Fiber Reinforced Polymers (FRP) Systems are the most advanced systems in structural repair and strengthening field for their minimal time of application, limited space needed, and high durability. However, FRP systems still have a major drawback that limits their utilization in many projects, namely low fire-resistance. A novel material that was introduced lately with a substantial thermal performance is Aerogel, which has been widely utilized in other fields. This study attempted to develop fire-protective plaster incorporating nano silica-aerogel particles and phyllosilicates. During the experimental process, different surfactants were assessed as wetting agents, and their impact on both cement and mineral matrices. Finally, the selected plaster was evaluated under fire conditions. The results reveal that aerogel incorporation in mineral (gypsum) matrix was successfully achieved using various types of surfactants. The mechanical and thermal performance of the developed plasters were promising, with a fire-rating performance reaching 82 minutes for FRP system.