Extra Charge Research Articles

Two unequal shots in the same hole: statistical versus deterministic deconvolution

Determination of the source time function and earth impulse response for explosive source seismic reflection data is traditionally performed using predictive deconvolution, which assumes the reflection seismogram is the convolution of a minimum-phase wavelet with a white, random, stationary sequence of impulses. We compare this statistical method with a new deterministic method that uses two unequal shots close together in the same hole and assumes a seismogram is the convolution of a source time function with a Green's function, plus noise. The seismograms from the two shots share essentially the same Green's function to any receiver, because the shots are close together. The Green's function is estimated by deconvolving the two seismograms at a given receiver for the corresponding source time functions, modelled independently; source parameters are obtained by trial-and-error by minimising the difference between the two estimates of the Green's function. We test these competing theories using seismic reflection data acquired with two charges fired separately in the same hole into a receiver spread of 1178 bunched geophone groups at 10 m intervals: a 1 kg charge at 42 m depth and 2 kg at 40 m depth. The criterion for comparison of the theories is the similarity of the recovered impulse responses at any receiver. Each method recovers a wavelet, or source time function, for each shot and two estimates of the impulse response, or Green's function, at each receiver. The Green's functions recovered from the two shots using the deterministic method are almost identical and are measurably more similar than the impulse responses recovered using predictive deconvolution. That is, the deterministic method is better. The resolution of explosive source seismic reflection data can now be significantly improved with the new method and minimal additional field effort of loading one extra charge per shot hole.

Ti- and Ba-rich phlogopitic micas in alkaline basic and upper mantle igneous rocks; stoichiometry, stability, and Fe valence estimation reassessed and rationalised

Ti- and Ba-rich tri-octahedral micas occur in fractionated basic igneous rocks, metasomatized mantle peridotites, metamorphosed pelites/carbonates, and hydrothermally altered mineral deposits. Electron microprobe analyses (EMP), with all iron reported as FeO, were widely used in the 1970/80s to interpret Ti and Ba substitution mechanisms, based on 22 O2– unit cell calculations, implying that cation vacancies occur in octahedral and/or intersheet sites. In 1996 EMP with chemical and physical analyses for ferric and total Fe, H2O, (OH), and element-specific Fe X-ray Absorption Spectroscopy (both K and L-edges) established valence states for Fe and Ti and cation site occupancies, that ∼50 % O replaces (OH) molecules, and that 24 anion cell formulae show the absence of cation vacancies. Cell formula calculation protocol for phlogopitic micas is refined here and results tested against the stoichiometric formula for vacancy-free phlogopite, XIIK2VIMg6IV[Si6Al2]O20(OH)4. Hypothetical sheet silicate compositions, calculated with fixed contents of vacancies linked to particular mixed-valence element substitutions, confirm that reliable unit cell formulae for natural mica solids require that each stoichiometric vacancy must be accounted for. If reliable estimates for ‘excess O’ (denoted WO2−) are assigned to EMP analyses, the proportion of the oxy-mica component in a mica solid solution can be defined. This approach is tested using published analyses for Ti- and Ba-rich biotites from fractionated basic and ultramafic volcanic igneous rocks (oxymica range 2.5–45 %; TiO2 up to 14 %; BaO up to 23 %), upper mantle peridotites (equivalent values 7–18 %; 6 %; 0.7 %), and metasomatised upper mantle (2–37 %; 9 %; 23 %). Enrichments of Ti and Ba in micas are clearly linked to the extra oxygen charge required to neutralise the more highly charged Ba2+ and Ti4+ replacing K+ and Mg2+.Substitution mechanisms involving Ba, Ti, and Fe3+ in ideal phlogopite involve coupled inter-site / inter-valence interactions so both site-ordering and valence-balance between the different cation sites must be accounted for. The cation exchange 2XIIK+ + 4VI(Mg2+ + Fe2+) + 4IVSi4+ ↔ XIIBa2+ + 3VITi4+ + 4(Altotal + Fe3+ + Crtotal)3+ is used here so that valence and site order can be considered together. Compositional variations show well-defined trends towards high-oxymica content and vacancy-free Ti and Ba mica end-members, rather than to oxy-free end-members with essential vacancies. Average compositions for different source rock micas are used to assess compositional trends; molecular WO2− values are refined by relating initial estimates directly to the wt.% TiO2 contents; and refined WO2− and stoichiometrically calculated Fe3+/Fetotal ratios ranging ∼0.1–0.5) are correlated with possible primary magmatic values.

Investigating the ions emitted by multiply charged ionic liquids from a porous electrospray ion source

A porous electrospray ion source was tested with three ionic liquids in order to investigate the effects of ionic liquid properties on the sizes of ion clusters emitted by purely ionic electrospray sources. Two of the ionic liquids, bis(1-ethyl-3-methylimidazolium) tetrathiocyanatocobaltate and 1,6-bis(3-methylimidazolium-1-yl)hexane bis(trifluoromethylsulfonyl)amide, were selected due to them having a dication or dianion, which were termed multiply charged ionic liquids due to them containing anions or cations with more than one charge within them. These were selected in order to investigate ionic clustering within electrospray ion emission and were compared against one of the most common ionic liquids, EMI-BF4. The current–voltage data showed that EMI-BF4 emitted similar levels of current to bis(1-ethyl-3-methylimidazolium) tetrathiocyanatocobaltate, even though the latter liquid had significantly lower conductivity and higher viscosity, suggesting an improvement in current speculated to be due to the extra charges contained by the ions. Time-of-flight and retarding potential analysis data are provided, showing all three liquids emitting ions comprising of monomers, dimers, trimers, and quadramers, with some of the 1,6-bis(3-methylimidazolium-1-yl)hexane bis(trifluoromethylsulfonyl)amide data showing heavier species emission. The data also suggested that the multiply charged ionic liquids produced ions that have two anions or cations attached, termed “double ions,” with these ions not been previously reported using porous electrospray sources. Furthermore, it was found that the dimers emitted by both of the multiply charged ionic liquids seemed to be more stable than EMI-BF4 dimers, providing insight into ion cluster formation.

Facilitating the Hydrogen Evolution Reaction on Basal-Plane S Sites on MoS2@Ni3S2 by Dual Ti and N Plasma Treatment.

Atomic engineering of the basal plane active sites in MoS2 holds great promise to boost the electrocatalytic activity for hydrogen evolution reactions (HER), yet the performance optimization and mechanism exploration are still not satisfactory. Herein, we proposed a dual-plasma engineering strategy to implant Ti and N heteroatoms into the basal plane of MoS2 supported by Ni3S2 nanorods on nickel foam (MSNF) for efficient electrocatalysis of HER. Owing to the low formation energy of Ti dopants in MoS2 and the extra charge carriers introduced by N dopants, the optimally codoped samples N1.0@Ti500-MSNF demonstrate significant morphology changes from nanorods to urchin-like nanospheres with the surface active areas increased by seven-fold, as well as enhanced electrical conductivity in comparison with the nondoped counterparts. The HER performance of N1.0@Ti500-MSNF is comparable with the Pt-based catalyst: overpotential of 26 mV at 20 mA cm-2, Tafel slope of 35.6 mV dec-1, and long-term stability over 50 h. First-principles calculation reveals that N doping accelerates the dissociation of water molecules while Ti doping activates the adjacent S sites for hydrogen adsorption by lowering the Gibbs free energy, resulting in excellent HER activity. This work thus provides an effective strategy for basal plane engineering of MoS2 heterostructures toward high-performance HER and sustainable energy supply at reasonable costs.

(La1−xCax)MnO3−δ (x = 0, 0.2, 0.3, 0.4) Perovskites as Redox Catalysts in Chemical Looping Hydrogen Production Process: The Relation between Defect Chemistry and Redox Performance

The interaction between point defects in (La1−xCax)MnO3−δ (x = 0, 0.2, 0.3, 0.4) perovskites and their redox catalytic properties in a three-reactor chemical looping hydrogen production process is investigated. During the reduction step with CH4, the behavior of the materials is extrinsically determined and strongly depends on the Ca content. At small oxygen deficiencies, CH4 becomes oxidized to CO2. As the deficiency increases, partial oxidation to CO and H2 at a molar ratio of approximately 2 is favored. During the water-splitting step, the dependency on the Ca content is much weaker since it is intrinsically determined by the Mn2+→Mn3+ oxidation with simultaneous annihilation of oxygen vacancies that are not required to compensate for the extra negative charge of the Ca dopant. Hydrogen productivities in the order of 13 cm3 (STP) H2/g solid could be achieved during the water-splitting step at 1000 °C. The materials exhibited reproducible catalytic behavior during 10 cycles of the complete three-step process and were found to retain their perovskite structure.

Milking the Alternatives: Understanding Coffee Consumers' Preferences for Non-Dairy Milk.

Consumer interest in plant-based milk alternatives is growing, despite extra charges in coffeehouses. While much research exists on non-dairy alternatives, plant-based milks in coffee drinks remain understudied. This study examines consumer preferences and behaviors regarding milk alternatives in coffee, using the Theoretical Domains Framework (TDF) and the Behavior Change Wheel (BCW). A survey of 200 participants from 19 countries explored demographics, coffee habits, attitudes towards non-dairy milk charges, and marketing awareness. Market insights showed taste as the main reason for coffee choice, with a preference for cow's milk and local cafes for quality. Many opposed the extra charges for non-dairy options, citing lactose intolerance or allergies, especially among Gen Z and Millennials. Regional variations included stronger opposition in the UK and Germany compared to the UAE and USA. The marketing for non-dairy milk was less memorable than general coffee advertisements. Regression analysis confirmed that viewing non-dairy milk as a dietary staple increased consumption, aligning with the TDF's "Beliefs about Consequences" domain. Finally, within the BCW framework, the intervention strategies centered on training and coercion were discussed. Implementing these approaches could encourage the wider adoption of non-dairy milk options in coffee shops, fostering inclusivity, health awareness, and supporting environmental sustainability efforts.

Incidence and Risk Factors of Delirium Following Brain Tumor Resection: A Retrospective National Inpatient Sample Database Study

The aim of this study was to evaluate the occurrence and factors predisposing to delirium following brain tumor resection. Data from patients who underwent brain tumor resection surgery from 2016 to 2019 were extracted from the National Inpatient Sample database and retrospectively analyzed. The difference between the 2 groups was compared by Wilcoxon rank test or χ2 test was used. Univariate and multivariate logistic regression analyses were used to identify the risk factors of delirium after brain tumor resection. From 2016 to 2019, 28,340 patients who underwent brain tumor resection were identified in the National Inpatient Sample database, with the incidence of delirium being 4.79% (1357/28,340). It was found that increased incidence of delirium was significantly associated with age over 75years and males (all P<0.001). Besides, patients with delirium were more likely to have multiple comorbidities and to receive elective surgery (all P<0.001). The results of logistic regression analysis showed that self-pay (odds ratio [OR]=0.51; confidence interval [CI]=0.31-0.83; P=0.007), elective admission (OR=0.53; CI=0.47-0.60; P<0.001), obesity (OR=0.77; CI=0.66-0.92; P=0.003), females (OR=0.79; CI=0.71-0.88; P<0.001), and private insurance (OR=0.80; CI=0.67-0.95; P=0.012) were associated with lower occurrence of delirium. Besides, delirium was related to extra total hospital charges (P<0.001), increased length of stay (P<0.001), higher inpatient mortality (P=0.001), and perioperative complications (including heart failure, acute renal failure, urinary tract infection, urinary retention, septicemia, pneumonia, blood transfusion, and cerebral edema) (P<0.001). Many factors were associated with the occurrence of delirium after brain tumor resection. Therefore, clinicians should identify high-risk patients prone to delirium in a timely manner and take effective management measures to reduce adverse outcomes.

Topological phases and edge modes of an uneven ladder

Abstract We investigate the topological properties of a two-chain quantum ladder with uneven legs, i.e., the two chains differ in their periods by a factor of 2. Such an uneven ladder presents rich band structures classified by the closure of either direct or indirect bandgaps. It also provides opportunities to explore fundamental concepts concerning band topology and edge modes, including the difference of intracellular and intercellular Zak phases, and the role of the inversion symmetry (IS). We calculate the Zak phases of the two kinds and find excellent agreement with the dipole moment and extra charge accumulation. We also find that configurations with IS feature a pair of degenerate two-side edge modes emerging as the closure of the direct bandgap, while configurations without IS feature one-side edge modes emerging as not only the closure of both direct and indirect bandgaps but also within the band continuum. Furthermore, by projecting to the two sublattices, we find that the effective Bloch Hamiltonian corresponds to that of a generalized Su–Schrieffer–Heeger model or the Rice–Mele model whose hopping amplitudes depend on the quasimomentum. In this way, the topological phases can be efficiently extracted through winding numbers. We propose that uneven ladders can be realized by spin-dependent optical lattices and their rich topological characteristics can be examined by near future experiments.

Laparoscopic assisted colectomy versus laparoscopic complete colectomy: a cost analysis.

To compare the short-term outcomes and explore the potential economic benefits of laparoscopic-assisted colectomy with extracorporeal anastomosis (LAC/EA) vs. laparoscopic complete colectomy with intracorporeal anastomosis (LCC/IA) for patients with non-metastatic resectable colon cancer. Data of patients who underwent laparoscopic hemicolectomy from January 2017 to March 2023 were collected and analyzed. Propensity score matching (PSM) analyses was carried out to minimize the selection bias. Before PSM, a total of 113 patients met the inclusion criteria (39 in the LCC/IA vs. 74 in the LAC/EA). Clinicopathologic characteristics were comparable except for the median number of removed lymph nodes (P = 0.023). LCC/IA was associated with longer operative time, less intraoperative blood loss, and shorter incision length. The rate of 30-day postoperative complications was similar, but the time to first flatus and soft diet was shorter in the LCC/IA. No deaths were reported in either group within 30days after surgery. Costs of surgical instruments (25,945.8 ± 1,918.0 vs. 23,551.9 ± 2,665.5 RMB; P < 0.01) were higher for the LCC/IA but overall costs were similar (LCC/IA, 43,220.0 ± 4,954.0 vs. LAC/EA, 41,269.2 ± 6,685.9 RMB; P = 0.112). After PSM, 38 patients in the LCC/IA and 63 patients in the LAC/EA were compared. LCC/IA was superior in terms of intraoperative blood loss, incision length, and postoperative functional recovery. There was an extra charge of 2385.0 RMB regarding surgical instruments in the LCC/IA but the overall cost did not reach statistical significance. LCC/IA is a feasible, safe, and cost-effective surgical treatment for patients with non-metastatic resectable colon cancer.

Role of charge-compensation process on the structural, microstructure and electrical properties of pure and Nb-doped Sr2SnO4

This article explores the charge compensation method by synthesising Sr2SnO4, Sr2Sn0.99Nb0.01O4, and Sr1.995Sn0.99Nb0.01O4. The synthesis of a monophasic, tetragonal sample was achieved using a typical ceramic approach and high-temperature heat treatment. The XRD followed by Rietveld refinement, confirmed the crystallization of material under the space group I4/mmm. The crystallite sizes for all samples determined to be less than 50 nm, while the micro-strain falls within the range of (1.78–2.93) × 10–3. The microstructure exhibits a cuboidal shape for all samples, and the grain size is observed to decrease with the addition of Nb. The dielectric characteristics of the samples indicate the existence of Maxwell-Wagner and Orientational polarization in the sample. The sample Sr2Sn0.99Nb0.01O4 demonstrates a greater conductivity value compared to Sr1.995Sn0.99Nb0.01O4. This is attributed to the presence of excess electrons that compensate for the overall charge, as opposed to Sr1.995Sn0.99Nb0.01O4 where the extra charge is compensated by a cationic vacancy VSr″. The time-temperature-superposition principle (TTSP) is applicable to all compositions and indicates that similar sources are responsible for both conduction and relaxation processes. The dielectric permittivity and dissipation factor are found to be in the range of 150 to 175 and 0.2 to 0.5, respectively. This suggests that they have potential for future use in millimeter-wave communication with dielectric resonator antennas (DRAs). Due to the presence of oxygen ions and the ability to conduct both ions and electrons, at temperatures above 400 °C, it is a suitable choice for electrode materials in the application of intermediate temperature solid oxide fuel cell (IT-SOFCs). Exploring the manipulation of defects using electrical and ionic charge compensation methods shows potential for enhancing materials in semiconductor technology.

Online advertisement in a pink-colored market

It is surprising that women are often charged more for products and services marketed explicitly to them. This phenomenon, known as the pink tax, is a major issue that questions women’s buying power. Nevertheless, it is not just limited to physical products – even online advertising can be subject to this type of gender-price discrimination. That is where our research comes in. We have developed a new methodology to measure what we call the digital marketing pink tax – the additional expense of delivering advertisements to female audiences. Analyzing data from Facebook advertising platforms across 187 countries and 40 territories shows this issue is systematic. Particularly, the digital marketing pink tax is prevalent in 79% of audiences across the world and 98% of audiences in highly developed countries. Therefore, advertisers incur a median cost of 30% more to display advertisements to women than men. In contrast, advertisers have to pay less digital marketing pink tax in less-developed countries (5%). Our research indicates that countries in the Middle East and Africa with a low Human Development Index (HDI) do not experience this phenomenon. Our comprehensive investigation of 24 industries reveals that advertisers must pay up to 64% of the digital marketing pink tax to target women in some industries. Our findings also suggest a connection between the digital marketing pink tax and the consumer pink tax – the extra charge placed on products marketed to women. Overall, our research sheds light on an important issue affecting women worldwide. Raising awareness of the digital marketing pink tax and advocating for better regulation.

“Light battery” role of long afterglow phosphor for round-the-clock environmental photocatalysis

Owing to its convenient, sustainable and green process, photocatalysis has become a feasible technique for solving environmental pollution issues. So far, significant achievements have been realized in photocatalytic pollutant elimination. Nevertheless, photocatalytic processes require a continuous external light illumination to drive photoredox reactions, seriously prohibiting their applications in darkness. In this context, exploring a photocatalyst with reliable photocatalytic activity in dark condition is therefore highly meaningful and an ultimate target of photocatalysis technique. Recently, long afterglow phosphor has aroused great attention due to its “light battery” role for driving catalytic reactions in dark conditions. To be specific, long-afterglow phosphor or long-afterglow phosphor/semiconductor composite can be used as a photocatalyst to simultaneously promote the photoredox processes and store extra photoexcited charges in the trapping states upon light irradiation. When the light illumination terminates, a gradual release of the charges from trapping states occurs in long-afterglow phosphor, which can continuously spur photoredox reactions under the dark environment and even maintains the photocatalysis around the clock. In this work, we comprehensively reviewed the recent advances of long afterglow phosphor based round-the-clock photocatalysts in environmental pollutant elimination. Meanwhile, the inherent mechanism of long afterglow photocatalysis was discussed in depth. More importantly, the relationship between the improved long afterglow photocatalytic capability and the engineering of long afterglow system is correlated systematically. Finally, the ongoing challenges and future prospects for the mass production and commercial utilization of round-the-clock photocatalysts are analyzed and outlooked.

Factors Affecting the Participation of Tanzanian College Youths in Purchasing Online Products

Recently, Tanzania has experienced an exponential growth of internet users, with youths forming the largest number of users who access internet service. Despite statistics showing that youths form the largest number of internet users in the country, the number of youths who purchase online products is still limited. This study aimed to analyse factors affecting youth online purchasing in Tanzania and suggest strategies to improve its adoption. The subjects of the study were 43 students from the Arusha Technical College in Tanzania who were studying an E-commerce and Internet Technology course. The data were collected using questionnaires and participatory workshop. The collected data were analysed using both quantitative and qualitative techniques. The findings reveal ten factors that influence youth engagement in online purchases: quality risks, delayed deliveries, e-commerce skill gaps, fraud fears, extra charges, internet costs, payment issues, network reliability, local availability, and absence of bargaining habits. To enhance the participation of youths in online shopping, the study recommends several strategies which, if implemented, will help improve e-commerce adoption in Tanzania. The major contribution of this study is to reveal the status of online purchase adoption among Tanzanian youths and document strategies for accelerating its adoption in the country.

The partial Bondi gauge: Gauge fixings and asymptotic charges

In the companion paper [SciPost Phys. 13, 108 (2022)] we have studied the solution space at null infinity for gravity in the partial Bondi gauge. This partial gauge enables to recover as particular cases and among other choices the Bondi-Sachs and Newman-Unti gauges, and to approach the question of the most general boundary conditions and asymptotic charges in gravity. Here we compute and study the asymptotic charges and their algebra in this partial Bondi gauge, by focusing on the flat case with a varying boundary metric \delta q_{AB}≠0δqAB≠0. In addition to the super-translations, super-rotations, and Weyl transformations, we find two extra asymptotic symmetries associated with non-vanishing charges labelled by free functions in the solution space. These new symmetries arise from a weaker definition of the radial coordinate and switch on traces in the transverse metric. We also exhibit complete gauge fixing conditions in which these extra asymptotic symmetries and charges survive. As a byproduct of this calculation we obtain the charges in Newman-Unti gauge, in which one of these extra asymptotic charges is already non-vanishing. We also apply the formula for the charges in the partial Bondi gauge to the computation of the charges for the Kerr spacetime in Bondi coordinates.

Electrochemical control of photoluminescence in pure wurtzite CdSe/CdS core/shell nanocrystals

Spectroelectrochemical methods are employed to systematically investigate the impacts of external charge filling in three pure wurtzite CdSe/CdS core/shell nanocrystals (NCs) with different shell thicknesses. We observed that electrons can penetrate the thick CdS shell and inject into the conduction band with an abnormal brightening, while holes are blocked. The formed negative trions result in a different spectral shift according to the size of the NCs, with a redshift of 3.7 nm for 12.5 nm NCs and almost no movement for 23.4 nm NCs. Meanwhile, due to the formation of biexcitons, a variational spectral blueshift with the NCs' size can be determined in time-resolved photoluminescence spectroscopy. This indicates that the binding energy of both biexcitons and negatively charged excitons can be regulated by controlling the shell thickness. Extra charges can also be used to activate/passivate trap states, thereby confirming that the 12.5 nm sample has better surface/interface quality.

Solution-processed organic-inorganic hybrid material based on P3HT and SnS2 nanoparticles layers: Synthesis and properties

Sn-based nanocomposites attract extensive attention as a new generation of photoelectric hybrid materials due to their high photoelectric conversion efficiency. In this work we synthesized SnS2 nanoparticles by a hydrothermal method employing citric acid (capping agent) and performed a capping agent exchange by pyridine to improve their solution processing and final properties. We fabricated layers with pyridine-capped nanoparticles and poly(3-hexylthiophene-2,5-diyl) (P3HT), employing the classical partial film sequence of a solar cell (ITO/PEDOT:PSS/P3HT:Nps). We found a “coupling" between the nanoparticles and the polymer and highly ordered structures within the layers. The addition of nanoparticles improved the UV–vis absorption of P3HT and allowed the exploitation of the photoluminescence emission to promote extra charge carrier generation. Moreover, we found that SnS2_py nanoparticles form a nanoscopic mixture with the P3HT. Our pyridine-capped SnS2 nanoparticles are good candidates for fabricating hybrid materials, employing P3HT as the organic compound for application in polymeric-inorganic solar cells.

Extrinsic n-type semiconductor transition in ZrSe2 with the metallic character through hafnium substitution

Two-dimensional (2D) layered materials exhibit versatile electronic properties in their different phases. The intrinsic electronic properties of these materials can be modulated through doping or intercalation. In this study, we investigated the electronic properties of Hf-doped ZrSe2 single crystals using angle-resolved photoemission spectroscopy (ARPES) combined with first-principles density functional theory (DFT) calculations. It is observed that the valence band maxima of ZrSe2, located below the Fermi level, undergo a significant change with the introduction of Hf substitution. Hf can introduce extra charges into the conduction band, rather than making a mixed structure of HfSe2 and ZrSe2 band structure, which can cross the Fermi level. Compared to the semiconducting band structure of ZrSe2, we observed that the conduction band crosses the Fermi level at the high symmetry M point in Hf-doped ZrSe2. This suggests an increase of electron-type carriers around the Fermi level, resulting in an extrinsic charge carrier density in the conduction band, which can form a metallic behaviour. It can be noticed that the Hf cations can create disorder in the form of excess atoms of Zr, which yields more carriers in the conduction band in the shape of “smeared bands”. The tails of the “smeared band” occupied the d-orbitals extended into the Fermi level and left the d-band below. Similarly, the electrical resistance measurements further confirm the metallic-like character of Hf-doped ZrSe2 compared to the semiconductor ZrSe2, indicating increased carriers. This metallic-like behavior is suggested to be predisposed by the extrinsic electrons induced by the substitutional disorder. This study further demonstrates the possibility of band gap engineering through heavy metal doping in 2D materials.

Mail back or in-store dropoff? Optimal design of product-exchange policies in omnichannel retailing systems

Online retailing has been booming over the past several years as people grow increasingly comfortable with it and accustomed to its ease and speed. A major drawback of online retailing is the lack of consumer–product interaction before a purchase is finalized, which often leads to consumer dissatisfaction due to mismatched expectation of the received product. In response, retailers usually promise that online orders may be returned or exchanged free of extra charges, which can be processed either online (e.g., by mail) or onsite i.e., in-store dropoff. In this work, we study the implications of both online and onsite exchange policies in the setting of a queueing model that offers omnichannel services. Taking into account customers’ behavioral responses to these policies, we aim to inform the retailer of the one that generates a higher system revenue. Our results reveal that the online exchange policy is a double-edged sword: On the one hand, it helps eliminate the inconvenience cost for exchange customers to revisit the store; on the other hand, it can trigger more feedback orders and render a higher system congestion level, which in turn, deters future customers from placing orders. Specifically, we discover that online exchange becomes an inferior policy relative to in-store exchange when the market size is large.

Metodology for harmonic distortion level determination

In order to make an equitable application of bonuses or extra charges due to harmonic distortion, it is necessary to separate between harmonics exported by nonlinear loads used by costumers, and imported ones due to distortion at Point of Common Coupling (PCC) property of the electric utility. On this paper, a new methodology is presented to assign each costumer his own distortion. Same sampling instrumentation applied in charging electrical bills —with new software— registers total exported harmonic current, making possible determination of corrected non-sinusoidal apparent power and equivalent power factor during an invoicing period. Some effects of nonlinear loads on grids are determined and analyzed, and experiments done on compact fluorescent lamps are shown and described. ss

The Impact of Social Norms on Consumer Willingness to Choose Green Packaging for an Extra Charge in the United States and South Korea

Three studies examine the effectiveness of social norm messaging in a green consumption context. The overall goal is to identify theory-based ways to increase consumer choice of biodegradable take-out food packaging with an extra charge versus single-use plastic with no charge in the US and South Korea. Results indicate that descriptive norm messaging is superior to prescriptive norm messaging in both countries. Prescriptive norm messaging produced significantly higher reactance and more negative attitudes toward the packaging selection experience in the US, suggesting serious backfire effects in that country, but not in South Korea. Results advance theory regarding the use of social norm messaging to increase consumers’ willingness to pay an additional charge for take-out food packaging that is biodegradable versus single-use plastic. Managerial and policy implications are discussed.