Fluidized Fly Ash Research Articles

Usability of the Combination of Fly Ash from Different Species

This article deals with the possible combination of high temperature fly ash with fluidised fly ash. The aim of this experiment is to verify the effect of the combination of these two energy by-products not only on the parameters of cement mortar in the fresh state, but especially on its mechanical parameters in the hardened state.

Study of the Design and Mechanical Properties of the Mix Proportion for Desulfurization Gypsum–Fly Ash Flowable Lightweight Soil

In order to solve the global problem of bridge head jumping caused by the insufficient compaction of the roadbed in the transition section of highways and bridges, a desulfurization gypsum–fly ash flowable lightweight soil without vibration, capable of self-compaction, low bulk density, and economic and environmental protection, has been developed. This study selected low-grade cement, industrial waste (fly ash and desulfurization gypsum), and Yellow River silt as the raw materials for the design of the mix ratio of a desulfurization gypsum–fly ash flow-state lightweight soil mix. Through multiple indoor experiments, the influence of cement content, silt content, and the fly ash/desulfurization gypsum quality ratio on its fluidity and mechanical properties was systematically studied. The stress–strain relationship under uniaxial compression was analyzed and the strength formation mechanism was revealed through scanning electron microscopy (SEM). The results show that the mechanical properties of the prepared desulfurization gypsum–fly ash flowable lightweight soil meet the engineering requirements. Increasing both the cement and fly ash content results in the decreased fluidity of the desulfurization gypsum and fluidized fly ash. However, as the mass ratio of fly ash to desulfurization gypsum increases, the fluidity reaches its maximum when the mass ratio of fly ash to desulfurization gypsum is 2:1. Based on the stress–strain relationship test results, a uniaxial compressive constitutive model of the desulfurization gypsum–fly ash flowable lightweight soil was proposed. The model was fitted and analyzed with the test results, and the correlation was greater than 0.96. The high degree of agreement showed that desulfurization gypsum can promote the disintegration of fly ash, thereby increasing the specific surface area. This provides more contact points, promotes the hardening process, and enhances the interlocking force between particles and the formation of cementitious substances, further enhancing strength.

Carbonised fluidised fly ash (CFFA); A new product for mining engineering purposes (discussion of possible applications)

The article presents and summarises the current state of research and laboratory results on the carbonation of fly ash with carbon dioxide in the context of its use in mining engineering. Based on previous publications and patent applications, the possibilities of using carbonated fly ash from fluidised bed boilers for the following applications were discussed: securing excavations particularly susceptible to fire hazards, shotcreting and securing longwalls and supports, constructing cases, securing decommissioned shafts, and others, which means wherever the use of cement is required. It was pointed out that the removal of excess free calcium oxide makes it possible to use carbonated fly ash in mining applications for placement in workings requiring increased tightness. It was also stated that carbonation allows the removal of hydrogen from fluidised fly ash (FFA) obtained during co-combustion. The research highlighted the potential and importance of granulating carbonised FFA in expanding the applications of this innovative product in mining engineering.

Effect of the Combination of High Temperature and Fluid Fly Ash on the Compressive Strength of Concrete and its Dynamic Modulus of Elasticity

This paper deals with the effect of combining high temperature and fluidised fly ash, not only on the compressive strength of concrete but also on the determination of the dynamic modulus of concrete test bodies. The use of high-temperature fly ash in concrete mixes has become commonplace. However, the demand for this type of active admixture has increased to such an extent that it currently far exceeds supply, especially after selective non-catalytic nitrogen oxide reduction (SNCR) was introduced and the switch to low-temperature combustion units. This lack of supply makes it necessary to look for other alternative solutions to this situation. The partial replacement of high-temperature fly ash with fluidised bed fly ash appears to be a possible solution.

Comparative Study on Selected Properties of Modified Polyurethane Foam with Fly Ash.

The aim of the article is to compare two types of fly ash (from the fluidized and pulverized coal combustion process) as a filler for rigid polyurethane foam. Pulverized fly ash (PFA) is widely used in building materials, while fluidized fly ash (FFA) is not currently recycled, but landfilled. The produced rigid polyurethane foams were reinforced with 5 and 10% by weight addition of fly ash from two different types of boilers. The foaming process, physical properties, morphologies and thermal degradation were subject to comparative analysis. The research indicated that fly ash intensifies the reactions of foam synthesis, most commonly, polyurethane (PU) foam with an addition of 10% PFA. What is interesting is that both ashes can be used in PU foam technology as they do not cause deterioration of the physical parameters. As shown, the addition of filler affects the morphology and impairs the brittleness. Additionally, the use of fly ash from coal combustion in the technology of polyurethane materials complies with the guidelines of the circular economy stated in the European Union legislation. Partial replacement of petrochemical components with waste filler also reduces the total energy consumption in the production of PU composites.

The Effect of Class C Fly Ash on the Water Impermeability of Brick Body

The effect of fluidized fly ash (Tisová, ČEZ Group Czech Republic, class C according to ASTM C618) on the porosity (water absorption, bulk density, capillarity) and water impermeability of brick body used for the production of clay roofing tiles (Wienerberger, Czech Republic). The properties of plastic body (mixing water, drying shrinkage) are discussed too. The addition (10 %wt) of fluidized fly ash in the raw materials mixture for the production of clay roofing tiles generally reduces the sensitivity to the formation of reducing cores during firing thanks to higher porosity of dried green body (higher mixing water) - this is also related to the higher water absorption and capillarity of the fired body and hence to the impaired water impermeability when the fly ash is used.

Durability of Cement and Ash Mortars with Fluidized and Siliceous Fly Ashes Exposed to HCl Acid Environment over a Period of 2 Years.

The paper presents results of research on the impact of fly ash from fluidized bed combustion (FBC) of lignite, used in quantities of 30 and 45% by mass, and the mixture of FBC and silicious fly ash in amount of 45% by mass, on properties of cement–ash mortars. Mortars were exposed to aggressive environment of 1, 3, and 5% HCl solutions for 2 years. Mortars containing 45% FBC exposed to 1% HCl solution (pH = 2) showed the highest durability from among other mortars. The growth of their strength observed after 90 days of testing in 1% HCl environment, as well as the lowest drop of strength after 730 days of exposure to this environment, resulted from the reduced amount of large pores from 20 to 200 nm in mortars containing fly ash, with simultaneous growth of smaller pores of <20 nm during testing. A beneficial effect has been demonstrated of FBC addition to cement on properties of cement–ash mortars exposed to the aggressive impact of the HCl. Mortars with FBC fly-ash content increased to 45% by mass showed higher strength values, smaller differences in linear and mass changes, and increased durability in an aggressive environment observed during 730 days of testing.

The Influence of Fly Ash on Mechanical Properties of Clay-Based Ceramics

Elastic properties of mixtures of illitic clay, thermal power plant fly ash (fluidized fly ash—FFA and pulverized fly ash—PFA), and grog were investigated during the heating and cooling stages of the firing. The grog part in the mixtures was replaced with 10, 20, 30, and 40 mass% of the fly ash, respectively. The temperature dependence of Young’s modulus was derived using the dynamical thermomechanical analysis, in which dimensions and mass determined from thermogravimeric and thermodilatometric results were used. Flexural strength was measured at the room temperature using the three-point bending test. The following results were obtained: (1) Bulk density showed a decreasing trend up to 900 °C and a steep increase above 900 °C. During cooling, the bulk density slightly increased down to the room temperature. (2) Young’s modulus increased significantly during heating up to ~300 °C. Dehydroxylation was almost not reflected in Young’s modulus. At temperatures higher than 800 °C, Young’s modulus began to increase due to sintering. (3) During cooling, down to the glass transformation, Young’s modulus slightly increased and then began to slightly decrease due to microcracking between phases with different thermal expansion coefficients. (4) Around the β→α quartz transition, radial stresses on the quartz grain altered from compressive to tensile, creating microcracks. Below 560 °C, the radial stress remained tensile, and consequently, the microcracking around the quartz grains and a decreasing Young’s modulus continued. (5) With a lower amount of PFA and FFA, a higher Young’s modulus was reached after sintering. The final values of Young’s modulus, measured after firing, show a decreasing trend and depend linearly on the part of fly ash. (6) The flexural strength measured after firing decreased linearly with the amount of the fly ash for both mixtures.

Sulphur Dioxide Emissions during the Firing of Ceramic Bodies Based on Class C Fly Ash

Fluid fuel combustion technology in coal-fired power plants is very popular in the Czech Republic, resulting in a relatively high production of a specific by-product - fluidized fly ash (class C according to ASTM definition), which differs from the classical high-temperature fly ash in mineralogical composition with a high sulphur content of anhydrite CaSO4. Fluidized ash is not yet used in the production of fired building materials, where it could be used as a source of calcium oxide (for example, the production of porous ceramic tiles). However, high volume of sulphur dioxide emissions during the re-firing of fluidized fly ash in ceramic raw materials mixtures has been solved. The aim of the paper is definition of temperature ranges of anhydrite decomposition (formation of SO2 emission) from pure class C (fluidized) fly ashes from different sources (power plants) depending on granulometry of fly ash especially.

Comparative investigation of reactivity of different kinds of fly ash in alkaline media

Comparison of the influence of temperature and different alkali activators on the reactivity of two types of fly ash (conventional, fluidized) was presented. The main emphasis was put on fluidized fly ash as potential component of binding mixtures containing low amount of cement. Conventional fly ash was used as a reference. It was found that for these materials the key differences affecting products of activation are: availability of calcium and sulfate ions as well as structure of fly ash grains influencing dissolution of aluminate and silicate species. Fluidized fly ash, contrary to conventional fly ash, undergoes reaction in 0.1 M solutions of hydroxides forming mainly ettringite. In the case of 4 M hydroxides, both fly ashes undergo hydration processes. Conventional fly ash formed mainly amorphous aluminosilicate gel, while fluidized fly ash may create zeolitic products especially in the case of elevated temperature of early hydration. Sulfate and alkali ions can be incorporated into aluminosilicate structure of new formed products; however, this process depends strictly on the type of used hydroxide and its concentration. The presence of Ca(OH)2, carbonates and alkali sulfates was also registered in the case of hydrated fluidized fly ash.

The fly ash of class C for ceramic technology

The properties of different Czech fluidized fly ashes FFA (class C fly ash according to ASTM C618 12a with high content of CaO in the form of anhydrite primarily) and emisions of SO2 in flue gas during the firing of FFA are discussed. The decomposition of anhydrite CaSO4 was observed during the soaking time at 1200 °C during the firing of dry pressed bodies based on pure fluidized fly ash. The effect od fluidized fly ashes admixtures on the properties of ceramic bodies is as fluxing agent and the source of CaO for the creation of anorthite in the fired ceramic body. The properties of domestic fluidized fly ashes in connection with their utilization in ceramic technology are described.

Application of Granulated Cable Plastic Waste for Soil Stabilization

Paper deals with the assessment of practical utilization of granulated cable plastic waste (GCPW) for the production of stabilized soil layers in transport engineering. The main goal of the experimental work was the evaluation of the influence of GCPW on mechanical properties of soil stabilization based on the fluidized fly ash. Mechanical properties were investigated using standard procedures in soil mechanics. GCPW was dosed as a partial replacement of fluidized fly ash up to 30 %. It was concluded, that the studied level of replacement performs critical level, additional increasing of GCPW would lead to a decline of required mechanical properties. Besides, replacement by studied waste material caused lower values of the bulk density.

Influence of additives on properties of concrete with recycled aggregate and fly ash

It is possible to considerably enhance the environmental friendliness of concrete production by increasing the usage of recycled concrete aggregate (RCA) and supplementary cementitious materials (SCM) in concrete industry [1, 2]. The idea of concrete with recycled concrete aggregate (RCA), additives such as microsilica, metakaolin, fluidized fly ash and superplasticizers might be controversial - it assumes usage of waste material and expensive additives - it is popular though. The aim of this paper was to determine, what the frost resistance of such concrete is. Additionally tests of other properties (sorptivity, absorbability and air void parameters) were performed.

Effect of Fluidized Bed Ash on the Thermodynamic Stability of Hydraulic Binders

Fluidized bed ash, which is the youngest industrial waste can be considered on the basis of research, a high-quality secondary raw material base which can be easily used in the production of Portland cements and, in general, other hydraulic binders. Regarding the direct effect of anhydrite on the course of hydrating mixed cement with the fluidized fly ash and the consequent behaviour of the originated cement stone, its reaction with clinker materials on the mentioned Aft (Al2O3–Fe2O3-–tri) phase is clear. The creation of AFt phases, if they originate additionally, due to their morphology, is accompanied by significant volume changes which may lead to deformation up to the destruction of the cement stone. Some foreign publications show the possibility of the transformation of this thermo-dynamically unstable mineral into the further mineral from the group AFt phase, which is thaumasite, Ca3Si (CO3)(SO4)(OH)6.12H2O.

Influence of Use Fluidized Fly Ash Combined with High Temperature Fly Ash on Microstructure of Cement Composite

The constraint of using fluidized bed combustion fly ash as addition for concrete is mainly its chemical composition. Increased contents of sulphates and free lime in fluidized bed combustion fly ash causes development of undesirable ettringite during hydration. Expansive character of this mineral can have degrading effect on hardened concrete. Fluidized bed combustion fly ash as well as high temperature fly ash are considered pozzolanic addition, which is capable of reacting with Ca(OH)2 and form similar hydration products as cement hydration. Use of small amount of fluidized bed combustion fly ash can cause production of ettringite, however, when combined with high temperature fly ash, possible micro-failures could be healed with new hydration products - CSH gels. The paper deals with possibilities of confirming this theory mainly through examination of microstructure of cement composite with an electron microscope and clarifying observed hydration products.

Use of Fluidized Bed Combustion Fly Ash as Addition Reducing Shrinkage of Concrete

Volumetric changes during ageing belong to natural properties of concrete. These changes, either growing or shrinking, can present a problem, which has to be taken into account during design and realization phases. This phenomenon is influenced by various factors and volumetric changes can be eliminated in many ways. One of the possibilities is setting appropriate combination of input materials and use of special additions and admixtures. This paper focused on verification of the method reducing shrinkage of concrete by means of using high temperature combustion fly ash combined with fluidized bed combustion fly ash as addition. The precondition is growth of new forms, in particular primary ettringite and monosulphate, which form because of the content free lime and sulphates in fluidized fly ash. If these minerals are formed in fresh concrete, they can positive prevent shrinkage without destruction of the composite material.

The Influence of Particle Size of Cement and Different Additives on the Properties of Portland Cement Pastes

The consumption of concrete as a building material is still increasing over the world. Concrete production is closely associated with CO2 and other greenhouse gases emissions. The reduction of these emissions can be achieved by a higher utilization of secondary raw materials in cement mixtures. Particle size is an important factor for more effective use of these materials. This work is focused on the calorimetric determination of the effect of particle size of cement, finely ground granulated blast furnace slag (GBFS), high-temperature fly ash (FA) and fluidized fly ash (FFA) on the Portland cement hydration. Effect of particle size on the hydration of pure cement pastes and pastes with the addition of secondary raw materials is monitored by isoperibolic calorimetry. Other part of this work is aimed on the mechanical properties of resulting materials. The flexural strength and compressive strength were observed after 1, 7 and 28 days of curing.

Synthetic Preparation of Thaumasite – Several Possible Routes for Thaumasite Formation

Presented work is a part of an experiment where limestone is partially replaced by fluidized fly ash during cement manufacturing. Hydration of this type of cement is connected to formation of AFt phases – thaumasite and ettringite that cause serious damage to cement stone. Thaumasite (CaSiO3·CaCO3·CaSO4·15H2O) is less known and less common. It forms especially at lower temperatures. During its growth C-S-H phases are built into thaumasite unite cell, therefore, cement stone decomposes. To preclude thaumasite formation, further research of this mineral is necessary; therefore, its synthetic preparation in sufficient quality is important. The aim of this work was to verify several routes for thaumasite synthetic preparation. In the beginning, burning of mixtures prepared on stoichiometric proportions of compounds in thaumasite was done then two methods used in literature were tried and in the end a new method based on main calcium silicate phases was realized.

Measuring the Thermo-Technical Parameters of Autoclaved Aerated Concrete

Bulk density and moisture content are factors that significantly affect the physical properties of autoclaved aerated concrete (AAC) including thermal conductivity and other thermo-technical characteristics. This article shows the results of measurements of compressive strength, capillary absorption, water absorption and porosity of AAC (ash on fluidized fly ash) at different bulk density and also the results of thermal conductivity of AAC at different bulk density and variable moisture content of the material. The thermo-technical properties were measured using the Isomet 2104, a portable measuring device. Acquired results demonstrate dependence of physical properties including thermal conductivity of AAC on bulk density and moisture content. The reliability and accuracy of the method of measuring was also shown.

The influence of curing time on the shear strength of fluidized fly ash

Abstract The paper presents results of research on the influence of compaction and air and water curing on angle of internal friction and cohesion of fluidized fly ash from “Połaniec” Power Plant. It was stated that the increase in compaction resulted in an insignificant increase of the angle of internal friction and a quite significant increase of cohesion. While the type and time of curing had a great influence on the angle of internal friction and cohesion. The highest values of angle of internal friction were obtained in the air curing, and the lowest in the water curing whereas in case of cohesion there was an inverse relation. The rise of curing time resulted in largely increased cohesion and small changes of angle of internal friction.