Fluid Expulsion Research Articles

Influence of Overpressured Fluid Expulsion on Hydrocarbon Accumulation in Deep‐Buried Miocene Reservoirs of the Yinggehai Basin, Northwestern South China Sea

ABSTRACTThe overpressure record of the Cenozoic rifting basins in China was recently renewed in the Miocene reservoirs of the Yinggehai Basin, which became an ideal natural laboratory for revealing the hydrocarbon accumulation mechanism under the ultrahigh overpressure setting. Using 3D seismic data, two new fluid expulsion structures were identified in the Yinggehai Basin: layer‐bound faults and pipes. Layer‐bound faults were primarily generated at ~10.5 Ma and subsequently served as vertical channels for hydrocarbon migration. Pipes can be divided into three episodes, generated at ~5.5, ~2.4 and < 1.9 Ma, caused by hydraulic fracturing during focused flow in highly overpressured reservoirs. Pipes generated simultaneously with hydrocarbon charging indicate that the aqueous pressure before hydrocarbon charging did not reach the threshold of hydraulic fracturing and could result in dynamic hydrocarbon accumulation. In contrast, pipes generated before and after hydrocarbon charging increased the unfilling and draining risks of the traps, respectively.

First geological survey and characterisation of a giant depression in carbonate strata at the Rio Grande Rise (southwestern Atlantic)

Pockmarks are submarine depressions often considered the result of fluid (gas and oil) expulsion from the seafloor. Recent geophysical surveys at the Rio Grande Rise (RGR - SW Atlantic) revealed extensive presence of seafloor depressions, generically interpreted as pockmarks. To date, direct observations or sampling from these depressions are lacking. Moreover, hydrocarbons have never been detected at the site, questioning the possibility of pockmarks formation by fluid expulsion. Here we present the first visual inspection and rock characterisation of a giant circular depression located inside the RGR central graben. The depression was discovered during multibeam prospection and surveyed with a Remotely Operated Vehicle, with rock sampling along a vertical transect. The depression is conical (350 m wide and 80 m deep) with walls of stratified, sub-horizontal, white fossiliferous wackestone, with incipient gravitational collapse. Lithological, mineralogical, and geochemical characterisation of the wackestone rule out methane in the formation of the depression. Based on geochemical data and on the finding of anhydrite III (forming at 110–300 °C), we propose a novel perspective on the formation of this kind of depressions, invoking hypogenic karstification and collapse, due to hydrothermal fluids along deep faults. Our geochemical approach complements previous geophysical observations of circular depressions at the RGR and contribute to the general understanding of the formation mechanisms of these intriguing seafloor features.

Extensive glacitectonism and rapid deglacial fluid expulsion in the northeastern Barents Sea

High-latitude regions store large amounts of carbon trapped by ice sheets, permafrost and gas hydrates, yet joint evolution of these climate components is poorly understood. Covered by a cold-based ice-sheet during the last glaciation, the seafloor of the northeastern Barents Sea reveals one of the largest known glacitectonic provinces in the Arctic. Up to 200-m high glacitectonic landforms are cratered and overlie faults associated with ‘bright spots’ indicative of subsurface gas accumulations. However, sediment samples show low pore gas concentrations and no present-day gas seepage. We combine new observations and ice-sheet - hydrate modelling to propose that during the Late Weichselian, glacitectonism was caused by patchy substrate stiffening due to gradual growth of subglacial gas hydrates and permafrost. Ice decay led to rapid destabilisation and full drainage of shallow hydrate reservoirs and permafrost thaw, causing craterisation which was likely accompanied by large fluxes of carbon released into the water column. This study shows that these processes were more widespread across glaciated margins, also highlighting sensitivity and potential for abrupt changes of high-latitude carbon pools in response to complex interactions between the cryosphere, ocean, and solid earth.

Video camera and seismic monitoring of water bulge explosion at Strokkur Geyser, Iceland

Eruptions of volcanoes and geysers share many fundamental similarities: for example, they are manifestations of Earth’s geothermal energy, involving the pressure-driven expulsion of fluids from the Earth’s interior. However, while volcanoes can produce spectacular lava bubbles that burst, water bubbles are rarely observed on the surface of geysers. It is still unclear why some of these low-viscosity geyser systems produce none, while others produce them regularly. There is no quantification of the size, speed, and height of these bubbles at geysers, which is the gap we fill here. Strokkur creates a water bulge in its surface pool (bulge stage). When the bulge bursts, water is ejected into the air (jet stage). The steam then continues to rise buoyantly and drift away (drift stage). Here we study the evolution of the three stages using records from video camera campaigns and a local seismic network. We find that larger bulges are associated with larger ascent velocities and cause larger jet heights. As energy is channeled into a high jet, small seismic ground motions are recorded. The bulge formation itself is barely visible seismically. Our work suggests that the 0.74±0.27 s-long bulge stage can be used as a first-order proxy for predicting eruption height. This study might also be relevant for understanding fluid dynamics in volcanic systems.

Not so fast: Million-years of metal precipitation in Mississippi Valley type deposits inferred from in-situ petrochronology of hydrothermal carbonates

Mississippi Valley-type (MVT) deposits contain about 20% of global zinc resources and host critical raw materials crucial to the development of green technologies. Despite their economic and strategic importance, there is a lack of consensus on the duration of mineralizing fluid flow events in MVT systems. This study couples in-situ U-Pb dating with Sr-isotope and trace element analysis of syn- and post-ore gangue carbonates to establish: (1) timing and duration, (2) redox evolution, and (3) flow rates of mineralizing fluids in the world-class San Vicente Zn-(Pb) deposit (Peru). New radiometric ages bracket the crystallization of syn-mineralization dolomite, characterized by high Fe and Mn contents and Sr isotopic values overlapping with that of host carbonates, between 103.2 ± 4.1 Ma and 70.6 ± 5.6 Ma. This age interval reveals a direct genetic relationship between flow of mineralizing fluids and late Cretaceous Andean compressional tectonics. Basinal fluid expulsion coeval with known tectonic events continues in the district until Pliocene times, driving episodic crystallization of post-ore hydrothermal carbonates between 61.6 ± 9.3 and 2.7 ± 0.2 Ma. The low Mn and Fe content and high 87Sr/86Sr values characteristic of these post-ore, bedding-parallel and cross-cutting carbonate veins indicate a colder, oxidized environment. Our findings highlight the contribution of paired carbonate geochemistry and U-Pb geochronology in drawing links between tectonic events, fluid expulsion and the waxing and waning of mineralization potential in foreland basins. The results of this study challenge our understanding of timescales in MVT systems and imply that anomalous metal enrichment in basinal fluids over a short temporal interval is not a necessary precondition to form economic-sized, sediment-hosted Zn-Pb deposits. Rather, it is the coexistence of a focused fluid flow in an interconnected aquifer with suitable metal depositional mechanisms over a prolonged period of time (106–107 yr) that allows precipitation of economic amount of base metals at a specific site in the upper crust.

Mechanism of metamorphic fluid expulsion from ductile contact aureole: Insights from numerical modeling of a growing mid-crustal magma chamber

Metamorphic fluid flow around an igneous intrusion is governed by temperature, rheology, permeability and fluid pressure condition in the contact aureole. In the middle crust, where lithostatic fluid pressure and ductile deformation dominate, the impulse from incremental magma chamber growth facilitates ductile aureole compaction and induces syn-intrusive metamorphic devolatilization. However, the mechanism of metamorphic fluid expulsion from ductile contact aureole is vaguely understood. In this study, we numerically modeled the two-phase solid-fluid flow process in the ductile aureole above the growing chamber to examine the potential for fluid expulsion, the pattern of fluid flow and fluid pressure condition. The numerical model is constructed based on the geological structure of the Papoose Flat pluton in California, applying three different modes of pluton growth: continuous growth, episodic growth with an interval of 100 years and episodic growth with an interval of 1000 years. The results indicate that the metamorphic fluids propagate in the form of porosity wave in the ductile aureole with solid matrix compaction. Continuous pluton growth, with a slow pressurization of aureole, leads to a positive fluid pressure anomaly in most of the aureole, whereas the episodic growth results in a negative fluid pressure anomaly at the base and positive fluid pressure anomaly at the top of the aureole. Hydrofracturing can occur in the inner aureole, and the outer aureole may retain some fluid with low-frequency, high-flux magma injections. The solid-fluid flow models indicate that porosity wave is an important mechanism for metamorphic fluid expulsion from the pluton and wall rock system.

Soft‐sediment deformation structures and Neptunian dykes across a carbonate system: Evidence for an earthquake‐related origin (Norian, Dolomia Principale, Southern Alps, Italy)

AbstractIdentification of the processes producing soft‐sediment deformation structures, common in siliciclastic deposits and less abundant in carbonate successions, is complex, because different processes may produce similar structures. Thus, interpreting the origin of these structures may be challenging: it requires both a detailed sedimentological study, and the knowledge of the depositional environment and stratigraphic evolution, in order to provide hints to identify the processes affecting sediments after deposition. Among the potential causes of the formation of soft‐sediment deformation structures, seismic shock is one of the possibilities, but their origin could be also related to other triggering mechanisms, such as volcanic activity, sediment loading, salt tectonics, fluid expulsion, meteorite impacts and mass movements. Although it is a plausible option, the interpretation of these structures as ‘seismites' is not obvious: it must be supported by different lines of evidence, considering that the correct interpretation of soft‐sediment deformation structures as a consequence of seismic shocks acquires important implications in palaeoseismology studies. The occurrence of diverse soft‐sediment deformation structures in a fault‐controlled basin (i.e. in a geological setting characterized by syndepositional tectonics) preserved in different subenvironments of a Norian carbonate system in the Southern Alps of Italy provides the chance to characterize different types of soft‐sediment deformation structures along a platform‐to‐basin depositional profile. Presence of pseudonodules in basinal resedimented limestone, sedimentary dykes and clinostratified breccias with unlithified clasts in slope settings and liquefaction of inner platform facies at the platform top testify to an origin compatible with multiple seismic shocks, repetitively affecting the same stratigraphic intervals. The diverse types of soft‐sediment deformation structures in the studied carbonate system provide a rich catalogue of structures related to seismic shocks, representing a possible reference for other similar settings.

Unravelling Cenozoic carbonate platform fluid expulsion: Deciphering pockmark morphologies and genesis in the Tanintharyi shelf of the Andaman Sea as promising hydrocarbon reservoirs

Pockmarks, intriguing seafloor geological and geomorphological features, are commonly observed in marginal basins with hydrocarbon potential. As a Cenozoic marginal sea, the Andaman Sea is known for its significant petroleum reserves, and exploring its back-arc continental margin has revealed favourable conditions for petroleum occurrences. This study focuses on the Tanintharyi passive continental margin in the Andaman Sea, employing extensive stratigraphic and morphological analyses based on 2D and 3D seismic data interpretation techniques. Specifically, sub-seafloor characteristics of the Tanintharyi shelf region were investigated, focusing on comprehensively understanding pockmark morphologies, including their generation, evolution, migration, preservation, and the complete process leading to seabed leakage. This study revealed the potential of the Oligocene/Early Miocene carbonate platform in the Tanintharyi shelf region as a significant hydrocarbon reservoir for the upwelling buoyant fluids from the deep East Andaman Basin. Besides reservoir function, this carbonate platform serves as a passageway for the migration of fluids from the deep-sea area to the shallow-sea area, thereby playing a pivotal role in supporting fluid expulsion mechanisms in shaping a pockmark train adjacent to truncated sedimentary formations surrounding a geomorphological high on the contemporary seafloor. Additionally, the study examines the influence of changes in sedimentary facies and the tectonic setting of the Andaman Sea on pockmark evolutions, with a specific emphasis on the role of the uppermost shallow marine shale beds in developing sub-seafloor overpressure systems due to their impermeable seal rock properties. The article presents substantial evidence for the initiation of pockmark fields during the Middle Miocene period, followed by their transformation into pockmark trains on the present-day seafloor, attributed to the triggering effect of sub-seafloor overpressure systems due to changes in sedimentary dynamics in the Andaman Sea.

Serotonin neurons in mating female mice are activated by male ejaculation

Sexual stimulation triggers changes in female physiology and behavior, including sexual satiety and preparing the uterus for pregnancy. Serotonin (5-HT) is an important regulator of reproductive physiology and sexual receptivity, but the relationship between sexual stimulation and 5-HT neural activity in females is poorly understood. Here, we investigated dorsal raphe 5-HT neural activity in female mice during sexual behavior. We found that 5-HT neural activity in mating females peaked specifically upon male ejaculation and remained elevated above baseline until disengagement. Artificial intravaginal mechanical stimulation was sufficient to elicit increased 5-HT neural activity but the delivery of ejaculatory fluids was not. Distal penis expansion ("penile cupping") at ejaculation and forceful expulsion of ejaculatory fluid each provided sufficient mechanical stimulation to elicit 5-HT neuron activation. Our study identifies a female ejaculation-specific signal in a major neuromodulatory system and shows that intravaginal mechanosensory stimulation is necessary and sufficient to drive this signal.

Source and Migration of Fluids in a Meso-Tethyan Subduction Zone: Fluid Inclusion Study of Syn-Mélange Veins from the Mugagangri Accretionary Complex

The Mugagangri Group (MG), located at the southern margin of the Qiangtang terrane in Tibet, is a crucial research target for understanding the subduction and accretion history of the Meso-Tethys Ocean. Extensional crack-seal veins restricted within sandstone blocks from the broken formation in the MG (Gaize) formed synchronously in the mélange formation. The primary inclusions trapped in the veins recorded multiple pieces of information during the formation of the accretionary wedge. To precisely constrain the MG subduction–accretion processes, we investigated the trapping temperature, salinity, density, and composition of the fluid inclusions within the crack-seal veins derived from the broken formation in the MG (Gaize). The primary inclusions indicate that the crack was sealed at ~151–178 °C. The salinity of the primary inclusions exhibited a well-defined average of 3.3 ± 0.7 wt% NaCl equivalent, slightly lower than the average of seawater (3.5 wt%). There were no nonpolar gases, and only H2O (low salinity) was detectable in the primary inclusions. These characteristics suggest that the syn-mélange fluids were a type of pore fluid in the shallow subduction zone, with the principal source being pore water from sediments overlying the oceanic crust. Because of mineral dehydration and compaction, the pore fluids became more diluted with H2O and fluid overpressure owing to a pore fluid pressure that was greater than the hydrostatic pressure. Subsequently, the creation of cracks through hydraulic fracturing provided a novel pathway for the flow of fluids which, in turn, contributed to the décollement step-down and underthrusting processes. These fractures acted as conduits for fluid movement and played a crucial role in facilitating these peculiar occurrences of quartz veins. The depth (~5 km) and temperature estimates of the fluid expulsion align with the conditions of the décollement step-down, thereby leading to the trapping of fluids within the sandstone blocks and their subsequent underplating to the accretionary complex. In our preferred model, such syn-mélange fluids have the potential to provide valuable constraints on the subduction–accretion processes occurring in other accretionary complexes.

Episodic, compression-driven fluid venting in layered sedimentary basins

Fluid venting phenomena are prevalent in sedimentary basins globally. Offshore, these localized fluid-expulsion events are archived in the geologic record by the resulting pockmarks at the sea-floor. Venting is widely interpreted to occur via hydraulic fracturing, which requires near-lithostatic pore pressures for initiation. One common driver for these extreme pressures is horizontal tectonic compression, which pressurizes the entire sedimentary column over a wide region. Fluid expulsion leads to a sudden, local relief of this pressure, which then gradually recharges through continued compression, leading to episodic venting. Pressure recharge will also occur through pressure diffusion from neighbouring regions that remain pressurized, but the combined role of compression and pressure diffusion in episodic venting has not previously been considered. Here, we develop a novel poroelastic model for episodic, compression-driven venting. We show that compression and pressure diffusion together set the resulting venting period. We derive a simple analytical expression for this venting period, demonstrating that pressure diffusion can significantly reduce the venting period associated with a given rate of compression. Our expression allows this rate of compression to be inferred from observations of episodic venting. We conclude that pressure diffusion is a major contributor to episodic fluid venting in mudstone-dominated basins.

Discharge timing and origin of fluids at methane seeps in the late Cretaceous subduction zone of Hokkaido, Japan: Coupling U–Pb calcite dating with Sr–Nd isotope analysis

Seepage of methane-rich fluids is common in subduction zones throughout Earth's history. However, the causes and hydrogeological regimes of methane seepage in the geological past are commonly elusive. To provide insights into the hydrogeological regime and structural evolution of the Cretaceous subduction zone of Hokkaido, Japan, this study investigates the timing of discharge and migration pathways of fluids emitted at five ancient methane seeps using U–Pb dating and coupled Sr, Nd, C, and O isotope analyses of the authigenic seep carbonates. The carbonates were collected from forearc-basin sediments of the Yezo Group, which are underlain by a mafic igneous basement (lower Sorachi ophiolite) detached from the subducting plate. The subduction zone is known to have experienced intermittent accretionary and non-accretionary stages, and the U–Pb dates determined for seep carbonates document two fluid discharge events, ∼100 and ∼80 Ma, falling within the accretionary periods. The 87Sr/86Sr ratios (0.70682–0.70781) and εNd values (−5.9 to −0.1) of the carbonates show significant variability, indicating the seeping fluids experienced interactions with the mafic rocks of the lower Sorachi ophiolite and with siliciclastic sediments of the Yezo Group. The δ13C values of the carbonates, as low as −49‰, suggest a primarily microbial origin of the seeping methane, which makes methane migration from the underplating materials at high temperatures (>100 °C) unlikely. These results demonstrate that the episodic expulsion of the methane-rich fluids, originating from within the forearc basin rather than from the underplating materials, occurred during the accretionary stages and played a major role in methane seepage in the Cretaceous subduction system.

Diagenetic Study of Marrón Emperador Ornamental Stone (Upper Cretaceous, SE Spain)

The “Marrón Emperador” ornamental stone is known for its characteristic deep brown colour filled with white spots and veins. It consists of a brecciated dolostone with different generations of calcite/dolomite veins and veinlets that represent repeated episodes of fracture opening and partial or complete cementation, which likely corresponds to individual stages of fluid expulsion. Mineralogical, petrographic and geochemical studies point to the formation of these rocks through brecciation, dolomitization and rapid cementation processes in an active tectonic regimen. The composition and textural features of the stratiform dolomite geobody point to a structurally controlled dolomitization model. The overall breccia geometry, breccia texture and vein characteristics are all consistent with a brecciation origin driven by hydraulic fracturing, with subsequent calcite precipitation in open space and partial solution replacement of clasts. A paragenetic sequence includes: (1) marine sedimentation of original tidal carbonate sediments; (2) early lithification and marine cementation; (3) burial diagenesis with early fracturation of limestones; (4) entrance of dolomitizing fluids through fractures causing pervasive dolomitization (brown dolostones) and dolomite cements (fracture-lining and saddle dolomites); (5) fracturation by hydraulic overpressure under an active tectonic regime; (6) calcite cementation (white veins and veinlets); and (7) uplift and meteoric diagenesis producing dedolomitization, karstification and local brecciation.

Evolution of complex giant seafloor depressions at the northern Argentine continental margin (SW Atlantic Ocean) under the influence of a dynamic bottom current regime

Seafloor depressions (SD) are features commonly observed on the ocean floor. They often occur as circular, small-sized (up to 10 s of m) incisions caused by fluid expulsion. Larger depressions (100s m to km) are considerably less abundant, and their origin and development have been scarcely studied. This study investigated two giant morphological depressions (>5 km) using recently acquired multibeam bathymetry and backscatter, sediment echosounder, and high-resolution seismic data. An arc-shaped (SD-N) and a sub-circular depression (SD-S) are located on the Ewing Terrace at the Argentine Continental Margin north and south of the Mar del Plata Canyon, respectively. The study area is influenced by the Brazil-Malvinas Confluence, where major counterflowing ocean currents affect sedimentation, and northward flowing currents form a large contourite depositional system. Using an existing seismo-stratigraphy, the onset of SD-N was dated to the middle Miocene (∼15–17 Ma), whereas SD-S started developing at the Miocene/Pliocene boundary (∼6 Ma). Acoustic anomalies indicate the presence of gas and diffuse upward fluid migration, and therefore seafloor seepage is proposed as the initial mechanism for SD-S, whereas we consider a structural control for SD-N to be most likely. Initial depressions were reworked and maintained by strong and variable bottom currents, resulting in prograding clinoform reflection patterns (SD-N) or leading to the build-up of extensive cut-and-fill structures (SD-S). Altogether, this study highlights the evolution of two unique and complex seafloor depressions throughout the geologic past under intense and variable bottom current activity in a highly dynamic oceanographic setting.

Tectonic fluid expulsion: U-Pb evidence for punctuated hydrothermal fluid flow and hydraulic fracturing during orogenesis

Tectonic fluid expulsion has been linked to fluid flow in permeable foreland basin sequences, but it is unclear how fluids migrate through underlying low-permeability successions. Here we report U-Pb data which indicate that fluids expelled during tectonic compression migrated through older compacted shales inboard of the deforming craton margin by fracture permeability and enhanced diffusion. From a ∼350 m drill-core interval of Neoarchean shale (drill-hole ABDP9), Hamersley region, Australia, we document abundant bedding-parallel veins indicating pervasive hydraulic fracturing. Thermometry of vein-filling chlorite indicates temperatures between 329-374°C, which is higher than estimates (175-280°C) from metamorphic assemblages in underlying basalts, implying the passage of hydrothermal fluids. New in situ secondary ion mass spectrometry (SIMS) U-Pb geochronology of monazite and xenotime in bedding-parallel veins verifies and expands earlier results, showing that microfracturing and hydrothermal fluid flow spanned ∼650 million years and was restricted to five short intervals: 2.30 Ga, 2.20 Ga, 2.10 Ga, 2.05 Ga and 1.65 Ga. Three of the five age populations coincide with known fabric-forming orogenic events (i.e. 2.30 Ga Sylvania orogeny; 2.22-2.15 Ga Ophthalmia orogeny; 1.68-1.65 Ga Mangaroon orogeny), which are focused along the southern Pilbara Craton margin. Our results show that the timing of veining was not random, but coeval with major orogenic events, linking fluid overpressure and hydraulic fracturing to the expulsion of heated orogenic fluids 100s of km inboard of the craton margin. The crack-seal veins indicate repeated cycles of fluid overpressure resulting in hydrofracturing and fluid drainage, followed by cavity collapse. The tectonic expulsion of pressurized hydrothermal fluids produced fracture and matrix permeability in Earth's upper crust, leading to episodic open-system behaviour with enhanced fluid-rock reactions and the large-scale transfer of heat and mass.

Carbonate Reservoir Quality Variations in Basins with a Variable Sediment Influx: A Case Study from the Balkassar Oil Field, Potwar, Pakistan.

The carbonate reservoir quality is strongly reliant on the compaction process during sediment burial and other processes such as cementation and dissolution. Porosity and pore pressure are the two main factors directly affected by mechanical and chemical compactions. Porosity reduction in these carbonates is critically dependent on the overburden stress and subsidence rate. A variable sediment influx in younger basins may lead to changes in the reservoir quality in response to increasing lithostatic pressure. Deposition of molasse sediments as a result of the Himalayan orogeny caused variations in the sedimentation influx in the Potwar Basin of Pakistan throughout the Neogene times. The basic idea of this study is to analyze the carbonate reservoir quality variations induced by the compaction and variable sediment influx. The Sakesar Limestone of the Eocene age, one of the proven carbonate reservoirs in the Potwar Basin, shows significant changes in the reservoir quality, specifically in terms of porosity and pressure. A 3D seismic cube (10 km2) and three wells of the Balkassar field are used for this analysis. To determine the vertical and lateral changes of porosity in the Balkassar area, porosity is computed from both the log and seismic data. The results of both the data sets indicate 2-4% porosities in the Sakesar Limestone. The porosity reduction rate with respect to the lithostatic pressure computed with the help of geohistory analysis represents a sharp decrease in porosity values during the Miocene times. Pore pressure predictions in the Balkassar OXY 01 well indicate underpressure conditions in the Sakesar Limestone. The Eocene limestones deposited before the collision of the Indian plate had enough time for fluid expulsion and show underpressure conditions with high porosities.

Fibrous calcite veins record stepwise, asymmetric opening and episodic hydrocarbon expulsion from organic-rich shales

Episodic fluid expulsion through fractures is widely expected during hydrocarbon generation, yet direct evidence for this process is lacking in the case of organic-rich shales. We investigated the formation of antitaxial, bed-parallel fibrous calcite veins hosted in organic-rich shales of the Eocene Dongying Depression, Bohai Bay Basin, China. Our results from detailed, in situ geochemical traverses show that while some symmetric veins exhibit broadly synchronous and steady-state opening, other asymmetric veins consist of two geochemically distinct generations of calcite to either side of the median zone, suggesting asymmetric and asynchronous growth in two discrete episodes during hydrocarbon expulsion. Thus, we argue that each asymmetric vein recording two stages of opening implies that hydrocarbons were expelled from shales episodically.

Fibrous calcite veins record stepwise, asymmetric opening and episodic hydrocarbon expulsion from organic-rich shales

AbstractEpisodic fluid expulsion through fractures is widely expected during hydrocarbon generation, yet direct evidence for this process is lacking in the case of organic-rich shales. We investigated the formation of antitaxial, bed-parallel fibrous calcite veins hosted in organic-rich shales of the Eocene Dongying Depression, Bohai Bay Basin, China. Our results from detailed, in situ geochemical traverses show that while some symmetric veins exhibit broadly synchronous and steady-state opening, other asymmetric veins consist of two geochemically distinct generations of calcite to either side of the median zone, suggesting asymmetric and asynchronous growth in two discrete episodes during hydrocarbon expulsion. Thus, we argue that each asymmetric vein recording two stages of opening implies that hydrocarbons were expelled from shales episodically.

ТЕРАПЕВТИЧЕСКАЯ ЭФФЕКТИВНОСТЬ ЭСТРОФАНТИНА ПРИ ПСЕВДОБЕРЕМЕННОСТИ (ГИДРОМЕТРЕ) У КОЗ

The aim of the study was to carry out a comparative evaluation of the therapeutic potency of Estrophantine®, a drug of the highly active synthetic analog of prostaglandin F2 alpha (PgF2α) cloprostenol, when goats with hydrometer were twice injected intramuscularly with a 10-day interval in a dose of 0.5 and 1.0 ml, respectively. The objects of the study were breeding goats of breeding age (n=6) and lactating goats (n=37) of the Zaanen breed diagnosed with false pregnancy during screening ultrasound examination. The animals were divided into two experimental groups according to the analogy principle. The animals in the first experimental group (n=21) were twice injected intramuscularly with a 10-day interval in the dose of 0.5 ml (125 μg cloprostenol), and those in the second group (n=22) were also twice injected intramuscularly with with a 10-day interval, but in the dose of 1.0 ml (250 μg cloprostenol). The results of the study showed high therapeutic potency of Estrophantine® when goats with hydrometer were twice injected intramuscularly with with a 10-day interval in the dose of 1.0 ml. After the first dose of the preparation complete expulsion of intrauterine fluid was noted in 81.82% of goats with hydrometer. The effectiveness of the method for a complete course of treatment was 100% according to the percentage of cured animals, and 86.36% and 77.27% according to the frequency of renewal of sexual cycling and pregnancy rate, respectively. None of the 5 (22.73%) goats found to be infertile registered a re-lapse of hydrometra after treatment. An Estrofantin® dose of 0.5 ml (125 μg cloprostenol) was found to be inadequate for treat-ment of goats with hydrometra. After the first dose, complete expulsion of intrauterine fluid was noted in only 52.38% of animals. When Estrophantine® is used at the lowest therapeutic dose (125 μg cloprostenol) the effectiveness of prostaglandin therapy over a full course of treatment is reduced by 4.76% in the proportion of cured animals, by 10.17% in the renewal of sexual cycling and by 15.37% in pregnancy rate. At the same time, the risk of relapse is 5%.

Spatially heterogenous dynamics in colloidal gels during syneresis.

Syneresis, the compaction of a material accompanied by fluid expulsion, is a typical mechanical instability which exists among colloidal gel based materials and that negatively affects the quality of relevant applications. We shed light onto the internal dynamics of model colloidal gels undergoing syneresis using Laser Speckle Imaging (LSI). The resulting dynamical maps capture the distinct differences in spatial and temporal relaxation patterns between colloidal gels comprising solid and liquid particles. This indicates different mechanisms of syneresis between the two systems and highlights the importance of the constituent particles and their mobile or restrictive interfaces in the mechanical relaxation of the colloidal gels during syneresis.