External Quantum Conversion Efficiency Research Articles

A Switchable High-Sensitivity Photodetecting and Photovoltaic Device with Perovskite Absorber.

Amplified photocurrent gain has been obtained by photodiodes of inorganic semiconductors such as GaAs and Si. The avalanche photodiode, developed for high-sensitivity photodetectors, requires an expensive vapor-phase epitaxy manufacture process and high driving voltage (50-150 V). Here, we show that a low-cost solution-processed device using a planar-structured ferroelectric organo-lead triiodide perovskite enables light detection in a large dynamic range of incident power (10(-7)-10(-1) W cm(-2)) by switching with small voltage (-0.9 to +0.5 V). The device achieves significantly high external quantum conversion efficiency (EQE) up to 2.4 × 10(5)% (gain value of 2400) under weak monochromatic light. On a single dual-functional device, incident small power (0.2-100 μW cm(-2)) and medium to large power (>0.1 mW cm(-2)) are captured by reverse bias and forward bias modes, respectively, with linear responsivity of current. For weak light detection, the device works with a high responsivity value up to 620 A W(-1).

II–VI semiconductor color converters for efficient green, yellow, and red light emitting diodes

II–VI compound semiconductor quantum-well heterostructures were fabricated for use as efficient, narrow-spectrum, photoluminescent color converters to generate green, yellow, or red light when photopumped with blue GaInN light emitting diodes (LEDs). This approach promises high efficiencies in a wide range of wavelengths that includes the green-yellow portion of the spectrum where conventional LEDs offer relatively low efficiency. External quantum conversion efficiencies of 60%–70% and output spectra with full width at half maximum of 15 nm were achieved using CdZnSe–CdMgZnSe quantum wells grown by molecular beam epitaxy on InP substrates.

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells

Two organolead halide perovskite nanocrystals, CH(3)NH(3)PbBr(3) and CH(3)NH(3)PbI(3), were found to efficiently sensitize TiO(2) for visible-light conversion in photoelectrochemical cells. When self-assembled on mesoporous TiO(2) films, the nanocrystalline perovskites exhibit strong band-gap absorptions as semiconductors. The CH(3)NH(3)PbI(3)-based photocell with spectral sensitivity of up to 800 nm yielded a solar energy conversion efficiency of 3.8%. The CH(3)NH(3)PbBr(3)-based cell showed a high photovoltage of 0.96 V with an external quantum conversion efficiency of 65%.

Phosphorescent Iridium(III) Complexes with Nonconjugated Cyclometalated Ligands

A series of blue phosphorescent iridium(III) complexes 1-4 with nonconjugated N-benzylpyrazole ligands were synthesized and their structural, electrochemical, and photophysical properties were investigated. Complexes 1-4 exhibit phosphorescence with yields of 5-45 % in degassed CH2Cl2. Of the compounds, 1 showed emission that was nearly true blue at 460 nm with a lack of vibronic progression. These photophysical data clearly demonstrate that the methylene spacer of the cyclometalated N-benzylpyrazole chelate effectively interrupts the pi conjugation upon reacting with a third L X chelating chromophore. This gives a feasible synthesis for the blue phosphorescent complexes with a sufficiently large energy gap. In another approach, these complexes were investigated for their suitability for the host material in phosphorescent OLEDs. The device was synthesized by using 1 as the host for the green-emitting [Ir(ppy)3] dopant, which exhibits an external quantum conversion efficiency (EQE) of up to 11.4 % photons per electron (and 36.6 cdA(-1)), with 1931 Commission Internationale de L'Eclairage (CIE) coordinates of (0.30, 0.59), a peak power efficiency of 21.7 lmW(-1), and a maximum brightness of 32000 cdm(-2) at 14.5 V. At the practical brightness of 100 cdm(-2), the efficiency remains above 11 % and 18 lmW(-1), demonstrating its great potential as the host material for phosphorescent organic light-emitting diodes.

Megawatt peak power 8–13 μm CdSe optical parametric generator pumped at 2.8 μm

Infrared pulses, continuously tunable in the 8–13 μm range, and with up to 1 MW peak power, have been achieved using single-stage frequency conversion in a CdSe travelling-wave optical parametric generator, pumped by 100 ps pulses from an actively mode-locked, Q-switched and cavity dumped 2.8 μm Cr,Er:YSGG laser. The external quantum conversion efficiency reached 10%.