Polyethylene Fibers Research Articles

Current research status of high-performance UHMWPE fiber: A review

In the relentless evolution of technological innovation, the incorporation of engineered materials across numerous sectors is becoming increasingly widespread. Among them, ultra-high molecular weight polyethylene (UHMWPE) fiber, as a novel type of engineered material, has emerged as a critical hot topic in industries such as aerospace, national defense, and new energy due to its exceptional physical and chemical properties. This article attempts to introduce the characteristics of UHMWPE fibers, including their advantages and areas for enhancement, to provide researchers with a comprehensive overview and research trajectory of UHMWPE. Moreover, this article succinctly elucidates the preparation methodologies and advances of UHMWPE fibers, encompassing mainstream dry and wet spinning methods, revealing their research trajectories, pivotal positions, and practical significance in the realm of engineered materials. In summary, this review briefly discusses the research overview and recent advances in UHMWPE fibers, which contribute to accelerating comprehensive and sustainable progress in this field.

Mechanical characterization of large diameter UHMWPE ropes under quasi-static tensile loading: An experimental study

The Large diameter UHMWPEFR (Ultra High Molecular Weight Polyethylene Fiber Rope) are ideal for heavy lifting and slinging, with their mechanical properties and behaviour characterisation are key to the application.Therefore, this study conducts uniaxial tensile tests on a 115 mm diameter rope (FR-115) to investigate its mechanical properties under quasi-static tensile conditions. considering the anisotropic structural characteristics of UHMWPEFR, a method and criteria for eliminating inter-strand gaps and uneven force through pre-tensioning were proposed. Subsequently, tensile tests were carried out to examine the mechanical properties and constitutive relationship of the rope. The experimental results indicate that pre-tensioning can effectively eliminate the influence of non-elastic deformation of the rope, meeting the formal tensioning requirements based on the stability criteria of the rope structure constructed from mechanical and physical parameters. The stress-strain curve of FR-115 shows a linear bilinear shape without a yield segment during the tensioning process, presenting a typical brittle failure mode. The mechanical behavior is closely related to the historical load effects and loading speed, with the rope transitioning from soft and tough to hard and brittle, exhibiting hysteresis. Based on the above analysis, the graded load and time-varying modulus parameter are fixed, and the internal force is more sensitive to the quasi-static tensile velocity; a two-stage principal model is established based on the analysis of curve characteristics and time-dependent correlation, with 50 % MBS(Minimum Break Strength) as the characterization point, and the UHMWPEFR principal relationship in the pre-period is linear-elastic, and the strain-rate effect is taken into account for the dense section, and the rate correlation and nonlinear characteristics of the dense section of the rope can be accurately portrayed with the introduction of Cowper-Symonds.

The Flexural Behavior of Reinforced Ultra-High Performance Engineering Cementitious Composite (UHP-ECC) Beams Fabricated with Polyethylene Fiber (Numerical and Analytical Study)

Ultra-high performance engineered cementitious composite (UHP-ECC), which is a new and ductile version of concrete, has attracted researchers recently due to its exceptional mechanical properties: its very high compressive strength (from 100 to 200 MPa) and very high tensile strain capacity (not less than 3% and up to 8%). However, the available experimental literature is small due to its very high cost. To overcome the high cost of the experiments of UHP-ECC, the finite element modeling package ANSYS was used to create a new modeling technique using the Menetrey–Willam constitutive model, recently added to ANSYS. This technique was validated using previous experimental results for UHP-ECC beams and found to be accurate and effective. The previous FE model was used to conduct a parametric study and the variables—the compressive strength of the concrete, the percentage of the volume content of polyethylene fibers, the tensile reinforcement ratio, and the span-to-depth ratio—were found to be effective upon the flexure behavior of the reinforced UHP-ECC beams. As the analysis and design of UHP-ECC beams fabricated with polyethylene fiber are not available yet through design codes, an analytical model including some equations was deduced to calculate the flexure capacity of such beams. The results of the parametric study were used to investigate the validity and accuracy of the analytical model. The proposed equations demonstrated a good estimation compared with the numerical analysis results.

Clinical performance of polyethylenefiber reinforced resin composite restorations in endodontically treated teeth: (a randomized controlled clinical trial)

AimThe purpose of this study was to evaluate the performance of polyethylene fiber reinforced resin composite fillings compared to bulk fill resin composite fillings in endodontically treated teeth over a two-year monitoring period.MethodA total of 240 individuals with endodontically treated lower molars and a moderate amount of tooth structure were divided into two equal groups of 120 each. One group received polyethylene fiber reinforced bulk fill resin composite restorations while the other group received only bulk fill resin composite restorations, both applied as per manufacturer guidelines. Two proficient experienced blinded assessors assessed the restorations using modified USPHS criteria at baseline, 6, 12, and 24 months.Statistical analysis usedData analysis involved the utilization of Mann-Whitney U, Friedman’s test, and Nemenyi post hoc test, with age data being displayed as mean and standard deviation. The significance level was established as p < 0.05, and R software was utilized for statistical analysis.ResultsThere were no notable distinctions in any parameters or scores between the intervention and comparator groups at various time points. Alpha scores were present for retention, gross fracture, and secondary caries at all follow up intervals.ConclusionBoth direct resin composite restorations reinforced with polyethylene fibers and direct bulk fill resin composite restorations placed in endodontically treated molars with moderate remaining tooth structure demonstrated satisfactory clinical outcomes during a 24-month follow-up period.Clinical relevanceBulk fill resin composites directly placed in endodontically treated molars with moderate remaining tooth structure showed promise as a treatment option over a two-year period.Clinical trial registration(06-01-2022) on https://ClinicalTrials.gov with the ID (NCT05180903).

The Attachment of Juvenile Mussels via Byssus Weakened by Contaminated Polyethylene Fibers

In the process of mussel farming, the rope for attachment is indispensable, as it provides a stable attachment environment for mussel seedlings, directly affecting their survival rate and growth quality. The objective of this study is to examine the contamination of ropes, composed of polyethylene fibers, by heavy metals and polycyclic aromatic hydrocarbons (PAHs) after three years of deployment and to assess its influence on the attachment and locomotion behaviors of juvenile mussels. Utilizing a laboratory simulation of the seedling wrapping process, a comparative analysis was conducted to evaluate the number of juvenile mussels attached and their movement distances when exposed to contaminated old ropes versus uncontaminated new ropes. The findings indicated that the old ropes markedly diminished the attachment rate of juvenile mussels and heightened their movement distances. In particular, juvenile mussels utilizing old ropes exhibited a final attachment rate of 15.0% and an average movement distance of 0.86 cm, whereas those using new ropes achieved a final attachment rate of 96.7% with an average movement distance of 0.26 cm. Further inspection found that heavy metals and PAHs were present in the old rope, among which the concentrations of Zn (17.127 μg/g) and Pb (22.905 μg/g) in heavy metals were high, and the concentrations of Phe (5.53 μg/kg), Fla (6.35 μg/kg), and Pyr (5.17 μg/kg) in PAHs exceeded the detection limits, which were the main source of pollution. This research underscores the potential risk that heavy metal and PAHs contamination pose to the health of juvenile mussels and the profitability of aquaculture, emphasizing the critical need for the regular replacement of clean ropes.

Interlayer bonding performance of 3D printed engineered cementitious composites (ECC): Rheological regulation and fiber hybridization

The weak interlayer adhesion caused by the layer-by-layer 3D printing (3DP) process and the incorporation of organic fiber in Engineered Cementitious Composites (ECC), detrimentally impacts the integrity of 3DP-ECC structures, particularly for large-scale structures requiring extended open time. To optimize the printing quality and extent the operation time, cellulose filaments (CF) were employed as nano-reinforcement, viscosity modifier and water retainer, and were hybridized with polyethylene fiber (PE) and steel fiber (ST). The highest bonding strength was raised up to 3.51 MPa. The time-dependent escalation of rheological parameters was mitigated, reducing interlayer porosity to 0.56 % and limiting the reduction in bonding strength to 12.01 % within 60 min open time. The compressive anisotropy was almost eliminated, verifying the potential of CF in modifying interlayer adhesion. A linear correlation between rheological behavior and interlayer bonding performance was established, and a 0.508 Pa s/min plastic viscosity growth rate was suggested to avoid cold joint and ensure printing quality.

Integrative models for environmental forecasting of phthalate migration from microplastics in aquaculture environments

The pervasive utilization of plastic tools in aquaculture introduces significant volumes of microplastic fibers, presenting a consequential risk through the leaching of additives such as phthalates. This study scrutinizes the leaching dynamics of six prevalent phthalate esters (PAEs) from thirteen plastic aquaculture tools comprising polyethylene terephthalate (PET), polypropylene (PP), and polyethylene (PE), with ΣPAEs ranging from 0.24 to 4.26 mg g−1. Di(2-ethylhexyl) phthalate (DEHP) and dibutyl phthalate (DBP) emerged as predominant, marking significant environmental concern. Over a 30-day period, leaching quantities of Σ6PAEs from PET, PP, and PE fibers reached 36.65 μg g−1, 21.87 μg g−1 and 19.11 μg g−1, respectively, influenced by factors such as time, temperature, turbulence, and salinity. Notably, turbulence exerted the most pronounced effect, followed by temperature, with negligible influence from salinity. The kinetic models aligning with interface diffusion control was developed, predicting PAEs' leaching behavior with activation energies (Ea) indicative of the process's thermodynamic nature. The application of this model to real-world aquaculture waters forecasted significant risks, corroborating with empirical data and underscoring the pressing need for regulatory and mitigation strategies against PAEs contamination from aquaculture practices.

Multidisciplinary space shield origami composite: Incorporating cosmic radiation shielding, space debris impact protection, solar radiative heat shielding, and atomic oxygen erosion resistance

Origami composites have been extensively utilized in space structures with constrained payload volumes due to their capability to efficiently transform compact structures into larger surface area or volume configurations. The proposed origami composite incorporates hydrogen-rich benzoxazine polymers known for their high radiation shielding capability and ultra-high-molecular-weight polyethylene fibers known for their high ballistic performance, radiation shielding capability, and flexibility. The proposed origami composite and manufacturing method can enhance bonding strength by achieving precise origami shapes and utilizing the same matrix for both flexible and rigid components. Membrane sheets are manufactured at a low curing temperature to provide flexibility, while rigid facets are separately manufactured at a high curing temperature to increase rigidity. The integration of a polyimide protection layer significantly enhances space environment resistance and reduces mass loss due to atomic oxygen erosion. Despite a slight decrease in ballistic performance after exposure to space conditions, the proposed origami composite maintains superior ballistic performance compared to conventional space materials and conventional origami composites. Compared to existing origami composites or conventional space materials, the proposed origami composite exhibited superior radiation shielding performance. The laminated structure of the proposed origami composite can offer some solar radiation shielding capability. The proposed origami composite offers a multifunctional origami solution as a membrane-space shield material, fulfilling requirements for high ballistic performance, cosmic radiation shielding, solar radiative heat shielding, and space environmental resistance.

Facile fabrication of luminescent ultra‐high molecular weight polyethylene fibers based on novel alkyl‐substituted 1,8‐naphthalimide fluorescent dyes

AbstractUltra‐high molecular weight polyethylene (UHMWPE) fiber, with excellent light resistance, and chemical resistance, is one of the most important high‐performance fibers. However, the high hydrophobicity and crystallinity make it difficult to color, restricting the development of colored fluorescent UHMWPE protection materials. In this study, three hydrophobic fluorescent dyes (NC4, NC8, NC16) for fluorescent dyeing of UHMWPE were developed by introducing alkyl substituents of different lengths (butyl, octyl, and hexadecyl) and polar cyano groups onto 4‐NH‐1,8‐naphthalimide fluorescent chromophore. The relationship between the structures and the application performance was studied, and theoretical calculations were combined to explore the influence of the substituents on the spatial and electronic effects of fluorescent dyes. With the extension of the alkyl chain, the dye‐uptake rate and building‐up property was enhanced, and the equilibrium dye‐uptake rates for NC4, NC8, and NC16 were 18.21%, 93.22%, and 62.96%, respectively. NC8, which was proven to have high hydrophobicity and maximum dipole moment, exhibited the highest dye‐uptake rate. The dyed UHMWPE fabrics exhibited strong yellow‐green fluorescence. This study provides a facile strategy for constructing luminescent UHMWPE protection materials.

Soluble Polyimide Coated UHMWPE Fibers with Multiple Property Enhancements: Surface Activity, Tensile Strength, Heat Resistance, Acid Resistance, and Erasability.

Ultrahigh molecular weight polyethylene (UHMWPE) fibers possess excellent mechanical properties, yet their applications are severely limited by surface inertness and low melting points. To enhance surface activity and temperature resistance, soluble polyimide (PI) is applied to the surface of UHMWPE fibers. A mussel-inspired biomimetic polycatechol/polyamine (PA) coating is initially constructed on the UHMWPE fiber surface by oxidative self-polymerization, serving as a secondary reaction platform. Subsequently, multifunctional UHMWPE-PA-PI fibers are prepared by depositing soluble PI on the fiber surface via impregnation. The PA and PI layers are firmly bonded by hydrogen bonding interactions and physical adhesion. The results show that the PI-coated UHMWPE fiber surface exhibits enhanced chemical activity, hydrophilicity, and thermal stability, with an increased thermal decomposition temperature of approximately 30 °C. Compared to pristine UHMWPE, the breaking force of UHMWPE-PA-PI fibers increases by 14.9%, and the interfacial adhesion strength between the fiber and rubber improves by 65.5%. The PI coatings also provide thermal insulation, acid resistance, and erasability functionalities. This modification strategy is highly efficient, simple, and less damaging, offering a novel solution to address UHMWPE fibers' surface inertness and temperature intolerance.

Ultraviolet cross‐linked ultra‐high molecular weight polyethylene fiber laminate: Preparation and mechanism analysis for its excellent mechanical properties

AbstractThe development of high‐performance ultra‐high molecular weight polyethylene (UHMWPE) fiber laminate is of great significance in the field of bulletproof materials. However, due to the poor heat resistance of UHMWPE fibers, it is challenging to achieve exceptional mechanical properties in laminates prepared via hot‐pressing. In this study, we employ a self‐made ultraviolet (UV) cross‐linked fully drawn yarn of UHMWPE (UVFDY), which exhibits excellent heat resistance, to prepare a UVFDY/unsaturated polyester resin (UPR) laminate through hot‐pressing. The laminate possesses outstanding mechanical properties, which includes high Barcol hardness (~40 HBa), high tensile strength (~800 MPa), and high storage modulus (~13.7 GPa at 25°C), surpassing those of most conventional UHMWPE fiber laminates. Its remarkable mechanical properties are primarily attributed to the highly cross‐linked networks of cured UPR and the stable structures (gel content ~89%, crystallinity ~81.5%, orientation ~93%, and smoother fiber surface) of UVFDY during hot‐pressing. This work not only provides valuable insights into the preparation of high‐performance UHMWPE fiber laminates but also promotes applications for the self‐made UV cross‐linked UHMWPE fiber.Highlights Novel laminate possesses high Barcol hardness. The tensile strength and storage modulus of novel laminate are excellent. UV irradiated fiber with high structural stability during hot‐pressing.

Enhanced thermal conductivity of UHMWPE by coating boron nitride and polyurethane composites

The development of textile wearable electronics has increased demands and requirements for thermal management materials due to integrated and miniaturized soft equipment. In this work, the surface of ultrahigh molecular weight polyethylene (UHMWPE) fibers was first decorated by polydopamine (PDA) to improve the surface activity and construct a steady interface layer. Then the boron nitride/polyurethane coating surface modified UHMWPE composite yarns with good thermal conductivity were produced using a coaxial wet forming process. The thermally conductive composite yarns demonstrated great mechanical properties (5.09 % strain, 0.79 N/tex strength) and thermal conductivity (0.54 ± 0.02 W·mK−1) with the BN/PU weight ratio of 1. Furthermore, the resistance to failure cycles was taken place, and the composite yarns kept good thermal conductivity after multiple cycles twisting, bending, washing, cooling and heating cycles. By the coaxial wet fabrication, the thermally conductive composite yarns were constructed, offering a viable and trustworthy method for creating polymer-based thermal interface materials with high thermal conductivity.

Hybridization of Carbon Fiber Using Ultra-High-Molecular-Weight Polyethylene Fibers: How It Affects Density, Bending, and Impact Strength

Hybridization of Carbon Fiber Using Ultra-High-Molecular-Weight Polyethylene Fibers: How It Affects Density, Bending, and Impact Strength

Temporary splinting in periodontally mobile teeth: review before application

Introduction Temporary splinting of mobile, periodontally compromised teeth is an important stage in the complex treatment of periodontitis, used to improve mastication, aesthetics, and the prognosis for teeth with pathological mobility. It helps prevent this phenomenon and consolidate the success of conservative and surgical treatment, which also has a positive effect on the patient's psycho-emotional state. Material and methods 12 patients (6 female and 6 male), aged 26–60 years, with pathological teeth mobility due to chronic generalized periodontitis, were included in the study. Temporary splinting was performed using fiberglass threads braided with polyester microfibers, polyethylene fibers, and aramid fibers, and in all clinical cases, it was secured with photo-composite material designed for teeth splinting. Results Temporary splinting is a very important step in periodontitis treatment, and dynamic monitoring is necessary throughout the entire period of splinting. The interval between visits is determined based on the type of splinting, the risk of complications, the severity of periodontitis, systemic and local factors, the level of individual oral hygiene, and the patient's motivation. The interval can be 6 months, 4 months, or, in aggressive forms of periodontitis, 2 months. Conclusions Temporary splinting contributes to the effectiveness of pathogenetic and symptomatic therapy.

Posterior direct composite restorations reinforced with polyethylene fiber

Posterior direct composite restorations reinforced with polyethylene fiber

Effects of aggregates and fibers on the strength and permeability of concrete exposed to low vacuum environment

The performance and regulation of concrete in low vacuum environments are receiving increasing attention. This study investigates the effects of aggregates and fibers on the strength and permeability of concrete in a low vacuum environment, using varying gradients of sand ratios (37.5 %, 40 %, and 42 %) and aggregate-to-binder ratios (3.27, 3.92, and 4.14). Three types of non-metallic fibers are utilized: polyethylene (PE), polyvinyl alcohol (PVA), and glass fibers. Evaluations focus on concrete strength, mass loss, gas permeability, capillary water absorption, and porosity. Results indicate that higher sand and aggregate-to-binder ratios enhance both flexural and compressive strength. Fiber incorporation improves flexural and compressive toughness, with PE fibers showing the most significant toughening effect. The low vacuum environment increases the strength of the concrete but reduces its axial compression toughness ratio and increases brittleness, while fiber incorporation helps improve the compression toughness of the concrete. Higher sand and aggregate-to-binder ratios reduce mass loss and accelerate drying equilibrium, while fibers increase mass loss and prolong drying equilibrium, with PVA fibers causing greater mass loss. The pattern of concrete mass loss can be explained by the tortuosity of the moisture diffusion path. Additionally, low vacuum significantly increases the gas permeability of concrete. Enhancing the sand and aggregate-to-binder ratios reduces permeability both before and after low vacuum treatment. Although fibers increase the gas permeability, they help mitigate this increase under low vacuum condition. Capillary water absorption tests reveal that concrete under low vacuum condition has a significantly higher water absorption rate compared to air-drying condition. Increasing sand and aggregate-to-binder ratios reduces water absorption and capillary water content, whereas fibers have the opposite effect. Porosity tests show that moisture migration in a low vacuum environment is mainly related to permeable porosity, while total porosity is more closely related to compressive strength.

A Novel Approach to Modified Polyethylene Fibres with Size Effect in Cement Mortar

A Novel Approach to Modified Polyethylene Fibres with Size Effect in Cement Mortar

Self-sensing function and thermoelectric effect of engineered cementitious composites (ECC) with porous structures

This study investigates the self-sensing and thermoelectric mechanism of ultra-lightweight engineered cementitious composites (ULW-ECC) with porous structures by comparing seven different mixtures. Porous structures based on fly ash cenosphere (FAC) and polyethylene (PE) fibre are compared with those formed solely by individual materials (air-entraining admixture (AEA), FAC, PE fibre), as well as dense structure (pure cement). Mechanical properties, electrical conductivity, thermal conductivity, and self-sensing capabilities (compression, bending, and tension) were systematically tested. Additionally, thermoelectric behaviours were examined under various treatment methods (normal state and leaching treatment) and electrodes. Scanning electronic microscope (SEM) and mercury intrusion porosimeter (MIP) analysis were conducted to explain the self-sensing and thermoelectric mechanism of ULW-ECC. Results indicate that achieving self-sensing functionality in cementitious composites without conductive fillers and other special treatments is feasible through the creation of a porous structure, with enhanced performance corrected with increased porosity. Such porous structure can be achieved using high-volume FAC, PE fibres, and AEA either independently or in combination. Furthermore, cement-based composites exhibit ionic thermoelectric performance, with efficiency influenced by mineral admixtures, porosity, specific porous area, electrode types, and leaching treatment. The ionic Seebeck coefficient increases with higher porosity and specific surface area, resulting in ULW-ECC with a porous structure demonstrating a superior ionic Seebeck coefficient compared to pure cement. This study provides novel insights into the versatile applications of ULW-ECC and other cement-based composites.

Carbonation resistance of fly ash/slag based engineering geopolymer composites

Engineering geopolymer composites (EGC) are promising environmentally friendly building materials with excellent mechanical properties. However, the durability of EGC is compromised by gradual carbonation from atmospheric exposure. For the first time, this study provided an insight of the carbonation of EGC by comprehensively investigating the effect of mix design, such as fly ash/ground granulated blast furnace slag ratio (FA/GGBS ratio), alkali content, water/binder ratio (W/B ratio) and polyethylene (PE) fibre content, on its carbonation resistance. Our results showed the components in EGC affected the carbonation through the alternation of microstructures. An increase of FA content and W/B ratio significantly increased the carbonation depth by 206.6 % and 116.3 % respectively due to the increased porosity and transition pore fraction, resulting in more than 30 % reduction in tensile strength and 15 % reduction in compressive strength. However, increased alkali and fibre content prevent carbonation with around 60 % and 26 % decrease of the carbonation depth, leading to a less loss of the mechanical properties. Furthermore, we tested the pH values of the EGC along the carbonation depth, proposing a novel approach to assess the carbonation degree by dividing the area into completely carbonated area (pH around 9.21–10.44) and non-carbonated area (pH around 12.58–13.37). These findings provide insights for mitigating carbonation effects in EGC and facilitate the widespread use of this sustainable material in construction applications, ensuring long-term durability and reliability.

Chloride permeation resistance of sulphoaluminate cement-based composite characterized by both alternating current section and RCM methods

Sulphoaluminate cement (SAC) was widely used for rapid repair and strengthening of building structures due to its excellent quick hardening and high early strength behavior. This study developed a SAC-based engineering cement composites (ECC) with ultra-high molecular weight polyethylene (UHMWPE) and investigated its mechanical properties. Chloride ion permeability coefficient were evaluated by new alternating-current sectioning and rapid chloride migration (RCM). The mechanism of the SAC-ECC against chloride erosion were quantified using nitrogen isothermal adsorption. The results show that the fracture energy, tensile strength and strain of SAC-ECC samples are higher than that of normal ECC. The polyethylene (PE) fiber could significantly improve the flexural strength and toughness with PE fiber content of 0.75 % by volume. The hydration products generated could react with chloride ion to make it chemically stabilized, leading to reduce the chloride ion diffusion coefficient significantly. Based on microscopic analysis (SEM), the pore structure in SAC-ECC composite improved remarkedly while the volume of harmful pore decreased evidently as well. SAC-ECC developed in this paper could be poetically applied to strengthening and repair of marine concrete structures.