitrogen deposition, land use change, atmospheric CO2 concentration, anthropogenic water regulation, and fertilizer and manure application. Results showed that the average global annual terrestrial DOC loading was about 432.30 ± 53.59 Tg C yr−1, and rivers exported about 209.73 ± 36.58 Tg C yr−1 to oceans over the past four decades. Simultaneously, a significant increase in terrestrial DOC loading and riverine DOC export fluxes (3.36 Tg C yr−2 and 2.99 Tg Cyr−2, p < 0.01) was found, which increased by 26.88 % and 47.02 %, respectively. According to our factorial analysis, the interannual variability in DOC fluxes in most regions was mainly attributed to climate change and contributed more than 60 % of the long-term increase. In addition, rising atmospheric CO2 and land use change amplified the increase in terrestrial DOC loading, with the area dominated by the two factors expanding from 7.94 % in the 1980s to 23.84 % in the 2010s, and riverine DOC export showed a similar pattern, which may be related to the increased soil DOC sources. Anthropogenic water regulation and nitrogen addition have led to a slight increase in DOC fluxes, which should not be ignored, otherwise carbon fluxes may be underestimated.

Separating Neroli from Water Using the PDMS‐ZSM5 Mixed Matrix Membrane and the Pervaporation Method

AbstractIn this study, the separation of neroli from water by PDMS‐ZSM5 mixed matrix membrane and separation performance of the pervaporative process of the prepared membranes with the parameters of permeability flux and separation factor was investigated. The effect of adding nanoparticles in the polymer matrix, the effect of the operating parameter of temperature and concentration on the efficiency of the membrane in the pervaporative process to be placed. Comparison of the results for pure membrane and mixed matrix membrane shows a 3‐fold increase in flux along with a 5‐fold increase in the separation factor in the mixed matrix membrane with a ratio of 12% nano in the membrane matrix so that the permeability and separation factor are 1.256 kg/m2h and 550, respectively. Membrane function was also evaluated in the temperature range of 298–353 K and feed concentration of 122–209 ppm. With increasing temperature to 353 K, permeability of membrane containing 8% ZSM‐5 nanoparticles increased from 0.63 to 0.89 kg/m2h. Also, with increasing feed concentration, permeability increased from to 0.96 kg/m2h. The optimization of these conditions was investigated by response surface method (RSM) based on the design of central points (CCD). The effect of all three parameters on the permeability, flux, and separation factor was investigated simultaneously and the optimal conditions were obtained at 12 wt% of ZSM‐5, a concentration of 209 mg/L of neroli, and a temperature of 304 K. Under these optimal conditions, the values of permeability, flux, and separation factor were 1.414 kg/m2h and 1039.57, respectively.