Fe Oxide Content Research Articles

Does the presence of mineral nutrient enhance the carbon sequestration, soil aggregation, and microbial biomass in the subtropical clay soil?

Crop residue incorporation is considered as a promising approach for improving carbon sequestration coupling with soil aggregation (MWD). However, better understanding is needed regarding to the mechanism of carbon sequestration and aggregation following crop residue return in subtropical clay soil. A short-term field experiment (1.5 years) was conducted to explore the underlaying potential mechanism of carbon sequestration after crop residues return in the subtropical clay soil. Four treatments were applied as follows: (1) Control, (2) Inorganic fertilization (NPK), (3) Crop residue at 8-ton ha−1, (6) NPK + Crop residue at 8-ton ha−1. MWD, soil organic carbon (SOC), microbial biomass carbon (MBC), glomalin protein (GRSP), mineral and aggregate-associated SOC, and Fe oxides were determined. Results exhibited that the mineral nutrients with or without crop residue enhanced the SOC significantly in comparison to the only straw and control treatments (P < 0.05). The short-term residue return enhanced the MWD compared to the baseline soil, which was less than control due to the greater concentration of amorphous Fe oxides. Moreover, GRSP and MBC were significantly increased upon crop residue return in presence of mineral nutrients treatment (P < 0.01). SOC was reduced in the order of NPK > NPK + Crop residue > Crop residue > control, while MBC and GRSP were increased in the order of control < Crop residue < NPK < Crop residue + NPK. Aggregate-associated and mineral-associated SOC of aggregates were enhanced in presence of mineral nutrients (P < 0.001). Our results suggest that the nutrients addition in presence or absence of crop residue return under short-term field experiment is considered as a promising and sustainable clay soil management approach for enhancing carbon sequestration to mitigate climate change.

Effect of Vegetation Restoration on Soil Iron‐Associated Carbon Dynamics: Insights From Different Soil Textures

AbstractSoil iron (Fe)‐associated carbon (C) (Fe‐OC) plays a vital role in the soil C cycle due to its high stability, but vegetation restoration might alter the composition and quantity of Fe‐OC by introducing a large amount of plant‐derived C and affecting soil properties. However, how vegetation restoration affects soil Fe‐OC remains unclear. Herein, plant and topsoil samples from grasslands, shrublands, and forestlands across three soil types (loam, loess, and sandy soil) since cropland conversions were collected to address this issue. The results showed soil Fe‐OC content decreased in loam soil but increased in loess and sandy soil following vegetation restoration. Additionally, the Fe‐OC accumulation efficiency induced by vegetation restoration increased with the coarser soil texture. Vegetation restoration promoted the accumulation of Fe‐OC by increasing soil microbial biomass C, dissolved organic C, aromatic‐C, and citric acid, but also disrupted the combination of Fe oxides and C by introducing oxalic acid, reducing Fe oxide content and iron trivalent (Fe(III)). There were two‐sided effects of vegetation restoration on Fe‐OC, but the overall effect depends on the soil types. Moreover, isotopic evidence indicated that microbial source C is the main source of Fe‐OC, but Fe oxides preferentially adsorbed dissolved organic matter (DOM) and root deposits from plants rather than microbial residues and metabolites following vegetation restoration. In addition, Fe oxides preferentially adsorbed aromatic‐C compared to other functional group components. These findings indicated that vegetation restoration in coarser‐texture soils, coupled with selecting species that increase soil microbial biomass, produce more root deposits, and enhance DOM, contribute to the accumulation of soil Fe‐OC.

Soil organic carbon regulation by pH in acidic red soil subjected to long-term liming and straw incorporation

The manipulation of soil pH through liming and straw incorporation plays a pivotal role in influencing soil organic carbon (SOC) dynamics in acidic red soil. This study aimed to assess the impact of these practices on SOC and elucidate the relationship between SOC and pH. Over a 31-year field experiment, seven different fertilization treatments were implemented: unfertilized (CK), nitrogen and potassium fertilizers (NK), NK with lime (NKCa), nitrogen, phosphorous, and potassium fertilizers (NPK), NPK with lime (NPKCa), NPK with straw (NPKS), and NPKS with lime (NPKSCa). Results revealed that liming and straw incorporation significantly elevated soil pH by 0.13–0.73 units. Lime application boosted SOC and mineral-associated organic carbon (MAOC) by 20.2% and 28.7%, respectively, in NK treatment, whereas its impact on SOC in NPK and NPKS treatments were negligible. SOC witnessed a 17.1% increase with NPKS and a 15.2% increase with NPKSCa compared to NPK alone. Notably, NPKS and NPKSCa led to a significant surge in particulate organic carbon (POC) by 19.7% and 37.7%, respectively, albeit NPKSCa reduced MAOC by 14.9% relative to NPK. Linear regression analysis unveiled a positive correlation between POC and soil pH, while SOC and MAOC exhibited an initial rise at lower pH levels followed by stabilization as pH continuously increasing. A partial least squares path model showed two pathways through which pH influenced SOC: firstly, by positively affecting SOC through increasing Fe and Al oxides contents and enhanced aggregate stability, and secondly, by negatively influencing SOC through altered ratios of fungi/bacteria and Gram-positive bacteria/Gram-negative bacteria. In conclusion, the long-term effects of lime and straw application on SOC and MAOC were contingent upon soil pH, with more pronounced positive effects observed at lower pH levels. These findings underscore the importance of considering soil pH when implementing lime and straw strategies to mitigate acidification and regulate SOC in acidic red soil.

Design of a washing ejector and column flotation based on the microbubble for heavy metal contaminants removal from contaminated soils: A pilot and laboratory-scale studies

This study mainly examines the effects of combined washing ejector and column flotation process by remediation equipment for heavy metal remediation at a contaminated site. A washing ejector system is a sustainable technology that considers the concept of hydrodynamic cavitation. Soil aggregates strongly binding to poorly crystalline minerals and Fe oxide bonding with the soil create challenges for their elimination from soils contaminated with complex contaminants. The effects of the operating conditions of the cavitation flow on increasing the separation of fine particles were evaluated by determining the mass balance during the washing system process on a pilot scale. Cavitation flow in the washing ejector system can increase the dispersion of soil aggregates owing to the generation of hydroxyl radicals (•OH) and the increase in mixing intensity. Cavitation flow during the process can increased the dispersion of soil aggregates owing to the release of Fe oxides into the soil. The coarse and fine particles were readily separated from the bulk soil, and the fine particle distribution per mass increased after washing. The levels of Fe in the coarse fraction soil met the KS requirements after separation, whereas the Fe levels in the fine fraction soil were above than the KS limits. To reduce waste volume, column flotation was used to selectively separate Fe oxides from contaminated soil. Microbubbles in column flotation have the important function of facilitating the collision and attachment between air bubbles and Fe oxides and subsequently recovering the Fe oxides. When AF65 as a frother and oleic acid as an anionic collector were used in the column flotation, the concentration of Fe oxides increased from 9.67 % to 13.76 %, a recovery of approximately 10 % from the fine soil. According to the mass balance of the study area, after treatment using the washing ejector system, coarse (60 %) and fine (40 %) soils in the total soil were separated. Column flotation can be applied to fine soil to achieve a volume reduction of approximately 30 % of the total soil volume. The results of this study illustrate the feasibility of the proposed remediation process to reduce waste volume and improve sustainability while meeting Korean standards for heavy metal pollution in soil, thereby minimizing environmental risk.

Organic fertilizer enhances soil aggregate stability by altering greenhouse soil content of iron oxide and organic carbon

Both soil organic carbon (SOC) and iron (Fe) oxide content, among other factors, drive the formation and stability of soil aggregates. However, the mechanism of these drivers in greenhouse soil fertilized with organic fertilizer is not well understood. In a 3-year field experiment, we aimed to investigate the factors which drive the stability of soil aggregates in greenhouse soil. To explore the impact of organic fertilizer on soil aggregates, we established four treatments: no fertilization (CK); inorganic fertilizer (CF); organic fertilizer (OF); and combined application of inorganic and organic fertilizers (COF). The application of organic fertilizer significantly enhanced the stability of aggregates, that is it enhanced the mean weight diameter, geometric mean diameter and aggregate content (%) of >0.25 mm aggregate fractions. OF and COF treatments increased the concentration of SOC, especially the aliphatic-C, aromatic-C and polysaccharide-C components of SOC, particularly in >0.25 mm aggregates. Organic fertilizer application significantly increased the content of free iron oxide (Fed), amorphous iron oxide (Feo), and non-crystalline Fe in both bulk soil and aggregates. Furthermore, non-crystalline Fe showed a positive correlation with SOC content in both bulk soil and aggregates. Both non-crystalline Fe and SOC were significantly positively correlated with >2 mm MWD. Overall, we believe that the increase of SOC, aromatic-C, and non-crystalline Fe concentrations in soil after the application of organic fertilizer is the reason for improving soil aggregate stability.

Organic carbon sequestration by Fe oxides in aggregates in a Pinus massoniana conifer-broadleaf mixed forest

Stand conversion and Fe/Al oxides are potential variables that collectively determine soil organic carbon (SOC) sequestration. However, the mechanism of SOC sequestration provided by Fe/Al oxides in the conversion of Pinus massoniana plantations (PMs) into mixed conifer-broadleaf forests remains unknown. The increase in SOC content (4.08–151.80%) in PM-converted mixed forest was related to the significant increase in the content of all OC fractions. Light fraction (LF) contents were generally higher in larger aggregates and mixed forest aggregates, reflecting the greater plant C input and the driving effect of soil aggregation in mixed conifer-broadleaf forests. This plant C input to the soil as the core of aggregate formation provides physical protection from particulate organic carbon (POC), but this physical protection was achieved by the greater free Fe oxides (FeD) and amorphous Fe oxides (FeO) content in the mixed forests acting as an aggregate stabiliser. Potential processes are driven by pH-driven FeD and FeO binding to silt to improve aggregate stability and pore occlusion, which promotes physical protection of coarse intra-aggregate particulate organic carbon (c-iPOC). Moreover, this process reduces macroaggregate turnover (c-iPOC/f-iPOC ratio), allowing the transfer of c-iPOC in macroaggregates to microaggregate-associated fine intra-aggregate particulate organic carbon (f-iPOC). The higher mineral-associated organic carbon (MOC) content of conifer-broadleaf mixed forest soils was mainly derived from silt+clay and controlled by chemisorption of Fe/Al oxides (especially complex Fe oxides, FeP), but Fe/Al oxides do not provide physical protection for MOC. In addition, LF, c-iPOC and f-iPOC were significantly positively correlated with SOC content, reflecting the sensitivity of aggregate structure development and stabilization in predicting SOC sequestration, but these OC fractions will shift more towards MOC as conifer-broadleaf mixed forests develop. Overall, Fe oxides provide SOC accumulation and long-term stability by OC fractions associated with physical protection and chemisorption in the conversion of PM into mixed conifer-broadleaf forests.

Immobilisation remediation of arsenic-contaminated soils with promising CaAl-layered double hydroxide and bioavailability, bioaccessibility, and speciation-based health risk assessment

Arsenic (As)-contaminated soil poses great health risk to human mostly through inadvertent oral exposure. We investigated CaAl-layered double hydroxide (CaAl-LDH), a promising immobilising agent, for the remediation of As-contaminated Chinese soils. The effects on specific soil properties and As fractionation were analyzed, and changes in the health risk of soil As were accurately assessed by means of advanced in vivo mice model and in vitro PBET-SHIME model. Results showed that the application of CaAl-LDH significantly increased soil pH and concentration of Fe and Al oxides, and effectively converted active As fractions into the most stable residual fraction, guaranteeing long-term remediation stability. Based on in vivo test, As relative bioavailability was significantly reduced by 37.75%. Based on in vitro test, As bioaccessibility in small intestinal and colon phases was significantly reduced by 25.65% and 28.57%, respectively. Furthermore, As metabolism (reduction and methylation) by the gut microbiota inhabiting colon was clearly observed. After immobilisation with CaAl-LDH, the concentration of bioaccessible As(Ⅴ) in the colon fluid was significantly reduced by 61.91%, and organic As (least toxic MMA(V) and DMA(V)) became the main species, which further reduced the health risk of soil As. In summary, CaAl-LDH proved to be a feasible option for immobilisation remediation of As-contaminated soils, and considerable progress was made in relevant health risk assessment.

Iron-modified biochar inhibiting Cd uptake in rice by Cd co-deposition with Fe oxides in the rice rhizosphere.

Fe-enriched biochar has proven to be effective in reducing Cd uptake in rice plants by enhancing iron plaque formation. However, the effect of Fe on biochar, especially the biochar with high S content, for Cd immobilization in rice rhizosphere was not fully understood. To obtain eco-friendly Fe-loaded biochar at a low cost, garlic straw, bean straw, and rape straw were chosen as the feedstocks for Fe-enhanced biochar production by co-pyrolysis with Fe2O3. The resulting biochars and Fe-loaded biochars were GBC, BBC, BRE, GBC-Fe, BBC-Fe, and BRE-Fe, respectively. XRD and FTIR analyses showed that Fe was successfully loaded onto the biochar. The pristine and Fe-containing biochars were applied at rates of 0% (BC0) and 0.1% in pot experiments. Results suggested that BBC-Fe caused the highest reduction in Cd content of rice grain, and the reductions were 67.9% and 31.4%, compared with BC0 and BBC, respectively. Compared to BBC, BBC-Fe effectively reduced Cd uptake in rice roots by 47.5%. The exchangeable and acid-soluble fraction of Cd (F1-Cd) in soil with BBC-Fe treatment was 37.6% and 63.7% lower than that of BC0 and BBC, respectively. Compared to BC0, soil pH was increased by 0.53 units with BBC-Fe treatment. BBC-Fe significantly increased Fe oxides (free Fe oxides, amorphous Fe oxides, and complex Fe oxides) content in the soil as well. DGT study demonstrated that BBC-Fe could enhance the mobility of sulfate in the rhizosphere, which might be beneficial for Cd fixation in the rhizosphere. Moreover, BBC-Fe increased the relative abundance of Bacteroidota, Firmicutes, and Clostridia, which might be beneficial for Cd immobilization in the rhizosphere. This work highlights the synergistic effect of loaded Fe and biochar on Cd immobilization by enhancing Cd deposited with Fe oxides.

Enhancing soil redox dynamics: Comparative effects of Fe-modified biochar (N–Fe and S–Fe) on Fe oxide transformation and Cd immobilization

Biochar and modified biochar have gained wide attention for Cd-contaminated soil remediation. This study investigates the effects of rape straw biochar (RSB), sulfur-iron modified biochar (S–FeBC), and nitrogen-iron modified biochar (N–FeBC) on soil Fe oxide transformation and Cd immobilization. The mediated electrochemical analysis results showed that Fe modification effectively enhanced the electron exchange capacity (EEC) of biochar. After 40 days of anaerobic incubation, compared to the treatment without biochar (CK), the concentrations of CaCl2-extractable Cd in N–FeBC, S–FeBC, and RSB treatments decreased by 79%, 53%, and 23%, respectively. Compared with S–FeBC, N–FeBC significantly decreased the soil Eh and increased soil pH within the first 15 days, which could be attributed to its higher EEC and alkalinity. There is a negative correlation between the concentration of CaCl2-extractable Cd and soil pH (p < 0.01). The sequential extraction results showed that both N–FeBC and S–FeBC promoted Cd transfer from acid-soluble to Fe/Mn oxides bound fraction (Fe/Mn–Cd). N–FeBC significantly increased the concentration of amorphous Fe oxides (amFeox) from 4.0 g kg−1 in day 1 to 4.6 g kg−1 in day 15 by promoting the NO3−-reducing Fe(II) oxidation process, while S–FeBC significantly increased amFeox from 4.0 g kg−1 in day 15 to 4.8 g kg−1 in day 40 by promoting the Fe(II) recrystallization. There is a positive correlation between the concentration of amFeox and Fe/Mn–Cd (p < 0.01). The scanning electron microscopy analysis showed that Cd was bound to the amFeox coating on the surface of Fe-modified biochar. By acting as an electron shuttle, the active surface of Fe-modified biochar may serve as a hotspot for Fe transformation, which promotes amFeox formation and Cd immobilization. This study highlights the potential of Fe-modified biochar for the remediation of Cd-contaminated soils and provides valuable insights into the development of effective remediation approaches for Cd-contaminated soils.

Unravelling the role of iron and manganese oxides in colouring Late Antique glass by micro-XANES and micro-XRF spectroscopies

This research aims to understand colouring technologies in 5th–7th centuries glass imported to Atlantic Britain by correlating the iron (Fe) and manganese (Mn) ratios and oxidation states with colour. Despite having a similar matrix chemical composition and concentrations of Fe and Mn oxides, these vessels display different colours (from green to yellow/amber, sometimes with purple streaks). Colour changes can be induced by controlling the reduction-oxidation reactions that occur during glass production, which are influenced by the raw materials, furnace and melt atmosphere, and recycling. To evaluate these parameters, reference glasses were prepared, following the composition of Late Antique archaeological glass recovered from Tintagel (UK) and Whithorn (UK). A corpus of archaeological and experimental glass samples was analysed using bulk Fe and Mn K-edge x-ray absorption near edge structure (XANES) spectroscopy, micro-XANES and micro x-ray fluorescence (μ-XRF) at beamline ID21, at the European Synchrotron Radiation Facility. Fe and Mn XANES spectra of the archaeological glass indicate that Fe and Mn are in a similar oxidation state in all the yellow samples, predominantly Fe3+ and Mn2+. No detectable difference in Mn and Fe oxidation state occurs in the purple streaks compared to the yellow glass bulk but μ-XRF maps of the distribution of Fe and Mn show that Mn is more concentrated in the purple streaks. This indicates that the purple colour of the streaks is mainly due to a higher Mn/Fe ratio and persistence of more oxidised manganese in the purple areas, even though it is difficult to detect. Many archaeological fragments appear pale green in transmitted light but amber in reflected light. XANES studies detected the presence of surface layers where manganese is more oxidised. This layer is believed to scatter transmitted and reflected light differently and might be responsible for the optical features of the archaeological glass.

Evaluation of Ceramic Properties of Bauxitic Materials from SE of Iberian Range

The use of aluminum-rich clays and bauxites as refractory materials is common. Upon firing, these materials form mullite crystals in the shape of needles embedded in a siliceous and vitreous matrix, with mullite being responsible for the refractory properties. In this study, bauxite samples for use in refractory applications have been characterized. Chemical analysis revealed that the alumina content varied between 34 and 40%, with silica values generally being high (around 40%), except for one sample (26%). Two samples were found to be the most suitable for use as “refractory clay” refractories. However, high silica or Fe oxide contents can affect mineralogical transformations at high temperatures. Mineralogical analysis confirmed the presence of several minerals in the bauxite materials, including kaolinite, halloysite, anatase, rutile, gibbsite and boehmite. Differential thermal analysis (DTA) showed the decomposition of gibbsite and its partial transformation to boehmite and alumina, and the dehydroxylation of kaolinite, with primary mullite crystallization observed at a high temperature. These findings provide valuable information for the selection and optimization of bauxite materials for refractory applications, considering their chemical composition and mineralogical characteristics.

A comparative study on the corrosion behavior of Q235 steel in saturated acidic red and yellow soils

Purpose The purpose of this paper is to study the corrosion behavior of Q235 steel in saturated acidic red and yellow soils. Design/methodology/approach The corrosion behavior of Q235 steel in saturated red and yellow soils was compared by weight-loss, SEM/EDS, 3D ultra-depth microscopy and electrochemical measurements. Findings Rp of the steel gradually increases and icorr gradually decreases in both the red and yellow soils with time. The Rp of the steel in the red soil is lower, but its icorr is higher than that in the yellow soil. The uniform corrosion rate, diameter and density of the corrosion pit on the steel surface in the red soil are greater than those in the yellow soil. Lower pH, higher contents of corrosive anions and high-valence Fe oxides in the red soil are responsible for its higher corrosion rates and local corrosion susceptibility. Originality/value This paper investigates the difference in corrosion behavior of carbon steel in saturated acidic red and yellow soils, which can help to understand the mechanism of soil corrosion.

Characteristics of iron (hydr)oxides and Cr(VI) retention mechanisms in soils from tropical and subtropical areas of China

Though both iron (hydr)oxides and soil organic matter (SOM) significantly influence heavy metal behaviors in soils, studies on the characteristics of natural minerals and the synergic effects of the two on Cr(VI) transformation are limited. This study investigated Cr(VI) retention mechanisms in four soils from tropical and subtropical regions of China based on a comprehensive characterization of Fe (hydr)oxides. These soils exhibited varying quantities of hematite, ferrihydrite and goethite, with distinct Al substitution levels and varied exposed crystallographic facets. Adsorption experiments revealed a positive correlation between Fe (hydr)oxide content and Cr(VI) fixation amount on colloid, which was influenced by the mineral types, Al substitution levels and facet exposures. Further, Cr(VI) was sequestered on soil by adsorption and reduction. In soils enriched with crystalline Fe (hydr)oxides, Cr(VI) reduction was primarily governed by SOM, while in soils enriched with poorly crystalline Fe (hydr)oxides, mineral-associated Fe(II) also contributed to Cr(VI) reduction. Aging experiments demonstrated that SOM and mineral-associated Fe(II) expedited Cr (VI) passivation and diminished the Cr leaching. These results improve our understanding of natural Fe (hydr)oxide structures and their impact on Cr(VI) behavior in soils, and shed light on complex soil-contaminant interactions and remediation of Cr(VI) polluted soils.

Straw mulching decreased the contribution of Fe-bound organic carbon to soil organic carbon in a banana orchard

The association between iron (Fe) oxides (Fe-O) and organic carbon is a vital mechanism for the long-term accumulation and stabilization of soil organic carbon (SOC). To thoroughly explore the impacts of straw mulching on Fe-bound organic carbon (Fe-OC), we conducted a mulching application experiment in a 2-year no-tillage banana orchard. Two treatments (a 2-year straw mulching treatment and no straw return treatment) were established using a randomized complete block design. The Fe-OC and SOC pools in the surface soil were determined, and the results showed that straw mulching significantly increased the SOC contents by 34.02 %, and soil Fe-OC accounted for approximately 12.24 %–25.34 % of the SOC. Compared with the control treatment, straw mulching significantly decreased the Fe-OC contents and their contribution to SOC, which may have been due to soil dithionite-extractable Fe oxide (Fed) contents, the abundance of the Acidibacter, and α-glucosidase activities. Synchrotron radiation-based Fourier transform infrared (SR-FTIR) microspectroscopy indicated that straw mulching increased the colocalization between cellulose/hemicelluloses and peptides, and the relationships among lignin, Fe-O, and peptides became stronger than those in the CK treatment. These findings imply that straw mulching may decrease Fe-OC pools through various physicochemical and microbial mechanisms, these soil Fe-OC contents may be preserved as lignin derivatives and microbial-derived organic compounds.

Fractionation and transport of compost‐derived dissolved organic matter fractions in saturated red soil and black soil columns

AbstractThe fractionation and transport of compost‐derived dissolved organic matter (DOMC) could affect the transport and fate of nutrients and DOM‐associated pollutants in the soil environment. In this study, the humic acid fraction of DOMC (HAC) and fulvic acid fraction of DOMC (FAC) were selected to investigate the fractionation and transport of DOMC in repacked soil columns of a red soil and a black soil under different KCl concentrations. The effluent DOMC fractions were monitored by ultraviolet (UV)‐visible (Vis) light and fluorescence spectroscopy. The results showed that the molecular weight (MW) of the effluent DOM approached that of the influent DOMC fractions with the injection of DOMC fractions. Three‐dimensional fluorescence excitation emission matrices (3D‐EEMs) coupled with parallel factor analysis resolved three fluorescent components, that is, low MW UV humic‐like substances (C1), high MW UV humic‐like substances (C2), and protein‐like substances (C3). The mobility of HAC and FAC decreased with increasing KCl concentrations (1 mM–50 mM), implying that electrostatic interaction was an important mechanism for the retention of DOMC in soil columns. The fact that the mobility of DOMC fractions in the black soil was greater than that in the red soil could be attributed to the high free Fe oxide content in the red soil. The retained DOMC fractions did not entirely desorb by the background electrolyte solution, suggesting that a part of the DOMC fractions retained in soil columns was strongly bound. These results are helpful in understanding the fractionation and transport of DOMC in soil environments.

Soil acidification suppresses phosphorus supply through enhancing organomineral association

It has long been assumed that soil acidification increases reactive iron and/or aluminum (Fe/Al) oxides and promotes Pi sorption onto mineral surfaces, resulting in a decrease in Pi. However, this assumption has seldom been tested in long-term field experiments. Using a 12-year acid addition experiment in a tropical forest, we demonstrated that soil acidification increased the content of noncrystalline Fe and Al oxides by 16.3 % and 27.7 %, respectively; whereas it did not alter the absorbed Pi pool and Pi sorption capacity. Furthermore, soil acidification increased the Fe/Al-bound organic matter content by 82.5 %, causing a 54.9 % reduction in Pi desorption, a 42.3 % decrease in soluble Pi content, and a 9.2 % increase in occluded Pi content. Our findings demonstrate that soil acidification reduces Pi bioavailability by repressing Pi desorption rather than enhancing Pi sorption. These results could be attributed to the enhanced organomineral association, which competes for sorption sites with Pi and promotes the Pi occlusion. However, the interactions between organomineral-Pi have not been incorporated into global land models, which may overestimate ecosystem productivity under future acid rain scenarios.

Short‐term phosphorus sorption and desorption in contrasting cropped Vertisols

AbstractVertisols are important cropping soils in tropical and subtropical areas, but in many regions, decades of cropping has substantially reduced concentrations of plant‐available phosphorus (P), especially in the subsoil layers. Phosphorus behaviour in P‐depleted Vertisols has received comparatively little attention, and the availability of P following the addition of inorganic P fertilisers at different concentrations is poorly understood. In this study, we evaluated short‐term P sorption and desorption behaviour in cropped Vertisols in relation to specific soil physical and chemical properties. We collected the surface and subsurface of 15 Australian soils with a broad range of physical and chemical properties, comprising nine Vertisols, three Ferralsols, two Lixisols and one Calcisol. For each soil, we generated sorption and desorption curves (fitted with a Freundlich equation), determined soil physical and chemical properties likely to influence P sorption and evaluated the relationships between the measured soil properties and the Freundlich equation sorption coefficients. The P sorption curves differed drastically between soils, with the sorption equation coefficients (aS × b) significantly correlated with the P buffering index (PBI) and clay content. Clay content itself was correlated with citrate‐extractable Fe and Al oxides and BET surface area. Vertisols formed on basaltic parent materials had greater Fe and Al oxide concentrations, resulting in an overall greater P sorption capacity. Sorption and desorption hysteresis were mostly small. The reacting materials in these soils probably had limited ability to continue to react with P. The Vertisols differed in their capacity to replenish P in the soil solution by desorbing different proportions of previously sorbed P, although the proportion of desorbable P generally increased with greater concentrations of sorbed P. These results suggest that for fertiliser management in these soils, smaller volumes of P enrichment combined with higher P concentrations may result in a greater P recovery by the crop.

Rape straw biochar enhanced Cd immobilization in flooded paddy soil by promoting Fe and sulfur transformation

Cd is normally associated with sulfide and Fe oxides in flooded paddy soil. The mechanisms of biochar enhanced Cd immobilization by promoting Fe transformation and sulfide formation are unclear. Rape straw biochar (RSB) pyrolyzed at 450 °C (LB) and 800 °C (HB) was added to Cd-contaminated paddy soil at 1% (LB1, HB1) and 2% (LB2, HB2) doses. The results showed that Fe/Mn oxide–Cd (Fe/Mn–Cd) and free Fe oxide (Fed) concentrations decreased in the first 12 days and then rose, while Fe2+ in pore water (W–Fe2+) tended to rise first and then fall. The electron transfer rate of soil in the HB2 treatment was 4.9-fold higher than that in the treatment without biochar (CK). Fe oxide reduction was enhanced by RSB, with a maximum increase in W–Fe2+ by 62.1% in HB2 on Day 12. The negative correlation between W–Fe2+ and Fed showed that Fe2+ promoted the reformatted of seconded Fe minerals after Day 12, and the Fed in the HB2 treatments increased by 31.5% in this period. RSB addition also promoted the reformation of poorly crystallized Fe oxide (Feo) by increasing soil pH, which increased by 17.2% and 15.1% on average in the LB2 and HB2 treatments, respectively, compared to CK. Compared to Day 7, the increased rate of Fe/Mn–Cd on Day 30 in RSB was approximately twice that of CK. Compared to the molybdate group, the maximum decrease in CaCl2–Cd was 29.1% in LB2 on Day 12. LB2 increased SO42− and acid-volatile sulfide concentrations by 6.9- and 4.1-fold, respectively, compared to CK. These results suggested that RSB, particularly HB, promoted more Cd adsorption in Fe minerals by increasing Fe hydroxylation and recrystallization processes. LB increased the contribution of sulfide to Cd immobility.

Physicochemical and Microstructural Characterization of Klias Peat, Lumadan POFA, and GGBFS for Geopolymer Based Soil Stabilization

Peat soils are highly heterogeneous and considered problematic because they have a high moisture content and low shear strength. It requires stabilization to enhance its engineering properties before it is transformed into a viable construction material. The use of geopolymers as stabilizer materials for weak soils has been on the rise recently due to their low carbon footprint compared to the use of conventional stabilizer materials like cement. Geopolymerization occurs as a result of the alkali activation of aluminosilicate materials. In this study, peat soil and the aluminosilicate materials Palm Oil Fuel Ash (POFA) and Ground Granulated Blast Furnace Slag (GGBFS) are characterized to assess their suitability as geopolymer precursor materials. A series of laboratory studies were carried out to determine the physicochemical properties of the materials, such as particle size distribution, moisture and organic content, specific gravity, pH, and electrical conductivity. Furthermore, the XRD, XRF, and FESEM tests were carried out to ascertain the mineral characteristics, elemental chemical composition, and morphological characteristics of these materials, respectively. The peat soil is classified as hemic peat with sufficient aluminosilicate content (Si/Al ratio of 2.11). The POFA is identified as Class F pozzolan with adequate Si+Al+Fe oxide content (67.9%), as stipulated by ASTM C618. The GGBFS material was found to be appropriate for geopolymer production, with a Si/Al ratio of 2.17, a hydration modulus of 2.38 (good hydration), and a basicity coefficient of 1.32 (alkaline material favorable for geopolymerization). Based on the geopolymer precursor material suitability assessment criteria, all the materials assessed were deemed suitable for geopolymerization, and the effectiveness of POFA-GGBFS geopolymer to improve peat soil properties should be studied in depth. At present, there are limited studies pertaining to the use of alkali-activated POFA-GGBFS blends to improve peat soil properties. As a result of this material characterization phase, planned works involving the compressive strength testing program on alkali-activated POFA-GGBFS-peat soil blends at ambient temperature will be carried out in the near future. The eventual aim of this research is to remediate the peat soil to be repurposed as road subgrade material. Doi: 10.28991/HIJ-2023-04-02-07 Full Text: PDF

The importance of moisture in regulating soil organic carbon content based on a comparison of “enzymic latch” and “iron gate” in Zoige Plateau peatland

Due to the enormous amount of carbon (C) stored in peatlands, understanding the regulator of soil organic carbon (SOC) in peatlands is critical for global C cycling. Currently, “enzymic latch” and “iron gate” are the frequently debated mechanisms that propose phenol oxidase (PHO) and Fe2+ as important regulators driving SOC cycling in peatland. Therefore, this study compared “enzymic latch” and “iron gate” in the same peatland (Zoige Plateau, the largest peatland in China) to figure out the crucial regulator of SOC content via investigating the interrelationships among soil properties, C-related enzymes, phenolics, and iron (Fe) oxides. Moreover, waterlogged and non-waterlogged soils were chosen to take samples in both dry and wet season to understand the potential role of moisture in regulating SOC content. It was found that the contents of dissolved organic C, phenolics, SOC, Fe oxides, and β-glucosidase (BG) activities in waterlogged soils were higher than those in non-waterlogged soils. Compared to the dry season, soils in the wet season had higher phenolics, SOC, and Fe oxides contents. Also, this study observed an insignificant relationship between PHO and SOC (p > 0.05) and the small amounts of Fe2+ to total Fe (<2‰) in soils. Meanwhile, the highest effect of moisture (0.89) and negligible effect of PHO (0.04) and Fe2+ (-0.08) on SOC based on pathway analysis suggested that moisture might be the crucial regulator of SOC. Furthermore, pathway analysis implied that moisture could indirectly affect SOC by adjusting BG (p < 0.05) and soluble phenolics (p < 0.05). This study provided valuable information for understanding the importance of moisture in driving C cycling and helping against soil C loss by moisture management in Zoige Plateau.