Measurement of flow distribution in the fuel cell stack is a challenging task. This study proposes a new method to measure air flow distribution in high-temperature proton exchange membrane fuel cell stacks. The characteristic frequency related to channel impedance is extracted using the distribution of relaxation times analysis. A simple correlation between the air stoichiometry and the characteristic frequency is developed. The influence of various factors on the correlation, including cell operation conditions, fluid physical properties and channel dimensions, are investigated. The experimental results show a good agreement with the correlation. Error estimation indicates that the temperature distribution of the stack, gas humidity and pressure distribution in the inlet manifold have no significant effect on the proposed method under normal conditions. The accuracy and practicability are verified using a three-cell stack with separate mass flow controller (MFC) systems. The results show less than 3.11% of relative error between the reference air stoichiometry given by the MFC and those measured from our proposed method for air stoichiometry below 3.0 at 0.1 A cm−1. The present method provides powerful support for designing high consistency stacks and the real-time monitoring cells state-of-health in stacks.
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