Feldspar Grains Research Articles

Multiscale Pore Architecture and Its Influence on Porosity, Permeability, and Fluid Flow in Tight Gas Reservoirs of the Shihezi H8 Formation, Ordos Basin

Characterizing pore network morphology and its influence on critical reservoir properties such as porosity, permeability, and fluid flow pathways is imperative for maximizing production from tight gas sandstone reservoirs. This study integrated petrographic and pore-scale analyses to investigate diagenetic effects on the Shihezi H8 Formation, Ordos Basin, China. Sixty core plug samples spanning depositional facies from wells were analyzed using thin-section petrography, scanning electron microscopy, laser grain size analysis, mercury injection capillary pressure (MICP), nuclear magnetic resonance (NMR), and porosity–permeability measurements. Thin-section observations indicated that formation primarily comprises litharenite and sub-litharenite sandstones deposited in fluvial–deltaic environments composed primarily of quartz and feldspar grains. Diagenesis caused significant porosity reduction through initial mechanical compaction, 3–13% quartz cementation, and localized dissolution, resulting in secondary porosity of up to 5%. Three diagenetic facies were differentiated based on variations in mineralogy and diagenetic alterations. MICP classified pore networks into three reservoir types defined by mean throat radii ranging from 0.091 to 0.270 μm. NMR distinguished pore architectures as uniformly microporous, bimodally micro–mesoporous, and heterogeneously distributed multiscale pores. Larger throat radii correlated positively with higher porosity (up to 8.6%), gas porosity (10.5%), and permeability (0.1911 mD). Grain size analysis demonstrated a positive correlation between mean detrital grain diameter (>2.6 φ, 0.18 mm, (180 µm)), and significantly elevated average porosity (5–8%) compared to finer lithologies, implying depositional energy and sorting regimes. Integrating depositional features, diagenetic alterations, and multiscale pore architecture characterization quantitatively and qualitatively enhanced predictions of heterogeneity in hydrocarbon flow behavior amongst these tight reservoirs. The optimized insights from this integrated study provide a framework to guide development strategies and field appraisal methods for maximizing recovery from unconventional tight gas formations.

Survival of the brightest? pIRIR dating of volcanic sediments in Sulawesi, Indonesia, using micro-aliquots of K-rich feldspar

Volcanic sediments are challenging to date with luminescence-based methods. Both main minerals used for dating—quartz and K-rich feldspar—commonly have suboptimal luminescence properties when of volcanic origins, primarily a low signal intensity and, for K-rich feldspars, high rates of anomalous fading. The present work provides a case study of sediment samples from the Leang Bulu Bettue (LBB) archaeological site in Indonesia, a key site in our understanding of the early human occupation of the island of Sulawesi. We show that currently available state-of-the-art methods can provide robust optical ages for volcanic sediments. Through various reliability tests, we establish the suitability of a post-IR IR stimulated luminescence (pIRIR) standardised growth curve (SGC) procedure for De estimation of ‘micro-aliquots’ containing 5–10 grains of K-rich feldspar, and then combine this method with estimates of environmental dose rate to determine 10 new reliable and finite optical ages for the sedimentary deposits at LBB. Furthermore, by applying the LnTn method to circumvent truncation of the De distribution caused by the non-linearity of the dose response curve in the higher dose range, we could extend the site's luminescence-based chronology to span the interval ∼15–210 ka. The new chronology is in keeping with previous radiocarbon and U-series ages for the site's upper layers. We show that the low fading rate of micro-aliquots relative to using large aliquots composed of hundreds of grains lies in a brightness-based selection. By targeting bright grains with low fading rates, the need for fading corrections is greatly reduced and they can be made with a smaller uncertainty propagated through into the final age estimate, resulting in optical ages of improved accuracy and precision for volcanic sediments.

Fracturing, comminution and grain-size-sensitive creep as a record of coseismic loading in the middle-crust: Insights from the Urtiga mylonitic pluton (NE Brazil)

Evidence for mid-crustal seismic slip is scarce due to the limited capacity of downward propagation of rupture damage imposed by the confining pressure. Nevertheless, structures indicative of elevated stresses occur throughout the crustal profile. To further investigate this setting, we have studied the fabrics of the Urtiga pluton, emplaced at the south Patos shear zone (northeast Brazil), a major Neoproterozoic crustal boundary. K-feldspar and plagioclase porphyroclasts are fractured, with fine-grained K-feldspar + plagioclase mixtures filling cracks. The edges of the clasts are rimmed by fine feldspar grains that form a fine-grained matrix. Quartz ribbons are parallel to the mylonitic foliation and show microstructures and a fabric indicating deformation via dislocation creep. Chemical compositions of feldspars are typically similar between porphyroclasts, fractures and matrix, with plagioclase grains locally being more albitic within fractures. Crystallographic preferred orientations (CPO) in grains within fractures are host-controlled by the adjacent porphyroclast, while fine grains rimming the clasts show a weak CPO and are mostly strain-free. These characteristics suggest that grain size reduction in the Urtiga mylonitic pluton occurred through fracturing and subsequent grain-size-sensitive creep under mid-crustal conditions, which were possibly attained via downward propagation of seismic rupture from the overlying seismogenic zone during transient, seismic slip episodes, giving rise to spatially related pseudotachylytes at the boundaries of the southern Patos shear zone.

The petrogenesis of Cenozoic basalts from Daihai, western North China Craton: Constraints from 40Ar-39Ar chronology, major and trace elements, and Sr-Nd-Pb-Hf isotopes

The Daihai Cenozoic intraplate basalts are distributed in the western North China Craton (NCC), which is a part of the Cenozoic volcanic province in eastern China, and they are all alkaline basalts. The fine-scale determination of their mantle source region properties, partial melting mechanisms, and petrogenesis can provide crucial information for exploring lithospheric destruction and thinning in the western NCC. 40Ar-39Ar dating of potassium feldspar grains from the Daihai alkaline basalts yielded plateau ages of 18.22 ± 1.84 Ma and 26.86 ± 0.72 Ma, indicating that the Daihai basalts underwent multiple eruptive cycles during the Late Oligocene-Middle Miocene. These basalts exhibit ocean island basalt (OIB)-like geochemical features and were subjected to negligible crustal contamination. Moreover, basaltic magmas underwent intense fractional crystallization of olivine and clinopyroxene. The geochemical differences in the Daihai basalts were controlled by partial melting. The Daihai basaltic magmas were composed of at least two types (type I-enriched mantle and prevalent mantle) of mantle end-members that partially melted and then mixed, and the lithology of the mantle source region was predominantly peridotite. Under enriched mantle conditions, the mixing of garnet lherzolite partial melts (<1%) and spinel lherzolite partial melts (2-5%) can reasonably explain the elemental variations characteristic of the Daihai basalts. Most importantly, the melting depth and lithospheric thickness of the Daihai basalts were < 70 km or even close to 50 km, implying that the western NCC underwent lithospheric destruction and thinning during the Cenozoic. However, these effects were spatially heterogeneous. The most plausible genetic mechanism for the generation of the Daihai basalts was the coupled effects of subduction of the Pacific slab and subduction–collision of the Indo–Eurasian Plate since the Oligocene. The mantle flows generated by these two events convected, blocked and triggered upwelling mantle flows at the eastern margin of the Ordos Block. The upwelling mantle flows resulted in frequent magmatism in the region.

Exploring the use of averaged thermal kinetic parameters in luminescence thermochronometry

In luminescence thermochronometry, the thermal stability of feldspar minerals is conventionally constrained from isothermal decay experiments. However, despite recent refinement of the measurement protocol, measurements take several days and are routinely done for each individual sample. Following that most other thermochronometric methods usually use only a single reference set of thermal kinetic parameters, and that recent studies on direct physical probing of feldspar sample properties have shown that trap depth and band-tail width are broadly similar despite large variations in chemical composition, we sought to optimise luminescence thermochronometry measurements by exploring whether a single set of thermal kinetic parameters can describe luminescence thermal decay in feldspar. We explored the effect of using averaged thermal kinetic parameters rather than sample-specific thermal kinetic parameters to model luminescence signal accumulation under different thermal conditions. A set of K- and Na-feldspar minerals extracted from all over the world were analysed after being measured with a multi-elevated temperature protocol, comprising four different IRSL signals at 50, 100, 150, and 225 °C. Comparisons were done between the thermal kinetic parameters of each IRSL signal depending on different variables such as geographic region, transect, lithology, or mineralogy of the analysed feldspar grains. Even though it is not possible to generalise the thermal kinetic parameters between IRSL signals measured at different temperatures, the variance between the thermal kinetic parameters of different samples measured at the same IRSL temperature is consistent with the uncertainties on the individual parameters (i.e., <2–10%), suggesting that averaged, rather than sample-specific values may be appropriate. We then explored the effect of using these averaged parameters to model luminescence signal accumulation under different synthetic and natural thermal conditions. For our dataset, results show minimal impact on the obtained cooling histories and exhumation rates. We therefore propose the use of averaged rather than sample-specific thermal kinetic parameters for rapid investigation of luminescence thermochronometry samples. Based on careful initial characterisation of a few samples to verify the validity of using averaged thermal kinetic parameters, this would reduce measurement times by ca. 50% (i.e., 3–4 days per sample), allowing higher resolution sampling and measurement.

Granitic mush compaction by impingement of a large felsic enclave: Evidence from the Aztec Wash pluton (Nevada, USA)

Abstract Compaction and melt extraction are key processes in the generation of melt-dominated magma bodies. We analyze magmatic fabrics in the Aztec Wash pluton (15.7 Ma; Nevada, USA) to understand magma dynamics during emplacement of a large (2 m diameter) felsic enclave (LFE) in a silicic magma body. We hypothesize that the LFE moved through crystal-poor magma, settling into crystal-rich magma. We analyze four granite samples collected near the enclave: two 0.25 m below the enclave (E-5 and E-2); one 0.5 m below (E-6); and one 2.5 m to the side (E-3, far field). We use the scanning electron microscope (SEM) to gather data using backscattered electron (BSE) microscopy, energy dispersive spectroscopy (EDS), and electron backscatter diffraction (EBSD) imaging. BSE maps show large (up to 10 mm) euhedral alkali feldspar grains in E-5 and E-2, while E-6 and E-3 have large (up to 6 mm) alkali feldspar with distinct irregular and wavy rims. Dark BSE alkali feldspar rims correlate with Ba depletion in EDS maps. Broken feldspars in E-5 and E-2 have mismatched zones in BSE and orientation differences in EBSD. Grain orientation spread (GOS) maps show that alkali feldspar has the highest degree of intragrain deformation, followed by plagioclase, then quartz. Histograms of the angle between the vertical plane and the pole to the (010) plane demonstrate clustering in E-5, suggesting an enhanced fabric. Differences in rim texture suggest melt extraction beneath the enclave and melt retained in the far field. EBSD data reveal an enhanced foliation beneath the LFE. We conclude that mush under the LFE was deformed during emplacement of the LFE, expelling melt and reorienting grains.

Diverse Behaviors of Feldspar Grains during Sandstone Diagenesis: Example from the Xujiahe Formation in the Western Sichuan Basin, China

Feldspar alteration is among the most important processes in clastic rocks during diagenesis, but uncertainty remains about the factors that control feldspar diagenesis under subsurface conditions. Hence, the Upper Triassic Xujiahe formation of the Western Sichuan Basin were examined by an integrated petrographic, mineralogical and geochemical approach to unravel the causes and effects of feldspar diagenesis, with implication for mass transfer and openness of the geochemical system. The sandstones at various depths demonstrate three distinct, separate diagenetic behaviors of detrital feldspar within a single formation including (1) the complete dissolution of both plagioclase and K-feldspar in the upper member; (2) conservation of abundant detrital feldspar grains with minor albitization or overgrowths within the lower member of depths greater than 5 km; and (3) complete disappearance of K-feldspar within the uppermost horizons of the lower member, while plagioclase have survived in significant amounts. The exceptional disappearance of K-feldspar is the result of selective dissolution of K-feldspar during burial, accompanied by illite cementation and substantial K transfer at a scale of tens of meters. It is apparent that the clay diagenesis in the overlying mudstones, rather than porewater chemistry, is the major control of the reactivity of K-feldspar in adjacent deeply buried sandstones.

Luminescence dating of glacially sourced deposits from northern Switzerland: Comparing multigrain aliquots and single grains of quartz and feldspar

A complex picture of the Pleistocene glaciation history of northern Switzerland has been identified over the last three decades. To gain further insights into the long-term landscape evolution, numerical dating is required. In the absence of alternative dating techniques, luminescence dating is the key method for establishing chronological constraints of past glaciations. However, this is presented with complex challenges, especially in regard to the resetting of the luminescence signal prior to deposition, the components contributing to the signal as well as the signal intensity and stability. In this study, the luminescence properties of glacially sourced deposits from northern Switzerland are assessed using single aliquot (SA) and single grain (SG) measurements of feldspar (F) and quartz (Q). While no obvious connection between bleaching and distal or proximal deposition in relation to the proposed ice margin is observed, most samples seem to reveal a partially bleached signature in F SG De measurements. This appears to be masked in the respective F SA measurements even though only few grains emit luminescence signals. In addition, comparisons between fading corrected infrared stimulated luminescence (IR) and post-infrared infrared stimulated luminescence (pIR) De values appear to be unreliable indicators of bleaching, even though these signals bleach at different rates. Hence, it is recommended to conduct both IR and pIR investigations in combination with Q measurements on a SG level. The dating potential of the investigated deposits remains rather limited, yet, in the sedimentologic context the presented results reveal that several glacial advances occurred prior to the Last Interglacial in the study area.

Testing the performance of an EMCCD camera in measuring single-grain feldspar (thermo)luminescence in comparison to a laser-based single-grain system

Risø laser-based luminescence readers (XY) are well-established in measuring single-grain luminescence for dating and tracing purposes. The use of novel EMCCD cameras is upcoming within the luminescence community, but not common practice yet. In this study we optimize Risø EMCCD camera system settings for detecting single-grain feldspar luminescence and compare system performance to the XY system. We suggest approaches to avoid quartz window staining (which may cause blurred EMCCD images), and to remove Bremsstrahlung-induced spikes from EMCCD-derived decay curves. We show that aperture size has little effect on signal intensity and crosstalk, and that a signal integration Region Of Interest (ROI) of 450 μm diameter provides a good trade-off regarding signal intensity and crosstalk. Our comparison of the XY and EMCCD systems shows that the detection sensitivity and grain acceptance of both systems is similar in measuring feldspar grains. Furthermore, we demonstrate that the EMCCD system allows automated detection of single-grain feldspar thermoluminescence signals, providing new opportunities for sediment tracing and mineral identification.

Do attenuation coefficients based on luminescence bleaching fronts reflect true light attenuation in rocks?

The emerging technique of rock surface luminescence dating employs a double-exponential fitting dating model based on the Bouguer-Lambert law. The accuracy of exposure age determination is sensitive to the light attenuation coefficient, μ, which is usually derived from fitting the luminescence profile as a function of depth into the rock. Alternatively, μ might be determined by direct measurement using a spectrophotometer. However, their directly measured values of μ were significantly larger than those estimated from field luminescence bleaching data. Here, we aim to confirm these previous results by measuring the luminescence-depth profiles of both IRSL and IRPL signals from granite rock exposed to different light sources, including sunlight, SOL2 and IR LEDs under controlled conditions. We also measured monochromatic light (blue LED: (470 ± 30) nm, green LED: (520 ± 30) nm, and infrared LED: (850 ± 30) nm) attenuation in granite rock slices of varying thickness (0.62–2.60 mm) using a high-sensitivity photodiode. Finally, we use a camera-based measurement system and a Risø Luminescence Imager to investigate spatial variation in transmitted light as a function of slice thickness. The spatial correlation between direct light transmission and luminescence emission is then investigated, to investigate the underlying reasons for the difference between direct measurement and luminescence-based estimates of μ. We find that light attenuation through a granite rock slice is very heterogeneous; most light penetrates through localized low attenuation light paths corresponding to transmission through the most transparent grains, presumably quartz. The light penetration and escape into the surrounding matrix are assumed to be influenced by the surface area of quartz grains. As a result, transmissive light paths result in a significant area of feldspar grains at depth in the slice being exposed to more light than might be expected from average attenuation measurement. When the incident light predominantly travels through feldspar minerals, simultaneously stimulating luminescence from within any potassium feldspar (K-feldspar), the attenuation coefficients derived from the luminescence-depth profiles tend to be smaller than the average of 1.18 ± 0.07 (n = 79) irrespective of the kinetic model used for fitting. Thus, luminescence-based attenuation coefficient estimates appear to be affected by the distribution of light attenuation across and within the rock slice, making such estimates preferable to directly measured (average) estimates of light attenuation coefficients. These insights are important for our understanding of the significance of light attenuation coefficients in rock samples; they contribute to the reassessment of parameters and measurement methods in dating models and so to improvements in accuracy of rock surface luminescence dating techniques.

Processing of gypsum-bearing materials in the bronze age Gonur Depe archeological site (Southeast Karakum Desert)

The technology of preparation of an ancient binder mixture used in construction work at the Gonur Depe archeological site (Southeast Karakum desert) is interpreted on the basis of study of its mineral composition and textural-structural features. The material is composed of thin prismatic-angular and fbrous aggregates of reduced gypsum (60–70 %) and β-bassanite (3 %) enclosed in clay-siliceous matrix (20–30 %). The mixture also contains grains of quartz (5–10 %), feldspar (up to 1%), mica (up to 1 %) and other minerals. The mixture was produced from a crushed natural gypsum stone, which was calcinated in air. In this case, gypsum is converted to β-bassanite and partly to anhydride. The morphology and sizes of mineral particle confrm the presence of the calcination stage up to 200 °C. The further addition of water to a dry mixture caused rapid thickening and cementation of the material, which could be used for whitewashing and plastering of the walls.

Slow failure during faulting and formation of a porous framework under hydrothermal conditions: Role of feldspar sintering in granitoids

Earthquakes induced during the construction of fracture reservoirs in granitoids are an important issue for the development of ultra-high-enthalpy geothermal systems. We performed axial compression experiments on granite specimens under hydrothermal conditions to evaluate this potential, simulating Quaternary granitoids at approximately 4 km depth. Our experiments were primarily conducted under a confining pressure, pore pressure, and loading velocity of 104 MPa, 39 MPa, and 0.1 μm/s, respectively, and we varied the temperature from 400 °C to 750 °C. Although failures occurred in all specimens, we observed several temperature-dependent deformation parameters. Both the apparent Young's modulus in the elastic deformation stage and the peak stress decreased with increasing temperature. Furthermore, the stress drop during failure after attaining the peak stress was slower at higher temperatures, taking almost 5 times longer at 650 °C and 750 °C than at 400 °C. We found that the fracture patterns evolved from localized to distributed and then to dissipated with increasing temperature. Well-developed fractures in quartz grains were observed at the thin-section scale, whereas fractures in feldspar grains seemed to be inconspicuous. However, SEM observations revealed that feldspar grains had actually been more fragmented, and that submicrometer feldspar particles formed within the fault gouge zone. Additionally, those feldspar fragments were sintered at temperatures above 550 °C. Sintering enhanced fracture healing during faulting, explaining the slower observed stress drop at higher temperatures and possible leading to the suppression of dynamic rupture propagations (induced earthquakes). In contrast, sintering of quartz particles in the gouge did not occur at temperatures below 750 °C, allowing for the preservation of the porous network necessary for geothermal reservoirs.

Novel insights about petroleum systems from source and reservoir rock characterization, Cretaceous Deposits, Babouri-Figuil Basin, Northern Cameroon

The Babouri-Figuil Basin (BFB) is a frontier basin for petroleum in Cameroon. It belongs to the series of Cretaceous rift basins of the West and Central Rift System (WCARS), the origin of which is related to the opening of the South Atlantic. Within the same rift system, commercial hydrocarbon accumulations have been discovered in Chad, Sudan, Niger and, more recently, in Nigeria (Gongola Basin). The study of the geology of the BFB just recently received considerable attention, mainly because of its presumed hydrocarbon potential. In the pursuit of researching possible petroleum systems in the BFB, the current study provides a first look into the characterization of source and reservoir rock and its integration into a 2D lithostratigraphic model. The study was solely based on outcrop samples. Black shale and massive claystone are good to excellent hydrocarbon source rocks [e.g., up to 38 wt% total organic carbon (TOC), up to 943 mg/g hydrogen index, up to 85 m thickness, up to 20–30 km lateral extension], with moderate to high values of extractable organic matter (e.g., >10,000 ppm). Calcareous claystone, on the other hand, are poor source rocks [e.g., <0.20 wt% TOC]. The samples are thermally immature, except for those located close to volcanic intrusion at Golombe that have reached the threshold for oil generation (Tmax >435 °C, production index >0.1). The petrographic analysis of sandstone revealed that they are fine-grained to coarse-grained, poorly to moderately sorted, texturally and compositionally immature to submature, subarkosic to arkosic arenites. The main diagenetic processes that affected sandstones are as follows: moderate to intense compaction characterized by the development of long, concavo-convex, and sutured contacts between grains; cementation through calcite, iron oxide, and quartz cements; alteration of mica and feldspar grains; partial to complete dissolution of feldspar, mica, amphibole grains, and calcite cement; and the replacement of feldspar and mica grains by clay minerals. Alteration and dissolution increase the porosity of sandstone through the creation of secondary pores. However, mechanical compaction through the development of a pseudomatrix and cementation as pore-filling materials have significantly reduced the quality of sandstone beds as conventional petroleum reservoirs. Hence, the best reservoir-quality sandstones in the basin are generally located in the upper portion of the basin in terms of its lithostratigraphic model. They are the cleanest sandstones with the smallest amount of cement and the lowest ductile grain content (pseudomatrix), with a thickness that varies from 3 m to 120 m and a lateral extension of 20 km. The lithostratigraphic model of the basin is characterized by an extensive lacustrine environment that provided a thick sequence of organic-rich formations; sand deposited as extensive reservoirs sandwiched between shale/claystone beds; the development of stratigraphic traps through lateral facies change; and the widespread deposition of lacustrine and floodplain claystone that provide regional seals. The similarities between the Babouri-Figuil Basin and proven petroleum systems in other WCARS rift basins suggest that the basin may host at least one petroleum system where actively generating source rocks are present.

Short communication: Synchrotron-based elemental mapping of single grains to investigate variable infrared-radiofluorescence emissions for luminescence dating

Abstract. During ionizing irradiation, potassium (K)-rich feldspar grains emit infrared (IR) light, which is used for infrared radiofluorescence (IR-RF) dating. The late-saturating IR-RF emission centred at ∼880 nm represents a promising tool to date Quaternary sediments. In the present work, we report the presence of individual grains in the K-feldspar density fraction displaying an aberrant IR-RF signal shape, whose combined intensity contaminates the sum signal of an aliquot composed of dozens of grains. Our experiments were carried out at the National Synchrotron Light Source (NSLS-II) at the submicron-resolution X-ray spectroscopy (SRX) beamline. We analysed coarse (&gt;90 µm) K-feldspar-bearing grains of five samples of different ages and origin in order to characterize the composition of grains yielding the desired or contaminated IR-RF emission. Using micro-X-ray fluorescence (μ-XRF), we successfully acquired element distribution maps of up to 15 elements (&lt;1 µm resolution) of sections of full grains previously used for IR-RF dating. In keeping with current theories of IR-RF signal production, we observed a trend between the relative proportions of Pb and Fe and the shape of the IR-RF signal, namely that most grains with the desired IR-RF signal shape had high Pb and low Fe contents. Interestingly, these grains were also defined by high Ba and low Ca contents. Our study also represents a proof of concept for mapping the oxidation states of Fe using micro-X-ray absorption near-edge structure spectroscopy (μ-XANES) on individual grains. The high spatial resolution enabled by synchrotron X-ray spectroscopy makes it a powerful tool for future experiments to elucidate long-standing issues concerning the nature and type of defect(s) associated with the main dosimetric trap in feldspar.

Controls of Multi-Scale Fractures in Tight Sandstones: A Case Study in the Second Member of Xujiahe Formation in Xinchang Area, Western Sichuan Depression

Abstract Different scales of fractures affect the reservoir quality in tight sandstone. There are more studies on macroscopic tectonic fractures but less on bedding fractures and microfractures. The control factors of multi-scale fractures are unclear. In this paper, we analyzed the types and controls of fractures in the second member of the Xinchang region in Western Sichuan. We use core and outcrops observations, imaging logging, scanning energy spectra, and rock slices. Natural fractures can be classified into tectonic, bedding, and microscopic types. The tectonic fractures are mainly low- to medium-angle tensile fractures. The bedding fractures are nearly horizontally distributed along the bedding surface, including parallel, dark mineral interface, and carbonaceous fragments interface bedding fractures. The microfractures develop intra-grain, edge-grain, and inter-grain types. The intra-grain microfractures are inside quartz or feldspar grains, whereas inter-grain types penetrate multiple grains with larger extension lengths. The tectonic fractures are related to the stress, grain size, mineral component, argillaceous content, and lithologic thickness. Parallel bedding fractures are controlled by the coupling of water depth and flow velocity. Bedding fractures at the interface are controlled by rock component. The microfractures are controlled by the length-width axis ratio of the grain, grain element content, and brittleness index. Fractures of different scales form a three-dimensional fracture system that has a substantial impact on the gas production.

Mineralogical, Petrographical and Geochemical Properties of the Late Oligocene Coal Seam (Seam-VI): Insights into Elemental Enrichments and Palaeodepositional Environment (İbrice field, Thrace Basin)

The Thrace Basin hosts several mineable coal seams (upwards numbered I to VII) within the coal-bearing Late Oligocene-age Danişmen Formation. For the first time, the properties of the Seam-VI in the İbrice (Malkara) area have been investigated in order to evaluate elemental enrichments and palaeoenvironmental conditions. The xylite-rich and mineral-rich lithotypes were identified from the studied coal samples representing the whole-coal thickness. The coal samples, on a dry basis, display variable ash yields (13.2–63.0%), total C (21.2–57.8%), and total S (0.9–4.1%) contents. The minerals identified using XRD-whole rock analysis include clay minerals, quartz, pyrite, calcite, dolomite, and feldspars. Siderite is only identified in a single sample. Aragonite is detected in two samples, which contain fossil shell remains. The SEM observations agree with XRD data, and apatite, barite, biotite, pentlandite, sphalerite, Ti-oxide, and zircon were also identified as accessory phases. Huminite is the predominant maceral group in the studied samples, while liptinite and inertinite group macerals display variable proportions. The mean %Rr values of ulminite macerals are around 0.40-0.41±0.01-0.02%, indicating relatively low-rank coal. This study implies that the precursor peat-mires of the Seam-VI were mainly developed under forested mire conditions, where woody peat-forming plants were abundant, and occasionally the contributions of herbaceous plants were important. The coexistence of syngenetic pyrite and carbonate minerals (e.g., siderite and carbonate mineral bands) could be related to the development of weakly acidic to neutral conditions within palaeomires. Furthermore, the predominance of clay minerals and the presence of detrital accessory minerals (e.g., apatite, pentlandite, and Ti-oxides) can also be indicators of clastic influx into palaeomires. Although aluminosilicate minerals (e.g., clay minerals) are abundant in dominant phases, SEM-EDX data shows that accessory minerals mainly control the elemental enrichments in the Seam-VI. The Mn enrichments in the samples seem to be controlled by Mn-bearing siderite micronodules. Considering the presence of sulphide mineralization and metallic ore deposits in the Strandja and Rhodope massifs, enrichments of Cr, Co, Ni, Ge, and Mo are related to As-bearing pyrite grains and accessory sphalerite and pentlandite grains within clay mineral aggregates in the samples. In addition, the Sr-bearing barite overgrowths around feldspar grains and syngenetic carbonate mineral bands could also cause Sr enrichments. Overall, clastic influx ratios into palaeomires and pH conditions during peat accumulation controlled the elemental enrichments in the Seam-VI.

Neoproterozoic passive margin formation and evolution during the Rodinia–Gondwana supercontinent cycle at the eastern margin of the West African Craton

Abstract Petrographical and geochemical data from the Togo structural unit (TSU), also referred to as the Atacora structural unit, are presented together with the existing dataset; geochemical and age data from the sedimentary and metasedimentary rocks from the passive margin sequences of the Dahomeyide belt in Ghana to infer their provenance and depositional setting and expand the discussion on the Rodina–Gondwana supercontinent assembly during the Pan-African orogeny. The metasedimentary rocks of the TSU are quartzites and phyllites. The framework grains of the quartzites consisting dominantly of quartz and small amounts of feldspar grains and relict lithic fragments classify them as quartz arenite, subarkose and sublitharenite. Generally, the studied rocks show similar rare-earth element and multi-element patterns, which imply derivation from similar sources. Elemental ratios, including (La/Lu)N, Th/Sc and La/Sc, suggest sediments sourced from intermediate to felsic rocks. Provenance and depositional setting indicators of the TSU suggest deposition in a passive margin setting, with the West African and Amazonian cratons’ granitoids and granitic gneisses as possible provenance, akin to siliciclastic rocks of the Buem structural unit and the Voltaian Supergroup of the Volta Basin. The deformational history of the TSU is similar to those of the Buem structural unit and the eastern margin of the Voltaian Supergroup, indicating the effect of the Pan-African orogeny on the passive margin of the Dahomeyide belt. We, therefore, propose the formation and evolution of a Neoproterozoic passive margin unit, which was tectonically deformed during the Rodinia–Gondwana supercontinent cycle.

Diagenetic effect on reservoir quality of siliciclastic and volcaniclastic sandstones from a Paleogene volcanic rifted margin, East Greenland

ABSTRACT Siliciclastic and volcaniclastic sediments in a volcanic rifted-margin succession may experience a complex diagenetic history during burial that can have a large impact on sandstone reservoir properties. To understand such changes, variations in initial sediment composition and succeeding diagenetic changes have been studied for a Paleogene outcrop analogue in the Kangerlussuaq area, East Greenland. The nature of the mafic volcanics-bearing succession, which consists of intra-volcanic sandstones, accommodated over quartz-rich pre-volcanic fluvial sandstones, are comparable to the settings of recently discovered hydrocarbon-producing sandstones in the Faroe–Shetland Basin on the conjugate Atlantic margin. Our petrographic and provenance investigations of the pre- and intra-volcanic sandstones are supported by geochemical and X-ray diffraction analyses. The intra-volcanic sandstones were deposited in shallow marine environments with mixed siliciclastic and volcaniclastic input, the latter rich in felsic to mafic volcanic rock fragments and feldspar grains. Similar zircon age distributions of pre- and intra-volcanic sandstones support a continued supply from the same siliciclastic sediment source after the onset of volcanism. Variations in initial detrital grain and pore-fluid (fresh to marine) compositions resulted in different diagenetic changes in the pre- and intra-volcanic sandstones. However, where siliciclastic sandstones were overlain by volcaniclastic rocks rather than massive lava flows, the diagenetic changes resemble those of the intra-volcanic sandstones. The cementing phases are typically quartz, illite (probably illitized kaolinite), and rare anatase in the pre-volcanic sandstones. Chlorite, calcite, zeolite/feldspar, opal/quartz, and titanite are characteristic authigenic phases in the intra-volcanic sandstones. Precipitation of different minerals in the pre- and intra-volcanic sandstones show that the detrital composition (and to a lesser extent depositional environment) played a major role during early and late diagenesis after deep burial (up to 6–8 km). Inter-eruptive siliciclastic units may prove to form highly valuable reservoirs when they are composed of mixed siliciclastic and volcaniclastic material. In the stratigraphically youngest intra-volcanic sandstones and pre-volcanic sandstones overlain by hyaloclastite or tuff, there is a high potential for preservation of interparticle porosity during burial (&amp;lt; 5 km) due to early chlorite rims and the generation of secondary porosity after the dissolution of early zeolite cement.

Soil organic matter and biogenic-abiogenic interactions in soils of Larsemann Hills and Bunger Hills, East Antarctica

Although Antarctic soils are usually described as weakly developed, recent studies indicated the significant variability in soil forming conditions across the sixth continent as well as considerable diversity of soils. The identification of pedogenetic processes in Antarctica is crucial for understanding not only the current state of its environment, but also for better understanding of soil development on Earth through time. Our study provides a detailed investigation of micromorphological features and molecular composition of organic matter of soil and soil-like bodies of remote areas of East Antarctica - Larsemann Hills and Bunger Hills, which are characterized by harsh environmental conditions. Studied soils showed predominantly coarse structure and low organic carbon content, alkaline to almost neutral pH range. Thin sections of studied soils were characterized by predominance of grains of quartz, feldspars, and other primary minerals with angular shapes indicating relatively weak degree of their alteration. All studied humic substances are characterized by the predominance of aliphatic structures. Moreover, it was observed that studied humic acids contains significant amounts of carbohydrates, polysaccharides, esters and amino acids and hydrophilic fragments predominate. Organo-mineral interactions were mostly connected with development of biofilms in the topsoil horizons with the maximal biological activity among studied soils.

Rock - soil transition during weathering of rhyolite

Concentric layers of weathered materials around core-stones show the rhyolite to experience sequential, but gradational, changes in visible features, textures and mineralogy as it transforms from ‘rock’ into ‘soil’. The changes start with the opening-up of grain boundaries and micro-cracks (stage 1) followed by their dark brown staining (stage 2) and the subsequent alteration (to sericite and clay minerals) of plagioclase feldspar groundmass grains and phenocrysts (stage 3). Biotite flakes are then bleached and altered (to chlorite and clay minerals) (stage 4) before there starts alteration (to sericite and clay minerals) of groundmass alkali feldspar grains (stage 5) and finally alteration of alkali feldspar phenocrysts (stage 6). Quartz grains are not altered during these stages of weathering but disaggregate and reduce in size due to continual opening-up of grain boundaries and micro-cracks. Increasing stages of weathering are marked by decreasing dry unit weights, dry densities and uniaxial compressive strengths, but increasing apparent porosities. The transition between ‘rock’ and ‘soil’ occurs during weathering stage 6 when all plagioclase groundmass grains and phenocrysts have been altered as have been all alkali feldspar groundmass grains and most phenocrysts. Stage 6 is marked by large apparent porosities (&gt;14%) but low values of dry unit weight (&lt;21.90 kN/m3) and dry density (&lt;2,232 kg/m3).