In this paper we discuss the calibration of the NEVOD-EAS array which is a part of the Experimental Complex NEVOD, as well as the results of studying the response features of its scintillation detectors. We present the results of the detectors energy calibration, performed by comparing their response to different types of particles obtained experimentally and simulated with the Geant4 software package, as well as of the measurements of their timing resolution. We also discuss the results of studies of the light collection non-uniformity of the NEVOD-EAS detectors and of the accuracy of air-shower arrival direction reconstruction, which have been performed using other facilities of the Experimental Complex NEVOD: the muon hodoscope URAGAN and the muon tracking detector DECOR.