External Structure Research Articles

Selective Enhancement of Viewing Angle Characteristics and Light Extraction Efficiency of Blue Thermally Activated Delayed Fluorescence Organic Light-Emitting Diodes through an Easily Tailorable Si3N4 Nanofiber Structure.

We selectively improved the viewing angle characteristics and light extraction efficiency of blue thermally activated delayed fluorescence (TADF) organic light-emitting diodes (OLEDs) by tailoring a nanofiber-shaped Si3N4 layer, which was used as an internal scattering layer. The diameter of the polymer nanofibers changed according to the mass ratio of polyacrylonitrile (PAN) and poly(methyl methacrylate) (PMMA) in the polymer solution for electrospinning. The Si3N4 nanofiber (SNF) structure was fabricated by etching an Si3N4 film using the PAN/PMMA nanofiber as a mask, making it easier to adjust parameters, such as the diameter, open ratio, and height, even though the SNF structure was randomly shaped. The SNF structures exhibited lower transmittance and higher haze with increasing diameter, showing little correlation with their height. However, all the structures demonstrated a total transmittance of over 80%. Finally, by applying the SNF structures to the blue TADF OLEDs, the external quantum efficiency was increased by 15.6%. In addition, the current and power efficiencies were enhanced by 23.0% and 25.6%, respectively. The internal light-extracting SNF structure also exhibited a synergistic effect with the external light-extracting structure. Furthermore, when the viewing angle changed from 0° to 60°, the peak wavelength and CIE coordinate shift decreased from 20 to 6 nm and from 0.0561 to 0.0243, respectively. These trends were explained by the application of Snell's law to the light path and were ultimately validated through finite-difference time-domain simulations.

Facile Semiconductor p–n Homojunction Nanowires with Strategic p-Type Doping Engineering Combined with Surface Reconstruction for Biosensing Applications

HighlightsA novel photoelectrochemical (PEC) photosensor composed of GaN nanowire-on-Si platform demonstrates record-high responsivity of 247.8 mA W−1 with ultra-stable operation characteristics.Strategic internal and external band structure engineering of semiconductor nanowires promotes efficient PEC reaction via controlling carrier dynamics while preserving nanowires from material degradation.The glucose sensing system is constructed to successfully analyze blood glucose levels in real human serum samples, featuring a high sensitivity of 0.173 µA µM−1 cm−2 and a low detection limit of 0.07 µM.

Dynamic microvilli sculpt bristles at nanometric scale

Organisms generate shapes across size scales. Whereas patterning and morphogenesis of macroscopic tissues has been extensively studied, the principles underlying the formation of micrometric and submicrometric structures remain largely enigmatic. Individual cells of polychaete annelids, so-called chaetoblasts, are associated with the generation of chitinous bristles of highly stereotypic geometry. Here we show that bristle formation requires a chitin-producing enzyme specifically expressed in the chaetoblasts. Chaetoblasts exhibit dynamic cell surfaces with stereotypical patterns of actin-rich microvilli. These microvilli can be matched with internal and external structures of bristles reconstructed from serial block-face electron micrographs. Individual chitin teeth are deposited by microvilli in an extension-disassembly cycle resembling a biological 3D printer. Consistently, pharmacological interference with actin dynamics leads to defects in tooth formation. Our study reveals that both material and shape of bristles are encoded by the same cell, and that microvilli play a role in micro- to submicrometric sculpting of biomaterials.

Antennal chemoreceptors in the European ectoparasitoid Sclerodermus cereicollis (Hymenoptera: Bethylidae).

Sclerodermus cereicollis is a European flat wasp ectoparasitoid of some longhorn beetle species. This species is important as a suitable biological control agent against xylophagous pests. To better understand its chemical ecology, the ultrastructure of the antennal sensilla of the adult was studied using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The sensilla are located mainly in the ventro-medial side of the antennae. We report a clearly sexual dimorphism with respect to antennae length, and to types, number, and distribution of chemosensilla. The antennae in males are significantly longer than those of females. We describe in detail the external and internal structure of different chemoreceptors represented by sensilla placodea, long sensilla basiconica, multiporous sensilla chaetica, grooved sensilla ampullacea, uniporous grooved sensilla chaetica. The potential involvement of the different kinds of chemoreceptors in inter- (mainly sexual recognition and social behavior-kin recognition) or intra-specific communication (mainly host selection) is discussed on the basis of behavioral and electrophysiological investigations performed on other parasitoid species belonging to the same family. Other sensilla with morphology that is not consistent with that of chemoreceptors are represented by grooved pegs, coeloconic pegs, trichoid sensilla. Such detailed ultrastructural investigation of the flagellar chemoreceptors of S. cereicollis, clarifying the number of chemosensory neurons innervating the different sensilla, is crucial for further electrophysiological investigations on this important species. RESEARCH HIGHLIGHTS: Evident sexual dimorphism concerning antennae length, type, number, and distribution of chemosensilla. Long sensilla basiconica (LSB) present only in females could play a role in host location and/or maternal care. Multiporous sensilla chaetica (MSC), significantly longer and mostly represented in males, could play a role in the perception of sexual pheromones. Detailed ultrastructural study is crucial for electrophysiological investigations on this important species.

Lythria (Microlythria subgen. nov.) venustata Staudinger, 1882 (Lepidoptera: Geometridae): distribution and description of the female, with a brief review of the genus

The article provides new localities for the little-known species Lythria venustata Staudinger, 1882; a map with all currently known locations is presented. A new subgenus, Microlythria subgen. nov., within Lythria Hübner is proposed for L. venustata. A morphological description of L. venustata female and illustration of its genital structure are given for the first time; some corrections in the description of the male genitalia are made. Both male and female genitalia of all other species of the genus are also shown, and a comparison of L. venustata with its congeners is made. Colour plates depicting males and females of all species of the genus Lythria are provided. The systematic position of the genus in the family Geometridae, and the implication of the features of L. venustata female genitalia for tribal association within the Sterrhinae are discussed. Identification keys (based on external morphology and genital structure) to Lythria species are given.

Study on mechanical properties and bearing capacity calculation of eccentric compression of RC columns reinforced with prestressed lattice steel

The external steel structure and RC column under eccentric compression have a reduced ability to work together, and using prestressing technology can significantly improve their ability to work together. Therefore, the paper proposes a new prestressed column reinforcement technology by adopting a space profile steel structure instead of angle steel and combining prestressing technology with the bolted connection. By conducting eccentric compression test studies on 11 specimens with different reinforcement methods, prestressing and eccentricity, load-displacement curves, stress distribution laws, ultimate bearing capacity, damage modes and prestressing influence rules were obtained. The main conclusions are as follows: prestressing can significantly improve the ability of external reinforcement steel structure and core column to work together and inhibit the development of concrete cracks. Compared with the traditional angle steel reinforcement, the bearing capacity is increased by 17.5 %, the stiffness is increased by 26.6 %, and the ductility is increased by 12.3 %. However, the reinforcement effect will be reduced if the prestressing is too large. It is recommended that the prestressing should be applied according to the size of 0.09 fc of the unilateral area of the core column. According to the prestressed lattice steel constraint mechanism, a mechanical analysis model of the reinforced member was established. Finally, based on the cross-section equilibrium method, a calculation method of eccentric compressive ultimate bearing capacity was proposed, and the research results can provide a basis for the engineering application of the new reinforcement method.

Revision of the taxonomic status of Amathuxidia morishitai from Hainan, China (Lepidoptera: Nymphalidae)

Based on the external characters, genital structures, distribution, and intermediate individuals from contact zones, the endemic species Amathuxidia morishitai Chou & Gu, 1994 from Hainan, China is treated as conspecific with A. amythaon (Doubleday, 1847) and is downranked to a subspecies of the latter, i.e., Amathuxidia amythaon morishitai stat. nov. Meanwhile, two subspecies groups of A. amythaon are recognized by morphological and genetic evidence, termed amythaon-group (A. a. amythaon + A. a. dilucida (Honrath, 1884)) and annamensis-group (A. a. morishitai + A. a. annamensis Talbot, 1932) with the latter group showing a deeper divergence than normal on a subspecific level genetically.

Grinding-stimulated fluorescence enhancement in carbon nanoparticles/poly(vinyl chloride) composite

The physical damage of engineering materials is challenging to perceive, particularly when they occur with only a slight extent. To present the location of damage to engineering is still difficult to achieve. Mechanical responsive engineering materials are therefore highly desired. Herein, a type of composites comprised of carbon nanoparticles (CNP) and poly(vinyl chloride) (PVC) was prepared via a heating incubation process. Notably, we found that these composites were in a metastable state and exhibited a grinding-stimulated fluorescence enhancement performance. After grinding stimulation, a bright orange-yellow color emission appeared and the fluorescence intensity of the composites exhibited a 75-fold enhancement. It was noted that grinding had no effect on the fluorescence of CNP alone. The fluorescence enhancement may be due to the change in the surface environment of CNP, as grinding facilitates the entry of CNP into PVC. In addition, fluorescence enhancement was also observed in tightening screw experiments using commercialized PVC films, demonstrating the abrasive-stimulated fluorescence enhancement properties of this CNP/PVC. Such remarkable mechanical response property and interesting combination between CNP and PVC will provide avenue to promote the development of smart engineering materials and have considerable potentials in external force response and structure damage surveying.

Managing protracted displacement: How anchoring shapes ‘agency-in-waiting’ among middle-class Ukrainian female refugees in Berlin

The Russian invasion of Ukraine in February 2022 resulted in one of the largest refugee crises in Europe since World War II. A significant number of Ukrainian refugees, mostly women and children, have sought asylum in Germany, where they have been granted temporary protection status. These refugees found themselves in a state of protracted displacement, with uncertain futures. This article examines how middle-class Ukrainian women, with children, envision their futures and how this shapes their present. Engaging with the literature on protracted displacement and the concept of ‘agency-in-waiting’, we examine how this relatively privileged group variously respond to living in transit. To enable closer analysis of these variations, we extend examinations of protracted displacement with Grzymala-Kazlowska’s idea of anchors. This allows us to consider how previous social-class positioning, and also other external and internal structures in places migrated to, intersect to reveal the anchors facilitating or constraining ‘agency-in-waiting’.

Achievements in Preparation of Cyclodextrin–Based Porous Materials for Removal of Pollutants

Cyclodextrin–based porous materials have been widely applied in removing various organic pollutants from water environments, due to their unique physical and chemical properties, like the size–matching effect and hydrophobic interaction. Large numbers of hydroxyl groups in its external structure give cyclodextrin a high solubility in water, but the existence of these hydroxyl groups also endows cyclodextrin with the ability to be chemically modified with various functional groups to reduce its solubility in water and, meanwhile, to develop some novel functionalized cyclodextrin–based porous materials for selective removal of the target organic pollutants. This review focuses on the recent development in the synthesis of cyclodextrin–based porous materials (crosslinked cyclodextrin polymers and immobilized cyclodextrins), as well as highlighting their applications and mechanisms in the removal of dyes, endocrine disruptors, and mixed pollutants from water. Finally, the challenges and future perspectives in related research fields are discussed.

Visualizing the Internal Nanocrystallinity of Calcite Due to Nonclassical Crystallization by 3D Coherent X-Ray Diffraction Imaging.

The internal crystallinity of calcite is investigated for samples synthesized using two approaches: precipitation from solution and the ammonium carbonate diffusion method. Scanning electron microscopy (SEM) analyses reveal that the calcite products precipitated using both approaches have a well-defined rhombohedron shape, consistent with the euhedral crystal habit of the mineral. The internal structure of these calcite crystals is characterized using Bragg coherent diffraction imaging (BCDI) to determine the 3D electron density and the atomic displacement field. BCDI reconstructions for crystals synthesized using the ammonium carbonate diffusion approach have the expected euhedral shape, with internal strain fields and few internal defects. In contrast, the crystals synthesized by precipitation from solution have very complex external shapes and defective internal structures, presenting null electron density regions and pronounced displacement field distributions. These heterogeneities are interpreted as multiple crystalline domains, created by a nonclassical crystallization mechanism, where smaller nanoparticles coalescence into the final euhedral particles. The combined use of SEM, X-ray diffraction (XRD), and BCDI allows for structurally differentiating calcite crystals grown with different approaches, opening new opportunities to understand how grain boundaries and internal defects alter calcite reactivity.

Tea polyphenols postpone the evolution of multidrug tolerance in Escherichia coli under the stress of antibiotic in water

Tea polyphenols are non-toxic plant extracts. However, tea polyphenols' impact on antibiotic tolerance development in the environment remains uncertain. In this study, where Escherichiacoli K12 was exposed to tetracycline as a stressor, tea polyphenols were applied for 31 days to induce a tolerant phenotype. Transcriptomics analyses and flow cytometry were used to study the mechanisms. In simple terms, tea polyphenols can delay the onset of tolerance by decreasing cellular metabolism including (ATP synthetics, citrate cycle, and sulfur metabolism), reducing amino acid synthesis (such as methionine, cysteine, glycine, serine, and threonine metabolism), oxidizing external cellular structures, especially peptidoglycan and preventing cells into a dormant state. This sheds light on how natural polyphenolic substances have evolved to mitigate tolerance.

Comparative morphology of male genitalia in antlions (Insecta, Neuroptera, Myrmeleontidae), with emphasis on owlflies (Ascalaphinae) and a possible structural evolutionary scenario.

Male genitalia morphology in Myrmeleontidae has traditionally been insufficiently studied, although it has received increased attention for its diagnostic value in recent times. A neutral terminology has generally been applied in standard taxonomic practice, yet knowledge of an equivalent and stable terminology across taxa based on comparative morphology has been missing. Herein a detailed comparative morphology study with examples from most tribes within Myrmeleontidae, including owlflies (Ascalaphinae), attempts to relate external and internal genital structures based on a proposed groundplan for Neuroptera and Myrmeleontidae. We contend that a groundplan based on 10 abdominal segments, plus vestigial structures from an 11th segment, coherently depicts structural components across myrmeleontid taxa. A gonarcus, an element of Neuropterida amply referred in Neuroptera, is supported to represent the pair of abdominal appendages of segment X medially fused, with gonocoxite and gonostylus components. In most myrmeleontid taxa, basal (gonocoxites) and distal (gonostyli) components separate, with gonostyli positioned posteriorly with respect to gonocoxites, still united with translucent, lightly sclerotized tissue, forming a more or less conical structure, a proposed synapomorphy for the family. Ninth gonostyli are generally reduced (pulvini) and have migrated close to the base of gonarcus (10th gonocoxites). A pelta, also a potential synapomorphy for Myrmeleontidae, derives from paired setose surfaces of the 10th gonostyli, medially positioned (still evident in Bubopsis). Three structural types of gonarcus are diagnosed for illustrative purposes, as they may represent convergent constructs.

Potential contributions of digital finance to alleviating the ‘low-end lock-in’ dilemma for green innovation in enterprises

As climate change risks intensify worldwide, green technological innovation by enterprises has become a crucial factor affecting the balance between economic development and ecological governance. This paper utilizes data from Chinese A-share listed companies in heavily polluting industries from 2011 to 2021 to investigate the impact and mechanism of the knowledge spillover effect of enterprise digital finance development on the phenomenon of ‘low-end lock-in’ in green innovation. The study finds that digital finance development significantly promotes green innovation in enterprises, with a more pronounced enhancement in high-end green innovation output, thereby mitigating the phenomenon of ‘low-end lock-in’ in green innovation. Mechanism analysis reveals that the development of digital finance in enterprises facilitates high-end green innovation by alleviating financing constraints and enhancing internal control levels through internal and external governance structures. Heterogeneity tests indicate that the promotion effect of digital finance development on high-end green innovation is more pronounced in samples of state-owned enterprises, large and medium-sized enterprises, and enterprises in central and eastern regions. This paper constructs an index of digital finance development for enterprises through text analysis, providing theoretical support for micro-enterprise research on digital finance development and empirical support for the impact of financial development trends on theories of enterprise green innovation.

Comparative analysis of ocular biometry, ocular protrusion, and palpebral fissure dimensions in brachycephalic and nonbrachycephalic dog breeds.

This study compared skull morphology and ocular parameters in brachycephalic (BC, n=16) and nonbrachycephalic (NB, n=16) dogs using head CT scans. The results of a Schirmer tear test I (STT I), intraocular pressure (IOP), ocular biometry, external structure, ocular protrusion, and palpebral fissure dimensions were evaluated and compared between BC and NB dogs. There were no statistically significant differences in the STT I results, IOP, globe dimensions, globe volume, internal structure, and external structure between BC and NB dogs (P>.05). Brachycephalic dogs exhibited significantly greater ocular protrusion and significantly larger palpebral fissure dimensions compared with NB dogs. For all dogs, we found a strong positive correlation between globe volume and body weight (r=0.836, P=.0000). The globe volumes, external structure parameters, and ocular protrusion were normalized by body weight and were also significantly larger in BC dogs compared with NB dogs (P<.001). The ocular protrusion (r=0.521, P<.0000) and horizontal palpebral fissure (r=0.372, P=.0024) showed a moderate positive correlation with the cephalic index (CI). Additionally, normalized globe volume (r=0.435, P=.0003), normalized orbital depth (r=0.419, P=.0005), and normalized retrobulbar depth (r=0.444, P=.0002) had a moderate positive correlation with the CI. The study emphasizes how the distinctive skull structure of BC dogs, with shortened facial bones and thickened retrobulbar soft tissue, influences their ocular appearance and raises the risk of eye problems.

Surface-Pore-Modified N-Doped Amorphous Carbon Nanospheres Tailored with Toluene as Anode Materials for Lithium-Ion Batteries.

The surface modification of amorphous carbon nanospheres (ACNs) through templates has attracted great attention due to its great success in improving the electrochemical properties of lithium storage materials. Herein, a safe methodology with toluene as a soft template is employed to tailor the nanostructure, resulting in ACNs with tunable surface pores. Extensive characterizations through transmission electron microscopy (TEM), scanning electron microscopy (SEM), Raman spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and nitrogen adsorption/desorption isotherms elucidate the impact of surface pore modifications on the external structure, morphology, and surface area. Electrochemical assessments reveal the enhanced performance of the surface-pore-modified carbon nanospheres, particularly ACNs-100 synthesized with the addition of 100 μL toluene, in terms of the initial discharge capacity, rate performance, and cycling stability. The interesting phenomenon of persistent capacity increase is ascribed to lithium ion movement within the graphite-like interlayer, resulting in ACNs-100 experiencing a capacity upswing from an initial 320 mAh g-1 to a zenith of 655 mAh g-1 over a thousand cycles at a rate of 2 C. The findings in this study highlight the pivotal role of tailored nanostructure engineering in optimizing energy storage materials.

Activation of 2D/3D zeolitic-imidazole frameworks affecting crystal properties and adsorption performance

The zeolitic-imidazole frameworks (ZIFs) have become popular due to their uniformly structured cavities and portals of framework dimensions, which make them suitable for numerous applications. In order to access pores and functional surfaces, thermal activation is significantly post-treatment on the synthesis of ZIFs for their applications. This study explores the impact of different thermal activation conditions on two- to three-dimensional ZIFs, which significantly affect their structure, morphology, and properties. Their transform structure is evidenced by integrated X-ray diffraction technique, Thermogravimetric analysis, Scanning electron microscope, and Fourier transform infrared spectroscopy. Moreover, the performance of greenhouse gas adsorption (CO2 and CH4) applications is affected by the transformation through the thermal activation of materials. Therefore, understanding the activated conditions that impact material synthesis is crucial to maximizing the potential applications of ZIFs in various fields. The 2D ZIF-L has more exposed external surfaces and open structures, which makes it more reactive towards adsorptive reactants, unlike the 3D ZIFs. The 3D ZIFs have a robust structure and a higher porosity framework that can withstand challenging application conditions. Thus, it's essential to ensure appropriate activation conditions to maintain the functional properties of ZIFs, which are crucial for their optimal performance in various applications.

The Clinical Application of Double Taylor Spatial Frame in Segmental Tibial Fracture.

Multi-planar external fixation has been used for the management of segmental tibial fractures with severe soft tissue injuries. However, fewer specialized studies have been reported. The primary aim of this study was to describe our experience of treating fractures of this type using the Taylor Spatial Frame and Ilizarov external fixation methods. We retrospectively analyzed 33 patients with segmental tibial fracture treated at our institution between January 2016 and December 2020. The patients were divided into double Taylor Spatial Frame (D-TSF) and Ilizarov groups based on the external fixation structure. Baseline demographic data included sex, age, injury side and cause, open or closed fracture, time from injury to surgery, complications, and external frame removal and fracture healing time. The hip-knee-ankle angle (HKA) was measured from preoperative, immediate postoperative, and final follow-up full-length X-rays of bilateral lower limbs. We determined the degree of deviation in the HKA by calculating the difference between the measured angle and the ideal value of 180°; the absolute value was used to assess recovery of the lower limb force line. At the final follow-up, Johner-Wruhs tibial fracture outcome criteria (J-W TFOC) were used to classify the postoperative function of the affected limb as excellent, good, moderate, or poor. Count data were analyzed with the chi-square test or Fisher's exact test; the Mann-Whitney U test was used for rank data. No statistically significant differences were observed between the two groups in terms of sex, age, side of injury, cause of injury, closed or open fracture, or time between injury and surgery, which indicates that the groups were comparable (p > 0.05). A statistically significant difference was observed in external frame removal and fracture healing time between the D-TSF and Ilizarov groups (36.24 ± 8.34 vs 45.42 ± 10.21 weeks, p = 0.009; 33.33 ± 8.21 vs 42.00 ± 9.78 weeks, p = 0.011). The Johner-Wruhs criteria were used to assess the function of the affected limb, the D-TSF group performed better in correcting the lower limb force line than the Ilizarov group. A statistically significant difference in terms of excellent ratings was observed between the two groups (18/2/1/0 vs 5/5/1/1, p = 0.010). Postoperative follow-up X-rays demonstrated a significant improvement in the HKA in both groups immediately after surgery and at the final follow-up compared to the angle before surgery. At the final follow-up, a statistically significant difference was observed in the degree of deviation in the HKA between the two groups (1.58° ± 0.84° vs 2.37° ± 1.00°, p = 0.023). The D-TSF treatment is associated with minimal secondary damage to soft tissue, a straightforward and minimally invasive procedure, multiplanar stable fracture fixation, and optimization of fracture alignment and lower limb force lines, therefore, it is highly effective therapeutic option for segmental tibial fracture.

Induced Aggregation, Solvent Regulation, and Supracluster Assembly of Aluminum Oxo Clusters.

ConspectusRecent years have witnessed the development of cluster materials as they are atomically precise molecules with uniform size and solution-processability, which are unattainable with traditional nanoparticles or framework materials. The motivation for studying Al(III) chemistry is not only to understand the aggregation process of aluminum in the environment but also to develop novel low-cost materials given its natural abundance. However, the Al-related clusters are underdeveloped compared to the coinage metals, lanthanides, and transition metals. The challenge in isolating crystalline compounds is the lack of an effective method to realize the controllable hydrolysis of Al(III) ions. Compared with the traditional hydrolysis of inorganic Al(III) salts in highly alkaline solutions and hydrolysis of aluminum trialkyl compounds conducted carefully in an inert operating environment, we herein developed an effective way to control the hydrolysis of aluminum isopropanol through an alcoxalation reaction. By solvothermal/low melting point solid melting synthesis and using "ligand aggregation, solvent regulation, and supracluster assembly" strategies, our laboratory has established an organic-inorganic hybrid system of aluminum oxo clusters (AlOCs). The employment of organic ligands promotes the aggregation and slows the hydrolysis of Al(III) ions, which in turn improves the crystallization process. The regulation of the structure types can be achieved through the selection of ligands and the supporting solvents. Compared with the traditional condensed polyoxoaluminates, we successfully isolated a broad range of porous AlOCs, including aluminum molecular rings and Archimedes aluminum oxo cages. By studying ring expansion, structural transformation, and intermolecular supramolecular assembly, we demonstrate unique and unprecedented structural controllability and assembly behavior in cluster science. The advancement of this universal synthetic method is to realize materials customization through modularly oriented supracluster assembly. In this Account, we will provide a clear-cut definition and terminology of "ligand aggregation, solvent regulation, and supracluster assembly". Then we will discuss the discovery in this area by using a strategy, such as aluminum molecular ring, ring size expansion, ring supracluster assembly, etc. Furthermore, given the internal and external pore structures, as well as the solubility and modifiability of the AlOCs, we will demonstrate their potential applications in both the solid and liquid phases, such as iodine capture, the optical limiting responses, and dopant in polymer dielectrics. The strategy herein can be applied to extensive cluster science and promote the research of main group element chemistry. The new synthetic method, fascinating clusters, and unprecedented assembly behaviors we have discovered will advance Al(III) chemistry and will also lay the foundation for functional applications.

Local media sentiment towards pollution and its effect on corporate green innovation

This study examines the effect of local media sentiment on corporate green innovation based on a textual analysis of China's provincial official party newspapers from 2007 to 2018. The results show that the negative sentiment in official media positively influences firms' green innovation, measured by the number of green patents and green patent citations. This positive effect is more pronounced when firms have weaker internal or external governance structures, when the regional punitive measures are less stringent, or when the incentive measures are more complete, suggesting that official media plays a governance role in corporate green innovation. Further analysis shows that the negative sentiment from market-oriented media impedes green innovation and does not affect the relationship between official media sentiment and green innovation. Taken together, our findings reveal the real effects of local media negative sentiment on technological progress and pollution controls through its pressure on firms to engage in green innovation.