This study aimed to determine the best safety measures in case of accidental gas leakage, fire, or explosion in the LPG storage tank of a domestic school kitchen by analyzing the ranges potentially affected by toxicity, overpressure, and radiant heat. Using the Areal Locations of Hazardous Atmospheres (ALOHA) program, the range of damage impact of gas leakage, toxicity owing to VCE and boiling liquid expanding vapor explosion (BLEVE), overpressure, and radiant heat were analyzed for a 1,000 kg-capacity small LPG storage tank installed in the kitchen. It was classified into worst-case and alternative (local weather) scenarios, depending upon the weather conditions, and analyzed by dividing into 50% and 100% storage, as per the difference in storage. The observed risk of toxicity placed the entire school area at risk of death or disability. The risk of overpressure posed a threat to buildings in the entire school area and around the school. The risk of blasts revealed a risk of death up to a distance of 135 m, and the farther regions were at risk of second-degree burns. Additionally, the risks of toxicity and overpressure are affected by weather conditions and LPG storage, whereas blasts are primarily affected by LPG storage with minimal impact from weather conditions.