To investigate the finite-volume effects on the chiral symmetry restoration and the deconfinement transition for a quantum chromodynamics (QCD) system with [Formula: see text] (two quark flavors), we apply the Polyakov-loop extended Nambu–Jona-Lasinio model by introducing a chiral chemical potential [Formula: see text] artificially. The final numerical results indicate that the introduced chiral chemical potential does not change the critical exponents, but shifts the location of critical end point (CEP) significantly; the ratios for the chiral chemical potentials and temperatures at CEP, [Formula: see text] and [Formula: see text], are significantly affected by the system size [Formula: see text]. The behavior is that [Formula: see text] increases slowly with [Formula: see text] when [Formula: see text] is “large” and [Formula: see text] decreases first and then increases with [Formula: see text] when [Formula: see text] is “small.” It is also found that for a fixed [Formula: see text], there is a [Formula: see text], where the critical end point vanishes and the whole phase diagram becomes a crossover when [Formula: see text]. Therefore, we suggest that for the heavy-ion collision experiments, which is to study the possible location of CEP, the finite-volume behavior should be taken into account.