The hovering flight of a quadrotor Unmanned Aerial Vehicle (UAV) refers to maintaining the aircraft in a fixed position in the air, without lateral, vertical, or rotational movements, using only the vehicle’s control systems to maintain proper balance in all spatial dimensions. Algorithms and control systems have been developed to continuously adjust motor speeds to counteract deviations from the desired position and achieve effective hovering flight. This paper proposes a set of PID controllers with an integral effect based on the Riemann–Liouville fractional-order approach to improve the hovering flight of a quadrotor UAV. This research innovates by introducing a set of fractional-order PID controllers for UAV hover stability, which offer better adaptability to non-linear dynamics and robustness than traditional PID controllers. Also presented is the development of new performance metrics (MSE, BQC-LR), which allow for more comprehensive control system evaluations. A thorough comparative analysis with conventional control methods demonstrates the superior performance of fractional-order control in real-world simulations. The numerical simulation results show the effectiveness of the proposed Fractional Integral Action PID Controller in the control of UAV hovering flight, while comparative analyses against a classical controller emphasize the benefits of the fractional-order approach in terms of control accuracy.