Flux Composition Research Articles

Contact angle measurement for SMAW electrode coating fluxes: effect of electrode coating flux compositions on different wetting parameters using statistical models

Contact angle measurement for SMAW electrode coating fluxes: effect of electrode coating flux compositions on different wetting parameters using statistical models

Methane dynamics in the Baltic Sea: investigating concentration, flux, and isotopic composition patterns using the coupled physical–biogeochemical model BALTSEM-CH4 v1.0

Abstract. Methane (CH4) cycling in the Baltic Sea is studied through model simulations that incorporate the stable isotopes of CH4 (12C–CH4 and 13C–CH4) in a physical–biogeochemical model. A major uncertainty is that spatial and temporal variations in the sediment source are not well known. Furthermore, the coarse spatial resolution prevents the model from resolving shallow-water near-shore areas for which measurements indicate occurrences of considerably higher CH4 concentrations and emissions compared with the open Baltic Sea. A preliminary CH4 budget for the central Baltic Sea (the Baltic Proper) identifies benthic release as the dominant CH4 source, which is largely balanced by oxidation in the water column and to a smaller degree by outgassing. The contributions from river loads and lateral exchange with adjacent areas are of marginal importance. Simulated total CH4 emissions from the Baltic Proper correspond to an average ∼1.5 mmol CH4 m−2 yr−1, which can be compared to a fitted sediment source of ∼18 mmol CH4 m−2 yr−1. A large-scale approach is used in this study, but the parameterizations and parameters presented here could also be implemented in models of near-shore areas where CH4 concentrations and fluxes are typically substantially larger and more variable. Currently, it is not known how important local shallow-water CH4 hotspots are compared with the open water outgassing in the Baltic Sea.

Role of Activating Flux in Weld Bead Symmetricity during Dissimilar Metal Joining

Ferritic/martensitic steels and austenitic stainless steels are high‐strength steels, and highly recommended in high‐temperature and high‐pressure application. In general, multimetallics with different Inconel alloys are used for joining. This is quite a complex and time‐consuming procedure. The current work demonstrates the efforts made to weld 8 mm‐thick P91 steel and 316L SS plates in a single pass using activating flux tungsten inert gas (A‐TIG) welding process without any interlayers. The main challenge is to get the symmetric weld bead profile. Flux coating is optimized in terms of flux composition, coating density, and coating pattern to get the full penetration with symmetric appearance. The current work discusses the possible cause and their solution of asymmetricity during dissimilar welding. Differential flux coating density is found to be very effective in controlling the arc column shape, fluid flow, and consequently the bead geometry. High coating density is used in the P91 side compared to 316L side. Symmetric weld profile with full penetration is achieved by applying multicomponent flux (33–38% TiO2, 38–43% SiO2, 13–17% NiO, and 8–10% CuO) during A‐TIG welding.

Microstructural evolution and mechanical behavior of activated tungsten inert gas welded joint between P91 steel and Incoloy 800HT

This study examines the welded joint between P91 steel and Incoloy 800HT using the activated tungsten inert gas (A-TIG) welding process. The focus is on analyzing the microstructure and evaluating the mechanical properties of joints made with different compositions of activating flux. Owing to the reversal of the Marangoni effect in which the conventional direction of molten metal flow in the weld pool is reversed due to the application of oxide-based fluxes, a complete depth of penetration of 8 mm was successfully achieved. Conducting mechanical tests, such as microhardness, tensile, and Charpy impact toughness tests, elucidates the behavior of the welded specimens under different loading conditions. The findings highlight the effects of grain size, dislocations, and the evolution of fine-sized precipitates in the high-temperature matrix. This study highlights the importance of choosing suitable flux compositions to achieve consistent penetration and dilution in the base metals. Insights into different failure modes and the influence of temperature on the tensile strength were evaluated. Beneficial mechanical properties of the joints (meeting the criteria of ISO and ASTM standards) were found: ultimate tensile strength of 585 ± 5 MPa, elongation 38 ± 2%, impact toughness of 96 ± 5 J, and maximum microhardness of 345 ± 5 HV.

Atmospheric muons measured with the KM3NeT detectors in comparison with updated numeric predictions

The measurement of the flux of muons produced in cosmic ray air showers is essential for the study of primary cosmic rays. Such measurements are important in extensive air shower detectors to assess the energy spectrum and the chemical composition of the cosmic ray flux, complementary to the information provided by fluorescence detectors. Detailed simulations of the cosmic ray air showers are carried out, using codes such as CORSIKA, to estimate the muon flux at sea level. These simulations are based on the choice of hadronic interaction models, for which improvements have been implemented in the post-LHC era. In this work, a deficit in simulations that use state-of-the-art QCD models with respect to the measurement deep underwater with the KM3NeT neutrino detectors is reported. The KM3NeT/ARCA and KM3NeT/ORCA neutrino telescopes are sensitive to TeV muons originating mostly from primary cosmic rays with energies around 10 TeV. The predictions of state-of-the-art QCD models show that the deficit with respect to the data is constant in zenith angle; no dependency on the water overburden is observed. The observed deficit at a depth of several kilometres is compatible with the deficit seen in the comparison of the simulations and measurements at sea level.

SiO2-bearing Fluxes Induced Evolution of γ Columnar Grain Size

Understanding the controlling mechanisms of γ columnar grain size in the weld metal of low-carbon, low-alloy steel is critical for optimizing resultant microstructures and the weld metal’s ensuing properties. Here, we investigate the role of welding flux composition upon the γ columnar grain size by submerged arc welding of EH36 shipbuilding steel with designed CaF2-SiO2 fluxes. We found that the addition of SiO2 from 5 to 40 mass-% increases average columnar grain size by a factor of nearly 2.5, which results from the change of the weld pool solidification mode from peritectic to primary δ solidification. Such a change is directly related to element transfer behaviors between the flux and the weld metal. Furthermore, we offer compelling evidence that alterations in γ columnar grain size are not primarily governed by significantly populated inclusions and/or weld metal macro-morphological changes. Our findings may largely serve as a viable strategy toward designing welding consumables to match base metals to ensure the soundness of the weldment.

Implication and Chemical Composition of Ancient Green Glass from Hong Nang Sida Temple in Champasak, Lao PDR

In southern part of Laos, once prospered under the Khmer Empire in the past, lots of ancient cultural heritage including Hong Nang Sida temple is still preserved. In this study, the chemical compositions, chromaticity and occurrences for five ancient green glasses excavated from Hong Nang Sida temple by Korea Heritage Agency were analyzed, and their implication was examined. As a result, all glasses showed some differences in hue, size, weight and shape, however, the compositions of flux, stabilizer and colorant revealed large differences. These have been identified as potash, soda and lead glass based on their composition. Considering the diversity of composition, it is interpreted that the production location and period of each glass was different. Meanwhile, if it estimates the inflow route reflecting the characteristics of glass, may be possible to infer regional or international exchanges in Laos at the time. This will be important data for understanding not only the ancient glass of Laos but also the glass artifacts technology and trade of Southeast Asian countries in the Khmer Empire cultural sphere.

Element transfer, microhardness and metallurgical analysis of weld-bead using CaF2−CaO−Al2O3−BaO fluxes

This study investigates the influence of shielded metal arc welding electrode coating flux on microhardness, microstructure and element transfer. A series of multi-pass bead-on-plate studies were conducted using laboratory-developed electrodes. The flux composition has shown a significant effect on all the responses. An increase in [Formula: see text] and [Formula: see text] has shown a positive influence on nickel transfer, whereas an increase in [Formula: see text] reduces nickel transfer. The slag detachability was found good for ratio [Formula: see text]:: 1.76:0.73:0.51. Energy dispersive spectroscopy has shown inclusions rich in aluminum and oxygen with trace amounts of Ca, Mn, Ti and Si. Artificial neural network models have been developed and then compared to conventional regression predictions.

Capturing the Interaction Between Mold Flux and Different Steel Compositions During Industrial-Scale Continuous Casting Trials

Capturing the Interaction Between Mold Flux and Different Steel Compositions During Industrial-Scale Continuous Casting Trials

Frequency Spectrum of Radiation Flux Generated by Beam-Plasma System with Ten Joules Energy Content in Microsecond Pulse

The work reports the achievement of an energy content of 10 J per microsecond pulse in a directed flux of electromagnetic radiation in the frequency range of ~ 0.2–0.3 THz. The flux is generated by a fundamentally new method, which is realized through the pumping of upper-hybrid plasma oscillations in a magnetized plasma column with a relativistic electron beam (REB) and their subsequent transformation into a flux of electromagnetic radiation. In the described experiments at the GOL-PET facility, this method to generate THz radiation is implemented in the following way a beam of electrons with energy E ~ 0.5 MeV with a current density of (1–2) kA/cm2 is passing through a magnetized (4 T) plasma column with a density of 1014–1015 cm–3. By comparing the experimentally measured spectral composition of the radiation flux with the calculated spectrum, it is proved that this process is realized through resonant pumping of the branch of upper-hybrid plasma waves by such beam. A coordinated increase in plasma density and beam current density opens up the prospect of advancement in the generation of multi-megawatt radiation fluxes in the region of one terahertz.

Zone-specific longshore sampling as a strategy to reduce uncertainties of SGD-driven solute fluxes from high-energy beaches

Submarine groundwater discharge (SGD) from intertidal beach systems forms a source of fresh and saline, often nutrient-enriched water to the near-shore across the world. The chemical composition of solute flux via SGD depends on several factors, including solid phase composition, organic matter supply, hydraulic gradients, as well as pore water residence time and origin, which are partly related to the beach topography. High-energy sandy beaches are especially prone to frequent sediment relocation and a variable topography, often characterized by a ridge and runnel structure. Topography may not only change on a temporal scale, but also in the longshore direction, which may alter SGD-driven solute fluxes. However, sampling high-energy beach sites is challenging and often does not allow for high resolution cross- and longshore sampling. We tested the approach of zone-specific pore water sampling, whereby samples were taken at the high water line, in the runnel, on top of the ridge, and close to the low water line of eight cross-shore transects. This was done in order to assess the longshore variability of pore water composition and flux over a 2.5 km wide beach section. In this study we relied on relatively few data points per transect and still found a characteristic cross-shore distribution of pore water parameters, related to redox conditions of each zone. Recharge zones (high water line and ridge) exhibited higher O2 and NOx concentrations and discharge zones (runnel and low water line) exhibited higher nutrient, DOC, Mn, and Fe concentrations. Furthermore, DOC concentrations in pore waters were lower than in coastal seawater, supporting previous assumptions of rapid organic matter turnover. Nevertheless, we observed large concentration ranges among samples assigned to the same zone, which could partly be related to longshore topography differences. The measured pore water concentrations and calculated SGD-driven solute fluxes indicated that sampling of single cross-shore transects may be representative for a beach section when assessing a redox-independent parameter like Si, while it is less representative for parameters affected by more complex biogeochemical processes like P, NH4, Mn, and Fe. For these, we suggest that longshore distributed data coverage combined with higher resolution sampling in discharge zones is a good strategy to reduce the uncertainty associated with estimating SGD-driven solute fluxes in a practicable way.

Refining the roles of productivity, redox, and remineralization on the cadmium isotope composition of marine sediments

Cadmium (Cd) has a nutrient-like distribution in the ocean, similar to the macronutrient phosphate. Significant isotope fractionation induced by the biological cycling of Cd makes it a potential tracer for nutrients and productivity. However, the Cd flux and Cd isotope composition of marine sediments may also be influenced by local redox conditions and partial remineralization of organically hosted Cd. These confounding factors are under-constrained and render it challenging to use Cd as a reliable paleoproxy. To understand the relative importance of each of these processes, we examined the Cd isotope systematics of 69 modern sediments deposited across a wide range of environments. We complement these data with four profiles of particulate Cd isotope compositions from the Southern Ocean. We report three main results. First, we show that the sedimentary flux of Cd is tightly coupled to that of organic matter. Second, most Cd burial occurs in regions with some bottom-water oxygen, and the flux of CdS to anoxic regions is, globally, minor. Finally, we find that remineralization can substantially modify sedimentary Cd isotope compositions, though it is challenging to relate pelagic and sedimentary processes. For example, we find that the relationship between sedimentary Cd isotope compositions and surface seawater [Cd] is the reverse of that predicted by isotope reactor models. Likewise, sedimentary Cd isotope compositions are anti-correlated with bottom-water oxygen. While this pattern is consistent with preferential remineralization of isotopically heavy Cd, profiles of marine particulate matter reveal the reverse, whereby the Cd isotope composition of large particles, which are most likely to reach the seafloor, becomes increasingly ‘heavy’ with depth. These results highlight how productivity, redox, and remineralization all influence the flux and isotope composition of Cd to marine sediments. While our study suggests that there is no simple way to relate sedimentary Cd isotopes to surface nutrient utilization, our data point toward several potential controls that could form the basis of novel proxies for local redox conditions and remineralization.

Penetration depth, phase balance and corrosion behaviour in activated TIG welding of UNS S32205

The aim of this research is to investigate the impact of a flux containing 80% TiO2 and 20% CeO2, under protective atmosphere (100% Ar, 98% Ar-2% N2, and 95% Ar + 5% N2) on penetration depth, phase equilibrium, and corrosion behaviour of autogenous A-TIG welds generated at constant current density. The reason for choosing cerium in the flux composition and nitrogen in the shielding gas is their effect on the phase balance of austenite and ferrite in this alloy. Metallography, ferritoscopy, and potentiometry were employed in the examination of the welds. The use of a two-component flux increased the penetration depth in TIG welding by up to 87%. Adding 2% and 5% nitrogen gas to the shielding gas in active TIG welding further increased the penetration depth to 117% and 130%, respectively. The results of ferritoscopic analysis reported the amount of austenite in the base metal and conventional TIG weld as 48% and 32%, respectively. However, the use of two-component flux increased the amount of austenite in the weld metal to 39%. Additionally, the addition of 2% and 5% nitrogen to the shielding gas in active TIG welding increased the amount of austenite in the weld metals to 60% and 76.6%, respectively. According to cyclic potentiodynamic polarization studies, active TIG welding with different nitrogen gas concentrations showed improved general and pitting corrosion properties in weld metals compared to conventional TIG welding. Consequently, weld metal resulting from active TIG welding with 2% nitrogen gas exhibited corrosion properties almost identical to that of the base metal.

Recovery of Co-rich metal alloy from end-of-life Li-ion batteries

The end-of-life Li-ion batteries (LIBs) contain various metal values such as lithium (Li), cobalt (Co), aluminium (Al), copper (Cu), iron (Fe), nickel (Ni), and manganese (Mn) wherein the major value chain is found as Co, Li and Ni contents. The recovery of Co-rich metal alloy from the discarded LIBs using smelting at high temperature is investigated in this study. The black mass is obtained after safe discharging and manual dismantling of the discarded LIBs. The recovery of Co-rich metal alloy from the calcined black mass was examined at temperature range of 1400–1500 °C with addition of combination of flux. The smelting experiments of the calcined black mass were found adequate at 1450 °C with soaking period of 2 h. Subsequently, the cobalt (Co) rich metal alloy is separated from slag after solidification. The flux composition MnO2-SiO2-Al2O3 found suitable for complete smelting of calcined LIB black mass and as a result yield an effective recovery of Co-rich alloy. The recovered Co-rich alloy comprises of Co-Mn-Ni-Cu with elemental composition of 65.8 wt% Co, 7.8 wt% Mn, 6.7 wt% Ni and 3.2 wt% Cu. The recovered Co-rich metal alloy can be used to enhance the ultra-high strength and as a master alloy application.

Magnetic moments of astrophysical neutrinos

We study the impact of neutrino magnetic moments on astrophysical neutrinos, in particular supernova neutrinos and ultra-high energy neutrinos from extragalactic sources. We show that magnetic moment-induced conversion of Dirac neutrinos from left-handed states into unobservable right-handed singlet states can substantially change the flux and flavour composition of these neutrinos at Earth. Notably, neutrinos from a supernova's neutronisation burst, whose flux can be predicted with 𝒪(10%) accuracy, offer a discovery reach to neutrino magnetic moments ∼ few × 10-13 μB , up to one order of magnitude below current limits. For high-energy neutrinos from distant sources, for which no robust flux prediction exists, we show how the flavour composition at Earth can be used as a handle to establish the presence of non-negligible magnetic moments, potentially down to few× 10-17 μB if the measurement can be performed on neutrinos from a single source. In both cases, the sensitivity strongly depends on the galactic (intergalactic) magnetic field profiles along the line of sight. Therefore, while a discovery is possible down to very small values of the magnetic moment, the absence of a discovery does not imply an equally strong limit. We also comment on the dependence of our results on the right-handed neutrino mass, paying special attention to the transition from coherent deflection by a classical magnetic field to incoherent scattering on individual scattering targets. Finally, we show that a measurement of Standard Model Dirac neutrino magnetic moments, of order 10-19 μB , could be possible under rather optimistic, but not completely outrageous, assumptions using flavour ratios of high-energy astrophysical neutrinos.

Construction and validation of C3F8 electron impact and heavy particle reaction scheme for modeling plasma discharges

This work presents the results of developing a set of electronic and chemical reactions for a plasma discharge in octafluoropropane (C3F8). Electronic reactions were obtained using the most relevant set of cross sections at the moment, taking into account experimentally known dissociation and ionization channels. Based on the dissociation products obtained during electronic reactions, a set of chemical reactions was adapted by analogy with the C4F8 reaction scheme from the literature. Next, the resulting complete set of reactions was tested against published experimental data on the concentration of electrons, negative ions, and electronegativity in a capacitive plasma discharge at different gas pressures and discharge input powers. For this purpose, a one-dimensional hydrodynamic drift-diffusion model was used. Reasonable agreement was obtained between the model and experimental data on electronegativity. Eventually, the resulting set of reactions was adapted for a two-dimensional hydrodynamic drift-diffusion model of an ICP discharge. The results of the calculations are two-dimensional distributions of radicals and ions, radical and ion composition of fluxes onto the substrate under conditions typical for industrial reactors.

The connection between Submarine Groundwater Discharge and seawater quality: The threat of treated wastewater injected into coastal aquifers

Submarine Groundwater Discharge (SGD) delivers nutrients to the coastal sea triggering phytoplankton blooms, eutrophication, and can also serve as a pathway for contaminants. Wastewater treatment plants (WWTP) including injection wells in coastal areas influence coastal aquifers and might impact the composition and magnitude of SGD fluxes. In tourist areas, wastewater treatment may be less efficient and larger in volume during high seasons, potentially impacting nutrient fluxes from SGD and exacerbating environmental impacts. This study analyzes the nutrient transfer from treated wastewater injection in karstic aquifers to the coastal sea via SGD, considering the impacts of tourism seasonality. This study is conducted in Cala Deià, a small cove in the Balearic Islands, a Mediterranean tourist destination. The findings suggest that the seasonality of tourism, leading to variations in the volume of wastewater treated in the WWTP, influences the dynamics of the coastal aquifer. This leads to increased SGD water and nutrient fluxes to the sea in summer, i.e. the peak tourist season. The measured DIN, DIP, and DSi inventories in the cove are much larger in August than in April (3, 10, and 1.5 times higher, respectively) due to higher input of nutrients in summer due to SGD impacted by the WWTP. These elevated nutrient flows can support algal blooms in the cove, compromising water quality for local swimmers and tourists. Indeed, in August, shoreline stations exhibited eutrophic Chl-a concentrations, with peaks reaching approximately 4 mg Chl-a L−1. These elevated levels suggest the presence of an algal bloom during the survey. The anthropogenic origin of SGD-driven nutrients is traced in seawater and seagrass meadows, as evidenced by high ∂15N signatures indicative of polluted areas. Thus, the high pressure exerted on coastal areas by tourism activities increased the magnitude of SGD nutrient fluxes, thereby threatening coastal ecosystems and the services they provide.

Factors affecting mobility/export of particle-bound stable elements after erosive rainfalls in agroforestry Mediterranean catchments of Aragón (Spain)

The composition of sediment fluxes caused by erosion can vary greatly both spatially and temporally, causing different impacts on water bodies. The erosion process is mainly driven by soil and rainfall characteristics as well as land use. The aim of this research is to evaluate the combined effect of these factors in a mountain agroforestry system, analysing the relationship of the sediment composition generated after flooding events with soil and rainfall characteristics and the impact of land use. The analyses were based on data recorded in three catchments with Mediterranean climate. The sediments were collected after 21 seasonal campaigns and their characteristics were assessed taking into account rainfall characteristics and the main land uses in each catchment. The results confirm the differences in soil particle mobilization after high and low intensity events and the higher impact of croplands compared to other dominant land uses. The amount of sediments trapped in the catchment with the largest area of cropland almost doubled sediment collected in the other catchments. Clay and soil organic carbon in the sediments were lower than in the original sources, likely due to the lower content in the soils more susceptible to erosion and the washing out of the finer material by runoff under high amount/intensity precipitation. Differences were observed between catchments and between rainfall events in the export of stable elements, with a general sediment enrichment in Al, Be, B, Cu, Mn, S, Sr and Zn, reaching the highest values for Be, Sr and Zn. The elemental enrichment differed according to rainfall characteristics thus Cu, Zn or Mn were higher after low intensity events, while other elements like Be were enriched after high intensity events. These variable patterns evidence the complex interplay of involved factors and the key role of elemental bounds to particle sizes and organic matter.

Unusual sources of fossil micrometeorites deduced from relict chromite in the small size fraction in ~467 Ma old limestone

ABSTRACTExtraterrestrial chrome spinel and chromite extracted from the sedimentary rock record are relicts from coarse micrometeorites and rarely meteorites. They are studied to reconstruct the paleoflux of meteorites to the Earth and the collisional history of the asteroid belt. Minor element concentrations of Ti and V, and oxygen isotopic compositions of these relict minerals were used to classify the meteorite type they stem from, and thus to determine the relative meteorite group abundances through time. While coarse sediment‐dispersed extraterrestrial chrome‐spinel (SEC) grains from ordinary chondrites dominate through the studied time windows in the Phanerozoic, there are exceptions: We have shown that ~467 Ma ago, 1 Ma before the breakup of the L chondrite parent body (LCPB), more than half of the largest (>63 μm diameter) grains were achondritic and originated from differentiated asteroids in contrast to ordinary chondrites which dominated the meteorite flux throughout most of the past 500 Ma. Here, we present a new data set of oxygen isotopic compositions and elemental compositions of 136 grains of a smaller size fraction (32–63 μm) in ~467 Ma old pre‐LCPB limestone from the Lynna River section in western Russia, that was previously studied by elemental analysis. Our study constitutes the most comprehensive oxygen isotopic data set of sediment‐dispersed extraterrestrial chrome spinel to date. We also introduce a Raman spectroscopy‐based method to identify SEC grains and distinguish them from terrestrial chrome spinel with ~97% reliability. We calibrated the Raman method with the established approach using titanium and vanadium concentrations and oxygen isotopic compositions. We find that ordinary chondrites are approximately three times more abundant in the 32–63 μm fraction than achondrites. While abundances of achondrites compared to ordinary chondrites are lower in the 32–63 μm size fraction than in the >63 μm one, achondrites are approximately three times more abundant in the 32–62 μm fraction than they are in the present flux. We find that the sources of SEC grains vary for different grain sizes, mainly as a result of parent body thermal metamorphism. We conclude that the meteorite flux composition ~467 Ma ago ~1 Ma before the breakup of the LCPB was fundamentally different from today and from other time windows studied in the Phanerozoic, but that in contrast to the large size fraction ordinary chondrites dominated the flux in the small size fraction. The high abundance of ordinary chondrites in the studied samples is consistent with the findings based on coarse extraterrestrial chrome‐spinel from other time windows.

Composition of the sinking particle flux in a hot spot of dinitrogen fixation revealed through polyacrylamide gel traps

Diazotrophs regulate marine productivity in the oligotrophic ocean by alleviating nitrogen limitation, contributing to particulate organic carbon (POC) export to the deep ocean. Yet, the characterization of particles composing the sinking POC flux has never been explored in such ecosystems. Moreover, the contribution of the direct gravitational export of diazotrophs to the overall flux is seldom assessed. Here we explore the composition of the sinking POC flux in a hot spot of N2 fixation (the western sub-tropical South Pacific) using polyacrylamide gel-filled traps deployed at two stations (S05M and S10M) and three depths (170 m, 270 m, 1000 m) during the TONGA expedition (November-December 2019). Image analyses of particles collected in the gels was used to classify them into 5 categories (fecal aggregates, phytodetrital aggregates, mixed aggregates, cylindrical fecal pellets, and zooplankton carcasses). Fecal aggregates were the most abundant at both stations and all depths and dominated the flux (average of 56 ± 28% of the POC flux), followed by zooplankton carcasses (24 ± 19%), cylindrical fecal pellets (15 ± 14%) and mixed aggregates (5 ± 4%), whereas phytodetrital aggregates contributed less (<1%). Since N isotope budgets show that export is mainly supported by diazotrophy at these stations, these results suggest that the diazotroph-derived N has been efficiently transferred to the foodweb up to zooplankton and fecal pellets before being exported, pleading for an indirect export of diazotrophy. However, random confocal microscopy examination performed on sinking particles revealed that diazotrophs were present in several categories of exported particles, suggesting that diazotrophs are also directly exported, with a potential contribution to overall POC fluxes increasing with depth. Our results provide the first characterization of particle categories composing the sinking flux and their contribution to the overall flux in a hot spot of N2 fixation.