Ferromagnesian Minerals Research Articles

The Petrochemistry and Origin of Precambrian Gneisses around Madaka and Kwana-Bala Area, North Central Nigeria

This paper discusses the petrochemistry and origin of gneisses within basement complex of Nigeria around Madaka and Kwana-Bala area. The lithological units of rocks from Madaka and Kwana-Bala area comprises of gneisses (migmatitic, banded, granitic), kyanite-sillimanite schist, semi-pelitic schist, amphibolites, talcose rock, quartzite, phyllite, granodiorite, fine-medium-grained granites and porphyritic granite. Seven samples of gneisses were analyzed for major element oxides using (ICM-MS). The gneisses are often variable in colour which depending on the nature and proportion of the feldspar and the ferromagnesian minerals. The variation in textures of these rocks from study area is due to varying size and amount of the K-feldspar porphyroblasts couple with varying degree of foliation. In thin section, the characteristics granoblastic textures were observed in migmatitic and granitic gneisses. The mineral compositions of the gneisses rocks are variable, the common minerals assemblage includes: migmatitic gneiss quartz + plagioclase +microcline +biotite + chlorite +garnet, banded gneiss: quartz + plagioclase+ muscovite +biotite+sphene +chlorite+ garnet and granitic gneiss contain quartz +plagioclase+microcline + muscovite+ biotite + chlorite +garnet + opaque minerals. The gneisses of the study area are product of reworked rocks during the Pan-African with a positive DF values, this suggests igneous sources for the protoliths of these rocks in the study area. The chemistry of the gneissic rock also show a variable proportion of Na2O and K2O with alkali-calcic affinity, which suggests, a closed system behaviour during metamorphism on one hand, and possibly a co-magmatic origin of the igneous protolith on the other hand.

Potential engineering applications of volcanic scoria from Mount Cameroon area, Central Africa: evidence from petrography and geochemistry

This study was initiated to explore the suitability of volcanic scoria from Mount Cameroon along the Cameroon Volcanic Line (CVL) in engineering applications. The mineral composition has been obtained through thin sections observation and XRD method. The XRF analytical methods have been used to determine major element composition. The studied rocks are dark gray to reddish in color with a vacuolar structure and porphyritic microlithic texture recalling the Strombolian dynamism. They are mainly made up of pyroxene, olivine, plagioclase, opaque minerals, quartz, magnetite and iddingsite. The presence of phenocrysts of olivine and clinopyroxene is due to mantle contamination. The main chemical components of scoria of Mount Cameroon are silica, alumina, iron and calcium oxides. The abundant vitreous phases are responsible for the acidic character revealed by high SiO2 + Al2O3 contents. Fe2O3, MnO and MgO are hosted by ferromagnesian minerals while SiO2, Al2O3, K2O, NaO and P2O5 are found in acidic vitreous phases. The mineral and chemical composition of the scoria of Mount Cameroun is similar to those of scoria previously studied around the world. They can be used as absorbents for metals because of their high adsorption capacity and affinity for metals. The high SiO2 + Al2O3 + Fe2O3 contents and low LOI values show that the scoria from Mount Cameroon are suitable to the use in cement and concretes. They can improve the resistance to sulfate, and chlorite and alkali silica reaction. According to the chemical composition, the rocks are conforming to French standard NFP18310. Their high CaO contents are favorable to improve the quality of scoria blended cements.

Chemistry of biotite as petrogenetic discriminators of plutonic and volcanic granitoids from south-central Côte d’Ivoire, West Africa

Chemical compositions of biotite have been used to understand the petrogenesis of intrusive and extrusive magmatic rocks. Central southern Côte d’Ivoire is home to a wide variety of lithologies, including granodiorites, tonalites, and dacites. In this paper, we compare biotites from intrusive rocks with those from extrusive rocks. We used the composition of the mineral to describe the nature of the granitic magma and estimate the temperature at which the studied rocks were emplaced. Grano- diorite and tonalite are composed of biotite, hornblende, plagioclase, apatite, magnetite, and ilmenite. Dacite contains the minerals biotite, muscovite, quartz, and plagioclase. This work has shown contrasts in composition between biotites. The biotites in the intrusive rocks are muscovite-free. Some of these biotites coexist with amphiboles, while others are not accompanied by other ferromagnesian minerals. Some biotites in extrusive rocks are not accompanied by ferromagnesian minerals, while others coexist with muscovite. Extrusive rock biotites do not contain amphiboles. The major elements of the biotites show that they are located between the annite and siderophyllite poles. However, biotites in granodiorites and tonalites are rich in AlIV, giving them a siderophyllite tendency, while biotites in extrusive rocks, which are low in AlIV, converge towards the annite pole. The biotites in the intrusive rocks studied are rich in Mg (Mg-biotite) and Ti, while the biotites in the extrusive rocks studied appear to be rich in Fe (Fe-biotite) and Mn. Plutons could have formed in an orogenic setting from calc-alkaline magma in a subduction environment. Volcanic rocks are peraluminous. The intrusive rocks derive from I-type granites, while extrusive rocks appear to derive from S-type granites. Based on the incorporation of Ti into biotites, the rocks studied were emplaced in a temperature range estimated at 550-650°C at a pressure of 4-6 kbar.

Constraints of chemical and physical properties of soil on the growth of revegetation plants on ex-nickel mining land

The chemical and physical properties of soil as a planting medium in ex-mining land reclamation areas play an important role in supporting successful revegetation. This study aims to study the properties of soils in the reclamation area of a former nickel mine which is thought to be a factor inhibiting plant growth. Undisturbed and disturbed soil samples were taken in the reclamation area and the natural environment at depths of 0-30 cm and 30-60 cm. Soil sample analysis includes pH, organic C, total N, available P and potential P reserve, cation exchange capacity (CEC), base saturation, micronutrients, texture, bulk density, permeability, and pF curve. Soil biological properties are represented by the number of mycorrhiza parameters. Several plant leaf samples were also taken for analysis of N P K Ca Mg S and micronutrient content. The results showed that the soil in the reclamation area has several anomalous properties that cause the growth of revegetation plants to be hampered, i.e. the soil pH is slightly acidic to neutral, the CEC is very low due to a positive net charge, the exchangeable Ca/Mg ratio is less than 1, the levels of elements that are potentially toxic to plants are quite high, and the distribution of soil particles is dominated by silty size. These properties are closely related to iron oxides in the soil as a result of chemical weathering of ferromagnesian minerals contained in ultramafic rocks which are the parent material of the soil.

Soil fertility based on mineralogical properties to support sustainable agriculture management

<p>Detailed information on soil mineral composition has been crucial in providing the basis for designing sustainable agricultural practices, as this information offers long-term insights into natural soil fertility. This research aimed to further investigate the characteristics of soil mineral composition as a basis for managing soil fertility. Three soil profiles representing three different parent materials have been examined in the field, and soil samples have been collected for laboratory analysis. Profile 1 originates from the Raung Volcano Rock Formation (Qhvr). Profile 2 originates from the Sukamade Formation (Toms). Profile 3 originates from Puger Formation (Tmp). The presence of Mount Raung volcanic influence results in distinct soil characteristics in Profiles 2 and 3 compared to typical sedimentary and karst rock soils. The sand fraction minerals in all three profiles are predominantly composed of opaque minerals, followed by rock fragments, ferromagnesian mineral series (olivine, augite, hypersthene, and hornblende), plagioclase minerals (anorthite, biotite, and labradorite), iron concretions, epidote, and tourmaline. The clay fraction minerals in all three profiles consist of illite, kaolinite, and quartz. The minerals illite and ferromagnesian groups in all three profiles play a significant role in increasing the availability of potassium, calcium, and magnesium nutrients, thereby reducing the need for fertilizers for these elements. The soils in all three profiles naturally possess good fertility; however, designing a sustainable agricultural system requires consideration of the morphology, landform, and climate of all three profiles.</p>

Late Neoproterozoic alkaline intrusives in Huqf sediments; a new reservoir target in southern Oman

Abstract Recent drilling in Block 56 on the southern Oman coast NE of Salalah has revealed the presence of intrusive rocks in Huqf sediments. The igneous bodies are found as both discrete and composite, decametre scale sills separated by screens of Huqf host rock. Compositionally they form a cogenetic suite of monzonites and syenites that can be related by fractional crystallization to a gabbro–diorite parental magma. Enrichment in alkalis and other large ion lithophile elements points to either an enriched mantle source or magma-crust interaction on ascent. Geochemical profiles match closely those of the latest Neoproterozoic alkaline eruptives now found as exotic volcanic blocks entrained in the salt diapirs of the Ghaba Salt Basin. Limited geochronological data indicate that the Block 56 intrusives are contemporaneous and derived from the same magma source. Porosities in excess of 10% have been recorded in the intrusives; it is a dissolution porosity created by volume loss during the conversion of primary ferromagnesian minerals to biotite and ferroan dolomite. Porosity creation took place during a short lived, fault-controlled Cretaceous hydrothermal event contemporaneous with uplift and alkaline volcanic activity in the Masirah Ophiolite. The intrusives contain a Huqf-sourced oil with light to medium viscosity appearance. Charging is believed to be coming from the cooler and shallower parts of the South Oman Salt Basin to the north and from beneath thick Cenozoic cover in the basin to the south.

Exploring Rare Earth Element behavior in the Mount Etna volcanic aquifers (Sicily)

This study presents the first data on REY (Rare Earth Elements plus Yttrium) in the aquifer of Mount Etna (Sicily, Italy). Patterns normalized to chondrites indicate strong water–rock interaction, facilitated by a slightly acidic pH resulting from the dissolution of magma-derived CO2. REY patterns provide insights into the processes of both mineral dissolution and the formation of secondary phases. The relative abundance of light to heavy rare earth elements is compatible with the prevailing dissolution of ferromagnesian minerals (e.g., olivine or clinopyroxenes), reinforced by its strong correlation with other proxies of mineral dissolution (e.g., Mg contents). Pronounced negative Ce anomalies and positive Y anomalies demonstrate an oxidizing environment with continuous formation of secondary iron and/or manganese oxides and hydroxides. The Y/Ho fractionation is strongly influenced by metal complexation with bicarbonate complexes, a common process in C-rich waters. In the studied system, the measured REY contents are always below the limits proposed by Sneller et al. (2000, RIVM report, Issue 601,501, p. 66) for surface water and ensure a very low daily intake from drinking water.

The First (and Second) Known Occurrences of Bazzite in Canada – The Quadeville Rose Quartz Quarry, Ontario, and the Bugaboo Castles Aquamarine Deposit, British Columbia – Description and Crystal Structure

Abstract Bazzite, ideally Be3Sc2Si6O18, has been discovered for the first time at two granitic pegmatite localities in Canada: the Quadeville Rose Quartz quarry, Ontario (Bz-ON/CMNMC 90604), and the Bugaboo Castles aquamarine deposit, Purcell mountains, British Columbia (Bz-BC/CMNMC 90725). Bazzite from both Canadian localities occurs as colorless, hexagonal prismatic to acicular crystals up to 0.6 mm in length. The crystal chemistry and structure of the two samples, Bz-ON and Bz-BC, was determined and compared with bazzite from other known occurrences. The average composition of Bz-ON is Be2.99(Sc1.39Mg0.37Fe3+0.10Fe2+0.09Al0.06Mn0.01)Σ2.02Si5.99O18·[Na0.47(H2O)], and that of Bz-BC is Be3.00(Sc1.43Fe2+0.28Mg0.20Al0.05Fe3+0.03Mn0.01)Σ2.01Si6.00O18[(Na0.46Cs0.01)Σ0.47(H2O)]. Bazzite from the Quadeville Rose Quartz pegmatite contains Mg = 0.33–0.41 (avg. 0.37) apfu, Fe3+ = 0.00–0.18 (avg. 0.10) apfu, and Fe2+ = 0.05–0.13 (avg. 0.09) apfu, whereas bazzite from Bugaboo Castles is more Fe2+-rich, with Fe2+ = 0.19–0.38 (avg. 0.28) apfu, Mg = 0.16–0.22 (avg. 0.20) apfu, and Fe3+ = 0.00–0.08 (avg. 0.03) apfu. Both samples have low Al, Mn, Ca, and Cs contents and, compositionally, are more similar to bazzite from alpine fissures and orogenic pegmatites than that from more common anorogenic NYF pegmatites. Bazzite from Canada is hexagonal, P6/mcc, with unit cell parameters a = 9.52741(14), c = 9.19326(15) Å for Bz-ON and a = 9.54396, c = 9.16495(20) Å for Bz-BC, respectively. The structure is composed of SiO4 tetrahedra that share corners to form Si6O18 rings perpendicular to the c axis. Each Si6O18 ring is linked via corners to a 12-membered ring of edge-sharing BeO4 tetrahedra and AO6 octahedra (A), resulting in channels parallel to the c axis (2a and 2b sites). Voids in the channels contain H2O (2a) and large alkali cations (Na, 2b). Both Bz-ON and Bz-BC have fully occupied 2a sites and 2b sites which are 50% occupied by Na. Increased substitution of the smaller cations Mg ([6]r = 0.72 Å) and Fe3+ ([6]r = 0.65 Å) for Sc ([6]r = 0.75 Å) results in significant changes in the bazzite structure, including a decrease in the <A–O> distance and decreased distortions (compression) in the AO6 and SiO4 tetrahedra. Bazzite from Quadeville and Bugaboo Castles are late-stage minerals, the product of breakdown of beryl and/or bertrandite and a Sc-bearing mineral. At Bugaboo Castles, bazzite is the result of alteration of Sc-rich spessartine (up to 3000 ppm) and primary beryl by late-stage OH-bearing fluids. At Quadeville, the source of Sc for bazzite is less evident and suggested to be Sc-bearing columbite-group minerals (up to 0.23 apfu Sc), or primary ferromagnesian minerals.

Understanding the crustal architecture beneath the Bangui magnetic anomaly and its interactions with central African tectonic megastructures based gravity and magnetic analysis

The Bangui magnetic anomaly (BMA) in Central Africa is one of the largest continental magnetic anomalies on Earth in terms of amplitude and lateral size. Determining the sources of the BMA can lead to an increased understanding of the crustal dynamic in the Central African sub-region and the African continent as a whole. Magnetic and gravity analysis-based derivative, two-dimensional forward modelling and a Curie isothermal depth, showed that (a) the bottoms of the magnetic sources were between 15 and 35 km; (b) the BMA is a coalescence of several anomalies that trend E-W and roughly NE-SW. These directions coincide with regional Pan African-aged shear zones along the Central African orogenic belt and to thrust sheets at the northern edge of the Congo Craton. The depth of magnetization does not exceed 35 km with the amplitude of magnetization becoming smaller in the Central African Republic. The potential magnetic susceptibility sources have an average density of 2850 kg/m3 and magnetic susceptibilities between 0.06 and 0.25 SI. The BMA is interpreted to be a combination of middle and lower crustal bodies that are not continuous and consist of magnetic mineral rich granulites and banded iron formations. The gravity and magnetic modelling indicate that the entire crust was involved in the Pan African collisional event similar to what is seen in the Mozambique belt in East Africa. Combined with geological and geochemical studies, the models add evidence that one or two subduction zones were involved in accreting terranes on the northern edge of the Congo Craton. The tectonic accretions caused a crustal remobilization along major shear zones that has locally contributed to a probable circulation of fluids enriched in ferromagnesian minerals during late Neoproterozoic magmatism that created the BMA sources.

Syenites

Syenites are felsic plutonic igneous rocks characterized by the lack of quartz (<5 percent) or feldspathoids (<10 percent), although quartz syenites have 5–20 percent quartz. Typically they consist of feldspars, predominantly alkali feldspar with minor ferromagnesian minerals, usually pyroxene, amphibole or biotite. Syenites are overwhelmingly rocks of extensional environments and generally occur in areas of continental rifting, such as the African Rift Valley, and also on oceanic islands, such as the Canary archipelago. The extrusive equivalent of syenite is trachyte. As examples, we will look at two plutonic complexes containing syenites: the little‐known Kangerlussuaq intrusion in East Greenland and the more familiar Larvik Plutonic Complex in the Oslo region of Norway. Syenites occur in association with both oversaturated (quartz syenites and granites) and foid‐bearing rocks (typically nepheline syenites). Agpaitic syenites are highly evolved types with titano‐zircono‐silicates such as eudialyte. Syenites find use as dimension stones and countertops.

Petrography study of the recent sediments in Hareer’s region at Basrah Governorate - Southern Iraq

Two sites of Hareer’s region is located in the southern part of Iraq, specifically in the northern Basrah Governorate. The sites are at a depth of 5 meters. The results of heavy mineral analysis showed that there are fifteen types include; Opaque grain (Iron Oxide), Chlorite, Muscovite mica, Biotite, Orthopyroxene, Clinopyroxene, Amphibole (Hornblende and Actinolite), Epidote, Garnet, Kyanite, Staurolite, Zircon, and Tourmaline. On the other hand the light minerals and the results of the mineral analyses revealed that they were primarily composed of rock fragments, with a variety of quartz minerals, feldspar minerals, evaporate minerals, clay-coated grains, and trace amounts of unidentified minerals. The abundance and diversity of heavy minerals indicate the diversity of the sources of the parent rocks, such as igneous, metamorphic and sedimentary rocks. The large amount of opaque and small amount of other minerals in the study area samples is due to the oxidation process where many of the ferromagnesian minerals such as pyroxenes, and hornblende decompose to form iron oxides (e.g. hematite, limonite). Light minerals were visible as irregular, sharp, or occasionally semi-sharp crystalline forms, which suggests that the sources were close by and that the light minerals originated from the sedimentary basin or within it through the processes of deposit erosion and re-deposition. The study area, which is a part of the Undissected Arc, is primarily distinguished by a high content of quartz (mono- and polycrystalline quartz, including chert), and feldspar, which can occur in fluvial environments.

Distribution of soil minerals along the toposequence of Hyang-Argopuro Volcanic Mountain, Jember, Indonesia

The study was conducted in the Hyang-Argopuro volcanic mountain in Jember, Indonesia, with the aim of assessing the distribution of soil minerals along a toposequence and their relationship to soil genesis. Three soil profiles representing the upper, middle, and lower slopes of the toposequence were analyzed. The results revealed that the predominant sand minerals in the soils are opaque minerals, weatherable minerals, amphibole groups, and ferromagnesian minerals. The presence of magnetite, primarily found in the soil profile on the upper slope, suggests the effect of the well-drained topography on its formation. Clay mineral analysis showed that halloysite dominates in soil profile 1, along with traces of gibbsite and cristobalite in the surface horizon. Soil profile 2 is characterized by a combination of halloysite and illite, while kaolinite and illite dominate in soil profile 3. The presence of illite in these soils aligns with previous studies conducted in volcanic regions. The degree of soil development follows the sequence: Soil Profile 2 > Soil Profile 1 > Soil Profile 3. This corresponds to the soil classification, where soil profile 3 is classified as an Alfisol, soil profile 1 as a Mollisol, and soil profile 3 as an Inceptisol. The Andic properties, such as low bulk density and high pH in NaF, observed in soil profile 1 suggest its development from an Andisol. Overall, the study findings highlight the significant influence of basaltic andesite parent material, mountainous topography, and warm and wet climate on the mineral composition and development in the area.

Petrogenesis of early Paleozoic peraluminous A-type granites from southern China

ABSTRACT Early Paleozoic A-type granites in South China are rare, and their petrogenesis is still highly debated. This study focuses on the controversial Epo pluton in the Wuyi-Yunkai Orogen and conducts petrological and petrogeochemical research to discuss its origin. The Epo granites were emplaced at approximately 414 Ma and exhibit petrological and geochemical features of A-type granites. They contain only one ferromagnesian mineral, ferrum biotite. The granites mostly have high alkalis contents (Na2O + K2O = 6.48–8.85 wt.%), high field strength element (HFSE) contents (Zr + Nb + Ce + Y = 353–461 ppm), and high Ga/Al (104×Ga/Al = 2.50–3.72) and FeOT/(FeOT + MgO) (0.74–0.85) ratios. Besides, they formed under high-temperature (>850°C) and low-pressure (≤5 kbar) conditions. Their high A/CNK (average 1.20) and Eu/Eu* (average 0.46) values as well as Sr (average 128 ppm) and Ba (average 628 ppm) contents but relatively low Zr contents (approximately 200 ppm) further suggest a strongly peraluminous A-type affinity, a distinctive subtype of A-type granites. The Epo granites display enriched Sr-Nd-Hf isotope compositions with a whole-rock87Sr/86Sri average ratio of 0.712, whole-rock εNd(t) values ranging from − 8.9 to − 7.6, and zircon εHf(t) values clustering at − 8. Their two-stage Nd and Hf isotope model ages are 1.7 Ga to 2.0 Ga, suggesting ancient crustal sources. Furthermore, Nb/U (average 7.46), Ce/Pb (average 4.06) and other trace element ratios indicate negligible contributions from juvenile mantle materials. Our data on the Epo pluton, coupled with other contemporary A-type granites in South China, suggest that the high-temperature melting of metasedimentary basements generated strongly peraluminous A-type granites, while the involvement of metaigneous rocks or mantle-derived magmas resulted in metaluminous to weakly peraluminous A-type granites. Source diversity leads to different aluminium saturations. The heat required to produce high-temperature A-type magmas was supplied by upwelling mantle-derived magma in a postcollisional extensional setting.

Provenance of Beach Sands in the Northern Gulf of Guinea, SW Cameroon

Abstract Petrographical, mineralogical and geochemical studies were carried out on the beach sands of Limbe (South-West Cameroon) to highlight their provenance, source rocks alteration and the tectonic framework. The Limbe beach sediments were classified as sandy litharenite type. The sediments were derived from mafic and andesite source rocks. The sediments are composed of quartz, olivine, augite, amphibole, pyroxene, plagioclase, potassium feldspar, muscovite and biotite, indicating the primary phases of magmatic source rocks; kaolinite and illite in the secondary phase; and rutile in their residual composition. The presence of ferromagnesian minerals indicates that they were derived from the mafic rocks, which are the basalts of the Cameroon Volcanic Line (CVL). However, the presence of quartz associated with plagioclase and feldspars suggests that alkaline granites played a minor role in the sedimentation of the Limbe beaches. Total Quartz - Total Feldspar - Total Lithic Fragments (Qt-Ft-Lt) mineralogical relationships demonstrate that these beach sediments would be formed in an undissected arc tectonic context, typical of volcanic sources with high relief producing black sands or sands enriched in iron oxides. Their microscopic characteristics of angular to subangular shapes suggest that the magmatic sources are proximal to the shoreline deposits. The characteristics of microporosity, iron oxide inclusions, conchoidal fracture, heavy mineral grains, and opaque minerals support this proximal source. The conchoidal fractures defining the angularity of these beach sediments would suggest its derivation from crystalline rocks. The predominance of heavy minerals suggests that the rocks proximal to the beach have been altered. The abundance of primary minerals associated with these secondary heavy minerals justifies the existence of unweathered lithic grains in the source rocks and an alteration that occurred under a tropical monsoon climate that ranged from semi-humid to humid. The use of the multi-element tectonic discrimination diagram implies an arc framework that is compatible with the geology of the study area.

Radioactive remote signatures derived from Sentinel-2 images and field verification in West Sulawesi, Indonesia.

Mamuju, West Sulawesi, is an area in Indonesia with high radiation levels. A high radiation dose rate was detected in Adang volcanic rock. Activities related to radioactive minerals contained in rocks and soil may release hazardous radiation into the environment. The study area generally exhibits a highly irregular morphology that provides limited access because of the high slope gradient of the volcanic terrain. Therefore, it is challenging to identify and map minerals carrying radioactive elements via Sentinel-2 remote sensing. Since optical satellite images are superior in land cover detection, we proposed a mapping technique for radioactive carrier minerals based on vegetation indices verified by chlorophyll field measurements. We applied band rationing to identify the distribution of hydrothermal alteration minerals and vegetation stress, while field chlorophyll measurements of Dryopteris marginalis and Nephrolepis exaltata were conducted. The Sentinel-2 color composite of images with 4/2, 8A/11, and 11/12 RGB band ratios revealed the distribution of iron oxide, ferromagnesian silicates, and clay minerals. High levels of uranium (U) were scattered in leucite basalt rocks, with a broad distribution of iron oxide minerals and small amounts of ferromagnesian minerals. In contrast, the presence of thorium was not affected by the presence of these minerals. In addition, band rationing of chlorophyll spectra captured by the red edge vegetation index (REVI) was used as the basis for vegetation stress mapping related to radiation exposure based on the chlorophyll content in ferns in the study area. The REVI image showed an anomalous vegetation stress concordant with the high radioactivity. To obtain more accurate results, ground measurements were also performed to identify the vegetation stress due to the presence of minerals carrying radioactive elements. The areas with radioactive mineralization and vegetation stress were located upstream of the Mamuju River and the Botteng and Ahu areas in Tapalang.

Geochemical Characteristics and Geological Significance of Black Shale at the Bottom of the Mufushan Formation in the Lower Cambrian, Lower Yangtze Platform, South China

Black shale, as an important unconventional energy resource, has attracted significant attention in recent years. By studying its sedimentary and geochemical characteristics, it is possible to reconstruct ancient depositional environments and paleoclimatic conditions. The Lower Cambrian black shale is widely distributed in the Lower Yangtze region, but its tectonic background and provenance have been subject to debate. In this study, we conducted geochemical testing and analysis on samples collected from the basal black shale of the Mufushan Formation in the Mufushan section, Nanjing. The Th/Sc-Zr/Sc diagram indicates that the black shale of the Mufushan Formation has not undergone sedimentary recycling. Analysis of major element ratios, rare earth element (REE) distribution patterns, δEu, (La/Yb)N, and the La/Th-Hf and La/Yb-∑REE discrimination diagrams suggest that the source rocks of the black shale mainly consist of granites and sedimentary rocks rich in ferromagnesian minerals, representing felsic rocks derived from the upper crust, with some involvement of mafic rocks. Considering the provenance attributes, geological age relationships, and tectonic evolution of the South China continent, the granite component in the source rocks is inferred to have formed during Neoproterozoic magmatic activity, and the source area corresponds to the Jiangnan Orogenic Belt. Analysis of K2O + Na2O-SiO2, K2O/Na2O-SiO2/Al2O3, La-Th-Sc, Th-Co-Zr/10, and Th-Sc-Zr/10 diagrams suggests that the source area of the Mufushan Formation black shale was a passive continental margin.

Nature of the Shyok (Northern) Suture Zone between India and Asia: petrology, geochemistry and origin of the Tirit granitoids and associated dykes (Nubra Valley Ladakh Himalaya, NW India)

AbstractThe Shyok Suture Zone is an oceanic remnant of the Neo-Tethyan ocean sandwiched between the Ladakh Batholiths to the south and Karakoram Batholith to the north. The Tirit granitoids in this suture are dark-coloured, relatively rich in ferromagnesian minerals and range from granodiorite–tonalite to gabbro–diorite in composition. Mafic igneous enclaves are quite common and they are intruded by NW–SE parallel doleritic and aplitic dykes. The Tirit granitoids have a wide range of major oxide compositions (SiO2 = 52.1–72.11 wt %, TiO2 = 0.21–1.23 wt %, Al2O3 = 11.42–13.52 wt %, MgO = 1.69–10.69 wt % and CaO = 3.24–9.31 wt %) and show calc-alkaline, metaluminous, I-type characteristics, transitional between primitive and mature arc continental plutons. Rare earth elements (REE) show considerable enrichment in light REE (LREE) as compared to the heavy REE (HREE). Late Cretaceous U/Pb dates (74–68 Ma) show that they formed during the pre-collision northward movement of India. The Tirit dykes are only slightly younger and probably part of the same episode.

Petrology of Bengal Fan turbidites (IODP Expeditions 353 and 354): provenance versus diagenetic control

ABSTRACT High-resolution petrographic and heavy-mineral analyses of Bengal Fan turbidites from six cores drilled during IODP Expeditions 353 and 354 elucidate factors controlling their intersample compositional variability as a key to understanding sedimentary processes and erosional evolution of the Himalayan belt since the Miocene. Bengal Fan turbidites are feldspatho-quartzose to litho-feldspatho-quartzose with plagioclase > K-feldspar; slow-settling micas increase in abundance in very fine sand and coarse silt. The feldspar/quartz ratio and higher-rank metamorphic rock fragments notably increase from uppermost Miocene to Pleistocene deposits, which is ascribed to the onset of rapid exhumation of the Eastern Himalayan syntaxis since ∼ 5 Ma. The same trends are documented in Nicobar Fan turbidites, confirming that they belong to the same sedimentary system. Both Bengal and Nicobar fans record a pulse in mass accumulation rate at Tortonian times, when supply of sedimentary and very-low-grade metasedimentary detritus reflected accelerated exhumation of the Lesser Himalaya. In contrast to foreland-basin sediments, where ferromagnesian minerals have been completely dissolved in strata as young as Pliocene–Pleistocene, in both Bengal–Nicobar and Indus fans amphibole invariably represents about half of the moderately rich to rich transparent-heavy-mineral suite, demonstrating that amphibolite-facies Greater Himalaya metamorphic rocks were widely exposed in the Himalayan range well before the late Miocene and possibly since the late Oligocene, as indicated by a few sillimanite and kyanite grains in Bengal Fan sediments as old as 23 Ma and 28 Ma, respectively. Diagenetic dissolution strongly affected olivine and pyroxene in strata older than the middle and early Pleistocene, respectively, whereas amphibole decreases markedly through progressively older Miocene strata. Ferromagnesian minerals and sillimanite are almost completely dissolved in lower Miocene strata, where durable zircon, tourmaline, rutile, and apatite make up half of the strongly depleted heavy-mineral assemblage. Quaternary turbidites from the six studied cores have virtually the same compositional signatures, testifying to efficient homogenization by turbidite transport and reworking across the fan. Turbidites in western cores closer to peninsular India (U1444A and U1454B) are not different from those in eastern cores, indicating very minor supply from the subcontinent. Forward-mixing calculations based on integrated petrographic and heavy-mineral data indicate that sand supply from the Brahmaputra River to Quaternary turbidites was four times larger than supply from the Ganga River, indicating up to six times higher sediment yields and erosion rates in the Brahmaputra than in the Ganga catchment, largely reflecting superfast erosion of the Eastern Himalayan syntaxis.

Ceramics Properties of Indurated-Shale Quarry Wastes from Abakaliki, Southeastern Nigeria: Application as Raw Materials in Roofing-Tile Production

AbstractThe present study describes research carried out to evaluate the mineralogical, geochemical and technological properties of indurated shale-quarry wastes and assess the suitability of these low-cost and locally available quarry wastes generated from crushed indurated shales for possible use as alternatives to fresh raw materials in the manufacture of roofing-tile products. Firstly, the mineralogical and chemical properties of the indurated shales were investigated by X-ray diffraction (XRD) and X-ray fluorescence, while their physical properties were identified by grain-size distribution, Atterberg limits, and clay activity. Samples of indurated shale-quarry wastes (ISQWs) were subjected to heat treatment at elevated firing temperatures to provide the required strength and durability and their ceramics properties (linear shrinkage, weight loss, water absorption, bulk density, and flexural strength) were determined. From the results, the ISQWs were composed predominantly of fine particles with medium plasticity and clay activity with values generally >0.75. The mineralogy revealed a predominance of aluminosilicates (illite-kaolinite-smectite-chlorite) with large quartz contents and variable percentages of carbonate and feldspar. The oxides were dominated by SiO2 and Al2O3, small amounts of ferromagnesian minerals, and considerable amounts of alkalis (K2O and Na2O) which act as fluxes. The CaO concentrations were variable and related to carbonate contents. Characterizations based on compositional ternary (total clay mineral-carbonate-quartz + feldspar) systems, Casagrande clay workability charts, and Winkler and McNally diagrams revealed their suitability for ceramics applications as the majority of ISQW samples fell within the specifications for roofing tiles. The ISQWs fired at a high temperature of 1000°C revealed considerable weight loss, reduction in both linear shrinkage and water absorption with insignificant increase in flexural strength. In order to achieve excellent ceramics properties and further reduce sintering temperature for their suitability as raw materials in the production of roofing tiles, beneficiations of ISQWs are highly recommended.

Petrography and Geochemical Relationships of the Ultramafic Rocks in Galalah area within Erbil Governorate, NE Iraq

The current research to study the petrography, mineralogy and geochemical relationships of the ultramafic rocks in the Galalah area within Erbil Governorate, at the Unstable Shelf in the Imbricate Zone, to determine the origin of the ultramafic rocks. Dunite and Harzburgite are the most abundant rock bodies in the study area, and they represent most of the outer surface exposure of the ultramafic rock aggregates. The dunite rocks are characterized by pale brown color on the altered surface that is broken into olive green and dark green lithic. Dunite represents a homogenous lithologic feature that mainly consists predominately of olivine with accessory spinel and traces of orthopyroxene. While the harzburgite appears as a massive rock body consisting of olivine, orthopyroxene, and clinopyroxene. These rocks are mainly characterized by alteration to serpentinite, with accessory chromian spinel, secondary magnetite, chlorite, and talc. The studied ultramafic rocks are predominately rich in ferromagnesian minerals of less silica content, and other major elements affected by serpentinization are causing the deviation of elements. They have a strong decrease in sodium and calcium oxides relative to MgO and verified the silica and alumina with MgO and a slight increase in iron oxide. The low values of TiO2 in dunite and harzburgite are characteristic property of the Alpine type ophiolites during the primary process of the mantle in its upper part, before the tectonic emplacement of the ultramafic rocks, and also due to partial melting degree for the asthenospheric mantle. The MREE depletion relative to HREE and LREE may be attributed to the hornblende absence and the presence of olivine and pyroxenes minerals and/or to the source rock features. The U-shaped patterns of REE and their ratios are typical properties of ophiolitic ultramafic rocks, which are compatible with the supra-subduction zone. During the partial melting, the negative anomalies of Nb in ultramafic rocks with sequestration of the Nb concentration by sphene and ilmenite in various types of the source rocks have also been attributed to the crust contamination. These are also characterized by island arc conditions, and its depletion in the studied rocks may indicate the fore-arc tectonic environments