Photocatalytic technology provides a clean and sustainable method for producing hydrogen peroxide (H2O2), while, the yield is significantly hindered by the rapid recombination of charge carrier and the low oxygen reduction activity of catalyst. Herein, the Bi-BiOx/CN heterojunction was successfully constructed by homogeneously loaded amorphous Bi-BiOx species on stalactite-like CN just via one-step pyrolysis with the pre-coordination confinement strategy. In the Bi-BiOx/CN heterojunction, the Bi-BiOx species acted as electron storage layer and induced electrons directional migrate from CN to Bi-BiOx species, which promoted the carrier separation. Meanwhile, the three-dimensional stalactite structure of CN not only increased the active sites and gas shuttle pores, but also shorten the electrons and holes diffuse distance from the bulk phase to the surface. As expected, the H2O2 generation rate of optimal Bi-BiOx/CN-10 reached 6036 μM/g/h, which is 1.86 times higher than that of CN. The experimental results proved that ·O2– plays an important role in H2O2 production, and the direct 2e- ORR reaction and the indirect 2e- ORR reaction coexist. This work validates the potential of Bi-BiOx species as an alternative to noble metals for heterojunction construction, and provides a feasible path for regulating efficient directional transfer of charge transfer.
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