Fast Charge Research Articles

Supramolecular Crystals based Fast Single Ion Conductor for Long‐Cycling Solid Zinc Batteries

AbstractThe solid polymer electrolytes (SPEs) used in Zn‐ion batteries (ZIBs) have low ionic conductivity due to the sluggish dynamics of polymer segments. Thus, only short‐range movement of cations is supported, leading to low ionic conductivity and Zn2+ transference (tZn2+). Zn‐based supramolecular crystals (ZMCs) have considerable potential for supporting long‐distance Zn2+ transport; however, their efficiency in ZIBs has not been explored. The present study developed a ZMC consisting of succinonitrile (SN) and zinc bis (trifluoromethylsulfonyl) imide (Zn(TFSI)2), with a structural formula identified as Zn(TFSI)2SN3. The ZMC has ordered three‐dimensional tunnels in the crystalline lattices for ion conduction, providing high ionic conductivities (6.02×10−4 S cm−1 at 25 °C and 3.26×10−5 S cm−1 at −35 °C) and a high tZn2+ (0.97). We demonstrated that a Zn‖Zn symmetrical battery with ZMCs has long‐term cycling stability (1200 h) and a dendrite‐free Zn plating/stripping process, even at a high plating areal density of 3 mAh cm−2. The as‐fabricated solid‐state Zn battery exhibited excellent performance, including high discharge capacity (1.52 mAh cm−2), long‐term cycling stability (83.6 % capacity retention after 70000 cycles (7 months)), wide temperature adaptability (−35 to 50 °C) and fast charging ability. The ZMC differs from SPEs in its structure for transporting Zn2+ ions, significantly improving solid‐state ZIBs while maintaining safety, durability, and sustainability.

Accurate, Fast, and Non-Destructive Net Charge Measurement of Levitated Nanoresonators Based on Maxwell Speed Distribution Law

Nanoscale resonant devices based on optical tweezers are widely used in the field of precision sensing. In the process of driving the nanoresonator based on the Coulomb force, the real-time, precise regulation of the charge carried by the charged resonator is essential for continuous manipulation. However, the accuracy of the existing charge measurement methods for levitated particles is low, and these methods cannot meet the needs of precision sensing. In this study, a novel net charge measurement protocol for levitated particles based on spatial speed statistics is proposed. High-precision mass measurement based on Maxwell’s rate distribution law is the basis for improving the accuracy of charge measurement, and accurate measurement of net charge can be achieved by periodic electric field driving. The error of net charge measurement is less than 7.3% when the pressure is above 0.1 mbar, while it can be less than 0.76% at 10 mbar. This proposed method features real-time, high-precision, non-destructive, and in situ measurement of the net charge of particles in the medium vacuum, which provides new solutions for practical problems in the fields of high-precision sensing and nano-metrology based on levitated photodynamics.

Enabling Interfacial Lattice Matching by Selective Epitaxial Growth of CuS Crystals on Bi2WO6 Nanosheets for Efficient CO2 Photoreduction into Solar Fuels

AbstractPhotocatalytic CO2 reduction serves as an important technology for value‐added solar fuel production, however, it is generally limited by interfacial charge transport. To address this limitation, a two‐dimensional/two‐dimensional (2D/2D) p‐n heterojunction CuS‐Bi2WO6 (CS‐BWO) with highly connected and matched interfacial lattices was designed in this work via a two‐step hydrothermal tandem synthesis strategy. The integration of CuS with BWO created a robust interface electric field and provided fast charge transfer channels due to the work function difference, as well as highly connected and matched interfacial lattices. The p‐n heterojunction combination promoted the electron transfer from the Cu to Bi sites, leading to the coordination of Bi sites with high electronic density and low oxidation state. The Bi sites in the BWO nanosheets facilitated the adsorption and activation of CO2, and the generation of high‐coverage key intermediate b‐CO32−, while CuS (CS) acted as a broad light‐harvesting material to provide abundant photoinduced electrons that were injected into the conduction band of BWO for CO2 photoreduction reaction. Remarkably, the p‐n heterojunction CS‐BWO exhibited average CO and CH4 yields of 33.9 and 16.4 μmol g−1 h−1, respectively, which were significantly higher than those of CS, BWO, and physical mixture CS‐BWO samples. This work provided an innovative design strategy for developing high‐activity heterojunction photocatalyst for converting CO2 into value‐added solar fuels.

Health-aware battery fast charging technique with zonal battery model using pulsed amplitude-width modulation and multi-step constant current constant voltage

ABSTRACT This article presents an innovative method for rapidly charging batteries while considering health factors. The strategy utilizes a closed-loop control approach based on a mathematical model. Initially, an intricate thermo-electric aging cell model (TEACM) was constructed based on electrochemical aging study. The model’s parameters are continuously updated in real-time by pulling data from the battery pack while it is being charged. The TEACM algorithm analyzes the parameter values and calculates different battery statuses. These estimations are then used to improve the charging process. The charge optimization phase optimizes the precharging and boosts charging processes individually. Several pulse precharging approaches have been analyzed, and by calculating the diffusion coefficient, the most effective precharging method has been identified. The use of multistage constant current technique is utilized to optimize the battery charging process. The optimization is accomplished by implementing the non-linear model predictive controller. Ultimately, the two refined charging methods are combined and sent to the charger. The hypothesis was validated using a cell cycling test bench. The acquired findings were compared with other recognized benchmark charging techniques, demonstrating that the suggested approach charges the cell in half the time compared to the 1C-CCCV charging methodology while also increasing the cycle life by 6.67%.

Renewable energy driven on-road wireless charging infrastructure for electric vehicles in smart cities: A prototype design and analysis

The adoption of electrical vehicles (EVs) has increased due to the increasing concerns about fossil fuel shortages, rising costs, and environmental impacts. This increasing adoption of EVs significantly increase power demand on utility grids. Moreover the EVs require more time for charging compared to fossil fuel vehicles. To address these challenges, this study proposes a renewable energy-based on-road wireless charging (ORWC) infrastructureto reducing charging time and utilizing renewable energy within a smart city framework. This study develops a prototype of the ORWC system and examines its techno-economic and environmental benefits. Moreover, the study also evaluates annualized energy share, energy economics, and cost-effectiveness. The results of the proposed study indicate that the ORWC system in combination with RERs, effectively reduces the cost of energy from $0.112/kWh to $0.30/kWh and lowers carbon emissions from 76.9 tons/year to 29.5 tons/year. Furthermore, the results also reveals optimal energy distribution among different energy resources PV, BESS, and the grid. These results highlight that ORWC infrastructure can reduce peak load demand on existing grids and enhance the power density of EV charging systems. This has potential implications for future-oriented fast charging stations and policy development to support the widespread adoption of EVs.

Understanding Electrochemical Reaction Mechanisms of All-Electrochem-Active Mg2Si Electrode in All-Solid-State Batteries.

To better understand the electrochemical reaction mechanism of the Mg2Si electrode in all-solid-state batteries (ASSBs), a rational all-electrochem-active Mg2Si electrode is first designed to minimize the inactive component-related interfacial degradation. This is due to its unique mixed conductivity properties, including a high electronic conductivity of up to 8.9 × 10-2 S cm-1 and an ionic conductivity of 9.7 × 10-5 S cm-1, which allow for fast charges transport. In ASSBs, the Mg2Si electrode exhibits a higher initial Coulombic efficiency of 83.5% at 300 mA g-1 compared with the Si electrode (72.3%). X-ray diffraction and X-ray photoelectron spectroscopy results demonstrate that intermediate products (LixMg2Si, Li-Si alloy, and Li-Mg alloy) can form when the Mg2Si electrode discharges to 0.01 V, and partial Mg2Si still does not react with lithium. This work provides valuable insights into the reaction mechanisms and guides optimization strategies for developing next-generation Si-based ASSBs.

Rational design of MoS2/CNT heterostructure with rich S-vacancy for enhanced HER performance.

Molybdenum disulfide (MoS2) is a promising electrocatalyst for the hydrogen evolution reaction (HER) due to excellent stability and low cost. However, the utilization in electrocatalytic hydrogen evolution is constrained by inherent shortcomings, including fewer edge active sites, poor dispersion, and electrical conductivity. In this work, MoS2 was compounded with carbon nanotubes (CNTs), which are known for their high specific surface area and excellent electrical conductivity. These CNTs, laden with oxygen-containing functional groups, provided nucleation sites that facilitated the rapid assembly of MoS2 nanoflowers under hydrothermal conditions within 3h. Due to their diminutive size (∼300nm), these nanoflowers possess a large specific surface area and numerous active sites at their edges. Furthermore, MoS2 nanoflowers exhibited a high concentration of intrinsic S-vacancies. This heterojunction material exhibited superior HER properties. In addition, density functional theory simulation further confirmed that the MoS2 with S vacancy and CNT heterojunction electrocatalysts (VS-M/C) provided a fast charge transfer pathway for water electrolysis, and analysis showed that the conduction band minimum and valence band maximum were mainly contributed by the d orbits of Mo and the p orbits of C. This study proffered a novel approach for the engineering of high-performance MoS2-based HER electrocatalysts.

Fast Charging Sodium‐Ion Full Cell Operated From −50 °C to 90 °C

AbstractThe application of sodium‐ion batteries (SIBs) within grid‐scale energy storage systems (ESSs) critically hinges upon fast charging technology. However, challenges arise particularly with anodes such as hard carbon (HC), which exhibits a low working plateau (less than 0.1 V vs Na/Na+) and is susceptible to sodium dendrite issues under high current densities. In this study, a cost‐effective SIB system comprising Na2.4Fe1.8(SO4)3 (NFS) cathode, NaTi2(PO4)3 (NTP) anode, and ester‐based electrolyte is assembled to solve the fast‐charging obstacle. Benefiting from the fast sodium‐ion diffusion kinetics and relatively high voltage platform of NTP anode, this full cell can work for 10 000 cycles at 10 C rate with a notable capacity retention of 70.7%. Moreover, this investigation reveals that the full cell can operate safely between ‐50 to 90 °C even with an ester‐based electrolyte, thereby showcasing broad application prospects. This work provides a valuable guidance for designing fast charging and wide temperature SIBs.

Optimization Strategies of Hybrid Lithium Titanate Oxide/Carbon Anodes for Lithium-Ion Batteries

Lithium-ion batteries, due to their high energy density, compact size, long lifetime, and low environmental impact, have achieved a dominant position in everyday life. These attributes have made them the preferred choice for powering portable devices such as laptops and smartphones, power tools, and electric vehicles. As technology advances rapidly, the demand for even more efficient energy storage devices continues to rise. In lithium-ion batteries, anodes play a crucial role, with lithium titanate oxide standing out as a highly promising material. This anode is favored for its exceptional cycle stability, safety features, and fast charging capabilities. The impressive cycle stability of lithium titanate oxide is largely due to its zero-strain nature, meaning it undergoes minimal volume changes during lithium-ion insertion and extraction. This stability enhances the anode’s durability, leading to longer battery life. In addition, the lithium titanate oxide anode operates at a voltage of approximately 1.55 V vs. Li+/Li, significantly reducing the risk of dendrite formation, a major safety concern that can cause short circuits and fires. The material’s spinel structure, with its large active surface area, further allows fast electron transfer and ion diffusion, facilitating fast charging. This review explores the characteristics of lithium titanate oxide, the various synthesis methods employed, and its integration with carbon materials to enhance cycle stability, coulombic efficiency, and safety. It also proposes strategies for optimizing lithium titanate oxide properties to create sustainable anodes with reduced environmental impact using eco-friendly routes.

Accelerated Ion-Electron Transport in Bi-Heterostructures Constructed Based on Ohmic Contacts for Efficient Bi-Directional Catalysis of Lithium-Sulfur Batteries.

Although lithium-sulfur batteries have satisfactory theoretical specific capacity and energy density, they are difficult to further commercialize due to the shuttle effect of soluble polysulfides and slow sulfur oxidation kinetics. Based on this, in this work, the catalyst MXene-VS4-SnS2 (MVS), a dual heterostructured catalyst with ohmic contacts, is prepared by a one-step hydrothermal method and electrostatic self-adsorption for lithium-sulfur battery cathode materials. Experimental and theoretical results show that the ohmic contact induces spontaneous charge rearrangement, resulting in the formation of a fast charge transfer pathway at the MVS heterojunction interface, which helps to reduce the energy barrier for polysulfide reduction and Li2S oxidation during the discharge/charge process. In addition, the inherent sulfophilicity of VS4 and SnS2 promotes the conversion of S species, while the pleated MXene nanosheets not only provide a highly conductive network for the active sulfur but also retain a rich internal space to maintain the integrity of the cathode structure during the continuous cycling process. As a result, the MVS cathode exhibits excellent electrochemical performance even under high sulfur loading. The integration of excellent performance with a facile synthesis process provides a promising approach for designing highly efficient electrocatalysts suitable for the energy field.

Advancing sustainable EV charging infrastructure: A hybrid solar-wind fast charging station with demand response

This study aims to design an efficient hybrid solar-wind fast charging station with an energy storage system (ESS) to maximize station efficiency and reduce grid dependence. The research employs Monte Carlo simulation to capture renewable energy source (RES) uncertainties, models stochastic electric vehicles (EVs) driver behavior and fleet diversity, and utilizes an Erlang B queuing model for EV load demand estimation. A hybrid optimization approach combining the Binary-Gravitational Search Optimization Algorithm (B-GOA) and the Non-dominated Crowding Sort Optimization Algorithm (NCSOA) is implemented for efficient optimization in a combined binary-continuous solution space. Results demonstrate superior performance of the proposed approach compared to existing methods, with high-RES penetration significantly reducing grid reliance. This study contributes to advancing sustainable EV charging infrastructure development and enhancing overall grid stability through improved load flexibility and demand response management. The analysis reveals Scenario IV as the most economically viable, with the highest Net Present Value of 1,025,895.32€. Most scenarios favor 5 chargers (44–46 kW) and 4 Type 3 wind generators. Battery capacity varies widely (108–372 kWh), as does grid connection (0–292 kW). Despite varying initial investments, Scenarios II-VII show a consistent 4-year Internal Rate of Return, indicating good economic potential across different configurations.

Tailoring-Orientated Deposition of Li2S for Extreme Fast-Charging Lithium-Sulfur Batteries.

Precipitation/dissolution of insulating Li2S has long been recognized as the rate-determining step in lithium-sulfur (Li-S) batteries, which dramatically undermines sulfur utilization at elevated charging rates. Herein, we present an orientated Li2S deposition strategy to achieve extreme fast charging (XFC, ≤15 min) through synergistic control of porosity, electronic conductivity, and anchoring sites of electrode substrate. Via magnesiothermic reduction of a zeolitic imidazolate framework, a nitrogen-doped and hierarchical porous carbon with highly graphitic phase was developed. This design effectively reduces interfacial resistance and ensures efficient sequestration of polysulfides during deposition, leading to (110)-preferred growth of Li2S nanocrystalline between (002)-dominated graphitic layers. Our approach directs an alternative Li2S deposition pathway to the commonly reported lateral growth and 3D thickening growth mode, ameliorating the electrode passivation. Therefore, a Li-S cell capable of charging/discharging at 5C (12 min) while maintaining excellent cycling stability (82% capacity retention) for 1000 cycles is demonstrated. Even under high S loading (8.3 mg cm-2) and low electrolyte/sulfur ratio (3.8 mL mg-1), the sulfur cathode still delivers a high areal capacity of >7 mAh cm-2 for 80 cycles.

Optimizing EV fast charging infrastructure: integrating high-gain interleaved converter with advanced MPPT

ABSTRACT Modernizing the Electric Vehicle (EV) charging infrastructure is essential for the widespread adoption of electric mobility. This research addresses the imperative need for enhancing the power performance of photovoltaic (PV) grid-connected inverters for EV fast charging applications. The system integrates Voltage-Oriented Control (VOC) for the PV inverter, a High-Gain Interleaved (Single Ended Primary Inductance Converter) SEPIC-Cuk (HGISC) converter, and a Bald Eagle Search Optimized Adaptive Neuro Fuzzy Inference System (BESO-ANFIS)) algorithm. VOC with Proportional Resonant (PR) ensures optimized energy transfer to grid, while the HGIBC converter enhances power performance. The proposed BESO-ANFIS Maximum Power Point Tracking (MPPT) dynamically tracks the PV array’s Maximum Power Point (MPP) under varying conditions. Additionally, a bidirectional battery converter in the energy storage system optimizes power usage. The synergistic implementation of these advanced controller results in a comprehensive solution, showcasing improved power output, grid integration, and efficient solar energy utilization for EV fast charging. MATLAB simulations and experiments demonstrate 97% efficiency and reduced Total Harmonic Distortion (THD) of 0.98%, positioning this research as an advanced solution for EV charging infrastructure enhancement.

Water-Mediated Surface Engineering Enhances High-Voltage Stability of Fast-Charge LiCoO2 Cathodes.

Maintaining the surface structure stability of LiCoO2 (LCO) during rapid charge-discharge processes (>5C) and under high-voltage conditions (>4.2 V) is challenging due to interfacial side reactions, cobalt dissolution, and oxygen redox activity at deeply delithiated states, all of which contribute to performance degradation. Herein, different from traditional surface coating methods, we report a water-mediated strategy that modifies the surface architecture of LCO, creating a passivating layer to inhibit surface degradation and enhance cycling stability under fast charging conditions. The surface etching of LCO by H2O is accompanied by a concurrent Li+/H+ cation exchange, which passivates surface oxygen with H+ ions, thereby enhancing both the hydrophobicity and structural stability. Consequently, the modified LCO exhibits superior capacity retention, which is 2.5 times that of the pristine LCO, after 100 cycles at a current density of 1000 mA g-1 (∼6C at 4.5 V). Even at an elevated temperature of 45 °C, it maintains impressive cycling stability at a current density of 500 mA g-1 (∼3C), as demonstrated in practical full-cell configurations. Investigation with multiple samples confirmed that the water-mediated strategy demonstrated broad applicability. We emphasize that the water-mediated modification of the surface architecture on cathode materials offers significant insights into enhancing the stability of high-energy-density lithium-ion batteries (LIBs).

Optimized multi-stage constant current fast charging protocol suppressing lithium plating for lithium-ion batteries using reduced order electrochemical-thermal-life model

Multi-stage Constant Current (MCC) is a state-of-the-art fast-charging protocol considering battery aging. It divides the charging process into multiple stages, each with a different current amplitude based on specific transition criteria, significantly influencing battery performance, such as charging time, degradation rate, and thermal effects. A key challenge in designing MCC protocols is addressing the lithium plating (LiP), which can accelerate degradation and pose a severe risk of thermal runaway. Since the LiP onset conditions vary between fresh and aged cells, this paper proposes an optimized MCC (O-MCC) charging protocol suppressing LiP based on the battery's state of health. To accurately simulate LiP conditions, different platforms of reduced-order electrochemical-thermal-life models are designed, compared, and optimized for speed and accuracy using a genetic algorithm, resulting in a 36.4 % reduction in computational time while maintaining the accuracy of the Pseudo Two-Dimensional model. The Nonlinear Model Predictive Control algorithm is then used to optimize the MCC protocol, minimizing charging time while preventing LiP throughout life. Experimental results show that O-MCC reduces charging time by 11.7 % and capacity loss by 59.4 %, enhancing battery safety. Additionally, O-MCCs with varying constraints are developed to meet specific demands and simulated at the battery pack level.

Long‐Term Estimation of SoH Using Cascaded LSTM‐RNN for Lithium Batteries Subjected to Aging and Accelerated Degradation

ABSTRACTAccurate estimation of state of health (SoH) of the battery over long‐term is a critical challenge for the battery management systems in electric vehicles. This is due to the challenges in accurately modeling the accelerated aging and degradation phenomena caused by diverse operating conditions of the battery. This paper presents a cascaded recurrent neural networks (RNN) with long short‐term memory (LSTM) to estimate the internal resistance and SoH, taking account of various abnormal operating conditions of the battery. A datasheet‐based degradation model of the battery is developed using fade equations. The training and validation data set for LSTM‐RNN are generated by subjecting the battery model to various factors that cause accelerated degradation, such as fast charging, varying operating temperatures, overutilization, and cell imbalance. The cascaded LSTM‐RNN is trained to estimate SoH only once after the completion of every charge–discharge cycle. The training error index parameters of the proposed SoH estimator are well within 1%, demonstrating the reliability and robustness of the estimator to diverse operating conditions of the battery.

Nanoclay Mediated Two-Pronged Strategy for Infected-Wound Healing.

Photothermal therapy (PTT) is an efficient way to combat bacterial infections and circumvent multidrug resistance. However, balancing efficacious bacterial killing and minimizing damage to the surrounding normal tissues remain a great challenge. Herein, a highly cooperative Prussian blue/kaolinite (PB/Kaol) hybrid nanosystem is constructed for antibacterial therapy to accelerate the healing of infected wounds. After hybridization with Kaol, the prepared PB/Kaol forms interfacial Al-O-Fe bonds, a fast charge transfer channel from Kaol to PB, which contributes to the enhanced photothermal effect of PB/Kaol. Additionally, the hydroxyl and Lewis acid-base sites of the Kaol surface could promote the adhesion of PB/Kaol to bacteria, thereby ensuring that as much hyperthermia as possible is focused on the bacteria and minimizing damage to the surrounding healthy tissues. Furthermore, PB/Kaol inherits the anti-inflammatory and hemostasis functions of PB and Kaol, resulting in the rapid healing of infected wounds.

A Facile Electrochemical Strategy for Achieving a High-Conductivity Polypyrrole Derivative with Intrinsic Metallic Transport as a High-Performance Electrochromic Conducting Polymer Film.

Conjugated polymer electrochromic materials (PECMs) with tailored optical and electrical properties are applied in smart windows, electronic displays, and adaptive camouflage. The limitation in the electrical conductivity results in slow and monotonous color switching. We present a polypyrrole film incorporated with a toluene-p-sulfonic group (PPy-TSO-F), via a one-step electrodeposition technique. The PPy-TSO-F thin film (110 nm) achieves an impressive electrical conductivity of 1011 S cm-1, a high carrier mobility of 82 cm2 V-1 s-1, and intrinsic metallic electronic behavior. It demonstrates exceptionally reversible multicolor switching, transitioning from emerald green (-1.5 V), to bluish green (-1.4 V), bright yellow (-1.2 V), greenish yellow (-0.6 V), reddish brown (0.1 V), dark brown (0.3 V), and atrovirens (0.6 V). The fast charge transport and high carrier mobility render the film with an ultrafast electrochromic switching speed of 0.01 s/0.02 s. This research provides a new route to designing ultrafast multicolor switching PECMs with metallic charge transport.

Supramolecular Crystals based Fast Single Ion Conductor for Long-cycling Solid Zinc Batteries.

The solid polymer electrolytes (SPEs) used in Zn-ion batteries (ZIBs) have low ionic conductivity due to the sluggish dynamics of polymer segments. Thus, only short-range movement of cations is supported, leading to low ionic conductivity and Zn2+ transference (tZn2+). Zn-based supramolecular crystals (ZMCs) have considerable potential for supporting long-distance Zn2+ transport; however, their efficiency in ZIBs has not been explored. The present study developed a ZMC consisting of succinonitrile (SN) and zinc bis(trifluoromethylsulfonyl)imide (Zn(TFSI)2), with a structural formula identified as Zn(TFSI)2SN3. The ZMC has ordered three-dimensional tunnels in the crystalline lattices for ion conduction, providing high ionic conductivities (6.02 × 10-4 S cm-1 at 25 °C and 3.26 × 10-5 S cm-1 at -35 °C) and a high tZn2+ (0.97). We demonstrated that a Zn‖Zn symmetrical battery with ZMCs has long-term cycling stability (1200 h) and a dendrite-free Zn plating/stripping process, even at a high plating areal density of 3 mAh cm-2. The as-fabricated solid-state Zn battery exhibited excellent performance, including high discharge capacity (1.52 mAh cm-2), long-term cycling stability (83.6% capacity retention after 70000 cycles (7 months)), wide temperature adaptability (-30 to 50 °C) and fast charging ability.

A DFT Study of Band-Gap Tuning in 2D Black Phosphorus via Li+, Na+, Mg2+, and Ca2+ Ions.

Black phosphorus (BP) and its two-dimensional derivative (2D-BP) have garnered significant attention as promising anode materials for electrochemical energy storage devices, including next-generation fast-charging batteries. However, the interactions between BP and light metal ions, as well as how these interactions influence BP's electronic properties, remain poorly understood. Here, we employed density functional theory (DFT) to investigate the effects of monovalent (Li+ and Na+) and divalent (Mg2+ and Ca2+) ions on the valence electronic structure of 2D-BP. Molecular orbital analysis revealed that the adsorption of divalent cations can significantly reduce the band gap, suggesting an enhancement in charge transfer rates. In contrast, the adsorption of monovalent cations had minimal impact on the band gap, suggesting the preservation of 2D-BP's intrinsic electrical properties. Energetic and charge analyses indicated that the extent of charge transfer primarily governs the ability of ions to modulate 2D-BP's electronic structure, especially under high-pressure conditions where ions are in close proximity to the 2D-BP surface. Moreover, charge polarization calculations revealed that, compared with monovalent cations, divalent cations induced greater polarization, disrupting the symmetry of the pristine 2D-BP and further influencing its electronic characteristics. These findings provide a molecular-level understanding of how ion interactions influence 2D-BP's electronic properties during ion-intercalation processes, where ions are in close proximity to the 2D-BP surface. Moreover, the calculated diffusion barrier results revealed the potential of 2D-BP as an effective anode material for lithium-ion, sodium-ion, and magnesium-ion batteries, though its performance may be limited for calcium-ion batteries. By extending our understanding of interactions between ions and 2D-BP, this work contributes to the design of efficient and reliable energy storage technologies, particularly for the next-generation fast-charging batteries.