Fibrous Materials Research Articles

Methods for Visualization and Analysis of the Microstructure of a Fibrous Composite Material

Methods for Visualization and Analysis of the Microstructure of a Fibrous Composite Material

Optimization of sound absorption of recycled Nylon fibrous materials

A semi-empirical model for the assessment and an optimization procedure of the sound absorption coefficient of compressed nonwoven fibrous materials made from recycled Nylon fibers (RNF) is developed. In general, the prediction of the sound absorption properties of materials requires the measurement of non-acoustic parameters by specialized characterization tools that are not always within reach of most laboratories. The objective of the proposed model is to establish empirical relationships between these non-acoustic parameters and the bulk density of RNF materials. These empirical relationships are then substituted into a conventional acoustic model for porous materials, namely, the model of Johnson-Champoux-Allard. The proposed model accurately predicts the sound absorption coefficients of compressed RNF materials based solely on bulk density, thickness, and frequency. This prediction is validated through impedance tube measurements. Moreover, the model is used with a proposed optimization producedure to identify the ideal density and thickness for maximum sound absorption at a specific frequency. Impedance tube measurements on optimized configurations confirm the effectiveness of this optimization process.

Impact analysis of particle sphericity on the properties of porous materials via particle packing method for hydrogen fuel and electrolysis cells

This study focuses on the impacts of particle's sphericity on the properties of porous materials crucial to electrochemical devices. Three-dimensional structures with spherical and cylindrical particles were generated to simulate porous granular and fibrous materials. The constructed particle geometries are as follows: a sphere and cylinders with different aspect ratios (height-to-diameter) of 0.1, 0.5, 1.0, 2.5, 5.0, 10, and 20. Every model exhibits a porosity of 0.500 ± 0.001 to exclude the effects of porosity. The structures were binarized with 200×200×200 dimensionless voxels, which were analyzed with the specific surface area, grain and pore size distributions, geometrical tortuosity, conductivity, and diffusivity across the through- and in-planes. As a result, the particle geometry significantly impacts on tortuosity, conductivity, and diffusivity, with the absolute value of Spearman's correlation coefficient of up to 1. It may imply the necessity to consider particle geometry as an ex-situ characterization for better electrochemical performance.

Optimization of dissipative mufflers

The method of selecting the configuration of dissipative mufflers with the required acoustic efficiency is considered. The peculiarity of the considered approach is the use of an integral indicator of acoustic efficiency and dimensionless geometric parameters. The studies were carried out using finite element calculations. In the finite element model of a dissipative mufflers, acoustic characteristics of a fibrous sound-absorbing material obtained from experimental studies were used.

Cocoon microstructures through the lens of topological persistence.

Biological materials display a wide array of functionality, often dictated by complicated microstructures. New geometric and topological strategies allow one to describe the microstructures in a precise and systematic way. This article describes the application of topological persistence and other geometric methods to the microstructural analysis of three-dimensional X-ray micro-computed tomography scans of the Bombyx mori silkworm cocoons. These methods allow conclusions to be drawn about pore space gradients, silk fibre thickness gradients and fibre alignment within the cocoon. The study demonstrates the applicability of these topological and geometric methods to quantify and characterize fibrous materials.

Validation of heat transfer models and optimization of heat shielding performance of high-temperature multilayer insulations for hypersonic vehicles

Multilayer insulation (MLI) is widely used in hypersonic vehicles because of its low density and excellent thermal insulation performance. However, the insulation mechanism of MLI remains poorly understood, leading to conflicting views on how to enhance its thermal insulation capabilities. In this study, two different numerical models were built and validated with experiment data to investigate key factors influencing MLI performance. The analysis focused on the effects of reflective screen positioning, the surface emissivity of reflective screens and the radiation properties parameters of fibrous materials on the thermal insulation performance of the MLI. The results show that the thermal insulation performance is better when the reflective screens are placed close to the thermal boundary. Moreover, insulation materials with lower absorption coefficients enhance the effectiveness of the reflective screens, further improving the thermal insulation performance of MLI. In addition, the study reveals that the thermal insulation mechanisms differ between the upper and lower surfaces of the reflective screens. Lower emissivity on the upper surface combined with higher emissivity on the lower surface optimizes the thermal insulation performance of MLI. These findings offer valuable insights for advancing MLI designs and improving its application in future high-speed vehicles.

Mechanism of airborne sound absorption through triboelectric effect for noise mitigation

Mitigating broadband noise with passive airborne sound absorbers has been a long-lasting challenge, particularly for low-frequency anthropogenic sounds below kilohertz with long wavelengths, which require bulky materials for effective absorption. Here, we propose a strategy that utilizes local triboelectric effect and in-situ electrical energy dissipation mechanism for airborne sound absorption. This approach involves a fundamentally different mechanism that converts airborne sound into electricity for energy dissipation, in contrast to conventional mechano-thermal energy conversion mechanisms. We establish an equivalent acoustic impedance model to provide theoretical analysis of the underlying sound absorption mechanisms, with a theoretical maximum mechano-electro-thermal coupling efficiency approaching 100% under optimal conditions. We design fibrous triboelectric composite foam materials accordingly and show their substantially boosted acoustic absorption performance experimentally, where the adoption of diverse triboelectric material pairs validates that a larger difference in material charge affinities intensifies the local triboelectric effect and results in higher acoustic absorbing performance.

Key Advances in Solution Blow Spinning of Polylactic-Acid-Based Materials: A Prospective Study on Uses and Future Applications.

Solution blow spinning (SBS) is a versatile and cost-effective technique for producing nanofibrous materials. It is based on the principles of other spinning methods as electrospinning (ES), which creates very thin and fine fibers with controlled morphologies. Polylactic acid (PLA), a biodegradable and biocompatible polymer derived from renewable resources, is widely used in biomedical fields, environmental protection, and packaging. This review provides a theoretical background for PLA, focusing on its properties that are associated with structural characteristics, such as crystallinity and thermal behavior. It also discusses various methods for producing fibrous materials, with particular emphasis on ES and SBS and on describing in more detail the main properties of the SBS method, along with its processing conditions and potential applications. Additionally, this review examines the properties of nanofibrous materials, particularly PLA-based nanofibers, and the new applications for which it is thought that they may be more useful, such as drug delivery systems, wound healing, tissue engineering, and food packaging. Ultimately, this review highlights the potential of the SBS method and PLA-based nanofibers in various new applications and suggests future research directions to address existing challenges and further enhance the SBS method and the quality of fibrous materials.

Thermal diffusivity measurement of polymer microfibers while eliminating the effect of heat radiation

The thermal transport properties of polymer fibers are important for heat dissipation in apparel, matrix of wearable devices, and so on. However, it is difficult to precisely determine the thermal properties of a single polymer fiber because of non-negligible thermal radiation due to its relatively low thermal conductivity and high surface-area-to-volume ratio. Here, we developed a system in which the apparent thermal diffusivity and size of microfibers can be measured to estimate their intrinsic thermal diffusivity. We determined the thermal diffusivities of three fibrous materials: silk, spider silk, and cellulose microfibers to be 4.2 (±0.8)×10−7, 1.8 (±0.7)×10−7, and 4.7 (±0.5)×10−7, respectively. For all fibers, the apparent thermal diffusivity strongly depended on the fiber size, indicating that eliminating the radiation effect is indispensable for determining the thermal transport properties of polymer microfibers.

Study of the drive mechanism of the working bodies of a roller machine

A design of a roller machine with an improved drive mechanism of working bodies is developed in the article. The roller machine has expanded functionality when performing technological operations of dehydrating moisture-saturated fiber materials. The developed mechanism ensures stable and reliable operation of the drive of working bodies, regardless of the unevenness and variations in the parameters of the processed moisture-saturated fibrous materials, achieving synchronicity of the working body operation. The study aims to expand the functionality of the roller machine, ensure stable and reliable operation of working roller drives regardless of the unevenness and changes in the parameters of the processed moisture-saturated fibrous materials, and ensure synchronicity of the working rollers.

Fermented Palm Kernel Cake Improves the Rumen Microbiota and Metabolome of Beef Cattle.

In this study, we utilised palm kernel cake as a substrate and fermented it with a composite of bacteria (Pediococcus pentosaceus CGMCC No. 27203 and Lactobacillus plantarum CGMCC No. 27202) and enzymes. We conducted a trial with twenty-four cattle, randomly divided into two groups of twelve cattle each. The control group (CON) was fed the standard farm diet, whereas the treatment group (PKC) received a diet with 3% of soyabean replaced by fermented palm kernel cake. The trial lasted for six weeks. The results showed no significant differences in growth performance between the PKC and CON groups. The abundance of Firmicutes, Bacteroidetes, Proteobacteria, and Spirochaetes was significantly higher in the PKC group than in the CON group. At the genus level, the abundances of Anaeroplasma, norank_f__Bacteroidales_UCG-001, norank_f__Absconditabacteriales_SR1, norank_f__p-251-o5, Prevotellaceae_NK3B31_group, Prevotellaceae_UCG-001, Prevotellaceae_UCG-004, and Treponema significantly increased in the PKC group. Lipid digestion and absorption pathways were significantly enriched in the PKC group. The results indicate that adding fermented palm kernel cake to the diet can increase the abundance of Bacteroidetes and Fibrobacteres in the rumen of beef cattle, enhancing the ability of the PKC group to degrade protein, carbohydrates, and fibrous materials in the feed, thereby improving the feed utilisation efficiency in beef cattle. Adding fermented palm kernel cake to the diet improved carbohydrate metabolism, metabolism of cofactors and vitamins, and nucleotide metabolism. Correlation analysis between the rumen microbiota and metabolic pathways showed that Prevotellaceae_UCG-001 and Prevotellaceae_UCG-003 were positively correlated with amino acid metabolism, Rikenellaceae_RC9_gut_group and Succiniclasticum were positively correlated with metabolism of cofactors and vitamins, and Prevotella and Ruminococcus were positively correlated with nucleotide metabolism. These findings elucidate the differences in rumen microbiota when fermented palm kernel cake is added to the diet, providing a theoretical basis for the application of fermented palm kernel cake in the diet of beef cattle.

Fiber-Reinforced Flexible Self-Healing Strain Sensor with Failure-Improving Sensitivity Recovery.

In this work, we address the inherent limitations of porous, flexible, fibrous, and self-healing strain sensors. Specifically, we tackle issues such as the fatigue failure of carbon-fibrous materials and the long-term flow and low mechanical stability of self-healing materials. We achieve this by combining self-healing carbon/PBS blends with fibrous materials, creating a fiber-reinforced self-healing composite. The self-healing carbon/PBS blends provide strain sensitivity and the ability to recover after fatigue and impact failure, while the fibers prevent the long-term flow of material and the scattering of pieces during impact and fatigue failure within the elastic deformation regime, enabling shape recovery. We fabricated composite wearable strain sensors with a viscoelastic functional layer composed of two continuous phases: (i) a self-healing polymer-carbon blend and (ii) long electrospun fibers of commercial polyurethane. This setup also eliminates the other drawbacks of bulk materials, such as nonlinearity of volt-ampere characteristics, irreversibility of deformation, and a low working factor, and allows improvement of the working factor after failure and healing. Most importantly, we discovered that hindered self-healing, like in the case of the MWCNT/PBS system, enables improvement of sensor sensitivity after large strains and failure, which is due to partial failure of the network formed by conductive particles.

Collective self-caging of active filaments in virtual confinement

Motility coupled to responsive behavior is essential for many microorganisms to seek and establish appropriate habitats. One of the simplest possible responses, reversing the direction of motion, is believed to enable filamentous cyanobacteria to form stable aggregates or accumulate in suitable light conditions. Here, we demonstrate that filamentous morphology in combination with responding to light gradients by reversals has consequences far beyond simple accumulation: Entangled aggregates form at the boundaries of illuminated regions, harnessing the boundary to establish local order. We explore how the light pattern, in particular its boundary curvature, impacts aggregation. A minimal mechanistic model of active flexible filaments resembles the experimental findings, thereby revealing the emergent and generic character of these structures. This phenomenon may enable elongated microorganisms to generate adaptive colony architectures in limited habitats or guide the assembly of biomimetic fibrous materials.

Fracture Criteria for Matrix and Fibers in Unidirectional Polymeric Composites at Static Loadings

When analyzing the strength of structures made of layered fibrous polymer composite materials; the criteria for failure of a monolayer – a unidirectional reinforced composite – are used. A criterion of strength according to the conditions of matrix fracture is formulated, corresponding to conical limiting surfaces and the lowest destructive loads. The criterion of strength according to the condition of fiber failure, which does not allow the paradox of increasing strength in the region of transition from fiber destruction to matrix failure, is given. Experimental verification of the criteria for volumetric, planar, and one-dimensional loads is carried out. Their better correspondence to empirical data is shown and their advantages in comparison with known criteria are marked. A small number of easily detectable parameters of these criteria contribute to their reliability and stability in strength calculations of composite structural elements.

Alternative Solution for Towing Systems Used in the Automotive Industry

This paper aims, in the context of the need to reduce the weight and price of vehicles, to present theoretical and experimental results regarding towing systems made of alternative materials (fibrous composite materials and aluminum alloys). The study of the main element of the whole system, namely towbar research, was stressed, presenting comparative results. The FEM will be used to obtain the stress and strain field in the towball and the towing system. The experimental tests validate the theoretical results obtained. This paper studies five towing systems made by different materials and finally presents a series of practical recommendations, useful in the industry, regarding the improvement of the analyzed models.

Simplification of Johnson-Champoux-Allard-Lafarge model on fibrous materials

The Johnson-Champoux-Allard-Lafarge (JCAL) model, a pivotal framework in acoustics for analyzing sound absorption in fibrous materials, presents challenges in practical implementation due to its complexity. This paper introduces a refined variant of the JCAL model explicitly tailored for fibrous materials, aiming to balance accuracy and computational efficiency. The proposed model retains essential physical principles while simplifying computational intricacies, enhancing its usability for real-time applications and large-scale simulations. Through comprehensive validation against experimental data, we demonstrate the efficacy of the simplified model in accurately characterizing the sound absorption behavior of fibrous materials. This study contributes to advancing the practical applicability of the JCAL model, facilitating its broader adoption across various acoustic engineering domains. The proposed simplification approach holds promise for accelerating research and development in sound absorption materials and acoustic design methodologies within scientific and engineering communities.

Acoustic black hole combined with microperforated plate for a rectangular waveguide

The concept of an acoustic black hole (ABH) for anechoic termination of waveguides has been well-established and extensively studied. The fundamental principle underlying an ABH is the deceleration of acoustic waves, leading to the accumulation and subsequent absorption of acoustic energy within the thermoviscous boundary layer formed along the ribs forming its internal structure. The primary advantage of ABHs, in contrast to classical solutions, lies in their avoidance of porous or fibrous materials, rendering them suitable for deployment in challenging environments. While the majority of published works have focused on ABHs with circular cross-sections, recent advancements have demonstrated the effectiveness of the ABH effect also in waveguides with rectangular cross-sections. However, it has been revealed that these ABHs require very fine internal structure for optimal performance, posing challenges in manufacturing. This study addresses this issue by utilizing a microperforated plate to provide the necessary resistance. To model these ABHs, a simple mathematical model is proposed, enabling the optimization of their parameters. Subsequently, their performance is investigated through numerical experiments. The validity of the results is confirmed by comparing them with a detailed mathematical model, ensuring the accuracy and reliability of the proposed approach.

Acoustic Black Hole silencers for broadband dissipation in ducted geometries

The design of novel absorbers avoiding the use of porous or fibrous materials for ventilation and air-conditioning systems constitutes a challenging issue. Recently, the development of metamaterials has provided new noise control perspectives for this problem. Traditional Acoustic Black Holes (ABHs) have been derived with close-ended configurations to achieve broadband absorption. These solutions are suitable as anechoic termination but they cannot be used as silencer as they require a mean flow going through the axis of the acoustic treatment. In this study different configurations of opened ABHs will be considered. Nominal ABHs build on straight cavities of increasing depth along the axial direction. To extend the bandwidth of acoustic performance towards the low frequencies, two different types of ABH silencers will be studied. Cavities with coiled geometries will be considered as a first instance, while the entrance of these cavities will be covered by micro-perforated consequently. The transfer matrix formulation will be adapted to these configurations and used to provide the ABH acoustical performance in terms of reflection and transmission of the silencer to find out the best configuration. These results will be validated against a Finite Element method and experiments will be carried out for the nominal configuration.

High-Performance Membranes Based on Spherical-Beaded Nanofibers and Nanoarchitectured Networks for Water-in-Oil Emulsion Separation.

High-performance separation materials for oil-water emulsions are crucial to environmental protection and resource recovery; however, most existing fibrous separation materials are subject to large pore size and low porosity, resulting in limited separation performance. Herein, we create high-performance membranes consisting of spherical-beaded nanofibers and nanoarchitectured networks (nano-nets) using electrostatic spinning/netting technology, for water-in-oil emulsion separation. By manipulating the nonequilibrium stretching of jets, spherical-beaded nanofibers capable of generating a robust microelectric field are fabricated as scaffolds, on which charged droplets are induced to eject and phase separate to self-assemble nano-nets with small pores. Benefiting from 3D undulating networks with cavities originating from 2D nano-nets supported by 1D spherical-beaded nanofibers, the membranes exhibit under-oil superhydrophobicity (>152°), a striking separation performance with an efficiency of >99.2% and a flux of 5775 L m-2 h-1, together with wide pressure applicability, antifouling, and reusability. This work may open up new horizons in developing fibrous materials for separation and purification.

Thermal conductivity assessment of cotton fibers from apparel recycling for building insulation

The impressive growth of the clothing market in the last decades comes along with an increase in the textile waste, nowadays mostly incinerated or landfilled. To improve the circularity of the sector, the possibility to recycle the textile waste into thermal insulation products for the building envelope has started to emerge. While the scientific literature agrees that the thermal conductivity of products based on textile waste is comparable to conventional thermal insulators, very few studies provide a comprehensive characterization of their heat transfer behavior in terms of the relevant parameters. This study focuses on post-consume cotton in the form of loose fibers with density 30, 50 and 70 kg/m3. By exploiting complementary experimental techniques, it is found that the effective thermal conductivity ranges between 0.0381 W/(m∙K) (ρ = 30 kg/m3, T = 10 °C, RH = 17 %) and 0.0546 W/(m∙K) (ρ = 50 kg/m3, T = 30 °C, RH = 80 %). The conductivity of the loose cotton fibers is predominantly sensitive to temperature and relative humidity, while the influence of density and the vertical/horizontal orientation appear less significant. These results highlight the complexity of the characterization of the thermal performance of such fibrous materials and the need to perform tests under fully controlled environmental conditions. Moreover, they are key for an accurate prediction of the performance of such insulating materials in real building operation, possibly achieved through dynamic energy simulations including heat and vapor transfer and modelling the conductivity variation with temperature and moisture.