The paper presents the results of mathematical modeling, numerical and laboratory experiments aimed at developing an optical method for estimating the size distribution of droplets in a spray. The optical method is based on analyzing the brightness of light reflected by drops of a liquid. The ob-ject of study was a spray of a transparent liquid (distilled water) produced by a centrifugal axisym-metric nozzle. It is known that the intensity (brightness) of light reflected by a drop is proportional to the surface area of the drop, and for spherical drops, accordingly, to the square of the drop’s di-ameter (hereinafter, the terms intensity and brightness are used as synonyms). For a more detailed representation of the patterns of this dependence in the case of a flow of droplets, we considered a mathematical model representing the spray as a flow of spherical particles with parameterization of almost all significant properties: arbitrary distribution of droplets in size and speed as well as changes in these characteristics over time during the movement of drops along the flow. We ob-tained formulas and tested a mathematical model of nozzle spray that takes into account the change in droplet density due to the scattering of droplets in the spray cone and the inhomogeneity of veloc-ity fields. The zone of possible cessation of droplet fission was determined.