External Field Research Articles

On the selective formation of cubic tetrastack crystals from tetravalent patchy particles.

Achieving the formation of target open crystalline lattices from colloidal particles is of paramount importance for their potential application in photonics. Examples of such desired structures are the diamond, tetrastack, and pyrochlore lattices. Here, we demonstrate that the self-assembly of tetravalent patchy particles results in the selective formation of cubic tetrastack crystals, both in the bulk and in the systems subjected to external fields exerted by the solid substrate. It is demonstrated that the presence of an external field allows for the formation of well-defined single crystals with a low density of defects. Moreover, depending on the strength of the applied external field, the mechanism of epitaxial growth changes. For weakly attractive external fields, the crystallization occurs in a similar manner as in the bulk, since the fluid does not wet the substrate. Nonetheless, the formed crystal is considerably better ordered than the crystals formed in bulk, since the surface induces the ordering in the first layer. On the other hand, it is demonstrated that the formation of well-ordered cubic tetrastack crystals is considerably enhanced by the increase in external field strength, and the formation of the thick crystalline film occurs via a series of layering transitions.

Effect of the global electroneutrality condition on electromigration Taylor-Aris dispersion in a microcapillary with finite Debye layer thickness.

In this work, the electromigration dispersion (EMD) due to the charged electrolytes in microchannels is considered without using the thin electrical double layer assumption. The electrokinetic flow and transport of ions are actuated within a rectangular micro-/nanochannel having a negative surface charge density under the influence of an external electric field. Due to the local variation of the conductivity and the nonvalidity of the electroneutrality condition, the local electric field varies as a function of the solute concentration, wall surface charge density, valency, and Debye layer length. The resulting electrokinetic flow due to the external electric field drives the fluid along with the charged species, where the Taylor-Aris dispersion separates the solutes into their different constituents. The local concentration dependence of the electric field leads to the formation of concentration profiles that are slightly asymmetric with respect to the standard Gaussian distribution. Including a finite Debye layer thickness has an effect on the advection of the species as well as the diffusion of the species. It is found that in cases where Debye layers are thicker, the species advects faster within the microchannel. This might give valuable insights into the nature of the EMD. Our model aims to predict the evolution of ionic concentration at all positions within the channel. A study of the higher-order statistics in skewness and kurtosis has also been conducted to obtain a better understanding of the idealized model consisting of a buffer solution.

Screw dislocation in a Rashba spin-orbit coupled - Aharonov-Bohm quantum ring.

In this paper we investigate the effect of a topological defect, such as a screw dislocation in an - Aharonov-Bohm quantum ring and scrutinized the effects of an external transverse magnetic field and Rashba spin-orbit coupling therein. The screw dislocation yields an effective flux which reshape the periodic oscillations in the persistent current in both charge and spin sectors, with a period equal to one flux quantum. Moreover, they suffer a phase shift proportional to the degree of dislocation, and include scattering effects due to the dislocation present in the system. Such tunable oscillation of the spin persistent current highlights applications of our system as potential spintronic devices. Further, the behaviour of the current induced by the Burgers vector ( ) which denotes the strength of the dislocation is investigated in the absence and presence of an external magnetic field. In both the scenarios, an almost linear decrease in the current profile as a function of the Burgers vector is observed. Notably, without the external magnetic field, the Burgers current suffers a back flow for (dice lattice), while in the presence of the external magnetic field, for other values of (e.g., ) this back flow occurs for a specific value of . Additionally, the presence of the distortion induces a chirality effect, giving rise to an additional chiral current even in the absence of an external field. Furthermore, in the absence of field, the Burgers spin current initially rises, attains a maximum before diminishing as is enhance for all values of . However, such a non-monotonicity in the Burgers spin current is conspicuously non-existent in the presence of an external field. The chiral current discussed above may hold important applications to spintronics.

Strain and Electric Field Engineering of G-ZnO/SnXY (X, Y = S, Se) S-Scheme Heterostructures for Photocatalyst and Electronic Device Applications: A Hybrid DFT Calculation.

Using hybrid density functional theory calculations, we systematically study the biaxial strain and electric field modulated electronic properties of g-ZnO/SnS2, g-ZnO/SnSe2, and g-ZnO/SnSSe S-scheme van der Waals heterostructures (vdWHs). g-ZnO/SnS2 and g-ZnO/SnSSe are found to be promising photocatalysts for water splitting with high solar-to-hydrogen efficiencies, even under acidic, alkaline, and high-stress conditions. The strain effect on the bandgaps of g-ZnO/SnXY is explained in detail according to the correlation between geometry structure and orbital hybridization of SnXY, which could help understand the strain-induced band structure evolutions in other SnXY (X, Y = S, Se)-based vdWHs. It is surprising that under an external electric field, g-ZnO/SnS2, g-ZnO/SnSe2, and g-ZnO/SnSSe can offer the occupied nearly free-electron (NFE) states. In many materials, NFE states are usually unoccupied and is not conducive to the charge transport. The NFE state in g-ZnO/SnSe2 is the most sensitive to the electric field and might be promising electron transport channel in nanoelectronic devices. g-ZnO/SnSe2 might also have application potential in gas sensors and high-temperature superconductors.

Insights into Strain Engineering: From Ferroelectrics to Related Functional Materials and Beyond.

Ferroelectrics have become indispensable components in various application fields, including information processing, energy harvesting, and electromechanical conversion, owing to their unique ability to exhibit electrically or mechanically switchable polarization. The distinct polar noncentrosymmetric lattices of ferroelectrics make them highly responsive to specific crystal structures. Even slight changes in the lattice can alter the polarization configuration and response to external fields. In this regard, strain engineering has emerged as a prevalent regulation approach that not only offers a versatile platform for structural and performance optimization within ferroelectrics but also unlocks boundless potential in various functional materials. In this review, we systematically summarize the breakthroughs in ferroelectric-based functional materials achieved through strain engineering and progress in method development. We cover research activities ranging from fundamental attributes to wide-ranging applications and novel functionalities ranging from electromechanical transformation in sensors and actuators to tunable dielectric materials and information technologies, such as transistors and nonvolatile memories. Building upon these achievements, we also explore the endeavors to uncover the unprecedented properties through strain engineering in related chemical functionalities, such as ferromagnetism, multiferroicity, and photoelectricity. Finally, through discussions on the prospects and challenges associated with strain engineering in the materials, this review aims to stimulate the development of new methods for strain regulation and performance boosting in functional materials, transcending the boundaries of ferroelectrics.

Molecular Structures, Dipole Moments, and Electronic Properties of β-HMX under External Electric Field from First-Principles Calculations.

In order to investigate the impact of an external electric field on the sensitivity of β-HMX explosives, we employ first-principles calculations to determine the molecular structure, dipole moment, and electronic properties of both β-HMX crystals and individual β-HMX molecules under varying electric fields. When the external electric field is increasing along the [100], [010], and [001] crystallographic directions of β-HMX, the calculation results indicate that an increase in the bond length (N1-N3/N1'-N3') of the triggering bond, an increase in the main Qnitro (N3, N3') value, an increase in the minimum surface electrostatic potential, and a decrease in band gap all contribute to a reduction in its stability. Among these directions, the [010] direction exhibits the highest sensitivity, which can be attributed to the significantly smaller effective mass along the [010] direction compared with the [001] and [100] directions. Moreover, the application of an external electric field along the Y direction of the coordinate system on individual β-HMX molecules reveals that the strong polarization effect induced by the electric field enhances the decomposition of the N1-N3 bonds. In addition, due to the periodic potential energy of β-HXM crystal, the polarization effect of β-HMX crystal caused by an external electric field is much smaller than that of a single β-HXM molecule.

Experimental study on screening-current induced strain in REBCO insert coils: under critical current control and operation current cycles

The screening-current effect is an inhomogeneous distribution of current density inside the REBCO conductors. The additional strain induced by the screening current, known as screening-current induced strain (SCS), is considered to affect the structural integrity of REBCO windings, especially when operating high-field REBCO insert magnets. In this work, we wound and tested a series of 50-turn REBCO coils inside a 10 T LTS external to investigate the influencing mechanism of multiple electromagnetic factors on SCS. We varied the critical current in different coils by different heat treatment procedures. Each coil was tested individually, experiencing a external field cycle and multiple operation current cycles at constant external fields. The extreme scenario for each coil was being energized to 400 A while the external field was 10 T. We adapted the discrete-coupled model to estimate the hoop strain distribution, monitored the experimental results by multiple strain gauges at the outermost turn. Test coil with a lower critical current endured a lower maximum hoop strain. When we were energizing the test coils, hoop strain increased at the edge of REBCO tapes while remaining nearly constant in the middle region. Additionally, the maximum hoop strain at the outermost turn decreased after each excitation cycle. This work could be an experimental reference for optimizing the electromagnetic design and the excitation scheme during the development of high-field REBCO magnets.

The neural implausibility of the diffusion decision model doesn't matter for cognitive psychometrics, but the Ornstein-Uhlenbeck model is better.

In cognitive psychometrics, the parameters of cognitive models are used as measurements of the processes underlying observed behavior. In decision making, the diffusion decision model (DDM) is by far the most commonly used cognitive psychometric tool. One concern when using this model is that more recent theoretical accounts of decision-making place more emphasis on neural plausibility, and thus incorporate many assumptions not found in the DDM. One such model is the Ising Decision Maker (IDM), which builds from the assumption that two pools of neurons with self-excitation and mutual inhibition receive perceptual input from external excitatory fields. In this study, we investigate whether the lack of such mechanisms in the DDM compromises its ability to measure the processes it does purport to measure. We cross-fit the DDM and IDM, and find that the conclusions of DDM would be mostly consistent with those from an analysis using a more neurally plausible model. We also show that the Ornstein-Uhlenbeck Model (OUM) model, a variant of the DDM that includes the potential for leakage (or self-excitation), reaches similar conclusions to the DDM regarding the assumptions they share, while also sharing an interpretation with the IDM in terms of self-excitation (but not leakage). Since the OUM is relatively easy to fit to data, while being able to capture more neurally plausible mechanisms, we propose that it be considered an alternative cognitive psychometric tool to the DDM.

Charge-generation structures and their applications in light-emitting devices

Abstract Due to their unique properties, charge-generation layers (CGLs) have been used as interconnect layers for organic and quantum-dot light-emitting devices (LEDs) consisting of multiple emission units. Furthermore, CGLs have also been integrated into single-emission-unit LEDs and alternating-current LEDs. The charge-generation structures provide charge carriers (electrons and holes) to the devices under an external electric field, instead of charge injection from the electrodes. Therefore, there is no strict requirement for precise matching of energy levels between the electrodes and charge-injection layers. This affords greater flexibility for device design and enhances the efficiency and operational lifespan of devices. In this Review, we summarize the devolopment of charge-generation structures and discuss the existing challenges and opportunities. A particular focus is placed on the working mechanism of CGLs and their applications in various LEDs. Additionally, issues such as voltage drop in CGLs, charge generation efficiency, increased operating voltage for the devices, and optimizations of existing CGLs are discussed.

Synergistic influence of external electric field on laser ablation in liquid: correlating nanoparticle synthesis and cavitation bubble dynamics

The present study aims to investigate the changes in the properties of nanoparticles (NPs) and cavitation bubble dynamics by applying an external electric field during laser ablation in liquid (LAL). Investigating electric field assisted laser ablation in liquid (EFLAL) is crucial since phenomena such as plasma charging effect and electrostatic pressure have important role in determining the size, shape, and crystallinity. of the NPs. With this motivation, the present study has been conducted with different electric fields of 0, 100, 500 and 1000 V cm−1 to probe the effect of an external electric field on the dynamics of EFLAL. The charging effect observed on NPs during cavitation bubble dynamics was also investigated at these field intensities. The size of NPs witnesses a reduction from ∼30 nm without electric field to ∼19 nm in presence of electric field. Also, a significant narrowing of the size distribution by over 4 times was observed in the presence of electric field. This clearly demonstrates that EFLAL can be used to obtain NPs with uniform size distribution. Moreover, NPs of different shapes have also been observed by varying the electric field intensities (100 and 1000 V cm−1). The effect of the external electric field on the dynamics of the cavitation bubble produced during EFLAL has been probed using shadowgraphy technique. It has been observed that the bubble size increases with the presence of an electric field. The estimation of the bubble pressure in the presence of an electric field has revealed that the implosion bubble pressure is significantly lower than pressure in the absence of the field. The results obtained for NPs have been correlated to the changes in bubble parameters in this work.

The original composition of the gas forming first-generation stars in clusters: Insights from HST and JWST

Globular cluster (GC) stars composed of pristine material, also known as first-generation (1G) stars, are not chemically homogeneous as they exhibit extended sequences in the chromosome map (ChM). Recent studies characterized 1G stars within the center of 55 Galactic GCs, revealing metallicity variations. Despite this progress, several unanswered questions persist, particularly concerning the link between the 1G metallicity spread and factors such as the radial distance from the cluster center or the host GC parameters. Additionally, it remains unclear whether the extended 1G sequence phenomenon is exclusive to old Galactic GCs with multiple populations. This work addresses these open issues, examining 1G stars in different environments. First, we combine Hubble Space Telescope (HST) and James Webb Space Telescope photometry of the GC 47\,Tucanae to study 1G stars at increasing distances from the cluster center. We find that metal-rich 1G stars are more centrally concentrated than metal-poor ones, suggesting a metallicity radial gradient. Additionally, the two groups of 1G stars share similar kinematics. Since our analysis focuses on giant stars in the cluster center and M dwarfs in external fields, we discuss the possibility that the metallicity distribution depends on stellar mass. Subsequently, we analyze HST multi-band photometry of two simple-population clusters, NGC\,6791 and NGC\,1783, revealing elongated sequences in the ChM associated with metallicity variations. Finally, we investigate the 1G color distribution in 51 GCs, finding no connections with the host cluster parameters. These results shed light on the complex nature of 1G stars, providing insights into the GC formation environment.

Dielectric response of metal-organic frameworks as a function of confined guest species investigated by molecular dynamics simulations.

When using metal-organic frameworks (MOFs) as electric field-dependent sensor devices, understanding their dielectric response is crucial as the orientation of polar groups is largely affected by confinement. To shed light on this at the molecular level, the response to a static field was computationally investigated for two structurally related MOFs, depending on their loading with guest molecules. The pillared-layer MOFs differ in their pillar moiety, with one bearing a rotatable permanent dipole moment and the other being non-polar. Two guest molecules with and without polarity, namely, methanol and methane, were considered. A comprehensive picture of the response of the guest molecules could be achieved with respect to both the amount and polarity of the confined species. For both MOFs, the dielectric response is very sensitive to the introduction of methanol, showing an anisotropic and non-linear increase in the system's relative permittivity expressed by a strongly increasing polarization response to external electric fields scaling with the number of confined methanol molecules. As expected, the effect of methane in the non-dipolar MOF is negligible, whereas subtle differences can be observed for the dipolar response of the MOF with rotatable dipolar linker groups. Taking advantage of these anisotropic and guest-molecule-specific confinement effects may open pathways for future sensing applications. Finally, methanol-induced global framework dynamics were observed in both MOFs.

Schwinger-like Pair Production of Baryons in Electric Field

In this Letter we evaluate the probability rate for the Schwinger production of baryons in an external electric field in the worldline instanton approach in holographic QCD. The new exponentially suppressed processes in a constant electric field involving the composite worldline instantons are suggested which include the non-perturbative decay of a neutron into proton and charged meson and the spontaneous production of p$$\bar {n}$$π– and n$$\bar {p}$$π+ states.

Photon-Dipole-Spin Interactions in M(TCNE)x/P(VDF-TrFE) Multiferroic Heterostructure Available for Bimodal Control of Multistate Data-Storage.

Organic multiferroic heterostructure is one of the most promising structures for the future design of high-density flexible energy-efficient data storage. Here, we fabricate organic ferromagnetic M(TCNE)x/ferroelectric P(VDF-TrFE) multiferroic heterostructures, where the excited state in M(TCNE)x interacted with localized dipole in P(VDF-TrFE) provides a key link for the interfacial coupling. Thus, aligned dipoles in P(VDF-TrFE) by external electric field can affect the magnetization of Fe(TCNE)x effectively to result in a pronounced magnetization-voltage (M-V) hysteresis loop. Moreover, light-induced electron-hole pairs in Fe(TCNE)x with long lifetime will effectively interact with the dipoles in P(VDF-TrFE) to lead to an effect in external light control of electric polarization of P(VDF-TrFE). Overall, the organic multiferroic heterostructure provides the possibility of realizing two storage modes, light control of dipole as well as electric field control of spin, which can broaden multifunctional applications of organic multiferroic materials in the area of multistate storage. This article is protected by copyright. All rights reserved.

Computational fluid dynamics numerical simulation of flue gas emission from stack and tower integration system of coal-fired power plant

ABSTRACT The method of Computational Fluid Dynamics (CFD) simulation has been extensively employed in the stack and tower integration technology (STIT) research; however, a significant number of studies overlooked the impact of thermal buoyancy on the external flow field of cooling tower. In light of this, an improved approach is proposed in this study. A model of a cooling tower and its surrounding flow field was established, and its reliability was confirmed too. Based on our model, the performance of three enhancement strategies under various crosswind speeds and ambient temperatures was simulated. The results indicate that all three enhancement strategies can effectively simulate the effects of thermal buoyancy. In the simulations, the elevation of the flue gases increased from 306 m to either 426 m or 476 m. In the present study, ambient conditions characterized by crosswind speeds below 4 m/s and temperatures below 297.15 K were deemed suitable for the dispersion of stack and tower integration (STI) flue gases. A power function distribution was identified between crosswind speed and the mean height of the plume, while a linear relationship was observed between ambient temperature and the mean height of the plume.

Responsivity Surge in MAPbI3:PC61BM/Au/ZnO Sandwich‐Structured Photodetector

AbstractThe low gain in the presence of a single transverse external electric field limits the application of metal‐semiconductor‐metal (MSM) photodetectors. Here, a longitudinal built‐in electric field by spin‐coating CH3NH3PbI3:PC61BM on the electrode region of an Au/ZnO MSM photodetector, which constitutes a vertically crossed composite electric field with a transverse external electric field, is constructed. In this case, the transverse electric field collects the electrons, and the longitudinal electric field separates them. Based on this novel electric field structure, carrier multiplication at lower voltage conditions is achieved. Compared to the low voltage, there is a significant amplification effect when the voltage reaches 7 V. The responsivity is increased ≈270 times for UV–vis wavelengths, escalating from ≈0.02 to ≈5.4 A W−1. This study provides a novel carrier transport control scheme for high‐gain perovskite‐based photodetectors.

Strongly correlated multielectron bunches from interaction with quantum light.

Strongly correlated electron systems are a cornerstone of modern physics, being responsible for groundbreaking phenomena from superconducting magnets to quantum computing. In most cases, correlations in electrons arise exclusively because of Coulomb interactions. In this work, we reveal that free electrons interacting simultaneously with a light field can become highly correlated via mechanisms beyond Coulomb interactions. In the case of two electrons, the resulting Pearson correlation coefficient for the joint probability distribution of the output electron energies is enhanced by more than 13 orders of magnitude compared to that of electrons interacting with the light field in succession (one after another). These highly correlated electrons are the result of momentum and energy exchange between the participating electrons via the external quantum light field. Our findings pave the way to the creation and control of highly correlated free electrons for applications including quantum information and ultrafast imaging.

Electrical engineering of topological magnetism in two-dimensional heterobilayers

The emergence of topological magnetism in two-dimensional (2D) van der Waals (vdW) magnetic materials and their heterostructures is an essential ingredient for next-generation information technology devices. Here, we demonstrate the all-electric switching of the topological nature of individual magnetic objects emerging in 2D vdW heterobilayers. We show from the first principles that an external electric field modifies the vdW gap between CrTe2 and (Rh, Ti)Te2 layers and alters the underlying magnetic interactions. This enables switching between ferromagnetic skyrmions and meron pairs in the CrTe2/RhTe2 heterobilayer while it enhances the stability of frustrated antiferromagnetic merons in the CrTe2/TiTe2 heterobilayer. We envision that the electrical engineering of distinct topological magnetic solitons in a single device could pave the way for novel energy-efficient mechanisms to store and transmit information with applications in spintronics.

Photovoltaic spatial gap solitons in biased photorefractive optical lattices

We investigate the existence and characteristics of spatially confined optical gap solitons within an optical lattice embedded in a biased bulk photovoltaic photorefractive crystal. The Floquet-Bloch theory is used to analyze the uniform lattice and derive the optical lattice band structure. In the photonic band gaps, which are typically opaque to light transmission, the photorefractive nonlinearity permits the formation of solitons. The paraxial Helmholtz equation is set up and solved thereby discovering single hump and double hump soliton states in both band gaps. Interestingly, we have not found any multi peak solitons to exist in this particular case. We examine the characteristics of these gap solitons, finding that the soliton width (an indicator of nonlinearity) and intensity depend on their location within the band gap. We find that the magnitude of the external electric field profoundly affects the gap soliton characteristics. Additionally, the Vakhitov-Kolokolov (VK) criterion, perturbation analysis and numerical techniques are used to analyze the stability of the various types of the spatial gap solitons in both the band gaps.

Nonvolatile optical phase shift in ferroelectric hafnium zirconium oxide

A nonvolatile optical phase shifter is a critical component for enabling the fabrication of programmable photonic integrated circuits on a Si photonics platform, facilitating communication, computing, and sensing. Although ferroelectric materials such as BaTiO3 offer nonvolatile optical phase shift capabilities, their compatibility with complementary metal-oxide-semiconductor fabs is limited. Hf0.5Zr0.5O2 is an emerging ferroelectric material, which exhibits complementary metal-oxide-semiconductor compatibility. Although extensively studied for ferroelectric transistors and memories, its application to photonics remains relatively unexplored. Here, we show the optical phase shift induced by ferroelectric Hf0.5Zr0.5O2. We observed a negative change in refractive index at a 1.55 μm wavelength in a pristine device regardless of the direction of the applied electric field. The nonvolatile phase shift was only observed once in a pristine device. This non-reversible phase shift can be attributed to the spontaneous polarization within the Hf0.5Zr0.5O2 film along the external electric field.