AbstractThis study delves into a Pick‐Up Ion (PUI) event captured by the Mars Ion and Neutral Particle Analyzer aboard Tianwen‐1, revealing a faster acceleration than expected within the Martian magnetosheath. This event suggests the presence of a convection electric field considerably stronger than that typically observed in the solar wind. Through Magnetohydrodynamic simulation, we identified two regions of intensified convection electric fields within the inner magnetosheath, prominently manifested at mid to high solar zenith angles (SZA = 40°–70°) in the X‐Z plane of the Mars Solar Electric field coordinates. Tianwen‐1 observed that the peak of the electric field strength, up to five times of that in the solar wind, is located at the upper edge or within the Magnetic Pileup Boundary. Further study by test particle simulations showed acceleration by the electric field effectively doubles the energy gain of PUIs, in comparison to scenarios absent of this extra acceleration. It is revealed that the presence of such electric field regions within the Martian magnetosheath is a prevailing feature, shaped by the solar wind's interaction with Mars and modulated by the planet's rotating crustal magnetic fields.